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51. 发明授权

US07381838B2 Preparation of tertiary carboxylic acids 失效
标题翻译：叔羧酸的制备
公开(公告)号：US07381838B2
公开(公告)日：2008-06-03
申请号：US11071166
申请日：2005-03-04
申请人： Klaus-Diether Wiese , Wilfried Bueschken
发明人： Klaus-Diether Wiese , Wilfried Bueschken
IPC分类号： C07C51/14 , C07C51/10
CPC分类号： B01J19/243 , B01J19/2415 , B01J2219/00033 , B01J2219/00103 , B01J2219/00108 , B01J2219/00243 , C07C51/14 , C07C53/126
摘要： Process for carrying out catalytic multiphase reactions in a tubular reactor, in which at least three reactants are present in three different phases, wherein the process is carried out in at least one tubular reactor, and the catalyst is present in a continuous phase, at least one reactant is present in this continuous phase, and at least two reactants are present dispersed in the continuous phase and the loading factor B of the tubular reactor is equal to or greater than 0.2. In particular, the multiphase reaction is a hydrocarboxylation of at least one olefin to a carboxylic acid.
摘要翻译：在管式反应器中进行催化多相反应的方法，其中至少三种反应物存在于三个不同的相中，其中该方法在至少一个管式反应器中进行，并且催化剂至少存在于连续相中在该连续相中存在一种反应物，并且至少两种反应物分散在连续相中，并且管式反应器的负载因子B等于或大于0.2。特别地，多相反应是至少一种烯烃与羧酸的加氢羧化反应。

52. 发明授权

US07323586B2 Phthalic acid alkyl ester mixtures with controlled viscosity 失效
标题翻译：邻苯二甲酸烷基酯混合物具有可控的粘度
公开(公告)号：US07323586B2
公开(公告)日：2008-01-29
申请号：US10487061
申请日：2002-09-20
申请人： Klaus-Diether Wiese , Michael Grass , Wilfried Bueschken
发明人： Klaus-Diether Wiese , Michael Grass , Wilfried Bueschken
IPC分类号： C07C67/08 , C07C67/10 , C07C69/76 , C09K3/00
CPC分类号： C07C69/80 , C08K5/12 , C10M105/36 , C10M129/72 , C10M2207/285 , C10M2207/2855 , C10N2240/08 , C10N2270/00
摘要： Mixtures of isomeric dialkyl phthalates that have a desired viscosity are prepared by esterifying phthalic acid or phthalic anhydride with a mixture of isomeric alkyl alcohols having a certain carbon number of carbon atoms, where the molar fraction of each alkyl alcohol isomer of the isomeric alcohol mixture is determined, and where the viscosity parameter of each alkyl alcohol isomer of the alcohol mixture, which, upon reacting with phthalic acid or phthalic anhydride, results in a mixed isomer dialkyl phalate ester product having a specific desired viscosity, is determined in accordance with formula (I): ln(η)=Σχi*ln(ηi) (I) where η=the calculated viscosity of a dialkyl phthalate mixture, χi=the molar fraction of an isomerically pure alcohol (i), and ηi=the viscosity parameter of isomerically pure alcohol (i).
摘要翻译：具有所需粘度的异构二烷基邻苯二甲酸酯的混合物通过用具有一定碳原子数的异构烷基醇的混合物酯化邻苯二甲酸或邻苯二甲酸酐来制备，其中异构醇混合物的各烷基醇异构体的摩尔分数为并且其中与邻苯二甲酸或邻苯二甲酸酐反应产生具有特定所需粘度的混合异构体癸酸二烷基酯产物的醇混合物的每种烷基醇异构体的粘度参数根据式（ I）：<？in-line-formula description =“In-line Formulas”end =“lead”？> ln（eta）= Sigmachi >）（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中eta =邻苯二甲酸二烷基酯混合物的计算粘度，异构纯的醇（i）的摩尔分数，和异构纯的醇钠的粘度参数（i）。

