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51. 发明授权

US6042133A Index shifter for bicycle transmissions 失效
标题翻译：用于自行车变速箱的换档装置
公开(公告)号：US6042133A
公开(公告)日：2000-03-28
申请号：US926818
申请日：1997-09-10
申请人： Berndt Leiter , Bernhard Johanni , Max Rumpel , Klaus Konig , Klaus Stuhler , Markus Arbeiter
发明人： Berndt Leiter , Bernhard Johanni , Max Rumpel , Klaus Konig , Klaus Stuhler , Markus Arbeiter
IPC分类号： B62M25/04 , B62M1/02
CPC分类号： B62M25/04 , Y10T74/20043 , Y10T74/20287
摘要： An index shifter for a bicycle transmission, which index shifter is mounted on a part of a bicycle and has a casing, a locking element with notches which is connected to a rotary hand grip, and a winding drum for actuating a cable pull. The casing has a ring-shaped recess disposed therein, in which recess a detent spring is arranged. The detent spring is braced by two feet against the casing and has a lug which engages with the locking ring. Inside the casing is a casing projection with which one foot of the detent spring can be fixed to achieve a small amount of shift play. This permits small amounts of shift play, in particular for shifting hub gears on bicycles.
摘要翻译：一种用于自行车传动装置的换档装置，该换档装置安装在自行车的一部分上并具有壳体，具有与旋转手柄相连的凹口的锁定元件以及用于致动拉绳的卷绕鼓。壳体具有设置在其中的环形凹部，其中布置有制动弹簧。制动弹簧用两脚支撑在壳体上，并具有与锁定环接合的凸耳。壳体内部是一个套管突起，其中一个脚爪可以被固定，以实现少量的换档。这允许少量换挡，特别是用于在自行车上换档轮毂。

52. 发明授权

US5972844A Sulphonyl amino (thio) carbonyl-1,2,4-triazolin (thi) one derivatives and the use thereof as herbicides 失效
标题翻译：磺酰基氨基（硫代）羰基-1,2,4-三唑啉（thi）一种衍生物及其作为除草剂的用途
公开(公告)号：US5972844A
公开(公告)日：1999-10-26
申请号：US875221
申请日：1997-07-18
申请人： Klaus-Helmut Muller , Joachim Kluth , Ernst Rudolf F Gesing , Klaus Konig , Markus Dollinger , Hans-Joachim Santel
发明人： Klaus-Helmut Muller , Joachim Kluth , Ernst Rudolf F Gesing , Klaus Konig , Markus Dollinger , Hans-Joachim Santel
IPC分类号： A01N47/38 , C07D249/12 , C07D249/14 , C07D401/12 , C07D403/12 , C07D409/12 , C07D417/12 , C07D487/04 , A01N43/653
CPC分类号： C07D409/12 , A01N47/38 , C07D249/12 , C07D249/14 , C07D487/04
摘要： The invention relates to sulphonylamino(thio)carbonyl-triazolin(ethi)ones of the general formula (I) ##STR1## in which Q.sup.1 represents oxygen or sulphur,Q.sup.2 represents oxygen or sulphur,R.sup.1 represents hydrogen, hydroxyl, amino, alkylideneamino or a respectively optionally substituted radical from the group consisting of alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkylamino, dialkylamino, alkanoylamino, cycloalkyl, cycloalkylamino, cycloalkylalkyl, aryl and arylalkyl,R.sup.2 represents hydrogen, hydroxyl, mercapto, amino, halogen or a respectively optionally substituted radical from the group consisting of alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkinyloxy, alkylthio, alkenylthio, alkinylthio, alkylamino, alkenylamino, alkinylamino, dialkylamino, alkanoylamino, aziridino, pyrrolidino, piperidino, morpholino, cycloalkyl, cycloalkenyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylalkylthio, cycloalkylalkylamino, aryl, arylalkyl, aryloxy, arylalkoxy, arylthio, arylalkylthio, arylamino and arylalkylamino, orR.sup.1 and R.sup.2 together represent optionally branched alkanediyl, andR.sup.3 represents respectively optionally substituted aryl, arylalkyl or heteroaryl,with the proviso that either Q.sup.1 or Q.sup.2 represents sulphur or both represent sulphur, and to salts of the compounds of the formula (I), furthermore to a plurality of processes for preparing the novel compounds of the formula (I) and the salts thereof and to the use of these compounds as herbicides.
摘要翻译： PCT No.PCT / EP96 / 00141 Sec。 371日期1997年7月18日 102（e）日期1997年7月18日PCT 1996年1月15日PCT PCT。公开号WO96 / 22982 日期：1996年8月1日本发明涉及通式（I）中的磺酰基氨基（硫代）羰基 - 三唑啉（ethi），其中Q1表示氧或硫，Q2表示氧或硫，R1表示氢，羟基，氨基，亚烷基氨基或由烷基，烯基，炔基，烷氧基，烯氧基，烷基氨基，二烷基氨基，烷酰基氨基，环烷基，环烷基氨基，环烷基烷基，芳基和芳基烷基组成的组中的任意取代的基团，R 2表示氢，羟基，巯基，氨基，卤素或分别为烷基，链烯基，炔基氧基，烷硫基，烯硫基，炔基硫基，烷基氨基，烯基氨基，炔基氨基，二烷基氨基，链烷酰氨基，氮丙啶基，吡咯烷子基，哌啶子基，吗啉代，环烷基，环烯基，环烷氧基环烷硫基，环烷基氨基，环烷基烷基，环烷基烷氧基，环烷基烷硫基，环烷基烷基氨基，芳基，芳烷基，芳基芳基烷氧基，芳硫基，芳基烷硫基，芳基氨基和芳基烷基氨基，或者R1和R2一起代表任意支链的烷二基，R3代表分别是任选取代的芳基，芳基烷基或杂芳基，条件是Q1或Q2代表硫或两者都表示硫，式（I）化合物的盐，以及制备式（I）的新型化合物及其盐的多种方法以及这些化合物作为除草剂的用途。

