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    • 51. 发明授权
    • Laser ablation imaging of zirconia-alumina composite ceramic printing
member
    • 氧化锆 - 氧化铝复合陶瓷印刷部件的激光烧蚀成像
    • US5836249A
    • 1998-11-17
    • US848332
    • 1997-05-01
    • Dilip K. ChatterjeeSyamal K. Ghosh
    • Dilip K. ChatterjeeSyamal K. Ghosh
    • B41C1/10B41N1/00
    • B41N1/006B41C1/1033B41C1/1041Y10S430/146
    • Reusable lithographic printing members are prepared from a ceramic that is a composite of a zirconia alloy and .alpha.-alumina. In use, a printing surface of the zirconia-alumina composite ceramic is imagewise exposed to electromagnetic radiation such as from a laser under controlled conditions to provide ablation of the zirconia alloy in the exposed areas. Those areas are transformed from a hydrophilic to an oleophilic state or from an oleophilic to a hydrophilic state, thereby creating a lithographic printing surface that is hydrophilic in non-image areas and is oleophilic and thus capable of accepting printing ink in image areas. Such inked areas can then be used to transfer an image to a suitable substrate in lithographic printing. The printing members are directly laser-imageable as well as image erasable, and can include printing plates, printing cylinders, printing tapes and printing sleeves.
    • 可再利用的平版印刷构件由氧化锆合金和α-氧化铝的复合材料制成。 在使用中,氧化锆 - 氧化铝复合陶瓷的印刷表面在受控条件下成像暴露于诸如激光的电磁辐射,以在暴露的区域中提供氧化锆合金的烧蚀。 这些区域从亲水性状态转变为亲油性状态或从亲油性状态转变为亲水状态,从而产生在非图像区域中亲水的亲和性并且因此能够接受图像区域中的印刷油墨的平版印刷表面。 然后可以使用这样的油墨区域在平版印刷中将图像转印到合适的基底上。 印刷部件直接可激光成像,图像可擦除,可包括印版,印刷滚筒,印刷胶带和印刷套筒。
    • 55. 发明授权
    • Method for micromolding ceramic structures
    • 微型陶瓷结构的方法
    • US5735985A
    • 1998-04-07
    • US749256
    • 1996-11-15
    • Syamal K. GhoshEdward P. FurlaniWilliam J. Grande
    • Syamal K. GhoshEdward P. FurlaniWilliam J. Grande
    • B28B3/02B28B1/00B28B7/34C04B35/486C04B35/622B32B31/26B29C33/40
    • B28B7/346B28B1/002C04B35/486C04B35/622B29K2883/00
    • A method for micromolding ceramic articles and structures having spatial features as small as 0.1 .mu.m and having a depth ranging from 2.0 .mu.m to 100 .mu.m. A master mold of the article or structure to be molded is first fabricated using a silicon wafer and dry etching technology. A negative master mold is then produced by placing the silicon master mold device in a surrounding mold form and filling the surrounding mold form with a silicone or silicone rubber, preferably an RTV.TM. (a room temperature-vulcanizing silicone rubber compound). Such material replicates each of the micro features of the master mold in great detail to a resolution on the order of 0.1 .mu.m. The negative master mold is then used in a die to mold the desired individual elements or structures from a ceramic powder which is capable of replicating each of the micro features of the negative master mold to the desired resolution. Depending on the resolution required in a particular micromolded element, it may be necessary to use ceramic nano-particles in the micromolding process. For resolution of spatial features having dimensions as small as 0.1 .mu.m and a depth of about 2.0 .mu.m, ceramic nano-particles ranging in size from about 0.01 .mu.m to about 0.02 .mu.m can be used to micromold these features. If an integral structure is to be created from multiple micromolded ceramic elements, the elements are first assembled prior to sintering. Sintering results in an integration of the assembled elements to form a contiguous structure. A single element, or alternatively, multiple elements can be molded simultaneously from the stone mold cavity preferably using a dry pressing process or, in the alternative, a cold isostatic pressing process.
