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51. 发明授权

US07482423B2 Polycarbonates and method of preparing same 有权
标题翻译：聚碳酸酯及其制备方法
公开(公告)号：US07482423B2
公开(公告)日：2009-01-27
申请号：US11427861
申请日：2006-06-30
申请人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr.
发明人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr.
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08G64/307 , C08G64/04
摘要： Polycarbonates incorporating terminal carbonate groups derived from ester-substituted activated carbonates, for example terminal methyl salicyl carbonate (TMSC) derived from the use of BMSC as the activated carbonate in a transesterification process, have unfavorable properties with respect to color, hydrolytic stability and thermal stability, particularly when the polycarbonate containing such end groups is molded. The number of activated carbonate end groups formed during the melt transesterification formation of polycarbonate can be reduced, however, without sacrificing the benefits of using an activated diaryl carbonate, and without requiring a separate reaction or additional additives by reacting a dihydroxy compound with an activated diaryl carbonate in the presence of an esterification catalyst to produce a polycarbonate, wherein the molar ratio of activated diaryl carbonate to dihydroxy compound is less than 1 when expressed to at least three decimal places, for example 0.996 or less.
摘要翻译：由酯取代的活性碳酸酯衍生的末端碳酸酯基团的聚碳酸酯，例如在酯交换法中使用BMSC作为活性碳酸酯的末端甲基水杨酸碳酸酯（TMSC）在颜色，水解稳定性和热稳定性方面具有不利的性质特别是当含有这种端基的聚碳酸酯被模制时。然而，在聚碳酸酯的熔融酯交换形成期间形成的活化碳酸酯端基的数量可以降低，但不会牺牲使用活性碳酸二芳基酯的优点，并且不需要单独的反应或另外的添加剂，通过使二羟基化合物与活化的二芳基在酯化催化剂存在下制备碳酸酯以制备聚碳酸酯，其中活化的碳酸二芳酯与二羟基化合物的摩尔比当表示至少三位小数，例如0.996或更小时小于1。

52. 发明申请

US20080004379A1 Polycarbonate with Reduced Color 有权
标题翻译：聚碳酸酯减少颜色
公开(公告)号：US20080004379A1
公开(公告)日：2008-01-03
申请号：US11688551
申请日：2007-03-20
申请人： Sjef Berndsen , Hans Peter Brack , Bernd Jansen , Dennis Karlik , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey
发明人： Sjef Berndsen , Hans Peter Brack , Bernd Jansen , Dennis Karlik , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey
IPC分类号： C08G64/08
CPC分类号： C08K5/49 , C08L69/00
摘要： A method of making polycarbonate includes the steps of forming polycarbonate by a melt transesterification method using an activated diaryl carbonate, and compounding the polycarbonate with a phosphorus-containing compound that has an abstractable proton or hydrolyzable group. The phosphorus-containing compound is compounded with the polycarbonate in an amount sufficient to result in an improvement in the color properties of the polycarbonate as compared to pellets formed from the same polycarbonate without addition of the phosphorus-containing compound.
摘要翻译：制备聚碳酸酯的方法包括通过使用活化的碳酸二芳基酯的熔体酯交换法形成聚碳酸酯的步骤，并将聚碳酸酯与具有可抽提的质子或可水解基团的含磷化合物混合。含磷化合物与聚碳酸酯混合，其量足以导致与不加入含磷化合物相同的聚碳酸酯形成的粒料相比，聚碳酸酯的着色性能得到改善。