53. 发明授权

US5892054A Process for the preparation of alkoxytriazolinones 失效
标题翻译：制备烷氧基三唑啉酮的方法
公开(公告)号：US5892054A
公开(公告)日：1999-04-06
申请号：US934501
申请日：1997-09-19
申请人： Heinz-Jurgen Wroblowsky , Klaus Konig
发明人： Heinz-Jurgen Wroblowsky , Klaus Konig
IPC分类号： C07C281/04 , C07C281/16 , C07D249/12
CPC分类号： C07D249/12 , C07C281/04
摘要： Alkoxytriazolinones of the formula (I), ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent in each case optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl,(which can be used as intermediates for the preparation of herbicidal active compounds) are obtained in good yields and in high purity by reacting iminocarbonic diesters (II) with carbazinic esters (III) ##STR2## in which R.sup.2 and R.sup.3 in each case represent, for example, alkyl or aryl,at -20.degree. C. to +120.degree. C. (1st step) and subjecting the semicarbazide derivatives (IV) formed in this process with elimination of R.sup.2 -OH ##STR3## to a cyclizing condensation reaction in the presence of a base at 20.degree. C. to 150.degree. C. with elimination of R.sup.3 --OH, if appropriate (2nd step) and, finally, by reacting the resulting 5-alkoxytriazolinones of the formula (V) �=formula (I) where R.sup.1 =H! with an alkylating agent of the formula R.sup.1 --X (VI) �X, for example,=halogen or --OSO.sub.2 OR.sup.1 ! at 0.degree. C. to 150.degree. C., if appropriate in the presence of a base (3rd step: highly selective 4-alkylation).
摘要翻译：式（I）的烷氧基三唑啉酮，其中R 1和R 2彼此独立地表示，各自为任选取代的烷基，烯基，炔基，环烷基，环烷基烷基，芳基或芳基烷基（可用作中间体用于制备除草活性化合物）以良好的产率和高纯度通过使亚氨基碳酸二酯（II）与咔嗪酸酯（III）反应获得，其中R2和R3各自表示例如，烷基或芳基，在-20℃至+ 120℃（第一步），并将在该过程中形成的氨基脲衍生物（Ⅳ）与R 2 -OH反应生成环状在20℃至150℃存在下，在适当的情况下消除R3-OH（第二步），最后通过使得到的式（V）的5-烷氧基三唑啉酮[= 式（I）其中R1 = H]与式R1-X（VI）的烷基化剂[X，例如=卤素或 -OSO2OR1]在0℃至150℃，如果合适的话，在碱的存在下（第3步：高选择性4-烷基化）。

