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51. 发明授权

US5167690A Tetrahydroindazoles with a phenyl ether structures, herbicidal compositions and use 失效
标题翻译：具有苯基醚结构的四氢吲唑，除草组合物和用途
公开(公告)号：US5167690A
公开(公告)日：1992-12-01
申请号：US592906
申请日：1990-10-04
申请人： Lothar Rueb , KArl Eicken , Peter Plath , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Lothar Rueb , KArl Eicken , Peter Plath , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： C07D231/56 , C07D405/12 , C07D409/12
CPC分类号： C07D231/56 , C07D405/12 , C07D409/12
摘要： N-(Phenyl)-tetrahydroindazole derivatives of the general formula Ia and Ib ##STR1## where R.sup.1 is halogen;R.sup.2 C.sub.1 -C.sub.6 -alkoxycarbonyl-C.sub.3 -C.sub.5 -alkenyl or C.sub.1 -C.sub.3 -alkyl which is substituted in the 1- or 2-position by C.sub.1 -C.sub.6 -alkoxycarbonyl or a 5-or 6-membered saturated or monounsaturated heterocycle which contains one oxygen or sulfur as heteroatom and can be substituted by rom one to four C.sub.1 -C.sub.4 -alkyls, andR.sup.3 is C.sub.2 -C.sub.7 -alkyl, C.sub.3 -C.sub.6 -C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkoxycarbonyl-C.sub.3 -C.sub.5 -alkenyl or C.sub.1 -C.sub.3 -alkyl which is substituted in the 1-or 2-position by C.sub.1 -C.sub.6 -alkoxycarbonyl or a 5- or 6-membered saturated or monounsaturated heterocycle which contains one oxygen or sulfur as heteroatom and can be substituted by from one to four C.sub.1 -C.sub.4 -alkyls,their manufacture and their use.
摘要翻译：通式Ia和Ib的N-（苯基） - 四氢吲唑衍生物，其中R 1是卤素; R2-C1-C6-烷氧基羰基-C3-C5-烯基或C1-C6-烷氧基羰基或5-或6-元饱和或单不饱和杂环被1或2-位取代的C 1 -C 3烷基，氧或硫作为杂原子，可以被一至四个C 1 -C 4烷基取代，R 3是C 2 -C 7 - 烷基，C 3 -C 6 -C 3 -C 6 - 炔基，C 1 -C 6 - 烷氧基羰基-C 3 -C 5 - 烯基或被C1-C6烷氧基羰基取代的1-或2-位的C1-C3-烷基或含有一个氧或硫作为杂原子的5或6元饱和或单不饱和杂环，并可被一个到四个C 1 -C 4烷基，其制备及其用途。

