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51. 发明申请

US20050241080A1 Fibre-reactive azo dyes, their preparation and their use 失效
标题翻译：纤维反应偶氮染料，其制备及其用途
公开(公告)号：US20050241080A1
公开(公告)日：2005-11-03
申请号：US10523241
申请日：2003-07-15
申请人： Athanassios Tzikas , Bernhard Muller , Georg Roentgen
发明人： Athanassios Tzikas , Bernhard Muller , Georg Roentgen
IPC分类号： B41J2/01 , B41M5/00 , C07D251/50 , C07D487/22 , C07D498/04 , C09B62/08 , C09B62/09 , C09B62/44 , C09B62/507 , C09B62/513 , C09D11/00 , D06P1/382 , D06P3/66 , C09B1/00
CPC分类号： C09B62/4411
摘要： Reactive dyes of formula (I), wherein A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, Q1, and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1,-C4alkyl, (Q3)n denotes n substituents selected from the group C1,-C4alkyl, C1-C4alkoxy, halogen and sulfo, X is halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C1-C4alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C1-C4alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, k is a number 2, 3, 4, 5 or 6, m is a number 0 or 1, and n is a number 0, 1 or 2, with the proviso that when A denotes a monoazo chromophore it is not directly linked to the triazinyl radical through a hydroxynaphthalenesulfonic acid coupling component and does not denote a radical of formula (II), are suitable for dyeing cellulosic or nitrogen-containing fibre materials.
摘要翻译：式（I）的活性染料，其中A是单偶氮，多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an或二恶嗪发色团，Q 1和Q 2的基团，各自独立地为另一个氢或未取代或取代的C 1 -C 4烷基，（Q 3 N）n 表示选自C 1〜C 4烷基，C 1 -C 4烷基的n个取代基，烷氧基，卤素和磺基，X是卤素，3-羧基吡啶-1-基，3-氨基甲酰基吡啶-1-基，羟基，C 1 -C 4烷氧基在烷基部分中未被取代或被取代的苯基部分中未被取代或取代的苯氧基，未取代的或在烷基部分被取代的未取代或取代的C 1 -C 4烷基硫基，未取代或取代的氨基，或可以含有或不含有其它杂原子的N-杂环，Y为乙烯基或基团-CH 2 -CH 2 -NU，U为可以在碱性条件下，k是nu mber 2，3，4，5或6，m是数字0或1，n是数字0,1或2，条件是当A表示单偶氮发色团时，它不直接与三嗪基直接相连，通过羟基萘磺酸偶联组分并不表示式（II）的基团，适用于染色纤维素或含氮纤维材料。

52. 发明授权

US06504016B2 Reactive dyes, processes for the preparation thereof and the use thereof 失效
标题翻译：活性染料，其制备方法及其用途
公开(公告)号：US06504016B2
公开(公告)日：2003-01-07
申请号：US10061125
申请日：2001-11-13
申请人： Athanassios Tzikas , Bruno Cortese
发明人： Athanassios Tzikas , Bruno Cortese
IPC分类号： C09B62513
CPC分类号： C09B62/4415
摘要： Reactive dyes of the formula (1) wherein the variables are as defined in the specification are especially suitable for dyeing cotton and yield dyeings having good all-round fastness properties.
摘要翻译：式（1）的反应性染料，其中变量如本说明书中所定义，特别适用于染色棉和具有良好全面坚牢度性能的染色。

53. 发明授权

US5731421A Monoazo dyes having a fiber-reactive 2-vinylsulfonyl-5-sufoaniline diazo component and a fiber-reactive halotriazinyl-substituted coupling component of the benzene or naphthalene series 失效
标题翻译：具有纤维反应性2-乙烯基磺酰基-5-磺胺基苯胺重氮组分的单偶氮染料和苯或萘系的纤维反应性卤代三嗪基取代的偶联组分
公开(公告)号：US5731421A
公开(公告)日：1998-03-24
申请号：US497123
申请日：1995-06-30
申请人： Athanassios Tzikas , Claudia Carisch
发明人： Athanassios Tzikas , Claudia Carisch
IPC分类号： C09B62/503 , C09B62/44 , C09B62/447 , C09B62/507 , D06P1/38 , C09B62/513 , D06P1/384 , D06P3/66
CPC分类号： C09B62/447 , C09B62/4411 , C09B62/507
摘要： Reactive dyes of the formula ##STR1## in which K and Z are as defined in claim 1, are suitable in particular for the dyeing and printing of cellulose-containing fibre material and produce dyeings and prints having good fastness properties in high coloristic yield.
摘要翻译：其中K和Z如权利要求1所定义的式（1）的活性染料特别适用于含纤维素纤维材料的染色和印花，并产生具有高色牢度性能的染色和印花产量。