53. 发明授权

US06916950B2 Process for preparing carboxylic esters 失效
标题翻译：羧酸酯的制备方法
公开(公告)号：US06916950B2
公开(公告)日：2005-07-12
申请号：US09945736
申请日：2001-09-05
申请人： Dietmar Gubisch , Uwe Ernst , Wilfried Bueschken
发明人： Dietmar Gubisch , Uwe Ernst , Wilfried Bueschken
IPC分类号： C07B61/00 , C07C67/08 , C07C67/54 , C07C69/80 , C07C67/36 , C07C67/00 , C07C67/12 , C07C69/52
CPC分类号： C07C67/54 , C07C67/08 , C07C69/54 , C07C69/80
摘要： Carboxylic esters are prepared by a process, which comprises reacting dicarboxylic or polycarboxylic acids or their anhydrides with alcohols in a liquid medium with the concomitant removal of water formed by the esterification reaction by azeotropic distillation together with the alcohol in the medium, wherein the amount of liquid removed from the reaction medium by azeotropic distillation is replaced in whole or in part with the alcohol.
摘要翻译：羧酸酯通过一种方法制备，该方法包括在液体介质中使二羧酸或多元羧酸或其酸酐与醇反应，同时通过与介质中的醇共沸蒸馏与酯化反应形成的水一起除去，其中，通过共沸蒸馏从反应介质中除去的液体全部或部分地被醇代替。

54. 发明授权

US07495134B2 Carbonylation method by adding secondary sterically hindered amines 有权
标题翻译：通过添加第二空间位阻胺的羰基化方法
公开(公告)号：US07495134B2
公开(公告)日：2009-02-24
申请号：US12065091
申请日：2006-06-02
申请人： Dieter Hess , Dagmara Ortmann , Oliver Moeller , Klaus-Diether Wiese , Dirk Fridag , Wilfried Bueschken
发明人： Dieter Hess , Dagmara Ortmann , Oliver Moeller , Klaus-Diether Wiese , Dirk Fridag , Wilfried Bueschken
IPC分类号： C07C45/50 , B01J31/00
CPC分类号： C07C45/50 , B01J31/0237 , B01J31/0247 , B01J31/24 , B01J2231/321 , C07F9/65744 , C07C47/02
摘要： The invention relates to a process for reaction of a carbonylatable compound using a metal complex catalyst comprising a metal of transition group VIII and an organophosphorus ligand and in the presence of a stabilizer based on a sterically hindered secondary amine.
摘要翻译：本发明涉及使用包含过渡族VIII金属和有机磷配体的金属络合物催化剂和基于空间位阻仲胺的稳定剂存在下使羰基化化合物反应的方法。

55. 发明授权

US06433230B1 Process for conducting an aldol condensation 有权
标题翻译：醛醇缩合的方法
公开(公告)号：US06433230B1
公开(公告)日：2002-08-13
申请号：US09716941
申请日：2000-11-22
申请人： Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann
发明人： Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann
IPC分类号： C07C49203
CPC分类号： C07C45/75 , C07C45/74 , C07C47/21 , C07C49/203
摘要： &agr;,&bgr;-Unsaturated keto compounds are prepared by base-catalyzed aldol condensation of aldehydes and/or ketones having from 1 to 15 carbon atoms, comprising: reacting the aldehydes and/or ketones with an aqueous catalyst solution under adiabatic reaction conditions; and separating the reaction mixture obtained by rapid distillation into a top product comprising water, aldehyde and/or ketone and a bottom product comprising &agr;,&bgr;-unsaturated keto compounds and aqueous catalyst phase.
摘要翻译： α，β-不饱和酮化合物通过醛和/或具有1至15个碳原子的酮的碱催化醛醇缩合制备，包括：在绝热反应条件下使醛和/或酮与含水催化剂溶液反应; 并将通过快速蒸馏获得的反应混合物分离成包含水，醛和/或酮的顶部产物和包含α，β-不饱和酮化合物和含水催化剂相的底部产物。

56. 发明授权

US06184424B2 Process for the hydrogenation of hydroformylation mixtures 失效
标题翻译：加氢甲酰化混合物氢化的方法
公开(公告)号：US06184424B2
公开(公告)日：2001-02-06
申请号：US09396367
申请日：1999-09-15
申请人： Wilfried Bueschken , Dietmar Gubisch
发明人： Wilfried Bueschken , Dietmar Gubisch
IPC分类号： C07C2916
CPC分类号： C07C31/125 , C07C29/141 , C07C29/16
摘要： A process for the hydrogenation of reaction mixtures from the hydroformylation of C5 to C24 olefins using hydrogen on fixed catalysts at elevated temperature, in which the aldehydes, alcohols, formates and low-boilers are evaporated from the reaction mixture and passed in the vapor state over a support-free Cu/Cr catalyst.
摘要翻译：使用氢气在固定催化剂上升高的温度下从C5加氢甲酰化C5至C24烯烃的反应混合物的氢化方法，其中醛，醇，甲酸酯和低沸点物从反应混合物中蒸发并在蒸汽状态下通过无支撑的Cu / Cr催化剂。