52. 发明授权

US5123952A 5-amino-6-pyridazone derivatives, their preparation and herbicidal mixtures containing these derivatives 失效
标题翻译： 5-氨基-6-吡啶酮衍生物，其制备和除草剂混合物含有这些衍生物
公开(公告)号：US5123952A
公开(公告)日：1992-06-23
申请号：US378798
申请日：1989-07-12
申请人： Ulrich Wriede , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
发明人： Ulrich Wriede , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
IPC分类号： A01N43/58 , C07D237/22 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D413/12 , C07D417/12
CPC分类号： C07D401/12 , C07D237/22 , C07D403/12 , C07D405/12 , C07D409/12 , C07D413/12
摘要： 5-Amino-6-pyridazones of the general formulae Ia and Ib ##STR1## where R.sup.1 is C.sub.1 -C.sub.4 -alkyl which may carry up to three halogen atoms, R.sup.2 is C.sub.1 -C.sub.4 -alkyl or C.sub.3 -C.sub.6 -alkenyl, where these groups may carry up to two phenyl radicals, or C.sub.3 -C.sub.6 -alkynyl, A is --CO-- or --SO.sub.2 --, B is C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, where these groups may carry up to three of the following radicals: halogen, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio and/or phenyl; an isocyclic or heterocyclic C.sub.3 -C.sub.7 -cycloalkyl group or an isocyclic or heterocyclic C.sub.3 -C.sub.7 -cycloalkenyl group, where these groups may be fused with one or two cycloalkyl groups of this type or with one or two benzene nuclei, where the total number of ring members is from 3 to 16 and these cyclic radicals may carry up to three of the following groups: halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 - C.sub.6 -alkynyl and/or phenyl; a mononuclear to trinuclear aromatic or heteroaromatic radical which may carry up to three of the following groups: C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, cyano, nitro, carbo-C.sub.1 -C.sub.4 -alkoxy, N,N-di-C.sub.1 -C.sub.4 -alkylcarbamido and/or halogen.These compounds are used as herbicidal active ingredients.
摘要翻译：通式Ia和Ib的5-氨基-6-哒嗪酮其中R 1是可以带有三个卤素原子的C 1 -C 4 - 烷基，R 2是C 1 -C 4 - 烷基或C 3 -C 6 - 烯基，其中这些基团可以带有两个苯基或C 3 -C 6 - 炔基，A是-CO-或-SO 2 - ，B是C 1 -C 6 - 烷基，C 2 -C 6 - 烯基或C 2 -C 6 - 炔基其中这些基团可以带有三个以下基团：卤素，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基和/或苯基; 一个环状或杂环的C 3 -C 7 - 环烷基或者是一个或多个杂环的C 3 -C 7 - 环烯基，其中这些基团可以与一个或两个这样的环烷基或一个或两个苯核稠合，环成员为3至16，并且这些环状基团可以带有三个以下基团：卤素，C 1 -C 4 - 烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基和/或苯基; 可以携带三个以下基团的单核到三核芳族或杂芳族基团：C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基，C 1 C 1-4烷基亚磺酰基，C 1 -C 4 - 烷基磺酰基，氰基，硝基，C 1 -C 4 - 烷氧基，N，N-二-C 1 -C 4烷基氨基甲酰基和/或卤素。这些化合物用作除草活性成分。

53. 发明授权

US5117005A Naphthindazole-4,9-quinones 失效
标题翻译：萘醌-4,9-喹啉
公开(公告)号：US5117005A
公开(公告)日：1992-05-26
申请号：US567627
申请日：1990-08-15
申请人： Klaus Ditrich , Gerhard Hamprecht , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen , Hartmut Laatsch
发明人： Klaus Ditrich , Gerhard Hamprecht , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen , Hartmut Laatsch
IPC分类号： A01N43/56 , C07D231/54 , C07D401/04 , C07D403/04 , C07D491/04 , C07D491/056
CPC分类号： C07D491/04 , C07D231/54 , C07D401/04 , C07D403/04
摘要： Naphthindazole-4,9-quinones of the formula ##STR1## where R.sup.1 to R.sup.5 have the meanings given in the disclosure, and their use for combating unwanted plant growth.

