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51. 发明申请

US20120216870A1 INTERLAYER FOR ORGANIC SOLAR CELLS 审中-公开
标题翻译：有机太阳能电池中间层
公开(公告)号：US20120216870A1
公开(公告)日：2012-08-30
申请号：US13505562
申请日：2010-11-02
申请人： Franky So , Jegadesan Subbiah , John R. Reynolds , Chad Martin Amb , Pierre Marc Beaujuge
发明人： Franky So , Jegadesan Subbiah , John R. Reynolds , Chad Martin Amb , Pierre Marc Beaujuge
IPC分类号： H01L51/46
CPC分类号： H01L51/4273 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0043 , H01L51/441 , H01L2251/308 , Y02E10/549
摘要： An organic PV solar cell that has an anode double interlayer situated between an electrode and an organic photoactive layer displays superior power conversion efficiency over that of equivalent devices with an anode single interlayer. The anode double layer can comprise a hole extraction layer adjacent to the anode and an organic hole accepting electron blocking material layer that comprises an aromatic amine compound with a plurality of N atoms. The hole extraction layer can be a metal oxide or an n-type organic semiconductor.
摘要翻译：具有位于电极和有机光活性层之间的阳极双层间隔的有机PV太阳能电池相对于具有阳极单中间层的等效器件的功率转换效率显示出优异的功率转换效率。阳极双层可以包括邻近阳极的空穴提取层和包含具有多个N原子的芳族胺化合物的有机孔接受电子阻挡材料层。空穴提取层可以是金属氧化物或n型有机半导体。

52. 发明申请

US20120120643A1 SOLAR-POWERED LIGHTING MODULE 有权
标题翻译：太阳能照明模块
公开(公告)号：US20120120643A1
公开(公告)日：2012-05-17
申请号：US13319981
申请日：2010-06-02
申请人： Ying S. Meng , Franky So , Jiangeng Xue , Karl R. Zawoy , John R. Reynolds
发明人： Ying S. Meng , Franky So , Jiangeng Xue , Karl R. Zawoy , John R. Reynolds
IPC分类号： F21S9/03
CPC分类号： F21S9/037 , B82Y10/00 , E06B9/24 , E06B2009/2464 , E06B2009/247 , E06B2009/2476 , H01L27/281 , H01L27/288 , H01L27/3232 , H01L51/0036 , H01L51/0047 , H01L51/4253 , H01L2251/5323 , H01L2251/5361
摘要： A solar-powered lighting module is provided, including a solar cell for generating electricity when exposed to light, a battery for storing charge from the generated electricity, and a light generating device powered by the stored charge. In an embodiment, the module further includes a controller that regulates the current transmitted between the components of the module. In a further embodiment, the module is incorporated into an interface to an environmentally controlled space and can be positioned to light an interior portion of the space. In another embodiment, the solar cell and light generating device are transparent to allow light to pass through the interface. In a further embodiment, tinted-color conjugated polymers incorporated into the module limit the spectrum of light that can pass through the interface. In yet another embodiment, a method of modifying an existing interface with such a module is provided.
摘要翻译：提供了一种太阳能照明模块，其包括用于在暴露于光时发电的太阳能电池，用于存储来自发电的电荷的电池以及由所存储的电荷供电的发光装置。在一个实施例中，模块还包括控制器，其调节在模块的组件之间传输的电流。在另一个实施例中，该模块被结合到与环境受控的空间的界面中，并且可以被定位成照亮该空间的内部部分。在另一个实施例中，太阳能电池和发光装置是透明的，以允许光通过界面。在另一个实施方案中，结合到模块中的着色共轭聚合物限制可以通过界面的光谱。在另一个实施例中，提供了一种使用这种模块修改现有接口的方法。