57. 发明授权

US5831135A Process for the catalytic selective hydrogenation of polyunsaturated organic substances 失效
标题翻译：多不饱和有机物催化选择性氢化方法
公开(公告)号：US5831135A
公开(公告)日：1998-11-03
申请号：US944433
申请日：1997-10-06
申请人： Wilfried Bueschken , Juergen Hummel
发明人： Wilfried Bueschken , Juergen Hummel
IPC分类号： B01J19/18 , B01J19/24 , C07B35/02 , C07B61/00 , C07C5/05 , C07C5/08 , C07C11/02 , C07C11/12 , C07C11/21 , C07C45/62 , C07C49/04 , C07C253/30 , C07C255/02 , C07C29/14
CPC分类号： C07C45/62 , B01J19/1862 , B01J19/245 , B01J19/2465 , C07B35/02 , C07C253/30 , B01J2219/00006 , B01J2219/0011 , B01J2219/00182
摘要： The present invention relates to a process for the catalytic selective hydrogenation of a polyunsaturated organic compound, wherein the hydrogenation is carried out in a plurality of two or more series-connected loops, wherein each loop involves the use of one reactor, which comprises: (a) feeding the polyunsaturated organic compound and hydrogen to an upper part of a reactor to catalytically hydrogenate said the polyunsaturated organic compound to produce a hydrogenation product, (b) recycling a portion of said hydrogenation product back into said upper part of said reactor, (c) feeding the remainder of said hydrogenation product from said reactor to an upper part of a subsequent reactor wherein the polyunsaturated organic compound is catalytically hydrogenated to produce a subsequent hydrogenation product, and wherein a portion of said subsequent hydrogenation product has been recycled and is fed with said remainder of said hydrogenation product to said upper part of said subsequent reactor, (d) repeating step (c) until the subsequent reactor is the last reactor, (e) recovering the remainder of said subsequent hydrogenation product from said last reactor, and (f) obtaining the desired compound(s) from the product of step (e).
摘要翻译：本发明涉及多不饱和有机化合物的催化选择性氢化方法，其中氢化在多个两个或多个串联连接的环中进行，其中每个环包括使用一个反应器，其包括：（ a）将多不饱和有机化合物和氢气供给到反应器的上部以催化氢化所述多不饱和有机化合物以产生氢化产物，（b）将一部分所述氢化产物再循环回所述反应器的上部（ c）将剩余的所述氢化产物从所述反应器进料到后续反应器的上部，其中所述多不饱和有机化合物被催化氢化以产生随后的氢化产物，并且其中所述后续氢化产物的一部分已经被再循环并进料所述剩余的所述氢化产物存在于所述后续的所述上部反应器，（d）重复步骤（c），直到后续反应器为最后一个反应器，（e）从所述最后一个反应器中回收剩余的所述后续氢化产物，和（f）从下列反应产物中获得所需化合物：步骤（e）。

