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51. 发明授权

US07407648B2 Merocyanine derivatives for cosmetic use 有权
公开(公告)号：US07407648B2
公开(公告)日：2008-08-05
申请号：US10520840
申请日：2003-07-01
申请人： Barbara Wagner , Thomas Ehlis , Kai Eichin
发明人： Barbara Wagner , Thomas Ehlis , Kai Eichin
IPC分类号： A61Q17/04 , A61K8/37 , A61K31/21 , A61K31/235 , A61K31/10 , A61K31/04 , A61K8/04 , A61Q1/10 , A01N37/00 , A01N31/235 , A01N41/10 , A01N33/24
CPC分类号： C07D239/54 , A61K8/4906 , A61Q17/04 , C07C255/30 , C07C255/31 , C07C2601/16 , C07D207/20 , C07D231/36 , C07D263/14 , C07D277/10 , C07D295/145 , C07D295/155 , C07D319/06
摘要： The use is described of merocyanine derivatives of formula (1), wherein R1 and R2 are each independently of the other hydrogen; C1-C22alkyl; cyclo-C3C8alkyl; or unsubstituted or C1-C5alkyl- or C1-C5alkoxy-substituted C6-C20aryl; orl; or R1 and R2 together with the nitrogen atom linking them form a —(CH2)m— ring which is uninterrupted or, interrupted by —O— or by —NH—; R3 is a cyano group; —COOR5; —CONHR5; —COR5; or —SO2R5; R4 is a cyano group; —COOR6; —CONHR6; —COR6; or —SO2R6; R5 and R6 are each independently of the other C1-C22alkyl; or unsubstituted or C1-C5alkyl substituted C6-C20aryl; or R3 and R4 together or R5 and R6 together form in a 5- to 7-membered, monocyclic, carbocyclic or heterocyclic ring; Z1, and Z2 are each independently of the other a —(CH2)n— group which is uninterrupted or interrupted by —O—, —S—, or by —NR7—, and/or is unsubstituted or substituted by C1-C5alkyl; R7 is (ClC5alkyl; 1 is from 1 to 4; m is from 1 to 7; n is from 1 to 4; when n=2, R1, R5 or R6 is a bivalent alkyl group; or R1, and R2 together with the 2 nitrogen atoms linking them form a —(CH2)m— ring; when n=3, R1, R5 or R6 is a trivalent alkyl group; when n=4, R1, R5 or R6 is a tetravalent alkyl group; and R1, and R2 in formula (1) are not simultaneously hydrogen, in protecting human and animal hair and skin from UV radiation.

52. 发明授权

US06961076B2 Reactive dye printing process 失效
公开(公告)号：US06961076B2
公开(公告)日：2005-11-01
申请号：US10853331
申请日：2004-05-25
申请人： Barbara Wagner , Ming Xu
发明人： Barbara Wagner , Ming Xu
IPC分类号： B41J2/325 , B41J31/00 , B41M5/025 , B41M5/382 , B41M5/385 , B41M5/39 , B41M5/392 , B41M5/395 , B41M5/50 , B41M5/52 , B41M7/00 , D06P1/382 , D06P3/10 , D06P3/14 , D06P3/24 , D06P3/54 , D06P3/66 , D06P3/82 , D06P5/00 , D06P5/20 , D06P5/24 , D06P5/26 , G01D15/16
CPC分类号： B41M5/0256 , B41M5/345 , B41M5/38257 , B41M5/385 , B41M5/392 , B41M5/395 , B41M5/52 , B41M7/00 , D06P3/10 , D06P3/148 , D06P3/248 , D06P3/54 , D06P3/66 , D06P3/8214 , D06P3/8252 , D06P5/003 , D06P5/007 , D06P5/2077
摘要： A formulation and method of printing an ink or meltable ink layer having reactive dyes or mixtures of reactive dyes and disperse dyes as colorants. The ink or ink melt layer also includes an alkaline substance, a binder, and optionally, a heat-activated printing additive. Permanently bonded color images are provided by the reaction between the reactive dye and the final substrate, which may be any cellulosic, protein, or polyamide fiber material, or mixtures with polyester. Reaction occurs upon heat activation of the printed ink image.

