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51. 发明申请

US20080188616A1 Method For Production of Bead Polymers With an Average Particle Size in the Range of 1 Micrometer to 40 Micrometers and Moulded Masses and Moulded Bodies Comprising Bead Polymers 审中-公开
标题翻译：平均粒度在1微米至40微米范围内的珠粒聚合物的生产方法和包含珠聚合物的成型体和成型体
公开(公告)号：US20080188616A1
公开(公告)日：2008-08-07
申请号：US11913325
申请日：2006-03-16
申请人： Sabine Scharz-Barac , Klaus Schultes , Michael Schnabel , Stefan Nau , Ursula Golchert
发明人： Sabine Scharz-Barac , Klaus Schultes , Michael Schnabel , Stefan Nau , Ursula Golchert
IPC分类号： C08K3/10
CPC分类号： C08F2/18 , C08F2/44 , C08F212/08 , C08F220/14 , C08F222/1006
摘要： Process for preparation of bead polymers whose average particle size is in the range from 1 μm to 40 μm, by dispersing and polymerizing a polymerizable composition in an aqueous phase, where the dispersion stabilized by an aluminium compound is prepared at a shear rate ≧103 s−1. A polymerizable composition is used here which, in each case based on its total weight, comprises a) more than 50.0% by weight of at least one compound of the formula (I), where the radicals 1R to 6R have definitions according to the Description, b) from 0.1% by weight to 10.0% by weight of at least one crosslinking agent and c) less than 49.9% by weight of at least one compound of the formula (II) where the radicals R and 7R to 9R have definitions according to the Description The bead polymers prepared according to the inventive process are particularly suitable for production of mouldings with light-scattering properties.
摘要翻译：通过在水相中分散和聚合可聚合组合物制备其平均粒度在1〜40μm范围内的珠粒聚合物的方法，其中通过铝化合物稳定的分散体以剪切速率> 10 ^{3 -1 。在这里使用可聚合组合物，其在每种情况下基于其总重量包含a）超过50.0重量％的至少一种式（I）化合物，其中基团R 1 至<6> R具有根据描述的定义，b）0.1重量％至10.0重量％的至少一种交联剂和c）小于49.9重量％的至少一种其中基团R和R 7至R 9 R的式（II）具有根据说明书的定义根据本发明方法制备的珠粒聚合物特别适用于生产具有光散射特性的模制品。}

52. 发明授权

US07381552B2 Macroporous material in the form of plastic pearls 失效
标题翻译：大孔材料以塑料珠的形式
公开(公告)号：US07381552B2
公开(公告)日：2008-06-03
申请号：US10498971
申请日：2003-08-25
申请人： Stefan Menzler , Hans-Ulrich Petereit , Christian Meier , Thomas Boller , Thomas Suefke , Klaus Schultes , Roger Recktenwald
发明人： Stefan Menzler , Hans-Ulrich Petereit , Christian Meier , Thomas Boller , Thomas Suefke , Klaus Schultes , Roger Recktenwald
IPC分类号： C12N11/08 , G01N33/545 , C07K17/08
CPC分类号： C08F220/28 , C08F246/00 , Y10S530/815
摘要： The invention relates to a macroporous plastics bead material with an average particle diameter from 10 to 1000 μm, containing a copolymer of a) 5-60 wt. % vinylically polymerizable monomers with a water solubility of at least 1% at 20° C., b) 1-40 wt. % vinylically polymerizable monomers with an additional functional group, which can enter into covalent bonds with the nucleophilic groups of the ligands in a polymer-like reaction, c) 10-40 wt. % hydrophilic, crosslinking radical-polymerizable monomers with two or more ethylenically unsaturated polymerizable groups and d) 10-60 wt. % vinylically polymerizable monomers with a water solubility of at most 1% at 20° C. are contained, as a rule with the monomers a) to d) adding up to 100%.
摘要翻译：本发明涉及平均粒径为10-1000μm的大孔塑料珠粒材料，其含有a）5-60wt。％乙烯基聚合性单体，水溶性在20℃下至少为1％，b）1-40wt。具有另外的官能团的具有可与聚合物样反应中的配体的亲核基团共价键的乙烯基聚合性单体的％，c）10-40wt。具有两个或更多个烯属不饱和可聚合基团的亲水性交联自由基聚合单体，和d）10-60wt。在20℃下水溶解度最多为1％的％乙烯基聚合性单体的含量通常与单体a）至d）相加至100％。