53. 发明授权

US06600004B1 Method of preparing polyestercarbonates 有权
标题翻译：聚碳酸酯的制备方法
公开(公告)号：US06600004B1
公开(公告)日：2003-07-29
申请号：US10118634
申请日：2002-04-10
申请人： Patrick Joseph McCloskey , Paul Michael Smigelski
发明人： Patrick Joseph McCloskey , Paul Michael Smigelski
IPC分类号： C08G6400
CPC分类号： C08G63/64
摘要： A method of preparing polyestercarbonates is presented in which a mixture of at least one activated diaryl carbonate is reacted under melt polymerization conditions with at least one aromatic dihydroxy compound together with at least one dicarboxylic acid. Polyestercarbonates possessing up to about percent 10 mole dicarboxylic acid residues based on the total amount of structural units derived from aromatic dihydroxy compounds are obtained. The method provides both for high levels of incorporation of the dicarboxylic acid into the polyestercarbonate backbone and a high level of polymer endcapping.
摘要翻译：提出了一种制备聚酯碳酸酯的方法，其中至少一种活化的碳酸二芳基酯的混合物在熔融聚合条件下与至少一种芳族二羟基化合物与至少一种二羧酸一起反应。得到基于衍生自芳族二羟基化合物的结构单元的总量，具有高达约10摩尔二羧酸残基的聚酯碳酸酯。该方法既提供高水平的二羧酸结合到聚酯碳酸酯骨架中，也提供高水平的聚合物封端。

54. 发明授权

US06569985B2 Method for making polycarbonate 有权
标题翻译：制作聚碳酸酯的方法
公开(公告)号：US06569985B2
公开(公告)日：2003-05-27
申请号：US09924137
申请日：2001-08-08
申请人： Patrick Joseph McCloskey , Alberto Nisoli , Warren William Reilly
发明人： Patrick Joseph McCloskey , Alberto Nisoli , Warren William Reilly
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： Polycarbonates having a high level of endcapping and containing a low level of Fries rearrangement product are prepared from dihydroxy aromatic compounds, such as bisphenol A, and diaryl carbonates such as diphenyl carbonate in a two stage process involving a tetraalkyl phosphonium carboxylate catalyzed oligomerization of the reactants in a first reaction stage followed by the addition of an alkali metal hydroxide co-catalyst in the second stage of the polymerization reaction. The late addition of the co-catalyst provides improved polymerization reaction rates as judged by higher polycarbonate molecular weights. The amount of alkali metal hydroxide co-catalyst is small thus avoiding the formation of excessive amounts of Fries product. The method has been used to provide Fries product levels between 200 and 800 parts per million in polycarbonates having Mn values between 7,500 and 8,500 Daltons.
摘要翻译：具有高水平的封端并含有低含量的Fries重排产物的聚碳酸酯由二羟基芳族化合物如双酚A和碳酸二芳基酯如碳酸二苯酯在涉及四烷基鏻羧酸酯催化的反应物低聚的两步法中制备在第一反应阶段，然后在聚合反应的第二阶段加入碱金属氢氧化物助催化剂。通过较高的聚碳酸酯分子量判断，辅助催化剂的晚期添加提供了改进的聚合反应速率。碱金属氢氧化物助催化剂的量很小，从而避免形成过量的油炸产品。该方法已经被用于在Mn值在7,500和8,500道尔顿之间的聚碳酸酯中提供200至800ppm之间的Fries产品水平。

55. 发明授权

US06548623B2 Method of polycarbonate preparation 有权
标题翻译：聚碳酸酯制备方法
公开(公告)号：US06548623B2
公开(公告)日：2003-04-15
申请号：US09911443
申请日：2001-07-24
申请人： Daniel Joseph Brunelle , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Ganesh Kailasam
发明人： Daniel Joseph Brunelle , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Ganesh Kailasam
IPC分类号： C08G6400
CPC分类号： C08G64/06 , C08G64/04 , C08G64/14 , C08G64/307
摘要： Polycarbonates containing low or undetectable levels of Fries rearrangement product may be prepared by the melt reaction of a dihydroxy aromatic compound such as bisphenol A with an ester-substituted diaryl carbonate such as the diaryl carbonate of methyl salicylate, bis-methyl salicyl carbonate. Low levels of Fries product are obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reaction using diphenyl carbonate.
摘要翻译：含有低或不可检测水平的Fries重排产物的聚碳酸酯可以通过二羟基芳族化合物如双酚A与酯取代的二芳基碳酸酯例如水杨酸甲酯的碳酸二芳基酯，碳酸双甲基酯的熔融反应来制备。通过抑制Fries反应的高效催化剂体系和相对于使用碳酸二苯酯的类似聚合反应所需的温度使用较低熔融聚合温度的综合结果，可以获得低水平的油炸产品。