54. 发明授权

US5834579A Tertiary amines having carbonate and urethane groups 失效
公开(公告)号：US5834579A
公开(公告)日：1998-11-10
申请号：US876724
申请日：1997-06-16
申请人： Klaus Konig , Ulrich Liman , Josef Sanders
发明人： Klaus Konig , Ulrich Liman , Josef Sanders
IPC分类号： C08G18/18 , C08G18/44 , C08G18/46 , C08G18/20
CPC分类号： C08G18/1841 , C08G18/1825 , C08G18/44 , C08G18/4615 , C08G2101/00 , Y10T428/31551
摘要： Tertiary amines having carbonate and urethane groups and optionally hydroxyl groups are produced by reacting a) a polyhydric alcohol and b) a primary-tertiary diamine with c) a carbonic acid derivative selected from the group consisting of optionally cyclic carbonates, urea, phosgene and bis-chlorocarbonates of alcohols of the same type as those used as component a). This reaction may be carried out in one or two steps. The tertiary amines produced by this process are useful as catalysts, which may optionally be incorporated into an isocyanate-reactive material, in the isocyanate addition reaction for the production of polyurethane plastics. These tertiary amines are particularly useful for the production of foam backed plastic films.

55. 发明授权

US5705672A Tertiary amines having carbonate and urethane groups 失效
标题翻译：具有碳酸酯和氨基甲酸酯基团的叔胺
公开(公告)号：US5705672A
公开(公告)日：1998-01-06
申请号：US510830
申请日：1995-08-03
申请人： Klaus Konig , Ulrich Liman , Josef Sanders
发明人： Klaus Konig , Ulrich Liman , Josef Sanders
IPC分类号： C07C271/20 , C08G18/18 , C08G71/02 , C07C271/00
CPC分类号： C08G18/1841 , C07C271/20 , C08G2101/00
摘要： Tertiary amines having carbonate and urethane groups and optionally hydroxyl groups are produced by reacting a) a polyhydric alcohol and b) a primary-tertiary diamine with c) a carbonic acid derivative selected from the group consisting of optionally cyclic carbonates, urea, phosgene and bis-chlorocarbonates of alcohols of the same type as those used as component a). This reaction may be carried out in one or two steps. The tertiary amines produced by this process are useful as catalysts, which may optionally be incorporated into an isocyanate-reactive material, in the isocyanate addition reaction for the production of polyurethane plastics. These tertiary amines are particularly useful for the production of foam backed plastic films.
摘要翻译：具有碳酸酯和氨基甲酸酯基团和任选的羟基的叔胺通过使a）多元醇和b）伯 - 叔二胺与c）选自任选环状碳酸酯，脲，光气和双与用作组分a）相同类型的醇的氯代碳酸酯。该反应可以在一个或两个步骤中进行。通过该方法生产的叔胺可用作用于生产聚氨酯塑料的异氰酸酯加成反应中的催化剂，其可任选地并入异氰酸酯反应性材料中。这些叔胺特别可用于生产泡沫塑料膜。

56. 发明授权

US5652372A Substituted 5-alkoxy-1,2,4-triazol-3-(THI) ones 失效
标题翻译：取代的5-烷氧基-1,2,4-三唑-3-（THI）
公开(公告)号：US5652372A
公开(公告)日：1997-07-29
申请号：US637995
申请日：1996-04-25
申请人： Klaus-Helmut Muller , Klaus Konig , Joachim Kluth , Klaus Lurssen , Hans-Joachim Santel , Robert R. Schmidt
发明人： Klaus-Helmut Muller , Klaus Konig , Joachim Kluth , Klaus Lurssen , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N47/38 , A01N51/00 , C07D249/12 , C07D249/14 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D471/04 , C07D487/04
CPC分类号： C07D401/12 , A01N47/38 , A01N51/00 , C07D249/12 , C07D249/14 , C07D403/12 , C07D405/12 , C07D409/12 , C07D471/04 , C07D487/04
摘要： Herbicidal 5-alkoxy-1,2,4-triazol-3-(thi)ones of the gerneral formula ##STR1## (in which the radicals R.sup.1, R.sup.2, R.sup.3, X and Y have the meanings given in the description),processes for their preparation, and their use as herbicides, and also new intermediates of the formula (II) ##STR2##
摘要翻译：除草剂5-烷氧基-1,2,4-三唑-3-（thi）取代的式（I）（其中基团R 1，R 2，R 3，X和Y具有在说明书中给出的含义）），它们的制备方法和它们作为除草剂的用途，以及式（II）的新的中间体<图像（II）