53. 发明申请

US20070276093A1 Use of Polyalkyl(Meth)Acrylate Bead Polymers and Moulding Material for Producing Extruded Moulded Parts With a Matt Surface 有权
标题翻译：使用聚烷基（甲基）丙烯酸酯珠聚合物和用于生产具有马特表面的挤压成型零件的成型材料
公开(公告)号：US20070276093A1
公开(公告)日：2007-11-29
申请号：US11661651
申请日：2005-08-30
申请人： Klaus Schultes , Peter Battenhausen , Ursula Golchert , Stefan Nau , Werner Hoss
发明人： Klaus Schultes , Peter Battenhausen , Ursula Golchert , Stefan Nau , Werner Hoss
IPC分类号： C08L33/12
CPC分类号： C08L33/12 , C08L2205/02 , C08L2205/18 , C08L2666/04
摘要： The invention relates to the use of polyalkyl(meth)acrylate bead polymers with an average particle size V50 that ranges between 30 and 70 μm for improving the stress cracking resistance of moulding materials containing polyalkyl(meth)acrylate. The invention also relates to moulding materials comprising: a) at least 50 wt. % of an impact resistance modifying agent, which contains at least one polyalkyl(meth)acrylate phase; b) at least 8 wt. % of a polyalkyl(meth)acrylate bead polymer with an average particle size V50 that ranges between 30 and 70 μm; and c) between 0 and 42 wt. % of a polyalkyl(meth)acrylate with a molecular weight ranging between 20,000 and 350,000 g/mol, whereby the wt. % of the components a) to c) amounts to 100 wt. %, and to moulded bodies that can be obtained from said materials.
摘要翻译：本发明涉及使用平均粒径为50〜30μm的聚（甲基）丙烯酸烷基酯聚合物，其范围在30〜70μm之间，以提高包含聚（甲基）丙烯酸烷基酯的成型材料的耐应力开裂性。本发明还涉及成型材料，其包含：a）至少50wt。％的耐冲击改性剂，其含有至少一种（甲基）丙烯酸烷基酯相; b）至少8wt。％的平均粒度V 50 N（30-30）的聚（甲基）丙烯酸烷基酯烷基酯聚合物; 和c）0至42wt。％的分子量在20,000和350,000g / mol之间的聚（甲基）丙烯酸烷基酯，其中wt。组分a）至c）的％相当于100wt。％，以及可以从所述材料获得的成型体。

54. 发明申请

US20070123610A1 PMMA MOULDING COMPOUNDS WITH IMPROVED IMPACT RESISTANCE 失效
标题翻译：具有改善抗冲击性的PMMA模塑化合物
公开(公告)号：US20070123610A1
公开(公告)日：2007-05-31
申请号：US11562669
申请日：2006-11-22
申请人： Klaus Schultes , Thomas Suefke , Reiner Mueller , Thomas Arndt , Goerg Michler , Joachim Laatsch
发明人： Klaus Schultes , Thomas Suefke , Reiner Mueller , Thomas Arndt , Goerg Michler , Joachim Laatsch
IPC分类号： C09D151/00
CPC分类号： C08F285/00 , C08F265/04 , C08F265/06 , C08L51/003 , Y10S525/902 , C08L2666/02
摘要： The invention describes a novel impact modifier, built up from core-shell1- and shell 2, the core being capable of plastic deformation. Good mechanical properties were achieved using a small amount of impact modifier.
摘要翻译：本发明描述了一种由核 - 壳1和壳2构成的新型抗冲击改性剂，该芯能够塑性变形。使用少量的抗冲改性剂可获得良好的机械性能。

55. 发明申请

US20070066708A1 Molding material containing a matting agent 有权
标题翻译：含有消光剂的成型材料
公开(公告)号：US20070066708A1
公开(公告)日：2007-03-22
申请号：US10579843
申请日：2004-09-15
申请人： Thorsten Goldacker , Andreas Spiess , Reiner Mueller , Klaus Schultes , Uwe Numrich
发明人： Thorsten Goldacker , Andreas Spiess , Reiner Mueller , Klaus Schultes , Uwe Numrich
IPC分类号： C09D11/00
CPC分类号： C08L51/003 , C08F265/04 , C08F265/06 , C08F279/02 , C08L33/12 , C08L35/06 , C08L55/02 , C08L101/00 , C08L2205/22 , C08L2666/02 , C08L2666/04
摘要： The invention relates to a moulding composition, comprising a) 50 to 99.9% by weight of a matrix composed of a thermoplastic polymer and b) from 0.1 to 50% by weight of a matting agent in the form of a (meth)acrylate copolymer dispersed in the matrix, characterized in that the matting agent is a (meth)acrylate copolymer which has been prepared from the following monomers, b1) from 50 to 95% by weight of methyl methacrylate b2) from 5 to 50% by weight of C1-C6-alkyl acrylates b3) from 0.01 to less than 0.5% by weight of a crosslinking monomer and/or graft-linking agent having two or more ethylenically unsaturated radicals capable of free-radical polymerization, b4) from 0 to 20% by weight of one or more other, non-crosslinking ethylenically unsaturated monomers capable of free-radical polymerization, where the entirety of the constituents b1) and b2) and, where appropriate, b3) and/or b4) gives 100% by weight, and the glass transition temperature Tmg of the matting agent is at least 20° C.
摘要翻译：本发明涉及一种模塑组合物，其包含a）50-99.9重量％的由热塑性聚合物组成的基质和b）0.1至50重量％的分散在（甲基）丙烯酸酯共聚物形式的消光剂在基质中，其特征在于消光剂是由以下单体制备的（甲基）丙烯酸酯共聚物，b1）50-95重量％的甲基丙烯酸甲酯b2）5-50重量％烷基丙烯酸酯b3）0.01至小于0.5重量％的交联单体和/或具有两个或更多个烯属不饱和基团的接枝交联剂的自由基聚合，b4）0至20重量％的一种或多种能够进行自由基聚合的其它非交联烯键式不饱和单体，其中组分b1）和b2的整体），并且在适当的情况下， b3）和/或b4）给出100重量％，玻璃化转变温度T 消光剂至少为20℃