56. 发明授权

US06420588B1 Interfacial method of preparing ester-substituted diaryl carbonates 有权
标题翻译：制备酯取代的碳酸二芳基酯的界面方法
公开(公告)号：US06420588B1
公开(公告)日：2002-07-16
申请号：US09911440
申请日：2001-07-24
申请人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Daniel Joseph Brunelle , Elliott West Shanklin , Paul Michael Smigelski, Jr. , Ganesh Kailasam
发明人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Daniel Joseph Brunelle , Elliott West Shanklin , Paul Michael Smigelski, Jr. , Ganesh Kailasam
IPC分类号： C07C6996
CPC分类号： C07C68/02 , C07C69/96
摘要： High yields of ester-substituted diary carbonates such as bis-methyl salicyl carbonate were obtained by the condensation of methyl salicylate with phosgene in the presence of a phase transfer catalyst (PTC) in an interfacial reaction system in which the pH of the aqueous phase was greater than 9.3. Using the method of the present invention conversions of greater than 99% were obtained whereas under standard conditions using triethylamine as the catalyst conversions were limited to 70-75% of the methyl salicylate starting material even with a 20 mole % excess of added phosgene. The optimized conditions of the of the present invention use only a slight excess of phosgene and represent an attractive route for the manufacture of bis methyl salicyl carbonate and ester-substituted diaryl carbonates generally.
摘要翻译：通过在界面反应体系中存在相转移催化剂（PTC）的情况下，通过水杨酸甲酯与光气的缩合得到高产率的酯取代的二元碳酸酯，其中水相的pH为大于9.3。使用本发明的方法获得大于99％的转化率，而在使用三乙胺的标准条件下，即使使用20摩尔％过量的加入的光气，催化剂转化率也限于水杨酸甲酯起始原料的70-75％。本发明的优化条件仅使用轻微过量的光气，并且代表通常用于制造碳酸双甲基水杨酸酯和酯取代的二芳基碳酸酯的有吸引力的途径。

57. 发明授权

US06414106B1 Process for the neutralization of residual acid species in crude dihydric phenols 有权
公开(公告)号：US06414106B1
公开(公告)日：2002-07-02
申请号：US09798221
申请日：2001-03-02
申请人： Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Patrick Joseph McCloskey
发明人： Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Patrick Joseph McCloskey
IPC分类号： C08G6400
CPC分类号： C07C37/86 , C07C39/16
摘要： The present invention relates to a method of neutralizing residual acid species in crude dihydric phenol comprising the step of introducing a thermally stable organic base selected from the group consisting of tetraalkyl phosphonium hydroxides, tetraorganophosphonium carboxylic acid salts, or a mixture thereof into the crude dihydric phenol.