    • 具有小至0.1μm的空间特征并且深度在2.0μm至100μm之间的陶瓷制品和结构的微成型方法。 首先使用硅晶片和干蚀刻技术来制造待模制的制品或结构的主模具。 然后通过将硅主模具装置放置在周围的模具形状中并用硅树脂或硅橡胶,优选RTV TM(室温硫化硅橡胶复合物)填充周围的模具形状来制造负模具。 这样的材料将主模具的每个微观特征复制到大约0.1μm的分辨率上。 然后将负母模用于模具中以从能够将负母模的每个微特征复制到期望分辨率的陶瓷粉末模制所需的各个元件或结构。 根据特定微成型元件中所需的分辨率,可能需要在微型成型工艺中使用陶瓷纳米颗粒。 为了解决具有小至0.1μm的尺寸和约2.0μm的深度的空间特征,可以使用尺寸为约0.01μm至约0.02μm的陶瓷纳米颗粒来微观地显示这些特征。 如果从多个微成型陶瓷元件产生整体结构,则元件首先在烧结之前组装。 烧结导致组​​合的元件的集成以形成连续的结构。 单个元件或可选地,多个元件可以从石模腔同时模制,优选使用干压工艺,或者替代地,冷等静压制工艺。
    • 58. 发明授权
    • Method of making core shell structured articles based on alumina
ceramics having spinel surfaces
    • 基于具有尖晶石表面的氧化铝陶瓷制造芯壳结构制品的方法
    • US5683481A
    • 1997-11-04
    • US700256
    • 1996-08-20
    • Dilip K. ChatterjeeSyamal K. GhoshGregory S. Jarrold
    • Dilip K. ChatterjeeSyamal K. GhoshGregory S. Jarrold
    • C04B35/10C04B35/119C04B35/64C04B41/50C04B41/87C03B19/01C03B19/09C04B33/34C04B33/36
    • C04B41/009C04B35/119C04B35/64C04B41/5046C04B41/87C04B2111/0025
    • An alumina ceramic article and a method for preparing the article. The method comprises the steps of: (1) Compacting a mixture of a first concentration of particulate aluminum oxide sufficient to prevent retention of the zirconium oxide alloy particles in the shell in a predominantly tetragonal crystal structure and a second concentration of particulate zirconium oxide alloy. The zirconium oxide alloy is zirconium oxide and a secondary oxide selected from the group consisting of MgO, CaO, Y.sub.2 O.sub.3, Sc.sub.2 O.sub.3, CeO.sub.2, and rare earth oxides having a concentration of secondary oxide generally of about 0.5 to about 5 mole percent Y.sub.2 O.sub.3, from about 0.1 to about 1 mole percent MgO, from about 0.5 to about 15 mole percent CeO.sub.2, from about 0.5 to about 7.0 mole percent Sc.sub.2 O.sub.3, or from about 0.5 to about 5 mole percent CaO, relative to the total of the zirconium oxide alloy. The compacting results in the formation of a blank.(2) Providing contact between the blank and a dopant oxide. (3) Sintering the blank in contact with the dopant oxide wherein said first concentration is from 50-75 weight percent of the total of the first and second concentrations.
    • 一种氧化铝陶瓷制品及其制备方法。 该方法包括以下步骤:(1)将第一浓度的微粒氧化铝的混合物压实成足以防止氧化锆合金颗粒以主要为四方晶体结构和第二浓度的颗粒状氧化锆合金在壳中的保留。 氧化锆合金是氧化锆和选自MgO,CaO,Y 2 O 3,Sc 2 O 3,CeO 2的二次氧化物和二氧化硫浓度通常为约0.5〜约5摩尔%Y 2 O 3的稀土氧化物,从约 0.1至约1摩尔%的MgO,约0.5至约15摩尔%的CeO 2,约0.5至约7.0摩尔%的Sc 2 O 3,或约0.5至约5摩尔%的CaO,相对于氧化锆合金的总量。 压实导致形成空白。 (2)提供坯料与掺杂剂氧化物之间的接触。 (3)烧结坯料与掺杂剂氧化物接触,其中所述第一浓度为第一和第二浓度总量的50-75重量%。