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51. 发明授权

EP0944656B1 VERFAHREN ZUR HERSTELLUNG KAUTSCHUKMODIFIZIERTER FORMMASSEN 失效
标题翻译：用于生产橡胶改性模塑料
公开(公告)号：EP0944656B1
公开(公告)日：2001-07-11
申请号：EP97952822.1
申请日：1997-11-28
申请人： BASF AKTIENGESELLSCHAFT
发明人： MC KEE, Graham, Edmund , JÜNGLING, Stephan , WARZELHAN, Volker , GAUSEPOHL, Hermann
IPC分类号： C08F265/04 , C08L51/00
CPC分类号： C08F20/12

52. 发明授权

EP0918806B1 VERFAHREN ZUR HERSTELLUNG VON DIENPOLYMERISATLÖSUNGEN IN VINYLAROMATISCHEN MONOMEREN 失效
标题翻译：用于生产DIENPOLYMERISATLÖSUNGEN乙烯基芳族单体
公开(公告)号：EP0918806B1
公开(公告)日：2000-11-08
申请号：EP97944765.3
申请日：1997-08-18
申请人： BASF AKTIENGESELLSCHAFT
发明人： LÄTSCH, Stefan , FISCHER, Wolfgang , GAUSEPOHL, Hermann , WARZELHAN, Volker , SCHADE, Christian
IPC分类号： C08F212/04 , C08F236/10 , C08F279/02 , C08F297/04
CPC分类号： C08F297/04 , C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F4/46 , C08F4/52 , C08F4/54 , C08F4/48

53. 发明公开

EP0973812A2 METHOD FOR PREPARING (CO)POLYMERS BY METAL-FREE ANIONIC POLYMERIZATION IN THE PRESENCE OF A PHOSPHONIUM CATION CONTAINING AT LEAST ONE ANNELLATED AROMATIC RING 失效
标题翻译：用于生产（CO）聚合物中的无金属阴离子聚合
公开(公告)号：EP0973812A2
公开(公告)日：2000-01-26
申请号：EP98921423.4
申请日：1998-04-02
申请人： BASF AKTIENGESELLSCHAFT
发明人： JÜNGLING, Stephan , WARZELHAN, Volker , GAUSEPOHL, Hermann , HOGEN-ESCH, Thieo, E. , DIMOV, Dimo, K.
IPC分类号： C08F20/12 , C08F20/08 , C08F4/00 , C07F9/54 , C08F20/44 , C08F22/32 , C08F26/06 , C08F297/02
CPC分类号： C07F9/5442 , C08F4/00
摘要： The present invention concerns a novel method for preparing polymers (preferably (meth)acrylate polymers and copolymers) having a narrow molecular weight distribution by metal-free anionic polymerization in the presence of a phosphonium cation containing at least one annellated aromatic ring as substituent on the phosphorous atom.

