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    • 55. 发明授权
    • Substituted 5-aminopyrazoles
    • US5486618A
    • 1996-01-23
    • US70386
    • 1993-06-07
    • Helmut HagenGerhard NilzHelmut WalterAndreas Landes
    • Helmut HagenGerhard NilzHelmut WalterAndreas Landes
    • A01N43/56A01N25/32C07D231/38C07D231/40C07D309/12C07D335/02C07D403/04C07D231/00
    • C07D403/04A01N25/32C07D231/40
    • Substituted 5-aminopyrazoles I ##STR1## where R.sup.1 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -hydroxyalkyl, phenyl which may carry 1-3 of the following radicals: halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or --NR.sup.6 R.sup.7, and which may additionally carry a number of halogen atoms so that the total number of radicals is 5, R.sup.6 and R.sup.7 are each H or C.sub.1 -C.sub.4 -alkyl, R.sup.2 is H, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl, R.sup.3 is CN, --CO--R.sup.8 or --CS--R.sup.8, R.sup.8 is OH, C.sub.1 -C.sub.4 -alkoxy, NH.sub.2, C.sub.1 -C.sub.4 -alkylamino or di-C.sub.1 -C.sub.4 -alkylamino, R.sup.4 and R.sup.5 are each H, C.sub.1 -C.sub.4 -alkyl, PX(OR.sup.9).sub.2, --SO.sub.2 --R.sup.9, --CX--R.sup.10, --CX--NH--CY--R.sup.9 or CX--NH--SO.sub.2 --R.sup.11, X and Y are each O or S, R.sup.9 is one of the substituents R.sup.1, R.sup.10 is C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.4 -alkoxy, unsubstituted or substituted phenyl or unsubstituted or substituted NH.sub.2, R.sup.11 is NH.sub.2, C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, pyrrolidinyl, piperidinyl or morpholinyl, R.sup.4 and R.sup.5 together form a group .dbd.CR.sup.12 R.sup.13 or --CO--W--CO--, R.sup.12 is H, NH.sub.2, C.sub.1 -C.sub.4 -alkylamino or C.sub.3 -C.sub.8 -cycloalkylamino, R.sup.13 is NH.sub.2, C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C.sub.3 -C.sub.8 -cycloalkylamino, pyrrolidin-1-yl, piperidin-1-yl, morpholin-4-yl, unsubstituted or substituted phenyl or unsubstituted or substituted pyridyl and W is an unsubstituted or substituted ethylene or ethenylene bridge, an unsubstituted or substituted 5-membered or 6-membered 1,2-C-bonded aromatic or heteroaromatic bridge, or an unsubstituted or substituted 5-membered or 6-membered 1,2-C-bonded cycloalkylene or cycloalkenylene bridge,and the basic salts of the compounds I in which R.sup.3 is hydroxycarbonyl or hydroxythiocarbonyl, and the acidic salts of the compounds I which contain a basic nitrogen atom,with the exception of 1-phenyl- and 1-methyl-4-cyano-5-acylaminopyrazole, 1-methyl-4-cyano-5-(chloromethylcarbonylamino)-pyrazole, 1-methyl-4-cyano-5-(phenylcarbonylamino)-pyrazole, 1-methyl-4-cyano-5-(p-chlorophenylcarbonylamino)-pyrazole and the compounds I in which R.sup.1 is methyl, phenyl, 4-chlorophenyl or 4-nitrophenyl, R.sup.2 is hydrogen, methyl or trifluoromethyl, R.sup.3 is cyano and R.sup.4 and R.sup.5 are simultaneously hydrogen, and herbicides which contain 2-(4-hetaryloxy)- and 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives and/or cyclohexenone derivatives as herbicidal active ingredients and substituted 5-aminopyrazoles I' or, in the case of acidic terminal groups or basic nitrogen atoms, the salts of I' as antidotes.
    • 56. 发明授权
    • Process for handling liquid radioactive waste
    • 处理液体放射性废物的过程
    • US5430227A
    • 1995-07-04
    • US007053
    • 1993-01-21
    • Dietmar ErbseReinhard ThieleHelmut Walter
    • Dietmar ErbseReinhard ThieleHelmut Walter
    • F26B25/22G21F9/08G21F9/00
    • G21F9/08F26B25/22
    • A process for handling liquid radioactive waste includes evaporating liquid radioactive waste with condensation of vapors; refilling the waste during the evaporation; and measuring a condensate quantity and controlling the refilling with the measure of the condensate quantity. A device for handling liquid radioactive waste includes a device for evaporating liquid radioactive waste with condensation of vapors; a device for refilling the waste during the evaporation; a measuring vessel for collecting condensate; a valve for controlled drainage of the condensate from the measuring vessel; and a device connected to the valve for determining the condensate quantity removed from said measuring vessel. The device for determining the condensate quantity removed controls the refilling of the waste in accordance with the condensate quantity removed.
    • 处理液体放射性废物的过程包括用蒸气冷凝蒸发液体放射性废物; 在蒸发期间重新填充废物; 并测量冷凝液的量,并通过测量冷凝液量来控制再填充。 用于处理液体放射性废物的装置包括用于蒸发具有蒸气冷凝的液体放射性废物的装置; 用于在蒸发期间重新填充废物的装置; 用于收集冷凝物的测量容器; 用于从测量容器控制排出冷凝物的阀; 以及连接到阀的装置,用于确定从所述测量容器移除的冷凝物量。 用于确定去除的冷凝物量的装置根据去除的冷凝物量控制废物的再填充。
    • 60. 发明授权
    • Process and filling adapter for the in-drum drying of liquid radioactive
waste
    • 用于液体放射性废物的滚筒内干燥的工艺和灌装适配器
    • US5378410A
    • 1995-01-03
    • US7055
    • 1993-01-21
    • Dietmar ErbseReinhard ThieleHelmut Walter
    • Dietmar ErbseReinhard ThieleHelmut Walter
    • F26B9/06G21F9/08G21F9/22
    • F26B9/06G21F9/08Y10S159/12Y10S422/903
    • A process for in-drum drying of liquid radioactive waste includes sealing a shielded container by placing a plug in a central opening formed in a lid of the container. The plug is removed from the opening and a filling adapter having an outside diameter that fits the opening is inserted into the opening. To measure the fill level a sensor is inserted into the filling adapter and protrudes from a free end of the filling adapter into the interior of the container. Liquid radioactive waste is poured into the sealed container and vapors are vented from the container, through the filling adapter. The liquid radioactive waste is heated in the container with a heater. A filling adapter for in-drum drying of liquid radioactive waste includes a rectilinear, preferably cylindrical steel casing with end regions, an outer periphery, a flange protruding past the outer periphery at one of the end regions, at least two connection points at another of the end regions, and a filling line extending from one of the connection points through the steel casing.
    • 用于液体放射性废物的滚筒内干燥的方法包括通过将栓塞放置在形成在容器的盖中的中心开口来密封屏蔽的容器。 将塞子从开口中取出,并且具有适合于开口的外径的填充适配器插入到开口中。 为了测量填充水平,将传感器插入到填充适配器中并从填充适配器的自由端突出到容器的内部。 将液体放射性废物倒入密封容器中,蒸气通过填充适配器从容器中排出。 液体放射性废物在容器中用加热器加热。 用于液体放射性废物的滚筒内干燥的填充适配器包括具有端部区域的直线的,优选圆柱形的钢壳体,外周边缘,凸缘经过端部区域中的一个的外周边的凸缘,在另一个端部区域的至少两个连接点 端部区域和从一个连接点通过钢壳体延伸的填充线。