58. 发明授权

US5675045A Process for the catalytic selective hydrogenation of polyunsaturated organic substances 失效
标题翻译：多不饱和有机物催化选择性氢化方法
公开(公告)号：US5675045A
公开(公告)日：1997-10-07
申请号：US668357
申请日：1996-06-26
申请人： Wilfried Bueschken , Juergen Hummel
发明人： Wilfried Bueschken , Juergen Hummel
IPC分类号： B01J19/18 , B01J19/24 , C07B35/02 , C07B61/00 , C07C5/05 , C07C5/08 , C07C11/02 , C07C11/12 , C07C11/21 , C07C45/62 , C07C49/04 , C07C253/30 , C07C255/02 , C07C29/14
CPC分类号： C07C45/62 , B01J19/1862 , B01J19/245 , B01J19/2465 , C07B35/02 , C07C253/30 , B01J2219/00006 , B01J2219/0011 , B01J2219/00182
摘要： The present invention relates to a process for the catalytic selective hydrogenation of a polyunsaturated organic compound, wherein the hydrogenation is carried out in a plurality of two or more series-connected loops, wherein each loop involves the use of one reactor, which comprises: (a) feeding the polyunsaturated organic compound and hydrogen to an upper part of a reactor to catalytically hydrogenate said the polyunsaturated organic compound to produce a hydrogenation product, (b) recycling a portion of said hydrogenation product back into said upper part of said reactor, (c) feeding the remainder of said hydrogenation product from said reactor to an upper part of a subsequent reactor wherein the polyunsaturated organic compound is catalytically hydrogenated to produce a subsequent hydrogenation product, and wherein a portion of said subsequent hydrogenation product has been recycled and is fed with said remainder of said hydrogenation product to said upper part of said subsequent reactor, (d) repeating step (c) until the subsequent reactor is the last reactor, (e) recovering the remainder of said subsequent hydrogenation product from said last reactor, and (f) obtaining the desired compound(s) from the product of step (e).
摘要翻译：本发明涉及多不饱和有机化合物的催化选择性氢化方法，其中氢化在多个两个或多个串联连接的环中进行，其中每个环包括使用一个反应器，其包括：（ a）将多不饱和有机化合物和氢气供给到反应器的上部以催化氢化所述多不饱和有机化合物以产生氢化产物，（b）将一部分所述氢化产物再循环回所述反应器的上部（ c）将剩余的所述氢化产物从所述反应器进料到后续反应器的上部，其中所述多不饱和有机化合物被催化氢化以产生随后的氢化产物，并且其中所述后续氢化产物的一部分已经被再循环并进料所述剩余的所述氢化产物存在于所述后续的所述上部反应器，（d）重复步骤（c），直到后续反应器为最后一个反应器，（e）从所述最后一个反应器中回收剩余的所述后续氢化产物，和（f）从下列反应产物中获得所需化合物：步骤（e）。

59. 发明授权

US08389774B2 Parallelized jet loop reactors 有权
标题翻译：平行喷射回路反应器
公开(公告)号：US08389774B2
公开(公告)日：2013-03-05
申请号：US13059355
申请日：2009-07-09
申请人： Marc Becker , Robert Franke , Wilfried Bueschken , Armin Boerner , Jens Holz
发明人： Marc Becker , Robert Franke , Wilfried Bueschken , Armin Boerner , Jens Holz
IPC分类号： C07C45/50 , B01J14/00
CPC分类号： B01J19/2425 , B01J4/002 , B01J8/1827 , B01J8/226 , B01J19/246 , B01J19/2465 , B01J2208/00221 , B01J2208/00849 , B01J2219/00038 , B01J2219/00094 , B01J2219/00777
摘要： The invention relates to a device and a method for the continuous reaction of a liquid and a second fluid, wherein the device comprises at least two jet loop reactors interconnected in parallel and common outer liquid recirculation.
摘要翻译：本发明涉及一种用于液体和第二流体的连续反应的装置和方法，其中所述装置包括至少两个并联连接的喷射回路反应器和共同的外部液体再循环。

60. 发明授权

US08044229B2 Alicyclic polycarboxylic ester mixtures with a high trans proportion and method for the production thereof 失效
标题翻译：具有高反式比例的脂环族多羧酸酯混合物及其制备方法
公开(公告)号：US08044229B2
公开(公告)日：2011-10-25
申请号：US10490028
申请日：2002-09-03
申请人： Dietrich Maschmeyer , Wilfried Bueschken , Michael Grass , Axel Tuchlenski
发明人： Dietrich Maschmeyer , Wilfried Bueschken , Michael Grass , Axel Tuchlenski
IPC分类号： C07C69/74 , C08G63/02
CPC分类号： C07C69/75 , C07C67/303
摘要： The present invention relates to the preparation of alicyclic polycarboxylic esters by ring-hydrogenation of the corresponding aromatic polycarboxylic esters on a catalyst which comprises at least one metal from the triad iron, cobalt, nickel, and at least one metal of the IInd, IIIrd, IVth, Vth, and/or VIth transition group of the Periodic Table.An alicyclic carboxylic ester mixture with a proportion above 10 mol % of the trans isomers.The use of the alicyclic polycarboxylic ester mixtures.Mixtures made from plastics and from alicyclic polycarboxylic ester mixtures.
摘要翻译：本发明涉及通过在催化剂上对相应的芳族多羧酸酯进行环加氢制备脂环族多羧酸酯，所述催化剂包含至少一种来自三联体铁，钴，镍和至少一种IInd，IIIrd， IV，Vth，和/或第六过渡组。一种比例高于10摩尔％的反式异构体的脂环族羧酸酯混合物。使用脂环族多羧酸酯混合物。由塑料和脂环族多羧酸酯混合物制成的混合物。

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