54. 发明授权

EP0802942B1 BIOLOGISCH ABBAUBARE POLYMERE, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBARER FORMKÖRPER 失效
标题翻译： BIOLOGISCH ABBAUBARE POLYMERE，VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBERFORMKÖRPER
公开(公告)号：EP0802942B1
公开(公告)日：1998-07-22
申请号：EP96900928.1
申请日：1996-01-08
申请人： BASF AKTIENGESELLSCHAFT
发明人： WARZELHAN, Volker , KRONER, Matthias , HOFMANN, Jürgen , SEELIGER, Ursula , YAMAMOTO, Motonori , BAUER, Peter
IPC分类号： C08G69/44
CPC分类号： C08G69/48 , B65D65/466 , C08G69/44 , C08L3/02 , C08L77/12 , C08L2201/06 , Y02W30/43 , Y02W90/13 , C08L2666/02
摘要： The invention concerns biologically degradable polyester amides Q1 obtainable through reaction of a mixture consisting essentially of the following: (a1) 95-99.9 wt % polyester amide P1 obtainable through reaction of a mixture consisting essentially of: (b1) a mixture consisting essentially of: 35-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-65 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof; and 0-5 mol % a compound containing sulphonate groups (the sum of the molar percentages is 100); (b2) a mixture of dihydroxy compounds consisting essentially of: (b21) 99.5-0.5 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols, (b22) 0.5-99.5 mol % an amino C2-C12 alkanol or an amino C5-C10 cycloalkanol, (b23) 0-50 mol a diamino C1-C8 alkane, and (b24) 0-50 mol % a 2,2´-bisoxazoline; (a2) 0.1-5 wt % a divinyl ether C1; and (a3) 0-5 mol % (in relation to components b1 from the production of P1) compound D. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, a process for manufacturing the same and the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles obtainable from the polymers or moulding materials according to the invention.
摘要翻译：本发明涉及可通过基本上由以下组分组成的混合物反应获得的生物可降解聚酯酰胺Q1：（a1）95-99.9wt％的聚酯酰胺P1，其可通过基本上由以下组分组成的混合物反应获得：（b1）基本上由以下组分组成的混合物： 35-95摩尔％己二酸或其成酯衍生物或其混合物，5-65摩尔％对苯二甲酸或其成酯衍生物或其混合物; 和0-5摩尔％含有磺酸盐基团的化合物（摩尔百分数之和为100）; （b2）主要由以下组分组成的二羟基化合物的混合物：（b21）99.5-0.5摩尔％选自C2-C6链烷二醇和C5-C10环烷二醇的二羟基化合物，（b22）0.5-99.5摩尔％氨基 C2-C12烷醇或氨基C5-C10环烷醇，（b23）0-50mol二氨基C1-C8烷烃，和（b24）0-50mol％2,2'-双恶唑啉; （a2）0.1-5重量％二乙烯基醚C1; 和（a3）0-5摩尔％（相对于来自P1生产的组分b1）化合物D.本发明还涉及其它生物可降解聚合物和热塑性模塑材料，其制造方法及其用于生物学生产可降解模塑制品和粘合剂，以及可由本发明聚合物或模塑材料获得的生物可降解模塑制品。

55. 发明公开

EP0809666A1 BIOLOGISCH ABBAUBARE POLYMERE, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBARER FORMKÖRPER 失效
标题翻译： BIOLOGISCH ABBAUBARE POLYMERE，VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBERFORMKÖRPER
公开(公告)号：EP0809666A1
公开(公告)日：1997-12-03
申请号：EP96902980.0
申请日：1996-02-03
申请人： BASF AKTIENGESELLSCHAFT
发明人： WARZELHAN, Volker , PIPPER, Gunter , SEELIGER, Ursula , BAUER, Peter , BEIMBORN, Dieter, Bernhard , YAMAMOTO, Motonori
IPC分类号： C08J5 , A61L15 , C08G63 , C08J9 , C08L67 , C08L101 , C09J167 , D21H19
CPC分类号： C08G63/91 , A61L15/26 , A61L15/62 , C08G63/20 , C08G63/60 , C08G63/668 , C08G63/672 , Y02W30/43 , C08L67/00
摘要： Biodegradable polyether esters P1 obtainable through the reaction of a mixture consisting essentially of: (a1) a mixture consisting essentially of 20 to 95 mol % adipic acid, ester-forming derivatives thereof or mixtures thereof, 5 to 80 mol % terephthalic acid, ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol % of a compound containing sulphonate groups, in which the sum of the individual mol percentages is 100; and (a2) a mixture of dihydroxy compounds consisting essentially of (a21) 15 to 99.8 mol % of a dihydroxy compound selected from the group consisting of C2-C6 alkane diols and C5-C10 cycloalkane diols, (a22) 85 to 0.2 mol % of an ether function-containing dihydroxy compound as per formula (I): HO-[(CH2)n-O]m-H, in which n is 2, 3 or 4 and m is a whole number from 2 to 250, or mixtures thereof, the molar ratio of (a1) to (a2) being in the range from 0.4:1 to 1.5:1, provided that the polyether esters have a molecular weight (Mn) in the range from 5000 to 80 000 g/mol, a viscosity index in the range from 30 to 450 g/ml (measured in o-dichlorobenzol/phenol ( weight ratio 50/50), at a concentration of 0.5 wt % polyether esters P1 at a temperature of 25 °C) and a melting point in the range from 50 to 200 °C, and with the further provisos that from 0.01 to 5 mol % related to the molar quantity of the component (a1) used of a compound D with at least three groups capable of ester formation are used to produce the polyether esters P1, and that the polyether esters P1 contain both hydroxyl and carboxyl terminal groups, the molar ratio of carboxyl to hydroxyl terminal groups being greater than one. The invention also relates to further biodegradable polymers and thermoplastic casting compounds, process for their production, their use in the manufacture of biodegradable casting compounds and adhesives, biodegradable mouldings, foams and blends with starch obtainable from the polymers or casting compounds of the invention.
摘要翻译：通过基本上由以下组分组成的混合物反应可得到的可生物降解聚醚酯P1：（a1）主要由20-95摩尔％己二酸，其成酯衍生物或其混合物组成的混合物，5-80摩尔％对苯二甲酸，形成其衍生物或其混合物，以及0-5mol％的含磺酸盐基团的化合物，其中各个mol％的总和为100; （a2）基本上由（a21）15-99.8mol％选自C2-C6链烷二醇和C5-C10环链烷二醇的二羟基化合物，（a22）85- 0.2mol％二羟基化合物组成的二羟基化合物的混合物，（I）的含醚官能团的二羟基化合物：HO - [（CH2）nO] mH，其中n是2,3或4，m是2至250的整数，或它们的混合物，（a1）与（a2）的摩尔比在0.4:1至1.5:1的范围内，条件是聚醚酯具有5000至80000g / mol的分子量（Mn），粘度指数在30至450g / ml范围内（在邻二氯苯酚/苯酚（重量比50/50）中测量，浓度为0.5重量％的聚醚酯P1在25℃的温度下）以及在范围为50至200℃，并且进一步的条件是0.01至5摩尔％与所用组分（a1）的摩尔量有关的化合物D与至少三个能形成酯的基团用于生产聚醚酯P1，并且聚醚酯P1含有羟基和羧基末端基团，羧基与羟基末端基团的摩尔比大于1。本发明还涉及进一步的可生物降解的聚合物和热塑性铸塑化合物，它们的生产方法，它们在制造可生物降解的浇铸化合物和粘合剂中的用途，可生物降解的模塑制品，泡沫材料和由本发明的聚合物或浇铸配混料可获得的淀粉共混物。

