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    • 52. 发明申请
    • FLAME RETARDANTS
    • 阻燃剂
    • US20110196052A1
    • 2011-08-11
    • US13022045
    • 2011-02-07
    • Klaus HahnOlaf KrihaIngo BellinPatrick SpiesSabine FuchsPeter DeglmannKlemens MassonneHartmut DeneckeChristoph FleckensteinGeert JanssensMaximilian Hofmann
    • Klaus HahnOlaf KrihaIngo BellinPatrick SpiesSabine FuchsPeter DeglmannKlemens MassonneHartmut DeneckeChristoph FleckensteinGeert JanssensMaximilian Hofmann
    • C08K5/5398C08L25/06C08J9/18C08J9/12
    • C08J9/0038C08J9/16C08J2325/04C08K5/5398C08L25/06
    • Phosphine sulfide derivatives of the formula (I), S═PR1R2R3  (I) are suitable as flame retardants, in particular for polymers, where the definitions of the symbols in the formula (I) are as follows: R1 and R2 are identical or different, being C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C8-C10-aryl-C1-C4-alkyl; R3 is H, SH, SR4, OH, OR5 or a —(Y1)n—[P(═X1)R6—(Y2)n]m—P(═X2)R7R8 group; or two groups R1, R2, R3 form, together with the phosphorus atom bonded thereto, a ring system; X1 and X2 are identical or different, being O or S; Y1 and Y2 are identical or different, being O or S; R4, R5, R6, R7 and R8 are identical or different, being independently from one another C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C6-C10-aryl-C1-C4-alkyl; n is 1 if Y1 and, respectively, Y2 is O, and is 1, 2, 3, 4, 5, 6, 7, or 8 if Y1 and, respectively, Y2 is S, and m is an integer from 0 to 100.
    • 式(I)的硫化膦衍生物,S = PR1R2R3(I)适用作阻燃剂,特别是用于聚合物的阻燃剂,其中式(I)中符号的定义如下:R1和R2相同或不同 可以不具有取代基或可以具有一个或多个C 1 -C 4烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基,C 2 -C 12 - 烯基,C 2 -C 12炔基,C 6 -C 10 - 芳基或C 8 -C 10 - 芳基-C 1 -C 4 - 烷基; R3是H,SH,SR4,OH,OR5或 - (Y1)n- [P(= X1)R6-(Y2)n] m-P(= X2)R7R8组; 或两个基团R 1,R 2,R 3与键合的磷原子一起形成环系; X1和X2相同或不同,为O或S; Y1和Y2相同或不同,为O或S; R 4,R 5,R 6,R 7和R 8相同或不同,彼此独立地为可以不具有取代基或可以具有一个或多个C 1 -C 4 - 烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基 ,C 2 -C 12 - 烯基,C 2 -C 12 - 炔基,C 6 -C 10 - 芳基或C 6 -C 10 - 芳基-C 1 -C 4 - 烷基; 如果Y1和Y1分别为0,则n为1,如果Y1分别为Y2,并且分别为1,2,3,4,5,6,7或8,并且m分别为0至100的整数。 。
    • 53. 发明申请
    • DISTILLATION OF IONIC LIQUIDS
    • 离子液体的分离
    • US20100300870A1
    • 2010-12-02
    • US12675445
    • 2008-08-15
    • Klemens MassonneMichael SiemerWerner MormannWei Leng
    • Klemens MassonneMichael SiemerWerner MormannWei Leng
    • B01D3/00
    • C07C51/44C07B63/00C07D233/54C07C53/122C07C53/10
    • Method of distilling mixtures comprising salts having a melting point of less than 200° C. at 1 bar (ionic liquids), wherein the cation of the ionic liquid comprises a heterocyclic ring system having at least one nitrogen atom and all nitrogen atoms of the heterocyclic ring system have an organic group as substituent, the anion of the ionic liquid is a compound having at least one carboxylate group (carboxylate for short) or at least one phosphate group (phosphate for short) and the distance from the surface via which the heat of distillation is introduced in the distillation (vaporizer surface) to the surface at which condensation takes place (condenser surface) is less than 50 cm at least one point, with the vaporizer surface and condenser surface themselves having at least one length dimension of greater than 50 cm.