53. 发明授权

US06849370B2 Energy activated electrographic printing process 有权
标题翻译：能量活化电印技术
公开(公告)号：US06849370B2
公开(公告)日：2005-02-01
申请号：US09977918
申请日：2001-10-16
申请人： Barbara Wagner , Rebecca Silveston , Ming Xu
发明人： Barbara Wagner , Rebecca Silveston , Ming Xu
IPC分类号： G03G9/09 , G03G13/08 , G03G13/20 , G03G13/14
CPC分类号： G03G9/0926 , G03G9/0928 , G03G13/08 , G03G15/6591 , G03G2215/00527
摘要： A reactive toner that is energy-activated is printed by means of an electrographic device such as a laser printer. The reactive toner is printed onto a substrate. Toner components that cross-link and bond the printed toner permanently onto the substrate, or another substrate through a transfer process, are activated by the application of energy to react after printing. Reaction of the energy-activated components may be inhibited with blocking or protecting agents. The image is permanently bonded onto the substrate when the protection provided by the protecting agents is removed by the application of energy to the printed toner. The toner may comprise energy-activated components, colorants, color enhancing polymeric materials, binder resins, internal and external additives such as waxes and charge control agents. The energy-activated components have multiple functional groups that react with active hydrogen, components that contain active hydrogen, or components that are capable of conversion to active hydrogen containing groups.
摘要翻译：通过诸如激光打印机之类的电子照相装置印刷能量激活的活性调色剂。将反应性调色剂印刷到基底上。通过施加能量在印刷之后反应来激活通过转印方法将印刷的调色剂永久地交联并结合到基底或另一基底上的调色剂组分。能量活化组分的反应可以用封闭剂或保护剂来抑制。当通过向印刷的调色剂施加能量去除由保护剂提供的保护时，将图像永久地粘合到基底上。调色剂可以包括能量活化组分，着色剂，增色聚合物材料，粘合剂树脂，内部和外部添加剂如蜡和电荷控制剂。能量活化组分具有与活性氢反应的多个官能团，含有活性氢的组分或能够转化为含活性氢基团的组分。

54. 发明授权

US06447629B1 Digital thermal printing process using reactive ink 有权
标题翻译：使用反应性墨水的数字热敏印刷工艺
公开(公告)号：US06447629B1
公开(公告)日：2002-09-10
申请号：US09542570
申请日：2000-04-04
申请人： Kimberlee Thompson , Barbara Wagner , Ming Xu
发明人： Kimberlee Thompson , Barbara Wagner , Ming Xu
IPC分类号： B44C1165
CPC分类号： B41M5/38257 , B41M5/0256 , B41M5/392 , B41M7/0054 , B44C1/1716 , C09D11/03 , D06P1/38 , D06P1/5285 , D06P5/001 , D06P5/007 , D06P5/2077 , D06Q1/10 , D06Q1/12 , Y10S428/914
摘要： A method of digitally printing reactive ink contained in a heat meltable ink layer comprising dyes or pigments or other colorants, using a thermal printer. The ink layer comprises compounds with functional groups capable of reacting with active hydrogen, and compounds with functional groups containing active hydrogen, or functional groups capable of conversion to active hydrogen containing groups. The reactive ink contains one or more blocking agents which prevent initiation of the reaction during thermal printing. An image is thermally printed onto a substrate, at a first temperature, so that the ink is not reacted during the process of printing on to the medium. The image is subsequently transferred or permanently fixed on the substrate by the application of heat and pressure, which removes the blocking agent and reacts the ink, bonding the colorant to the substrate.
摘要翻译：使用热敏打印机数字印刷包含在包含染料或颜料或其它着色剂的热熔性油墨层中的反应性油墨的方法。油墨层包括具有能够与活性氢反应的官能团的化合物，以及含有活性氢的官能团的化合物或能够转化为含活性氢基团的官能团。反应性油墨含有一种或多种在热敏打印期间防止反应开始的封闭剂。在第一温度下将图像热印刷到基底上，使得在印刷过程中墨水不会反应。随后通过施加热量和压力将图像转移或永久地固定在基材上，其除去封闭剂并使油墨反应，将着色剂粘合到基材上。