56. 发明公开

EP0792311A1 BIOLOGISCH ABBAUBARE POLYMERE, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBARER FORMKÖRPER 失效
标题翻译： BIOLOGISCH ABBAUBARE POLYMERE，VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBERFORMKÖRPER
公开(公告)号：EP0792311A1
公开(公告)日：1997-09-03
申请号：EP95937865.0
申请日：1995-11-04
申请人： BASF AKTIENGESELLSCHAFT
发明人： WARZELHAN, Volker , SCHORNICK, Gunnar , KRONER, Matthias , SEELIGER, Ursula , YAMAMOTO, Motonori , BÜSCHL, Rainer
IPC分类号： C08G63 , C08J5 , C08J9 , C08L67 , C08L101 , C09J167 , D21H19
CPC分类号： C08G63/91 , C08G63/60
摘要： The invention concerns biodegradable polyesters obtained by reacting a mixture comprising: (a1) 95 to 99.9 wt % of a polyester P1, obtained by reacting a mixture substantially comprising: (b1) a mixture comprising: 35 to 95 mol % adipic acid or esterifying derivatives thereof; 5 to 65 mol % terephthalic acid or esterifying derivatives thereof; and 0 to 5 mol % of a sulphonate group-containing compound; and (b2) a dihydroxy compound selected from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols, provided that a compound D having at least three groups capable of esterification is used to prepare the polyester P1; (a2) 0.1 to 5 wt % of a divinylether C1; and (a3) 0 to 5 mol %, relative to component (b1) from the preparation of P1, of compound D, and further biodegradable polymers and thermoplastic moulding compounds. The invention further concerns a process for their preparation and their use for producing biodegradable moulded bodies and adhesives.
摘要翻译：本发明涉及通过包含如下物质的混合物获得的生物可降解聚酯：（a1）95-99.9wt％的聚酯P1，其通过基本上包含以下物质的混合物反应获得：（b1）包含35-95mol％己二酸或酯化衍生物物; 5至65摩尔％的对苯二甲酸或其酯化衍生物; 和0-5摩尔％的含磺酸盐基团的化合物; 和（b2）选自C2-C6链烷二醇和C5-C10链烷二醇的二羟基化合物，条件是使用具有至少三个能够酯化的基团的化合物D来制备聚酯P1; （a2）0.1-5重量％的二乙烯基醚C1; 和（a3）相对于来自P1的制备的组分（b1），化合物D和其它可生物降解的聚合物和热塑性模塑化合物，0-5mol％。本发明还涉及它们的制备方法及其用于生产可生物降解的模塑体和粘合剂的用途。

