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    • 53. 发明申请
    • PROCESS FOR PRODUCING POTASSIUM FORMATE
    • 生产钾肥的方法
    • WO2008091186A1
    • 2008-07-31
    • PCT/SE2007/001060
    • 2007-11-30
    • PERSTORP SPECIALTY CHEMICALS ABAXELSSON, GöranPAULSSON, ChristofferOLSSON, Pär
    • AXELSSON, GöranPAULSSON, ChristofferOLSSON, Pär
    • C07C53/06C07C51/42
    • C07C51/41C07C53/06
    • The present invention relates to a process for producing potassium formate. Formaldehyde, potassium hydroxide and isobutyraldehyde are reacted in water, at a molar ratio of 1.0:1.0:1.0 to 3.0:2.0:1.0 and at a temperature of 0-1000C, preferably 30-700C. The obtained reaction solution is neutralised to pH 4-6 and evaporated in a first step, whereby two phases are obtained, one organic phase and one aqueous phase, the latter comprising the main part of the potassium formate. The organic phase is subsequently separated from the aqueous phase, where after a final evaporation of the aqueous phase takes place at a pressure of 0.0-1.0 bar and a temperature of 160-2500C, to obtain a melt of potassium formate. Water is added followed by filtration resulting in a solution having a content of >99% by weight of potassium formate, calculated on a water free basis.
    • 本发明涉及一种生产甲酸钾的方法。 甲醛,氢氧化钾和异丁醛在水中以1.0:1.0:1.0至3.0:2.0:1.0的摩尔比和0-100℃,优选30-70℃的温度反应。 将得到的反应溶液中和至pH 4-6,并在第一步骤中蒸发,得到两相,一个有机相和一个水相,后者包含甲酸钾的主要部分。 有机相随后从水相中分离出来,其中水相的最终蒸发在0.0-1.0巴的压力和160-250℃的温度下进行,得到甲酸钾的熔体。 加入水,然后过滤,得到含量> 99重量%的甲酸钾的无水溶液计算的溶液。
    • 59. 发明申请
    • METHOD FOR EXTRACTION IN A PROCESS FOR PRODUCTION OF A DI, TRI OR POLYHYDRIC ALCOHOL
    • 用于生产DI,TRI或POLYHYDRIC酒精的方法提取方法
    • WO2008156406A1
    • 2008-12-24
    • PCT/SE2008/000350
    • 2008-05-26
    • PERSTORP SPECIALTY CHEMICALS ABPAJALIC, OlegENGBERG, DavidAXELSSON, Göran
    • PAJALIC, OlegENGBERG, DavidAXELSSON, Göran
    • C07C29/86C07C31/22C07C31/24
    • C07C29/86C07C31/245C07C31/22
    • Disclosed is a method for extraction in a process for production of a 2-alkyl-l,3-propanediol, 2,2-dialkyl- 1,3 -propanediol, 2-alkyl-2-hydroxyalkyl-l,3-propanediol or 2,2-dihydroxialkyl- -1,3-propanediol. Said method comprises the steps of (i) feeding a mother liquid, obtained in a process for synthesis of a said di, tri or polyhydric alcohol, at a controlled mass flow to a first extraction unit, (ii) extracting said mother liquid in said first extraction unit in at least one high boiling solvent effective in extracting organic by-products, (iii) obtaining a raffmate and an extract comprising said solvent and organic by-products, (iv) recycling said raffmate to said process, (v) feeding at a controlled mass flow obtained extract to a second extraction unit, (vi) extracting said extract in water, (vii) obtaining a water phase comprising said organic by-products and a solvent phase, and (viii) recycling said solvent phase.
    • 公开了一种制备2-烷基-1,3-丙二醇,2,2-二烷基-1,3-丙二醇,2-烷基-2-羟基烷基-1,3-丙二醇或2 ,2-二羟基烷基-1,3-丙二醇。 所述方法包括以下步骤:(i)将以合成所述二,三或多元醇的方法获得的母液以受控的质量流送入第一提取单元,(ii)在所述第一提取单元中提取所述母液, 在有效提取有机副产物的至少一种高沸点溶剂中的第一提取单元,(iii)获得含有所述溶剂和有机副产物的萃取物,(iv)将所述反应物再循环至所述方法,(v) (vi)在水中提取所述提取物,(vii)获得包含所述有机副产物和溶剂相的水相,和(viii)回收所述溶剂相。
    • 60. 发明申请
    • ENERGY USAGE IN EXOTHERMIC REACTIONS
    • 能量反应中的能源使用
    • WO2007111553A1
    • 2007-10-04
    • PCT/SE2007/000274
    • 2007-03-21
    • PERSTORP SPECIALTY CHEMICALS ABMAGNUSSON, AndreasERLANDSSON, OlaMARKE, Birgitta
    • MAGNUSSON, AndreasERLANDSSON, OlaMARKE, Birgitta
    • C07C47/052
    • C07C45/38C07C47/04
    • A process for the manufacturing of formaldehyde wherein the formaldehyde is manufactured in a reactor and wherein exothermic energy is a result of the process. The reactor is pressurised through means of a compressor and that the exothermic energy from the process is used for feeding energy to the compressor, hereby, allowing increase in pressure in the reactor with a minimum of required power input from external source. The invention also relates to a apparatus for manufacturing formaldehyde wherein the formaldehyde is manufactured in a reactor and wherein exothermic energy is a result of the process. The reactor is pressurised through means of a compressor and that the exothermic energy from the process is used for feeding energy to the compressor, hereby allowing increase in pressure in the reactor with a minimum of required power input from external source.
    • 制造甲醛的方法,其中甲醛在反应器中制造,其中放热能是该方法的结果。 反应器通过压缩机加压,并且来自该方法的放热能用于向压缩机供给能量,因此允许以较少的外部源输入的最小功率来增加反应器中的压力。 本发明还涉及一种用于制造甲醛的装置,其中甲醛在反应器中制造,其中放热能是该方法的结果。 反应器通过压缩机进行加压,并且来自该方法的放热能用于向压缩机供给能量,从而允许以从外部源输入的最小功率来增加反应器中的压力。