53. 发明申请

US20120108778A1 CATHODICALLY COLORING YELLOW SOLUBLE ELECTROCHROMIC AND LIGHT EMITTING POLYMERS 有权
标题翻译：阴极颜色黄色可溶性电致发光和发光聚合物
公开(公告)号：US20120108778A1
公开(公告)日：2012-05-03
申请号：US13282999
申请日：2011-10-27
申请人： CHAD MARTIN AMB , Justin Adam Kerszulis , John R. Reynolds , Aubrey Lynn Dyer , Emily Thompson
发明人： CHAD MARTIN AMB , Justin Adam Kerszulis , John R. Reynolds , Aubrey Lynn Dyer , Emily Thompson
IPC分类号： C08G75/06 , B05D5/12 , B05D1/04 , B05D5/06
CPC分类号： C09K9/02 , C07D495/04 , C09K2211/1458 , C09K2211/1466
摘要： Embodiments of the invention are directed to yellow-to-transmissive conjugated polymers, a method to prepare the yellow conjugated polymers, the use of the yellow conjugated polymers in an electrochromic and/or electroluminescent device comprising neutral state primary subtractive colored conjugated polymers, and a method to prepare the device comprising the yellow conjugated polymer. The yellow conjugated polymers comprise a sequence of dioxythiophene units alternating with aromatic units, thiophene units, furan units, and/or pyrrole units. The yellow conjugated polymers are prepared by cross-condensation reactions. The yellow conjugated polymers can be soluble and preparation of the device involves deposition of the yellow conjugated polymer from solution onto a surface.
摘要翻译：本发明的实施方案涉及黄色至透射的共轭聚合物，制备黄色共轭聚合物的方法，在含有中性状态的主要减色共轭聚合物的电致变色和/或电致发光装置中使用黄色共轭聚合物，以及制备包含黄色共轭聚合物的装置的方法。黄色共轭聚合物包含与芳族单元，噻吩单元，呋喃单元和/或吡咯单元交替的二氧噻吩单元的序列。通过交联缩合反应制备黄色共轭聚合物。黄色共轭聚合物可以是可溶的，并且该装置的制备涉及将黄色共轭聚合物从溶液沉积到表面上。

54. 发明申请

US20110062860A1 INTERDIGITATED ELECTRODE DUAL ELECTROEMISSIVE/ELECTROCHROMIC DEVICES 有权
标题翻译：互连电极双电化学/电致变色器件
公开(公告)号：US20110062860A1
公开(公告)日：2011-03-17
申请号：US12936854
申请日：2009-04-15
申请人： John R. Reynolds , Aubrey Lynn Dyer
发明人： John R. Reynolds , Aubrey Lynn Dyer
IPC分类号： H01J1/62
CPC分类号： H01L51/5203 , G02F1/155
摘要： A dual electrochromic/electroluminescent (EC/EL) device of at least one pixel includes an interdigitated electrode where an electroactive layer is dispersed on and between the digits of the two electrodes of the interdigitated electrode. The electroactive layer is in contact with an electrolyte layer that also contacts a third electrode. The device acts as an electroluminescence device when an electrical bias between the two electrodes of the interdigitated electrode is established. The device acts as an electrochromic device when the electrical bias is established between the combined electrodes of the interdigitated electrode and the third electrode.
摘要翻译：至少一个像素的双电致变色/电致发光（EC / EL）器件包括交叉电极，其中电活性层分散在交叉电极的两个电极的数位之间和之间。电活性层与也与第三电极接触的电解质层接触。当建立交叉电极的两个电极之间的电偏压时，该器件用作电致发光器件。当在交叉电极和第三电极的组合电极之间建立电偏压时，器件用作电致变色器件。

55. 发明申请

US20110003967A1 SOLUBLE ALTERNATING DONOR-ACCEPTOR CONJUGATED POLYMER ELECTROCHROMES 有权
标题翻译：可溶性交替共轭聚合物聚合物电解质
公开(公告)号：US20110003967A1
公开(公告)日：2011-01-06
申请号：US12829903
申请日：2010-07-02
申请人： Chad Martin Amb , Pierre Marc Beaujuge , John R. Reynolds
发明人： Chad Martin Amb , Pierre Marc Beaujuge , John R. Reynolds
IPC分类号： C08G75/06
CPC分类号： C08G75/02 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/3223 , C08G2261/3243 , C08G2261/3246 , C09K9/02 , C09K2211/1458 , C09K2211/1483 , G02F2001/1512 , G02F2001/1515 , H01L51/0043 , H01L51/0558
摘要： Embodiments of the invention are directed to alternating donor-acceptor (DA) polymers that are soluble and display a blue or green neutral state that oxidizes to a transmissive state for use as an electrochromic polymer. The D units have 3,4-dioxythiophene, 3,6-dialkoxythieno[3,2-b]thiophene or 3,5-dialkoxy-dithieno[3,2-b:2′,3′-d]thiophene groups. Embodiments of the invention are directed to a method for preparation of the alternating DA polymeric sequences of the DA polymers by a cross-condensation of a nucleophilic acceptor monomer and an electrophilic donor monomer.
摘要翻译：本发明的实施方案涉及交替的供体 - 受体（DA）聚合物，其可溶并显示蓝色或绿色中性状态，其氧化成透射状态以用作电致变色聚合物。 D单元具有3,4-二氧噻吩，3,6-二烷氧基噻吩并[3,2-b]噻吩或3,5-二烷氧基 - 二噻吩并[3,2-b：2'，3'-d]噻吩基团。本发明的实施方案涉及通过亲核受体单体和亲电子供体单体的交叉缩合制备DA聚合物的交替DA聚合物序列的方法。