54. 发明授权

US5686584A Reactive dyes, their preparation, and their use 失效
标题翻译：活性染料，它们的制备及其用途
公开(公告)号：US5686584A
公开(公告)日：1997-11-11
申请号：US559263
申请日：1995-11-15
申请人： Rolf Deitz , Bernhard Muller , Athanassios Tzikas
发明人： Rolf Deitz , Bernhard Muller , Athanassios Tzikas
IPC分类号： C09B62/09 , C09B62/01 , C09B62/44 , C09B62/513 , D06P1/38
CPC分类号： C09B62/513 , C09B62/4415
摘要： Compounds of the formula ##STR1## in which the variables are as defined in the claims, and which are suitable as fibre-reactive dyes for dyeing and printing widely varying fibre materials, are described.
摘要翻译：描述了其中变量如权利要求中所定义并且适合作为用于染色和印刷广泛变化的纤维材料的纤维活性染料的式“IMAGE”（1）的化合物。

55. 发明授权

US5599911A Fiber-reactive dyes having a central 1,3,5-triazine ring to which are bonded to a monoazo chromophore having another 1,3,5-triazine moiety and a second chromophore 失效
标题翻译：具有中心1,3,5-三嗪环的纤维反应性染料与具有另一个1,3,5-三嗪部分的单偶氮发色团结合，第二发色团
公开(公告)号：US5599911A
公开(公告)日：1997-02-04
申请号：US296206
申请日：1994-08-25
申请人： Rolf Deitz , Bernhard M uller , Athanassios Tzikas
发明人： Rolf Deitz , Bernhard M uller , Athanassios Tzikas
IPC分类号： C09B62/503 , C09B62/08 , C09B62/44 , C09B62/665 , D06P1/38 , C09B62/006 , C09B62/507
CPC分类号： C09B62/4403 , C09B62/08
摘要： Reactive dyes of the formula ##STR1## in which the variables have the meanings stated in the claims, are described. The dyes according to the invention are particularly suitable for dyeing cellulosic fibre materials and give dyeings with good fastness properties and a high color yield.
摘要翻译：描述了其中变量具有权利要求中所述的含义的式（1）的活性染料。根据本发明的染料特别适用于染色纤维素纤维材料，并赋予具有良好牢度性能和高颜色产率的染色。

56. 发明授权

US5565553A Disazo dyes with a vinylsulfonyl type fiber-reactive radical substituted diazo component and a 2-sulfophenylene middle component carrying a fiber-reactive radical in the 5-position 失效
标题翻译：具有乙烯基磺酰基型纤维反应性自由基取代的重氮组分的双偶氮染料和在5位上携带纤维反应性基团的2-磺基亚苯基中间组分
公开(公告)号：US5565553A
公开(公告)日：1996-10-15
申请号：US584582
申请日：1996-01-11
申请人： Rolf Deitz , Paul Herzig , Athanassios Tzikas
发明人： Rolf Deitz , Paul Herzig , Athanassios Tzikas
IPC分类号： C09B62/513 , C09B62/44 , C09B62/447 , C09B62/665 , C09B62/67 , D06P3/66 , C09B62/09 , D06P1/38 , D06P3/58
CPC分类号： C09B62/4401 , C09B62/447
摘要： Reactive dyes of the formula ##STR1## where A, K and Z are each as defined in the claims, are especially useful for dyeing or printing cellulosic fiber materials, producing dyeings and prints having good fastness properties in a high yield.
摘要翻译：式（1）的活性染料其中A，K和Z各自如权利要求中所定义，特别可用于染色或印刷纤维素纤维材料，以高产率生产具有良好牢度性能的染色和印花。

57. 发明授权

US5554733A Reactive azo dyes containing phenylamino-chlorotriazinylamino and .alpha.,.beta.-dibromoproproylamino or .alpha.-bromoacryloylamino fiber reactive groups 失效
标题翻译：含有苯基氨基 - 氯三嗪基氨基和α，β-二溴丙酰氨基或α-溴丙烯酰氨基纤维反应性基团的活性偶氮染料
公开(公告)号：US5554733A
公开(公告)日：1996-09-10
申请号：US411258
申请日：1995-03-27
申请人： Athanassios Tzikas , Rolf Deitz
发明人： Athanassios Tzikas , Rolf Deitz
IPC分类号： C09B62/473 , C09B62/44 , C09B62/085 , D06P3/24
CPC分类号： C09B62/4413
摘要： Reactive dyes of formula ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by hydroxyl, R.sub.2 and R.sub.3 are each independently of the other hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, halogen or sulfo, and Y is .alpha.,.beta.-dihalopropionyl or .alpha.-haloacryloyl, are particularly suitable for dyeing or printing cellulosic fibre materials or natural or synthetic polyamide fibre materials, in high tinctorial yield, and give dyeings and prints with good fastness properties.
摘要翻译：式（1）其中R1是未被取代或被羟基取代的C1-C4烷基的反应性染料，R2和R3各自独立地为另一个氢，C1-C4烷基，C1-C4烷氧基，C2-C4烷酰基氨基，卤素或磺基，Y是α，β-二卤代丙酰基或α-卤代丙烯酰基，特别适用于以高着色产率染色或印刷纤维素纤维材料或天然或合成聚酰胺纤维材料，并给出具有良好牢度性能的染色和印花。