55. 发明授权

US6152038A Media and method for providing UV protection 有权
标题翻译：用于提供紫外线防护的介质和方法
公开(公告)号：US6152038A
公开(公告)日：2000-11-28
申请号：US322214
申请日：1999-05-28
申请人： Barbara Wagner , Ming Xu
发明人： Barbara Wagner , Ming Xu
IPC分类号： B41M5/035 , D06P5/24 , B41L35/14 , B32B27/14
CPC分类号： D06P5/003 , B41M5/035 , D06M2200/25 , Y10T428/24802
摘要： An intermediate media having a transferable UV stabilizer receives a printed image. A transferable UV absorber and/or free radical scavenger is present. The image, or dye layer, and UV stabilizer are transferred to a final substrate during subsequent heat transfer and activation. Alternatively, the UV stabilizer may be heat transferred from the intermediate transfer media onto a previously transferred image. The UV stabilizer is resistant to laundering at elevated temperatures after transfer and imparts no hand to the final substrate. The intermediate transfer media may comprise multiple layers including a layer containing one or more UV stabilizers. A release layer may be applied beneath the UV stabilizer layer. The release and UV stabilizer layers may sit beneath a dye screening layer. One layer may be a liquid permeable, gas impermeable membrane.
摘要翻译：具有可转印UV稳定剂的中间介质接收打印图像。存在可转移的UV吸收剂和/或自由基清除剂。在随后的热传递和活化期间，将图像或染料层和UV稳定剂转移到最终的底物。或者，UV稳定剂可以从中间转印介质热传递到先前转印的图像上。 UV稳定剂在转移后耐高温洗涤，并且不会将手放在最终的底物上。中间转印介质可以包括多层，包括含有一种或多种UV稳定剂的层。可以在UV稳定剂层之下施加剥离层。释放和UV稳定剂层可以位于染料筛选层下面。一层可以是液体可渗透的不透气膜。

56. 发明授权

US6105502A Reactive ink printing process 有权
标题翻译：活性油墨印刷工艺
公开(公告)号：US6105502A
公开(公告)日：2000-08-22
申请号：US166057
申请日：1998-10-02
申请人： Barbara Wagner , Kimberlee Thompson , Ming Xu
发明人： Barbara Wagner , Kimberlee Thompson , Ming Xu
IPC分类号： B41M7/00 , D06P5/24 , B41F31/00
CPC分类号： B41M5/025 , B41M7/00 , D06P5/003 , D06P5/007
摘要： A color image is printed onto a first substrate, which acts as an intermediate medium, using lithography, intaglio, gravure, relief printing or other printing process which uses plates. The image is subsequently transferred from the intermediate medium to a final substrate, which may be a textile of natural fabric, such as cotton.Bonding and/or crosslinking of the color images are provided by the reaction between compounds selected from each of two chemical groups. The first group comprises compounds with functional groups capable of reacting with active hydrogen, such as isocyanate or epoxy groups. The second group comprises compounds with functional groups containing active hydrogen, or compounds with functional groups containing active hydrogen after a conversion process. The functional groups of one or both reactive chemical groups are protected either by chemical blocking with blocking agents or by physical barrier such as encapsulating agents. The blocking agents are removed by the application of heat during the transfer of the image from the first substrate to the final substrate.
摘要翻译：使用平版印刷，凹版印刷，凹版印刷，凸版印刷或使用印版的其它印刷工艺，将彩色图像印刷到作为中间介质的第一基板上。随后将图像从中间介质转移到最终的基底，其可以是天然织物如棉花的织物。通过选自两个化学基团中的每一个的化合物之间的反应提供彩色图像的结合和/或交联。第一组包括具有能够与活性氢例如异氰酸酯或环氧基团反应的官能团的化合物。第二组包括具有含有活性氢的官能团的化合物，或在转化过程之后具有含有活性氢的官能团的化合物。一个或两个反应性化学基团的官能团通过用封闭剂的化学阻断或通过物理屏障例如包封剂来保护。在将图像从第一衬底转移到最终衬底期间通过施加热来去除封闭剂。