54. 发明授权

US5085685A Carboxylic acid derivatives 失效
标题翻译：羧酸衍生物
公开(公告)号：US5085685A
公开(公告)日：1992-02-04
申请号：US566536
申请日：1990-08-13
申请人： Joachim Rheinheimer , Karl Eicken , Uwe J. Vogelbacher , Wolfgang Rohr , Thomas Kuekenhoehner , Karl O. Westphalen , Bruno Wuerzer
发明人： Joachim Rheinheimer , Karl Eicken , Uwe J. Vogelbacher , Wolfgang Rohr , Thomas Kuekenhoehner , Karl O. Westphalen , Bruno Wuerzer
IPC分类号： C07D251/30 , A01N43/54 , A01N43/64 , A01N43/80 , A01N43/82 , A01N43/836 , C07D239/52 , C07D239/60 , C07D251/22 , C07D251/34 , C07D251/38 , C07D401/12 , C07D401/14 , C07D413/12 , C07D413/14 , C07D417/12 , C07D417/14
CPC分类号： C07D401/12 , A01N43/54 , A01N43/80 , A01N43/82 , C07D239/60 , C07D413/12 , C07D413/14
摘要： Carboxylic acid derivatives of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy and/or C.sub.1 -C.sub.4 -alkylthio;R.sup.3 is hydrogen, hydroxyl, cyano, nitro, formyl, halogen, unsubstituted or substituted amino, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyl or C.sub.3 -C.sub.6 -alkynyloxy;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is unsubstituted or substituted five-membered hetaryl or isoxazolinyl or --CR.sup.6 .dbd.NOR.sup.7 ;R.sup.6 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl or phenyl;R.sup.7 is unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.8 -cycloalkyl or phenyl;A is oxygen or sulfur;X is nitrogen or methine .dbd.CR.sup.8 --;R.sup.8 is one of the radicals R.sup.3, or R.sup.8 and R.sup.3 together form unsubstituted or substituted 1,3-butadiene-1,4-yl or aza-1,3-butadiene-1,4-yl, andY and Z are each nitrogen or methine .dbd.CH--, their preparation and agents containing them.
摘要翻译：其中R 1和R 2各自为C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷氧基和/或C 1 -C 4 - 烷硫基的通式I的羧酸衍生物; R3是氢，羟基，氰基，硝基，甲酰基，卤素，未取代或取代的氨基，C1-C4-烷基，C1-C4-烷氧基，C3-C6-烯基，C3-C6-烯氧基，C3-C6-炔基或C3 -C 6 - 炔氧基; R4是氢或C1-C4-烷基; R5是未取代的或取代的五元杂芳基或异恶唑啉基或-CR 6 = NOR 7; R6是氢或未取代或取代的C1-C4-烷基，C3-C8-环烷基或苯基; R 7为未取代或取代的C 1 -C 4 - 烷基，C 3 -C 6 - 烯基，C 3 -C 8 - 环烷基或苯基; A是氧或硫; X是氮或次甲基= CR8-; R8是基团R3之一，或R8和R3一起形成未取代或取代的1,3-丁二烯-1,4-基或氮杂-1,3-丁二烯-1,4-基，Y和Z各自为氮或次甲基= CH-，它们的制备物和含有它们的试剂。

55. 发明授权

US5076829A Substituted 2,3-epoxy-5-cyclohexenone derivatives, and fungicides and herbicides containing same 失效
标题翻译：取代的2,3-环氧-5-环己烯酮衍生物，含有其的杀真菌剂和除草剂
公开(公告)号：US5076829A
公开(公告)日：1991-12-31
申请号：US512509
申请日：1990-04-20
申请人： Ulrich Wriede , John-Bryan Speakman , Rudolf Karl , Ernst-Heinrich Pommer , Eberhard Ammermann , Bruno Wuerzer
发明人： Ulrich Wriede , John-Bryan Speakman , Rudolf Karl , Ernst-Heinrich Pommer , Eberhard Ammermann , Bruno Wuerzer
IPC分类号： A01N43/20 , C07D303/32
CPC分类号： C07D303/32 , A01N43/20
摘要： 2-substituted 2,3-epoxy-5-cyclohexenone derivatives of the formula I ##STR1## where W is C.dbd.O or CHOR.sup.1, R.sup.1 is hydrogen, alkyl, alkenyl, alkynyl or alkoxycarbonyl, R is a substituted or unsubstituted hydrocarbon chain, or phenyl or phenylalkyl whose phenyl radical is substituted or unsubstituted and whose alkyl radical may be interrupted by O or S and fungicides and herbicides containing these compounds.
摘要翻译：式（I）的2-取代的2,3-环氧-5-环己烯酮衍生物其中W是C = O或CHOR1，R1是氢，烷基，烯基，炔基或烷氧基羰基，R是取代或未取代的烃链，或其苯基被取代或未取代的苯基或苯基烷基，其烷基可被O或S间隔，并含有这些化合物的杀真菌剂和除草剂。

56. 发明授权

US5071470A Herbicidal 1,3,5-triazin-2-ylaminocarbonylamino-sulfonylbenzoic esters 失效
标题翻译：除草剂1,3,5-三氮杂-2-亚氨基羰基亚氨基磺酰基苯甲酸酯
公开(公告)号：US5071470A
公开(公告)日：1991-12-10
申请号：US494671
申请日：1990-03-16
申请人： Horst Mayer , Gerhard Hamprecht , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Horst Mayer , Gerhard Hamprecht , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： C07D251/16 , A01N43/66 , A01N47/36 , C07D251/42 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： [[(1,3,5-Triazin-2-yl)aminocarbonyl]aminosulfonyl]benzoic esters of the general formula I ##STR1## where R.sup.1 and R.sup.2 are methyl or ethyl, and R.sup.3 is hydrogen, fluorine or chlorine, agriculturally useful salts thereof, processes for their manufacture, and their use.
摘要翻译：具有通式I的化合物[[（1,3,5-三嗪-2-基）氨基羰基]氨基磺酰基]苯甲酸，其中R 1和R 2是甲基或乙基，R 3是氢，氟或氯，在农业上是有用的其盐，其制备方法及其用途。