58. 发明授权

US5530104A Fiber reactive disazo dyes having a 2-vinylsulfonyl-5-sulfoaniline diazo component or a precursor thereof 失效
标题翻译：具有2-乙烯基磺酰基-5-磺基苯胺重氮组分的纤维反应性双偶氮染料或其前体
公开(公告)号：US5530104A
公开(公告)日：1996-06-25
申请号：US324826
申请日：1994-10-18
申请人： Athanassios Tzikas , Claudia Carisch
发明人： Athanassios Tzikas , Claudia Carisch
IPC分类号： C09B62/503 , C09B62/44 , C09B62/447 , C09B62/507 , D06P1/38 , C09B62/513 , D06P1/384
CPC分类号： C09B62/447 , C09B62/4411 , C09B62/507
摘要： Reactive dyes of the formula ##STR1## in which K and Z are as defined in claim 1, are suitable in particular for the dyeing and printing of cellulose-containing fibre material and produce dyeings and prints having good fastness properties in high coloristic yield.
摘要翻译：其中K和Z如权利要求1所定义的式（1）的活性染料特别适用于含纤维素纤维材料的染色和印花，并产生具有高色牢度性能的染色和印花产量。

59. 发明授权

US5451665A Fibre-reactive dyes containing two halotriazine groups and dye mixtures and their use 失效
标题翻译：含有两个卤代三嗪基团和染料混合物的纤维反应性染料及其用途
公开(公告)号：US5451665A
公开(公告)日：1995-09-19
申请号：US48082
申请日：1993-04-15
申请人： Athanassios Tzikas
发明人： Athanassios Tzikas
IPC分类号： C07D251/50 , C09B62/02 , C09B62/04 , C09B62/06 , C09B62/085 , C09B62/09 , C09B62/095 , C09B62/10 , C09B67/22 , D06P1/38 , D06P1/382 , D06P3/66
CPC分类号： C09B62/04 , C09B62/02 , C09B67/004 , C09B67/0041 , C09B67/0042 , C09B67/0047 , Y10S8/918
摘要： The invention relates to dye mixtures which contain dyes of the formulae ##STR1## and to dyes of the formula ##STR2## in which A.sub.1, A.sub.2, A.sub.3, B, B.sub.1, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, Z.sub.1, Z,.sub.2, X.sub.1, X.sub.2 and X.sub.3 are as defined in claim 1.The dyes and dye mixtures are distinguished by generally good properties and produce dyeings and prints having good wet and light fastness properties.
摘要翻译：本发明涉及染料混合物，其含有式（1）和（IMAGE）（2）的染料和式（2a）的染料，其中A1，A2，A3，B，B1，R1 R2，R3，R4，R5，Z1，Z2，X1，X2和X3如权利要求1中所定义。染料和染料混合物的特征在于通常具有良好的性能并产生具有良好的耐湿和耐光性的染色和印花。

60. 发明授权

US5243033A Fiber-reactive disazo and tetrakisazo halotriazinyl dyes 失效
标题翻译：纤维反应性灭菌剂和四氮嘧啶氢化胆碱染料
公开(公告)号：US5243033A
公开(公告)日：1993-09-07
申请号：US819709
申请日：1992-01-13
申请人： Athanassios Tzikas
发明人： Athanassios Tzikas
IPC分类号： C07D251/50 , C09B62/04 , C09B62/09 , C09B62/533 , D06P1/382 , D06P3/66
CPC分类号： C09B62/09 , C09B62/043
摘要： Reactive dyes of the formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3, independently of one another, are C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, ureido, C.sub.1 -C.sub.4 acylamino, carboxyl and sulfo and n, m and p, independently of one another, are the number 0, 1, 2 or 3, X is fluorine or chorine and Z is an aliphatic, araliphatic, aromatic or heterocyclic amino group free from fibre-reactive radicals; or Z is the radical of an aliphatic or aromatic diamine which contains the radical of the formula ##STR2## in which R.sub.1, R.sub.2, R.sub.3, n, m, p and X are as defined, bound via the second amino group; or Z is a radical of the formula ##STR3## in which R.sub.1, R.sub.2, R.sub.3, n, m, and p are as defined; or Z is a radical --NH--SO.sub.2 --(CH.sub.2).sub.2 --OSO.sub.3 H; and the reactive dye of the formula (1) contains at least two sulfo groups, produce, on cellulose fibres, orange dyeings of high color strength and prints of good fastness properties.
摘要翻译：其中R 1，R 2和R 3彼此独立地是C1-C4烷基，C1-C4烷氧基，卤素，脲基，C1-C4酰氨基，羧基和磺基和n的式（Ⅰ）的反应性染料， m和p彼此独立地是数0,1,2或3，X是氟或氯，Z是不含纤维反应性基团的脂族，芳脂族，芳族或杂环氨基; 或Z是脂族或芳族二胺的基团，其含有下式的基团：其中R 1，R 2，R 3，n，m，p和X如上定义，其通过第二个氨基; 或Z是式（2a）的基团，其中R 1，R 2，R 3，n，m和p如所定义; 或Z是基团-NH-SO 2 - （CH 2）2 -OSO 3 H; 并且式（1）的活性染料含有至少两个磺基，在纤维素纤维上产生高色强度的橙色染色和耐牢度特性良好的印花。

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