56. 发明授权

US06906142B2 Molding materials exhibiting an improved low-temperature impact resistance 失效
标题翻译：具有改善的耐低温冲击性的成型材料
公开(公告)号：US06906142B2
公开(公告)日：2005-06-14
申请号：US10415100
申请日：2001-10-22
申请人： Klaus Schultes , Michael Wicker , Werner Hoess , Klaus Albrecht , Hans-Juergen Kress
发明人： Klaus Schultes , Michael Wicker , Werner Hoess , Klaus Albrecht , Hans-Juergen Kress
IPC分类号： C08F265/04 , C08F285/00 , C08L25/12 , C08L33/08 , C08L33/12 , C08L51/00 , C08L51/08 , C08L55/02 , C08L33/04 , C08L33/18 , C08L33/20 , C08L35/02 , C08L43/00
CPC分类号： C08L51/003 , C08F265/04 , C08F285/00 , C08L25/12 , C08L33/08 , C08L33/12 , C08L51/08 , C08L51/085 , C08L55/02 , C08L2666/02 , C08L2666/04
摘要： The invention relates to an impact-modified moulding composition which has particularly high impact resistance at low temperatures (−20° C., −40° C.). This low-temperature impact resistance is achieved by using a silicone elastomer.
摘要翻译：本发明涉及在低温（-20℃，-40℃）下具有特别高的抗冲击性的冲击改性模塑组合物。这种低温耐冲击性通过使用有机硅弹性体来实现。

57. 发明授权

US06890993B2 PMMA molding materials exhibiting an improved low-temperature impact resistance 失效
标题翻译：具有改善的耐低温冲击性的PMMA成型材料
公开(公告)号：US06890993B2
公开(公告)日：2005-05-10
申请号：US10415106
申请日：2001-10-22
申请人： Klaus Schultes , Michael Wicker , Werner Hoess , Klaus Albrecht , Hans-Juergen Kress
发明人： Klaus Schultes , Michael Wicker , Werner Hoess , Klaus Albrecht , Hans-Juergen Kress
IPC分类号： C08L25/12 , C08L33/08 , C08L33/12 , C08L51/08 , C08L27/10 , C08L33/04 , C08L33/18 , C08L35/02 , C08L43/00
CPC分类号： C08L25/12 , C08L33/08 , C08L33/12 , C08L51/085 , C08L2666/02
摘要： The invention relates to an impact-modified molding composition which has particularly high impact resistance at low temperatures (−20° C., −40° C.). This low-temperature impact resistance is achieved by using a silicone elastomer.
摘要翻译：本发明涉及在低温（-20℃，-40℃）下具有特别高的抗冲击性的冲击改性模塑组合物。这种低温耐冲击性通过使用有机硅弹性体来实现。