57. 发明授权

US5516749A Herbicidal and fungicidal substituted triazolinones 失效
标题翻译：除草和杀真菌剂取代的三唑啉酮
公开(公告)号：US5516749A
公开(公告)日：1996-05-14
申请号：US180721
申请日：1994-01-13
申请人： Klaus-Helmut Muller , Klaus Konig , Kurt Findeisen , Hans-Joachim Santel , Klaus Lurssen , Robert R. Schmidt , Stefan Dutzmann
发明人： Klaus-Helmut Muller , Klaus Konig , Kurt Findeisen , Hans-Joachim Santel , Klaus Lurssen , Robert R. Schmidt , Stefan Dutzmann
IPC分类号： A01N47/38 , C07D249/12 , C07D249/14 , C07D405/04 , C07D405/06 , C07D405/12 , A01N43/653
CPC分类号： C07D405/04 , A01N47/38 , C07D249/12 , C07D405/06 , C07D405/12
摘要： Herbicidal and fungicidal substituted triazolinones of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, alkoxyalkyl, cycloalkyl or cycloalkylalkyl, of represents tetrahydrofuranyl or tetrahydrofuranylalkyl, or represents in each case optionally substituted aralkyl or aryl,R.sup.2 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, cyanoalkyl, hydroxyalkyl, alkoxyalkyl, aryloxyalkyl, alkoxycarbonylalkyl, alkoxycarbonylalkenyl, alkylaminoalkyl or dialkylaminoalkyl, or represents in each case optionally substituted cyclocalkyl, cycloalkylalkyl, cycloalkenyl or cycloalkenylalkyl, or represents optionally substituted heterocyclyalkyl, or represents in each case optionally substituted aralkyl, aroyl, aryl, aralkyloxy or aryloxy, or represents alkoxy, alkenyloxy or alkinyloxy,R.sup.3 represents alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, cyanoalkyl, alkoxyalkyl or alkylthioalkyl, or represents in each case optionally substituted cycloalkyl, cycloalkylalkyl, aryl or aralkyl,X represents oxygen or sulphur andY represents oxygen or sulphur,and new intermediates.
摘要翻译：其中R1代表氢，烷基烯基，炔基，卤代烷基，卤代烯基，卤代烯基，烷氧基烷基，环烷基或环烷基烷基的式（Ⅰ）的除草和杀真菌的取代的三唑啉酮代表四氢呋喃基或四氢呋喃基烷基，或代表在各种情况下任选取代芳烷基或芳基，R 2表示氢，烷基，烯基，炔基，卤代烷基，卤代烯基，卤代烯基，氰基烷基，羟基烷基，烷氧基烷基，芳氧基烷基，烷氧基羰基烷基，烷氧基羰基烯基，烷基氨基烷基或二烷基氨基烷基，或在各种情况下表示任选取代的环烷基，环烷基烷基，环烯基或环烯基或代表任选取代的杂环烷基，或在每种情况下表示任选取代的芳烷基，芳酰基，芳基，芳烷氧基或芳氧基，或表示烷氧基，烯氧基或烷氧基，R3表示烷基，烯基，炔基，卤代烷基，卤代烯基，卤代烯基，氰基烷基，烷氧基烷基或烷硫基烷基，或在每种情况下表示任选取代的环烷基，环烷基烷基，芳基或芳烷基，X表示氧或硫，Y表示氧或硫，以及新的中间体。

58. 发明授权

US5488028A Herbicidal sulphonylaminocarbonyltriazolinones having two substituents bonded via oxygen 失效
公开(公告)号：US5488028A
公开(公告)日：1996-01-30
申请号：US174495
申请日：1993-12-28
申请人： Wilhelm Haas , Klaus-Helmut Muller , Klaus Konig , Hans-Joachim Santel , Klaus Lurssen , Robert R. Schmidt
发明人： Wilhelm Haas , Klaus-Helmut Muller , Klaus Konig , Hans-Joachim Santel , Klaus Lurssen , Robert R. Schmidt
IPC分类号： A01N47/38 , A01N51/00 , C07D249/12 , C07D249/14 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D471/04 , C07D487/04 , A01N43/80 , A01N43/78 , C07D417/12
CPC分类号： C07D401/12 , A01N47/38 , A01N51/00 , C07D249/12 , C07D249/14 , C07D403/12 , C07D405/12 , C07D409/12 , C07D471/04 , C07D487/04
摘要： Herbicidal sulphonylaminocarbonyltriazolinones having two substituents bonded via oxygen, of the formula ##STR1## in which R.sup.1 represents hydrogen or an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl and aralkyl,R.sup.2 represents an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl and aralkyl, andR.sup.3 represents an optionally substituted radical from the series comprising alkyl, aralkyl, aryl and heteroaryl,and their salts.