58. 发明授权

US06403754B1 Optimization of polycarbonate preparation by transesterification 失效
标题翻译：通过酯交换优化聚碳酸酯制备
公开(公告)号：US06403754B1
公开(公告)日：2002-06-11
申请号：US09770487
申请日：2001-01-29
申请人： Patrick Joseph McCloskey , Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Juan Rodriques Ordonez , Ignacia Vic Fernandez , Gerardo Hidalgo-Llinas , Rudy Francois Alain J. Peemans , Edward Venama
发明人： Patrick Joseph McCloskey , Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Juan Rodriques Ordonez , Ignacia Vic Fernandez , Gerardo Hidalgo-Llinas , Rudy Francois Alain J. Peemans , Edward Venama
IPC分类号： C08G6400
CPC分类号： C08G64/307 , Y02P20/582
摘要： Acidic impurities in dihydroxyaromatic compounds such as bisphenol A, as illustrated by sulfonic acids and mercaptocarboxylic acids, can have an adverse effect on the molecular weight of a polycarbonate prepared therefrom by transesterification. The same is true of acidic impurities in diaryl carbonates such as diphenyl carbonate, as illustrated by salicylic acid and ferric chloride. The reagents are analyzed for these impurities. Based on the analysis, the reagents are discarded or recycled, or a compensatory amount of alkali metal hydroxide is employed as a catalyst in the reaction.
摘要翻译：二磺基化合物如双酚A的酸性杂质如磺酸和巯基羧酸所示，可通过酯交换对其制备的聚碳酸酯的分子量产生不利影响。碳酸二芳基酯如碳酸二苯酯中的酸性杂质也是如此，如水杨酸和氯化铁所示。分析这些杂质的试剂。基于分析，将试剂废弃或再循环，或者在反应中使用补偿量的碱金属氢氧化物作为催化剂。

59. 发明授权

US06333394B1 Copolycarbonate preparation by solid state polymerization 有权
标题翻译：通过固态聚合制备共聚碳酸酯
公开(公告)号：US06333394B1
公开(公告)日：2001-12-25
申请号：US09379234
申请日：1999-08-23
申请人： Christian Maria Emile Bailly , Bhaskar Bhairavnath Idage , Swaminathan Sivaram , Nayaku Nivarati Chavan , Rein Mollerus Faber , Shamal Karunakaran Menon , Gautam Chatterjee , Godavarthi Satyana Varadarajan , James Day , Patrick Joseph McCloskey , Joseph Anthony King, Jr. , Arun Savalaram Jadhav
发明人： Christian Maria Emile Bailly , Bhaskar Bhairavnath Idage , Swaminathan Sivaram , Nayaku Nivarati Chavan , Rein Mollerus Faber , Shamal Karunakaran Menon , Gautam Chatterjee , Godavarthi Satyana Varadarajan , James Day , Patrick Joseph McCloskey , Joseph Anthony King, Jr. , Arun Savalaram Jadhav
IPC分类号： C08G6400
CPC分类号： C08G64/20 , C08G64/06 , C08G64/14 , C08G64/183 , C08G64/307
摘要： Copolycarbonates containing such structural units as birefringence-reducing or “soft block” units are prepared by conducting a reaction, such as melt polymerization or equilibration, between a precursor polycarbonate and a monomer, polycarbonate oligomer or high molecular weight polycarbonate which is a source of other structural units. The crystallinity of the resulting precursor copolycarbonate or one of the reagents employed in its preparation is enhanced and the precursor copolycarbonate is subjected to solid state polymerization.
摘要翻译：通过在前体聚碳酸酯和单体，聚碳酸酯低聚物或高分子量聚碳酸酯之间进行诸如熔融聚合或平衡的反应来制备含有诸如双折射降低或“软嵌段”单元的结构单元的共聚碳酸酯结构单位。得到的前体共聚碳酸酯或其制备中使用的试剂之一的结晶度提高，前体共聚碳酸酯进行固态聚合。

60. 发明授权

US06316578B1 Salts of non-volatile acids as polymerization catalysts 有权
标题翻译：不挥发酸的盐作为聚合催化剂
公开(公告)号：US06316578B1
公开(公告)日：2001-11-13
申请号：US09497938
申请日：2000-02-04
申请人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr.
发明人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr.
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： This invention relates to a method for the preparation of polycarbonate by the melt process comprising reacting a diphenol and a diarylcarbonate in the presence of a catalyst system comprising a catalytically effective amount of an alkali and/or alkali earth metal salt of a non volatile acid and a base.
摘要翻译：本发明涉及通过熔融法制备聚碳酸酯的方法，包括在催化剂体系存在下使二酚和二芳基碳酸酯反应，所述催化剂体系包含催化有效量的非挥发性酸的碱金属和/或碱土金属盐，和一个基地

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