57. 发明公开

EP0792309A1 BIOLOGISCH ABBAUBARE POLYMERE, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBARER FORMKÖRPER 失效
标题翻译： BIOLOGISCH ABBAUBARE POLYMERE，VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG ZUR HERSTELLUNG BIOABBAUBERFORMKÖRPER
公开(公告)号：EP0792309A1
公开(公告)日：1997-09-03
申请号：EP95924943.0
申请日：1995-06-27
申请人： BASF AKTIENGESELLSCHAFT
发明人： WARZELHAN, Volker , SCHORNICK, Gunnar , BRUCHMANN, Bernd , SEELIGER, Ursula , YAMAMOTO, Motonori , BAUER, Peter
IPC分类号： C08L3 , A01G13 , C08G18 , C08G63 , C08L67 , C08L75 , C08L101 , C09D167 , C09K17
CPC分类号： C08L3/02 , C08G18/4216 , C08G18/4219 , C08G18/4277 , C08G18/428 , C08G18/4286 , C08G18/4676 , C08G18/6659 , C08G63/20 , C08G63/60 , C08G2230/00 , C08L75/06 , C09D167/00 , C09K17/52 , Y02A40/284 , Y10S525/938 , Y10T428/31547 , Y10T428/31786 , Y10T428/31794 , C08L2666/02 , C08L2666/26 , C08L2666/36
摘要： Biodegradable polyesters P1 obtainable by the reaction of a mixture consisting essentially of (a1) a mixture essentially of 35 to 95 mol% adipic acid or ester-forming derivatives thereof or mixtures thereof, 5 to 65 mol% terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol% of a sulphonate group-containing compound in which the sum of the individual mol percentages is 100, and (a2) a dihydroxy compound selected from the group consisting of C2-C6 alkane diols and C5-C10 cycloalkane diols, in which the molar ratio of (a1) and (a2) is in the range from 0.4:1 to 1.5:1, provided that the polyester P1 have a molecular weight (Mn) in the range from 5000 to 50,000 g/mol, a viscosity index in the range from 30 to 350 g/ml (measured in o-dichlorobenzole/phenol (in a ratio by weight of 50/50) at a concentration of 0.5 wt.% polyester P1 at a temperature of 25 °C) and a melting point in the range from 50 to 170 °C, and with the further proviso that from 0.01 to 5 mol% in relation to the molar quantity of the component (a1) used of compound D with at least three groups capable of forming esters are used to produce the polyesters P1, and other biodegradable polymers and thermoplastic moulding compounds and adhesives, biodegradable mouldings, foams and blends with starch obtainable from the polymers or moulding compounds of the invention.
摘要翻译：生物可降解聚酯P1可通过基本上由以下组分组成的混合物反应获得：（a1）基本上35-95摩尔％己二酸或其成酯衍生物或其混合物的混合物，5-65摩尔％对苯二甲酸或其成酯衍生物或它们的混合物，和0-5mol％的其中单个mol％的总和为100的含磺酸盐基团的化合物，和（a2）选自C2-C6链烷二醇和C5-C6链烷二醇的二羟基化合物， C10环烷二醇，其中（a1）和（a2）的摩尔比在0.4:1至1.5:1的范围内，条件是聚酯P1的分子量（Mn）为5000-50,000g / mol，粘度指数为30-350g / ml（在邻二氯苯甲醚/苯酚（重量比为50/50）中测量，浓度为0.5重量％聚酯P1，温度为25℃ ℃），熔点为50-170℃，并且进一步为0.01 相对于使用具有至少三个能够形成酯的基团的化合物D的组分（a1）的摩尔量的5摩尔％用于生产聚酯P1和其他生物可降解聚合物和热塑性模塑化合物和粘合剂，生物可降解模制品，可从本发明的聚合物或模塑料获得的泡沫和与淀粉的共混物。