57. 发明授权

US5059240A 2,3-substituted 1,8-naphthyridines, their preparation and their use as antidotes 失效
标题翻译： 2,3-取代的1,8-萘啶，其制备及其作为抗体使用
公开(公告)号：US5059240A
公开(公告)日：1991-10-22
申请号：US486867
申请日：1990-03-01
申请人： Helmut Hagen , Juergen Pfister , Hans Ziegler , Bruno Wuerzer , Karl-Otto Westphalen
发明人： Helmut Hagen , Juergen Pfister , Hans Ziegler , Bruno Wuerzer , Karl-Otto Westphalen
IPC分类号： A01N25/32 , A01N43/90 , C07D471/04 , C07D471/14
CPC分类号： C07D471/04 , A01N25/32 , C07D471/14
摘要： 2,3-substituted 1,8-naphthyridines of the general formula I ##STR1## where: R is hydrogen or C.sub.1 -C.sub.4 -alkyl (n=1 or 2)R.sup.1 is amino or substituted amino,XR.sup.5, where X is oxygen or sulfur and R.sup.5 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-((C.sub.1 -C.sub.4)-alkyl, C.sub.5 -C.sub.8 -cycloakyl, substituted or unsubstituted phenyl, substituted or unsubstituted phenyl-(C.sub.1 -C.sub.3)-alkyl,halogen,isothiorhonium halide,C.sub.1 -C.sub.12 -alkyl,C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.4 -alkyl,substituted or unsubstituted phenyl or phenyl-(C.sub.1 -C.sub.3)-alkyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, cyano, carboxyl or a group ##STR2## where X is oxygen or sulfur,B is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or alkylthio, amino, mono- or dialkylamino, where each alkyl radical is of 1 to 4 carbon atoms, morpholino, piperidyl, chlorine, bromine or substituted or unsubstituted phenyl,D is C.sub.1 -C.sub.4 alkyl or NH.sub.2 andR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl or alkylcarbonyl,or R.sup.1 and R.sup.2 together are --NH--N.dbd.C(CH.sub.2)--,and their environmentally tolerated saltswith the proviso that R.sup.2 is not cyano, carboxyl or a carboxamido or carboxylic ester group when R.sup.1 is methyl, hydroxyl or amino (NH.sub.2), processes for their manufacture, and herbicidal agents containing a naphthyridine I as safener and at least one herbicidal active ingredient selected from the group consisting ofa) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid derivatives andb) cyclohexenone derivatives.
摘要翻译：具有通式I的2,3-取代的1,8-萘啶，其中：R是氢或C 1 -C 4 - 烷基（n = 1或2）R 1是氨基或取代的氨基，XR 5，其中X是氧或（C 1 -C 4） - 烷基，C 5 -C 8 - 环烷基，取代或未取代的苯基，取代或未取代的苯基 - （C 1 -C 3） - 烷基，卤素，异卤卤化物，C 1 -C 12 - 烷基，C 1 -C 4 - 烷氧基羰基-C 1 -C 4烷基，取代或未取代的苯基或苯基 - （C 1 -C 3） - 烷基，R 2为C 1 -C 4烷基，氰基，羧基或基团，其中X为氧或硫，B为C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基或烷硫基，氨基，单或二烷基氨基，其中每个烷基为1至4个碳原子，吗啉代，哌啶基，氯，溴或取代或未取代的苯基，D是C 1 -C 4烷基或NH 2，R 6是氢，C 1 -C 8 - 烷基或烷基羰基，或者R 1和R 2一起是-NH-N = C（CH 2）其环境耐受性盐，条件是R2不是氰基，羧基或a 当R1是甲基，羟基或氨基（NH2）时，羧酰胺基或羧酸酯基，其制备方法和含有萘啶I作为安全剂的除草剂和至少一种除草活性成分，其选自a）2-（4 - 杂芳氧基） - 或2-（4-芳氧基） - 苯氧基乙酸衍生物和b）环己烯酮衍生物。