    • 在1巴(离子液体)下蒸馏含有熔点小于200℃的盐的混合物的方法,其中离子液体的阳离子包括具有至少一个氮原子和杂环的全部氮原子的杂环体系 环系具有有机基团作为取代基,离子液体的阴离子是具有至少一个羧酸酯基团(简称为羧酸酯)或至少一种磷酸酯基团(磷酸酯)的化合物以及与表面的距离,通过该化合物的热量 蒸馏在蒸馏(蒸发器表面)中引入到发生冷凝的表面(冷凝器表面)至少一个点处50cm以下,蒸发器表面和冷凝器表面本身具有至少一个长度尺寸大于 50厘米
    • 60. 发明申请
    • FLAME RETARDANT
    • 不易燃的
    • US20120252911A1
    • 2012-10-04
    • US13516464
    • 2010-12-15
    • Christoph FleckensteinHartmut DeneckeIngo BellinOlaf KrihaPatrick SpiesSabine FuchsKlemens MassonneKlaus HahnPeter DeglmannMaximilian HofmannAlois Kindler
    • Christoph FleckensteinHartmut DeneckeIngo BellinOlaf KrihaPatrick SpiesSabine FuchsKlemens MassonneKlaus HahnPeter DeglmannMaximilian HofmannAlois Kindler
    • C07F9/655C07F9/6561C08K5/1535B29B9/06C08J9/16
    • C09K21/12C08J9/0038C08J9/14C08J9/20C08J2325/04C08K5/49C08K5/523C08K5/53C08K5/5313C08K5/5377C08K5/5398C08L2201/02C08L2203/14C08L25/00C08L25/06
    • Use of a phosphorus compound of the formula (I) as flame retardant, where the definitions of the symbols in the formula (I) are as follows: A is one of the following groups: Y is —P(═X2)SR3R4, H, a straight-chain or branched C1-C12-alkyl group, C5-C6-cycloalkyl, C6-C12-aryl, or benzyl, where the four last-mentioned groups are unsubstituted or have substitution by one or more radicals from the group of C1-C4-alkyl or C1-C4-alkenyl; R1, R2, R3, and R4 are identical or different and are hydrogen, OH, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9 COR10, COOR11, CONR12R13 or two radicals R1, R2, R3, or R4 form, together with the phosphorus atom to which they are bonded, or the P—O-A-O—P group, a ring system; R5, R6, R7, and R8 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy; R9, R10, R11, R12, R13 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy; X1 and X2 are identical or different and are S or O; r and s are identical or different and are 0 or 1; X3, X4, X5, and X6 are identical or different and are S or O, and n is a natural number from 1 to 50.
    • 式(I)的磷化合物作为阻燃剂的用途,其中式(I)中的符号的定义如下:A是以下基团之一:Y是-P(= X 2)SR 3 R 4,H 直链或支链C 1 -C 12 - 烷基,C 5 -C 6 - 环烷基,C 6 -C 12 - 芳基或苄基,其中四个最后提到的基团是未取代的或具有一个或多个自由基 C 1 -C 4 - 烷基或C 1 -C 4 - 烯基; R1,R2,R3和R4相同或不同,为氢,OH,C1-C16 - 烷基,C1-C16 - 烯基,C1-C16 - 烷氧基,C1-C16 - 烯氧基,C3-C10-环烷基,C3- C 1 -C 10 - 芳基,C 6 -C 10 - 芳氧基,C 6 -C 10 - 芳基-C 1 -C 16 - 烷基,C 6 -C 10 - 芳基-C 1 -C 16 - 烷氧基,SR 9 COR 10,COOR 11,CONR 12 R 13或两个基团R 1 R 2,R 3或R 4与它们所键合的磷原子一起形成,或与P-OAO-P基团形成环系; R 5,R 6,R 7和R 8相同或不同,为H,C 1 -C 16 - 烷基,C 1 -C 16 - 烯基,C 1 -C 16 - 烷氧基,C 1 -C 16 - 烯氧基; R9,R10,R11,R12,R13相同或不同,为H,C1-C16 - 烷基,C1-C16 - 烯基,C6-C10-芳基,C6-C10-芳基-C1-C16 - 烷基,C6-C10 芳基-C 1 -C 16 - 烷氧基; X1和X2相同或不同,为S或O; r和s相同或不同,为0或1; X3,X4,X5和X6相同或不同,为S或O,n为1〜50的自然数。