57. 外观设计

USD303639S Self-locking identification bracelet 失效
公开(公告)号：USD303639S
公开(公告)日：1989-09-26
申请号：US895719
申请日：1986-08-12
申请人： Barbara Wagner
设计人： Barbara Wagner

58. 发明授权

US09068080B2 Merocyanine derivatives 有权
标题翻译：梅花菁衍生物
公开(公告)号：US09068080B2
公开(公告)日：2015-06-30
申请号：US12311502
申请日：2007-10-05
申请人： Barbara Wagner
发明人： Barbara Wagner
IPC分类号： A61K31/695 , A61Q90/00 , C07F7/02 , C09B23/01 , A61K8/49 , A61K8/58 , A61K8/898 , A61Q17/04 , C07F7/08 , C09B23/06 , C09B23/10
CPC分类号： C09B23/0066 , A61K8/49 , A61K8/4926 , A61K8/494 , A61K8/498 , A61K8/585 , A61K8/898 , A61Q17/04 , C07F7/0838 , C09B23/0091 , C09B23/06 , C09B23/105
摘要： Disclosed are merocyanine derivatives which correspond to the formula (I), wherein L1, L2 and L3 independently of each other are hydrogen; or L1 and L3 may be linked together to form a carbocyclic ring; R3 and R4 independently of each other are CN; —COR5; —COOR5; —CONR5R6; C1-C22alkyl; C2-C22alkenyl; C2-C22alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C20aralkyl; C1-C20heteroalkyl; C3-C12cycloheteroalkyl; C3-C18heteroaralkyl; C6-C20 aryl; C1-C12alkylcarbonylamino-C6-C20aryl; C2-C12heteroaryl; or —X2—Sil2; n is a number from 1 to 4; the meaning of R1 and R2 depends on the definition of n. The compounds are useful as UV absorbers for cosmetic applications.
摘要翻译：公开了对应于式（I）的部花青衍生物，其中L1，L2和L3彼此独立地是氢; 或者L1和L3可以连接在一起形成碳环; R 3和R 4彼此独立地为CN; -COR5; -COOR5; -CONR5R6; C 1 -C 22烷基; C 2 -C 22烯基; C2-C22炔基; C 3 -C 12环烷基; C3-C12环烯基; C7-C20芳烷基; C 1 -C 20杂烷基; C 3 -C 12环杂烷基; C 3 -C 18杂烷基; C6-C20芳基; C 1 -C 12烷基羰基氨基-C 6 -C 20芳基; C2-C12杂芳基; 或-X2-Sil2; n是从1到4的数字; R1和R2的含义取决于n的定义。该化合物可用作化妆品应用的UV吸收剂。