58. 发明授权

US5043454A Crop protection agents based on 1-aryl- or 1-hetarylimidazolecarboxylic esters 失效
标题翻译：基于1-芳基或1-芳基咪唑羧酸酯的作物保护剂
公开(公告)号：US5043454A
公开(公告)日：1991-08-27
申请号：US462631
申请日：1990-01-09
申请人： Ulrich Wriede , Gerhard Hamprecht , Hermann Koehler , Bruno Wuerzer
发明人： Ulrich Wriede , Gerhard Hamprecht , Hermann Koehler , Bruno Wuerzer
IPC分类号： A01N35/10 , A01N37/14 , A01N43/50 , C07D233/90 , C07D401/04
CPC分类号： C07D401/04 , C07D233/90
摘要： 1-Aryl- and 1-hetarylimidazolecarboxylic esters of the general formulae Ia and Ib ##STR1## where R.sup.1 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl;R.sup.2 is substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl; C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or C.sub.3 -C.sub.6 -cycloalkyl;R.sup.3 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.4 is substituted or unsubstituted phenyl or 5- or 6-membered heteroaromatic,processes for their manufacture, and agents containing them.
摘要翻译：其中R 1是卤素或取代或未取代的C 1 -C 4 - 烷基;其中R 1是卤素或取代或未取代的C 1 -C 4 - 烷基; R2是取代或未取代的C1-C6-烷基; C3-C6-烯基，C3-C6-炔基或C3-C6-环烷基; R3是氢或C1-C4-烷基; R4是取代或未取代的苯基或5-或6-元杂芳族化合物，其制备方法和含有它们的试剂。

59. 发明授权

US5034049A Thiophene-2-carboxylic acid derivatives, their preparation and their use for controlling undesirable plant growth 失效
标题翻译：噻吩-2-羧酸衍生物，其制备及其用于控制不期望的植物生长的用途
公开(公告)号：US5034049A
公开(公告)日：1991-07-23
申请号：US463163
申请日：1990-01-09
申请人： Reiner Kober , Rainer Seele , Hans-Juergen Neubauer , Thomas Saupe , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
发明人： Reiner Kober , Rainer Seele , Hans-Juergen Neubauer , Thomas Saupe , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
IPC分类号： A01N43/10 , C07D333/38 , C07D333/40 , C07D333/42
CPC分类号： C07D333/38 , A01N43/10
摘要： Thiophene-2-carboxylic acid derivatives of the general formula I ##STR1## where R.sup.1 to R.sup.3 are each hydrogen, halogen, branched or straight-chain C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -haloalkoxy, nitro, cyano, unsubstituted phenyl or phenyl which is mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen, C.sub.1 -C.sub.5 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.5 -haloalkoxy;X is --OR.sup.4 or --NH--OR.sup.5,R.sup.4 being branched or straight-chain C.sub.3 -C.sub.10 -alkynylalkyl which is unsubstituted or substituted by halogen; andR.sup.5 being branched or straight-chain C.sub.1 -C.sub.5 -alkyl which is unsubstituted or substituted by halogen, or branched or straight-chain C.sub.3 -C.sub.10 -alkynylalkyl which is unsubstituted or substituted by halogen;with the proviso that R.sup.4 is not propargyl when R.sup.2 and R.sup.3 are both hydrogen or when R.sup.2 is halogen or R.sup.3 is chlorine, methyl or methoxy.The compounds I are suitable for combating the growth of unwanted plants.
摘要翻译：通式I的噻吩-2-羧酸衍生物其中R 1至R 3各自为氢，卤素，支链或直链C 1 -C 6 - 烷基，C 1 -C 8 - 烷氧基，C 1 -C 6 - 卤代烷基，C 1 C 1-6卤代烷氧基，硝基，氰基，未取代的苯基或被C 1 -C 4 - 烷基，卤素，C 1 -C 5 - 卤代烷基，C 1 -C 4 - 烷氧基或C 1 -C 5 - 卤代烷氧基单 - X为-OR4或-NH-OR5，R4为未取代或被卤素取代的支链或直链C 3 -C 10 - 炔基烷基; 并且R 5是未被取代或被卤素取代的支链或直链C 1 -C 5 - 烷基，或未被取代或被卤素取代的支链或直链C 3 -C 10 - 炔基烷基; 条件是当R 2和R 3均为氢时或R 2为卤素或R 3为氯，甲基或甲氧基时，R 4不是炔丙基。化合物I适用于对抗不想要的植物的生长。

