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    • 52. 发明申请
    • Carbide nanofribrils and method of making same
    • 硬质合金纳米纤维及其制造方法
    • US20060051280A1
    • 2006-03-09
    • US11265804
    • 2005-11-02
    • David MoyChun-Ming Niu
    • David MoyChun-Ming Niu
    • C01B31/36
    • C04B35/62277B82Y30/00C01B32/90C01B32/956C04B35/62281C04B2235/3418C04B2235/428C04B2235/5264C04B2235/5288C04B2235/5296C04B2235/5481C04B2235/767C04B2235/81C04B2235/9661C30B25/005C30B29/36D01F9/08Y10S977/734
    • A plurality of carbide, such as silicon carbide, tungsten carbide, etc., nanofibrils predominantly having diameters substantially less than about 100 nm and a method for making such carbide nanofibrils. The method includes the steps of: heating a plurality of carbon nanotubes or nanofibrils predominantly having diameters less than about 50 nm in a reaction chamber in the presence of a gas of the form QnAm, where Q is a metal capable of forming a carbide, A is an element or radical and n and m are integers necessary to satisfy valences, such as, for example silicon monoxide, and an inert gas in a reaction vessel to a temperature substantially less than 1700 C but sufficently high to cause substantial reaction of the metal in the gas with the carbon of said carbon nanotubes or nanofibrils to form, in situ, solid carbide nanofibrils, the temperature being sufficiently low to prevent substantial fusing together of individidual ones of said carbide nanofibrils, removing at least a portion of A-based gas from said reaction chamber as said reaction progresses, and maintaining said temperature until substantially all the carbon of said nanotubes or nanofibrils has been converted into Q-based carbide.
    • 多个碳化物,例如碳化硅,碳化钨等,主要具有基本上小于约100nm的直径的纳米原纤维和制造这种碳化物纳米原纤维的方法。 该方法包括以下步骤:在反应室中,在存在下列形式的气体的情况下,加热主要具有小于约50nm直径的碳纳米管或纳米原纤维 其中Q是能够形成碳化物的金属,A是元素或基团,n和m是满足价态所必需的整数,例如一氧化硅,以及反应容器中的惰性气体, 温度基本上小于1700℃,但足够高,导致气体中的金属与所述碳纳米管或纳米原纤维的碳的实质反应,原位形成整体碳化物纳米原纤维,其温度足够低以防止大量熔融在一起 所述碳化物纳米原纤维的单独的,当所述反应进行时,从所述反应室中除去至少一部分A基气体,并保持所述温度,直到所述纳米管或纳米原纤维的基本上全部为碳 转为Q型碳化物。
    • 58. 发明授权
    • Promoted method for producing carbamates
    • 促进生产氨基甲酸酯的方法
    • US4242520A
    • 1980-12-30
    • US7105
    • 1979-01-29
    • David Moy
    • David Moy
    • C07C271/06C07C125/063C07C125/07
    • C07C271/06
    • A process for the production of carbamates is provided which comprises contacting an organic primary or secondary amine with a source of carbon monoxide, an organic compound containing at least one hydroxyl group and a source of sulfur, selenium or tellurium, in the presence of a catalyst for the reaction and in the presence of at least one member selected from the group consisting of disulfides of the formulaR.sup.1 --S--S--R.sup.2wherein R.sup.1 and R.sup.2 comprise members selected from the group consisting of alkyl, aryl, cycloalkyl, alkaryl, aralkyl, heterocyclic, alkenyl, alkynyl, alkanoyl, aranoyl, halogenated derivatives of the foregoing groups, and derivatives of the foregoing groups in which one or more carbon atoms is replaced by an oxygen atom.
    • 提供了一种生产氨基甲酸酯的方法,其包括使有机伯胺或仲胺与一氧化碳源,含有至少一个羟基的有机化合物和硫,硒或碲源在催化剂存在下接触 对于该反应并且在至少一种选自式R1-SS-R2的二硫化物的存在下,其中R 1和R 2包含选自烷基,芳基,环烷基,烷芳基,芳烷基,杂环基 烯基,炔基,烷酰基,芳酰基,上述基团的卤代衍生物,以及前述基团的衍生物,其中一个或多个碳原子被氧原子代替。