58. 发明授权

US09062211B2 Reactive mixture for coating molded objects by means of reaction injection molding and coated molded object 有权
标题翻译：通过反应注射成型和涂覆成型物体涂覆成型物体的反应性混合物
公开(公告)号：US09062211B2
公开(公告)日：2015-06-23
申请号：US13546084
申请日：2012-07-11
申请人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Hoess , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
发明人： Klaus Schultes , Thorsten Goldacker , Klaus Koralewski , Werner Hoess , Ghirmay Seyoum , Elevtherios Gross , Erwin Felger
IPC分类号： B32B27/08 , B32B27/28 , B32B5/00 , B32B27/30 , B32B27/32 , C09D4/00 , C08F4/32 , C08F2/46 , B29C45/16 , B29C45/00
CPC分类号： C09D4/00 , B29C45/0001 , B29C45/1679 , C08F2/46 , C08F4/32 , Y10T428/263 , Y10T428/264 , Y10T428/31721 , Y10T428/31913 , Y10T428/31924 , Y10T428/31928
摘要： A reactive mixture for coating moldings by reaction injection molding includes at least 40% by weight of (meth)acrylates having at least two double bonds. The reactive mixture also includes at least one photoinitiator and at least one thermal initiator. Furthermore, a coated molding includes a molding obtainable by injection molding processes. The molding includes polymethyl methacrylate, polymethylmethacrylimide, styrene-acrylonitrile copolymer, styrene-maleic acid copolymer, polymethyl methacrylate copolymer, or a combination thereof. A coating is obtainable by polymerization of (meth)acrylates having at least two double bonds, the coating having an adhesive strength rating of not more than 1 according to the cross hatch test and a decrease in gloss at 20° after a scratch resistance test according to ASTM 1044 (12/05) (applied weight 500 g, number of cycles=100) of not more than 10%.
摘要翻译：用于通过反应注射成型涂覆模制品的反应性混合物包括至少40重量％的具有至少两个双键的（甲基）丙烯酸酯。反应性混合物还包括至少一种光引发剂和至少一种热引发剂。此外，涂覆的模制品包括可通过注射成型工艺获得的模制品。该模塑件包括聚甲基丙烯酸甲酯，聚甲基丙烯酰胺，苯乙烯 - 丙烯腈共聚物，苯乙烯 - 马来酸共聚物，聚甲基丙烯酸甲酯共聚物或其组合。可以通过聚合具有至少两个双键的（甲基）丙烯酸酯来获得涂层，该涂层根据交叉影线试验具有不大于1的粘合强度等级，并且在耐刮擦性试验后在20°下的光泽度降低至ASTM 1044（12/05）（施加重量500g，循环数= 100）不大于10％。

59. 发明授权

US08759450B2 Plastics moulding compositions, and mouldings and production processes 有权
标题翻译：塑料模塑组合物，模制品和生产工艺
公开(公告)号：US08759450B2
公开(公告)日：2014-06-24
申请号：US13377579
申请日：2009-07-07
申请人： Werner Hoess , Klaus Schultes , Guomin Liu
发明人： Werner Hoess , Klaus Schultes , Guomin Liu
IPC分类号： C08L33/12 , C08L51/00 , C08J5/18 , B29C45/00
CPC分类号： C08L33/12 , C08L51/003 , C08L2205/02 , C08L2666/04
摘要： The present invention relates to a plastics molding composition encompassing at least one poly(meth)acrylate A) and at least one impact-modified poly(meth)acrylate B), wherein the die swell of the plastics molding composition is at least 15%, measured at 5 MPa and 2200C to DIN 54811 (1984), and the melt flow rate of the poly(meth)acrylate A) is at least 10 ml per 10 minutes, measured to ISO 1133 at 2300C with a load of 3.8 kg. The present invention also describes moldings which encompass the plastics molding composition described above, and processes for the production of the said moldings.
摘要翻译：本发明涉及包含至少一种聚（甲基）丙烯酸酯A）和至少一种冲击改性聚（甲基）丙烯酸酯B）的塑料模制组合物，其中塑料模制组合物的模头膨胀至少为15％在5MPa和220℃下根据DIN 54811（1984）测量，并且聚（甲基）丙烯酸酯A）的熔体流动速率为至少10分钟/ 10分钟，在2300℃下测量为ISO 1133，载荷为3.8千克。本发明还描述了包含上述塑料模制组合物的模制品以及用于生产所述模制品的方法。

60. 发明授权

US08722788B2 Transparent TPU (thermoplastic polyurethanes)/PMMA (polymethyl (meth) acrylate) blends with improved low-temperature impact resistance 有权
标题翻译：透明TPU（热塑性聚氨酯）/ PMMA（聚甲基丙烯酸甲酯）丙烯酸酯）具有改善的耐低温冲击性能
公开(公告)号：US08722788B2
公开(公告)日：2014-05-13
申请号：US12094277
申请日：2006-08-28
申请人： Klaus Schultes , Peter Battenhausen , Ursula Golchert , Adalbert Loidl
发明人： Klaus Schultes , Peter Battenhausen , Ursula Golchert , Adalbert Loidl
IPC分类号： C08G18/08 , C08L75/00 , C08F8/30
CPC分类号： C08L33/12 , C08L33/10 , C08L75/04 , C08L2666/20 , C08L2666/04
摘要： The invention describes transparent plastics mixtures having low-temperature impact resistance composed of a thermoplastic polyurethane (TPU) and of an impact-modified poly(meth)acrylate (PMMA).
摘要翻译：本发明描述了由热塑性聚氨酯（TPU）和冲击改性聚（甲基）丙烯酸酯（PMMA）组成的具有低温耐冲击性的透明塑料混合物。

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