60. 发明授权

US5032167A Substituted sulfonylureas 失效
标题翻译：取代磺酰脲类
公开(公告)号：US5032167A
公开(公告)日：1991-07-16
申请号：US448984
申请日：1989-12-12
申请人： Horst Mayer , Gerhard Hamprecht , Bruno Wuerzer , Karl-Otto Westphalen
发明人： Horst Mayer , Gerhard Hamprecht , Bruno Wuerzer , Karl-Otto Westphalen
IPC分类号： C07D251/16 , A01N47/36 , A01N47/38 , C07D239/47 , C07D239/52 , C07D251/42 , C07D251/46 , C07D403/12 , C07D413/12 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Substituted sulfonylureas of the formula I ##STR1## where the substituents and indices have the following meanings: x is oxygen or sulfur;z is nitrogen or methine (=CH--);R.sup.1 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.3 -alkoxy, or a radical --CONR.sup.6 R.sup.7, whereR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl or C.sub.1 -C.sub.6 -alkoxy andR.sup.7 is hydrogen or C.sub.1 -C.sub.8 -alkyl;R.sup.2 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkyl;R.sup.3 is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkylthio, halogen, cyano, nitro, amino, mono-C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C.sub.2 -C.sub.6 -alkenyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkanoyl or benzyl; a 5- or 6-membered saturated heterocycle which is attached by its nitrogen atom and which, besides methylene and a nitrogen, may also contain an oxygen or a sulfur atom; or, bonded to adjacent ring positions, --OCRR'O--, where R and R' are each hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is halogen C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio or C.sub.1 -C.sub.4 -haloalkyl;m is from 0 to 3 or, when R.sup.3 is halogen, from 0 to 5, differences among the R.sup.3 radicals being possible when m is 2 or 3; andn is from 0 to 2, a difference between the R.sup.5 radicals being possible when n is 2;and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
摘要翻译：取代基和指数具有以下含义的式I的取代磺酰脲类：x是氧或硫; z是氮或次甲基（= CH-）; R 1是卤素或取代或未取代的C 1 -C 4 - 烷氧基羰基或C 1 -C 3 - 烷氧基或基团-CONR 6 R 7，其中R 6是氢，C 1 -C 8 - 烷基或C 1 -C 6 - 烷氧基，并且R 7是氢或C 1 -C 8 - 烷基; R2是卤素或取代或未取代的C1-C4-烷氧基或C1-C4-烷基; R 3是C 1 -C 4烷基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷硫基，卤素，氰基，硝基，氨基，单-C 1 -C 4烷基氨基， C 1 -C 4 - 烷基氨基，C 2 -C 6 - 烯基，C 1 -C 4 - 烷氧基羰基，C 1 -C 4 - 烷酰基或苄基; 通过其氮原子连接的5-或6-元饱和杂环，除了亚甲基和氮之外，还可以含有氧或硫原子; 或者，与相邻的环位置键合，-OCRR'O-，其中R和R'各自为氢或C1-C4-烷基; R4是氢或C1-C4-烷基; R5是卤素C1-C4-烷基，C1-C4-烷氧基，C1-C4-烷硫基或C1-C4卤代烷基; m为0至3，或当R3为卤素时为0至5，当m为2或3时，R3基团之间的差异是可能的; n为0〜2，当n为2时，R5基团之间的差异是可能的; 及其环境可接受的盐，其制备方法，以及它们作为除草剂的用途。

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