56. 发明申请

US20100298527A1 GREEN TO TRANSMISSIVE SOLUBLE ELECTROCHROMIC POLYMERS 有权
标题翻译：绿色传输可溶电解聚合物
公开(公告)号：US20100298527A1
公开(公告)日：2010-11-25
申请号：US12740570
申请日：2008-10-29
申请人： Pierre Marc Beaujuge , John R. Reynolds , Stefan Martin Ellinger
发明人： Pierre Marc Beaujuge , John R. Reynolds , Stefan Martin Ellinger
IPC分类号： C08G75/06
CPC分类号： C09K9/02 , C08G61/123 , C08G61/126 , C09K2211/1491
摘要： Green to transmissive soluble electrochromic polymers are conjugated polymers having a plurality of repeating units where repeating units are a plurality of substituted dioxyheterocycle based donor groups coupled to an acceptor group. The conjugated polymer absorbs radiation within a first band of the visible spectrum and a second band of the visible spectrum when in a neutral state resulting in a green color and is transmissive when in an oxidized state. The polymers are soluble allowing processing of films and coatings from solution.
摘要翻译：绿色至透射的可溶性电致变色聚合物是具有多个重复单元的共轭聚合物，其中重复单元是与受体基团偶联的多个取代的基于双氧杂环的供体基团。共轭聚合物在中性状态下吸收可见光谱的第一条带内的可见光谱的第二条带和产生绿色的可见光谱的第二条带，并且当处于氧化状态时是透射的。聚合物是可溶的，允许从溶液中处理膜和涂层。

57. 发明授权

US07807758B2 Chemical defunctionalization of polymeric alkylenedioxyheterocyclics 有权
标题翻译：聚合亚烷基二氧杂环化合物的化学去官能化
公开(公告)号：US07807758B2
公开(公告)日：2010-10-05
申请号：US12158941
申请日：2007-01-25
申请人： John R. Reynolds , Benjamin Dennis Reeves
发明人： John R. Reynolds , Benjamin Dennis Reeves
IPC分类号： C08G73/02
CPC分类号： C08G61/122 , C08G61/124 , C08G61/125 , C08G61/126 , C08G2261/1426 , C08G2261/3223 , C08G2261/80 , H01B1/127 , H01L51/0037
摘要： A method for preparing a defunctionalized alkylenedioxyheterocycle polymer or copolymer involves providing a polycarboxylic acid derivative functionalized alkylenedioxyheterocycle polymer or copolymer and transforming the polymer or copolymer into a defunctionalized alkylenedioxyheterocycle polymer or copolymer which is polyhydroxy, polythiol, polyamino, or polycarboxylic acid functionalized alkylenedioxyheterocycle polymer or copolymer. The monomers, homopolymers and copolymers for use in the method are new compositions of matter. The polymers containing polycarboxylic acid derivative functionalized alkylenedioxyheterocycle units are soluble polymers which are defunctionalized to yield insoluble polyhydroxy, polythiol, polyamino, or polycarboxylic acid functionalized alkylenedioxyheterocycle polymers. These polymers can be cast as films for use as: hole transport layers in organic light emitting diodes; active electrochrome in electrochromic windows, mirrors and displays; field effect transistors, supercapacitors, batteries, photovoltaic cells, and other electronic components; electronic paper; anti-stat conductors; and transparent conductors.
摘要翻译：制备非官能化的亚烷基二氧杂环聚合物或共聚物的方法包括提供多元羧酸衍生物官能化的亚烷基二氧杂环化合物或共聚物，并将聚合物或共聚物转化成功能化的亚烷基二氧杂环化合物或共聚物，其是多羟基，多硫醇，聚氨基或多元羧酸官能化亚烷基二氧杂环化合物或共聚物。用于该方法的单体，均聚物和共聚物是物质的新组合物。含有多元羧酸衍生物官能化亚烷基二氧杂环单元的聚合物是可溶性聚合物，其被去官能化以产生不溶性多羟基，多硫醇，聚氨基或多元羧酸官能化亚烷基二氧杂环聚合物。这些聚合物可以浇铸成膜，用作有机发光二极管中的空穴传输层; 电致变色窗，反光镜和显示屏中的主动电镀; 场效应晶体管，超级电容器，电池，光伏电池等电子部件; 电子纸; 防静电导体; 和透明导体。