59. 发明授权

US5326877A Herbicidal substituted triazolinones 失效
标题翻译：除草取代的三唑啉酮
公开(公告)号：US5326877A
公开(公告)日：1994-07-05
申请号：US962442
申请日：1992-10-16
申请人： Markus Lindig , Kurt Findeisen , Klaus-Helmut Muller , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang , Dieter Feucht , Klaus Konig , Klaus Lurssen
发明人： Markus Lindig , Kurt Findeisen , Klaus-Helmut Muller , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang , Dieter Feucht , Klaus Konig , Klaus Lurssen
IPC分类号： A01N47/38 , C07D249/12 , C07D249/14 , C07D405/12
CPC分类号： C07D405/12 , A01N47/38 , C07D249/12
摘要： Herbicidally active substituted triazolinones of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, alkoxyalkyl, cycloalkyl, cycloalkylalkyl, or represents tetrahydrofuranyl, tetrahydrofuranylalkyl, or represents in each case optionally substituted aralkyl or aryl,R.sup.2 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, cyanoalkyl, hydroxyalkyl, alkoxyalkyl, alkoxycarbonylalkyl, alkoxycarbonylalkenyl, alkylaminoalkyl, dialkylaminoalkyl, or represents in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl or cycloalkenylalkyl, or represents optionally substituted heterocyclylalkyl, or represents in each case optionally substituted aralkyl, aroyl, aryl, aralkyloxy or aryloxy, or represents alkoxy, alkenyloxy or alkinyloxy,X represents oxygen or sulphur andY represents oxygen or sulphur.New intermediates therefor are also shown.
摘要翻译：式（I）的除草活性取代的三唑啉酮，其中R 1表示氢，烷基，烯基，炔基，卤代烷基，卤代烯基，卤代烯基，烷氧基烷基，环烷基，环烷基烷基，或代表四氢呋喃基，四氢呋喃基烷基，或表示在各种情况下任选取代芳烷基或芳基，R 2表示氢，烷基，烯基，炔基，卤代烷基，卤代烯基，卤代烷基，氰基烷基，羟基烷基，烷氧基烷基，烷氧基羰基烷基，烷氧基羰基烯基，烷基氨基烷基，二烷基氨基烷基，或在每种情况下表示任选取代的环烷基，环烷基烷基，环烯基或环烯基烷基，或或者表示任意取代的芳烷基，芳酰基，芳基，芳烷氧基或芳氧基，或表示烷氧基，烯氧基或烷氧基，X表示氧或硫，Y表示氧或硫。还显示了其新的中间体。

60. 发明授权

US5300480A Herbicidal sulphonylaminocarbonyltriazolinones having two substituents bonded via oxygen 失效
标题翻译：具有通过氧键连接的两个取代基的除草磺酰基氨基羰基三唑啉酮
公开(公告)号：US5300480A
公开(公告)日：1994-04-05
申请号：US945194
申请日：1992-09-15
申请人： Wilhelm Haas , Klaus-Helmut Muller , Klaus Konig , Hans-Joachim Santel , Klaus Lurssen , Robert R. Schmidt
发明人： Wilhelm Haas , Klaus-Helmut Muller , Klaus Konig , Hans-Joachim Santel , Klaus Lurssen , Robert R. Schmidt
IPC分类号： A01N47/38 , A01N51/00 , C07D249/12 , C07D249/14 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D471/04 , C07D487/04 , A01N43/653
CPC分类号： C07D401/12 , A01N47/38 , A01N51/00 , C07D249/12 , C07D249/14 , C07D403/12 , C07D405/12 , C07D409/12 , C07D471/04 , C07D487/04
摘要： Herbicidal sulphonylaminocarbonyltriazolinones having two substituents bonded via oxygen, of the formula ##STR1## in which R.sup.1 represents hydrogen or an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl and aralkyl,R.sup.2 represents an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl and aralkyl, andR.sup.3 represents an optionally substituted radical from the series comprising alkyl, aralkyl, aryl and heteroaryl,and their salts.
摘要翻译：具有式（*化学结构*）（I）的两个通过氧键键合的取代基的磺酰基氨基羰基三唑啉酮，其中R 1表示氢或任选取代的基团，其包含烷基，烯基，炔基，环烷基，环烯基和芳烷基，R2表示烷基，烯基，炔基，环烷基，环烯基和芳烷基的任选被取代的基团，并且R 3代表包含烷基，芳烷基，芳基和杂芳基及其盐的任选取代的基团。

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