59. 发明授权

US08829192B2 Stabilization of body-care and household products against degradation by uv radiation using merocyanine derivatives 有权
标题翻译：使用部花青衍生物稳定身体护理和家用产品免受紫外线辐射降解
公开(公告)号：US08829192B2
公开(公告)日：2014-09-09
申请号：US11989164
申请日：2006-07-19
申请人： Barbara Wagner , Oliver Reich
发明人： Barbara Wagner , Oliver Reich
IPC分类号： C07D211/00 , C07C307/00 , C07C69/76 , C07D249/04 , C07C255/01 , C11D3/30 , A61K8/34 , A61K8/37 , A61K8/41 , A61K8/44 , A61K8/46 , A61K8/49 , A61Q1/02 , A61Q1/04 , A61Q1/06 , A61Q1/08 , A61Q1/10 , A61Q3/02 , A61Q13/00 , A61Q19/00 , C11D3/00 , C11D3/28 , C11D3/34
CPC分类号： C11D3/30 , A61K8/347 , A61K8/37 , A61K8/375 , A61K8/41 , A61K8/44 , A61K8/46 , A61K8/466 , A61K8/4926 , A61K8/496 , A61Q1/02 , A61Q1/04 , A61Q1/06 , A61Q1/08 , A61Q1/10 , A61Q3/02 , A61Q13/00 , A61Q19/005 , C11D3/0084 , C11D3/28 , C11D3/349
摘要： Described is the use of specific merocyanine derivatives for protecting body-care and household products from photolytic and oxidative degradation. These compounds perform outstanding UV absorber properties.
摘要翻译：描述了使用特定的部花青衍生物来保护身体护理和家用产品免受光解和氧化降解。这些化合物具有出色的紫外线吸收剂性能。

60. 发明申请

US20110224170A1 Pyranopyranone derivatives as antimicrobial agents 审中-公开
公开(公告)号：US20110224170A1
公开(公告)日：2011-09-15
申请号：US13028576
申请日：2011-02-16
申请人： Barbara Wagner , Janina Purschwitz , Karin Bieler
发明人： Barbara Wagner , Janina Purschwitz , Karin Bieler
IPC分类号： A61K31/366 , A61K31/695 , A01N43/90 , A01N55/10 , C07D493/04 , A61P31/00 , A01P1/00
CPC分类号： A61K31/366 , A01N43/90 , A01N55/00 , C07D493/04 , C07D493/08 , C07D493/10 , C07D493/20 , C07F7/0812 , A01N2300/00
摘要： Disclosed is the use of pyranopyranone derivatives of formula wherein R1, R2, R3, R4 and R5 independently of one another are hydrogen; C1-C30alkyl, C2-C30alkenyl, or C3-C12cycloalkyl, which may be substituted by one or more E and/or interrupted by one or more D; C6-C20aryl, which may be substituted by one or more G; C4-C20heteroaryl, which may be substituted by one or more G, C2-C18alkenyl, C2-C18alkynyl, C7-C25aralkyl, or —CO—R6; —SiR8R9R10; or R4 and R5 together form a five or six membered ring; or R3 and R4 together form a five or six membered ring; D is —CO—; —COO—; —S—; —SO—; —SO2—; —O—; —NR7—; —SiR8R9—; —POR10—; —CR12═CR13—; or —C≡C—; and E is —OR6; —SR6; —NR14R15; —NR14COR15; —COR6; —COOR6; —CONR14R15; —CN; halogen; or OSO3R11; SO3R11; SO2R11; PO3(R11)2; OPO3(R11)2; G is E; C1-C18alkyl, which is optionally interrupted by D; C1-C18 perfluoroalkyl; C1-C18alkoxy, which is optionally substituted by E and/or interrupted by D; wherein R6 is H; C6-C18aryl which is optionally substituted by OH, C1-C30alkyl or C1-C30alkoxy; or C1-C30alkyl which is optionally interrupted by —O—; R7 is H; C6-C18aryl which is optionally substituted by OH, C1-C30alkyl or C1-C30alkoxy; or C1-C30alkyl which is optionally interrupted by —O—; R8, R9 and R10 independently of each other are hydrogen; C1-C30alkyl; C6-C18aryl which is optionally substituted by C1-C30alkyl; and R11 is hydrogen; C6-C18aryl, which is optionally substituted by OH, C1-C30alkyl or C1-C30alkoxy; or C1-C30alkyl, which is optionally interrupted by —O—; R12, R13, R14 and R15 independently of each other are hydrogen; C6-C18aryl which is optionally substituted by OH, C1-C30alkyl or C1-C30alkoxy; C1-C30alkyl, which is optionally interrupted by —O—; or R14 and R15 together form a five or six membered ring; as antimicrobial and/or preserving agents.

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