58. 发明授权

US07557499B2 Dual light emitting and electrochromic device 有权
标题翻译：双重发光和电致变色装置
公开(公告)号：US07557499B2
公开(公告)日：2009-07-07
申请号：US11576616
申请日：2005-10-20
申请人： John R. Reynolds
发明人： John R. Reynolds
IPC分类号： H01L51/50 , H05B33/00 , G02F1/15 , G02F1/153
CPC分类号： H01L27/3232 , G02F1/155
摘要： A combined electrochromic/electroluminescent device includes at least one pixel 101-104. Each pixel includes a substrate 107 having an electrically conductive surface 105, and an electrochemically active counter electrode layer 110 disposed on the electrically conductive surface. An electrolyte layer 115 which provides electrolytes is disposed on the counter electrode 110. An electrically conductive layer 125 is disposed on the electrolyte layer 115. An electroactive layer 130 is disposed on the electrically conductive layer 125, the electroactive layer providing both electroluminescence and an electrochromically active working electrode, wherein the electrically conductive layer 125 provides transport of electrolytes therethrough.
摘要翻译：组合的电致变色/电致发光器件包括至少一个像素101-104。每个像素包括具有导电表面105的基板107和设置在导电表面上的电化学活性对置电极层110。提供电解质的电解质层115设置在对电极110上。导电层125设置在电解质层115上。电活性层130设置在导电层125上，电活性层提供电致发光和电致变色主动工作电极，其中导电层125提供电解质通过其的输送。

59. 发明申请

US20080299030A1 HIGHLY ACCESSIBLE, NANOTUBE ELECTRODES FOR LARGE SURFACE AREA CONTACT APPLICATIONS 有权
标题翻译：高可接触性，用于大面积面积的纳米电极接触应用
公开(公告)号：US20080299030A1
公开(公告)日：2008-12-04
申请号：US11853963
申请日：2007-09-12
申请人： Andrew Gabriel Rinzler , John R. Reynolds , Rajib Kumar Das
发明人： Andrew Gabriel Rinzler , John R. Reynolds , Rajib Kumar Das
IPC分类号： D01F9/12 , B05D5/12 , C25D15/00 , B32B5/14
CPC分类号： H01G11/36 , B82Y10/00 , H01L51/444 , Y02E60/13 , Y10S977/75 , Y10T428/24603
摘要： An highly porous electrically conducting film that includes a plurality of carbon nanotubes, nanowires or a combination of both. The highly porous electrically conducting film exhibits an electrical resistivity of less than 0.1 O·cm at 25 C and a density of between 0.05 and 0.70 g/cm3. The film can exhibit a density between 0.50 and 0.85 g/cm3 and an electrical resistivity of less than 6×1031 3 O·cm at 25 C. Also included is a method of forming these highly porous electrically conducting films by forming a composite film using carbon nanotubes or nanowires and sacrificial nanoparticles or microparticles. At least a portion of the nanoparticles or microparticles are then removed from the composite film to form the highly porous electrically conducting film.
摘要翻译：包括多个碳纳米管，纳米线或两者的组合的高度多孔的导电膜。高度多孔的导电膜在25℃下的电阻率小于0.1Ωcm，密度为0.05-0.70g / cm3。该薄膜可以在25℃下显示出0.50至0.85g / cm 3的密度和小于6×10 31 3 O.cm的电阻率。还包括通过使用碳纳米管形成复合膜来形成这些高度多孔的导电膜的方法或纳米线和牺牲纳米颗粒或微粒。然后从复合膜中除去至少一部分纳米颗粒或微粒，以形成高度多孔的导电膜。

60. 发明申请

US20080287638A1 Supramolecular Polymers Associative to Carbon Nanotubes 审中-公开
标题翻译：超分子聚合物与碳纳米管相关
公开(公告)号：US20080287638A1
公开(公告)日：2008-11-20
申请号：US12123347
申请日：2008-05-19
申请人： John R. Reynolds , Ryan M. Walczak , Eveline Maria van der Aa , Andrew Gabriel Rinzler
发明人： John R. Reynolds , Ryan M. Walczak , Eveline Maria van der Aa , Andrew Gabriel Rinzler
IPC分类号： C08G18/10
CPC分类号： C08G18/73 , B29C73/163 , B29C73/22 , B82Y30/00 , C08G18/2865 , C08J5/005
摘要： A supramolecular polymer and its composite with carbon nanotubes, CNTs, are described. The supramolecular polymer is an ensemble of precursors that independently contain “sticky feet” for non-covalent binding to carbon nanotube surfaces and associative groups. There is at least one of the associative groups covalently bound to each of the precursor and there is at least one covalently connecting moiety connecting associative groups within a precursor or connecting an associative group to a linker to a “sticky foot” in a precursor. When the associative groups are in a dissociative state, the supramolecular polymer precursors and CNTs can be combined to form a dispersion. Upon promotion, the dissociated associative groups in the dispersion can associate to yield a CNT/supramolecular polymer composite.
摘要翻译：描述了超分子聚合物及其与碳纳米管，CNT的复合物。超分子聚合物是独立包含用于非共价结合碳纳米管表面和缔合基团的“粘性脚”的前体的组合。至少有一个共价基团与每个前体共价结合，并且存在至少一个共价连接部分，其连接前体内的缔合基团或将缔合基团连接到前体中的“粘脚”。当缔合基团处于解离状态时，可以将超分子聚合物前体和CNT组合形成分散体。促进时，分散体中的离解的缔合基团可以缔合以产生CNT /超分子聚合物复合物。

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