58. 发明公开

EP1777258A1 Carbon nanotubes reinforced thermoplastic molding composition 有权
标题翻译：碳纳米管增强的聚合物组合物和它们的制备方法
公开(公告)号：EP1777258A1
公开(公告)日：2007-04-25
申请号：EP06122010.9
申请日：2006-10-10
申请人： BASF Aktiengesellschaft
发明人： DUIJZINGS, Wil , SUWIER, Davy, Roger , BREINER, Thomas , WARZELHAN, Volker , NIEßNER, Norbert , PEPERS, Michel
IPC分类号： C08K9/08 , C08L9/00 , C08L55/02 , C08J9/00
CPC分类号： C08K9/08 , C08K3/04 , C08K3/041 , C08L9/02 , C08L25/08 , C08L25/12 , C08L25/14 , C08L33/12 , C08L51/003 , C08L2205/025 , C08L2205/03 , C08L35/00 , C08L55/02
摘要： The invention relates to a carbon nanotube reinforced thermoplastic molding composition. This thermoplastic molding composition is produced from a graft copolymer containing single wall carbon nanotubes and a thermoplastic polymer. The graft copolymer is produced from a soft elastomeric particulate graft base with a glass transition temperature below 0°C obtained by emulsion polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer or of at least one C 1 -C 18 -alkyl acrylate, or of mixtures of these, upon which is grafted a vinyl aromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer.
The aqueous latex of the graft copolymer is mixed with a dispersion of carbon nanotubes (CNTs) in an aqueous medium. For the dispersing step of the carbon nanotubes (CNTs) in aqueous solution, a salt of an amphiphilic polymer is used.

59. 发明公开

EP1742980A1 OFFENZELLIGE SCHAUMSTOFFE, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG 审中-公开
标题翻译：开孔泡沫，其制造方法相同，它们的用途
公开(公告)号：EP1742980A1
公开(公告)日：2007-01-17
申请号：EP05733253.8
申请日：2005-04-14
申请人： BASF Aktiengesellschaft
发明人： STORK, Martin , EHRENSTEIN, Moritz , BREINER, Thomas , POPPE, Andreas , ALTEHELD, Armin , WARZELHAN, Volker
IPC分类号： C08G18/77 , C08G18/79 , C08G12/32 , C08J9/40 , C08J9/14
CPC分类号： C08G18/778 , C08G18/3895 , C08G18/792 , C08G18/807 , C08G18/809 , C08G2101/00 , C08J9/008 , C08J9/009 , C08J2205/05
摘要： The invention relates to modified open-cell foam materials having a density ranging from 5 to 1000 kg/m3, an average pore diameter ranging from 1 µm to 1 mm, a BET-surface ranging from 0.1 to 50 m2/g and a sound absorption factor of more than 50 % at a frequency of 2000 Hz and a layer thickness of 50 mm. The inventive foam materials comprise, in the range of 1 to 4000 ppm, based on the weight of the unmodified open-cell foam material, fixed particles (b) having an average diameter (number average) in the range of from 5 nm to 900 nm.

60. 发明授权

EP1124867B1 VERFAHREN ZUR ANIONISCHEN POLYMERISATION VON DIENEN 有权
标题翻译：方法阴离子聚合即成
公开(公告)号：EP1124867B1
公开(公告)日：2004-08-11
申请号：EP99947368.9
申请日：1999-09-16
申请人： BASF AKTIENGESELLSCHAFT
发明人： JÜNGLING, Stephan , SCHADE, Christian , GAUSEPOHL, Hermann , WARZELHAN, Volker , DESBOIS, Philippe , FONTANILLE, Michel , DEFFIEUX, Alain
IPC分类号： C08F36/04 , C08F4/44 , C08F4/48
CPC分类号： C08F36/00 , C08F4/44 , C08F4/48
摘要： The invention relates to a method for the anionic polymerisation of dienes in a solvent in the form of an aliphatic, isocyclic or aromatic hydrocarbon or hydrocarbon mixture, in the presence of an organic lithium polymerisation initiator and a dialkylmagnesium compound which is soluble in the hydrocarbon, the molar ratio of Mg/Li being greater than 0.8.

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