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41. 发明专利

GB1443639A QUATERNARY AMMONIUM SALTS OF MALIC ACID 未知
公开(公告)号：GB1443639A
公开(公告)日：1976-07-21
申请号：GB5490274
申请日：1974-12-19
申请人： ANVAR
IPC分类号： C07C59/245 , A61K20060101 , A61K8/00 , A61K8/30 , A61K8/36 , A61K8/365 , A61K8/40 , A61K8/41 , A61Q5/00 , A61Q5/02 , A61Q19/00 , C07C20060101 , C07C51/00 , C07C67/00 , C07C209/00 , C07C211/63 , C07C211/64 , C07C87/30 , A61K7/00 , C07C87/68 , C07C59/12
摘要： 1443639 Quaternary ammonium salts of malic acid ANVAR AGENCE NATIONALE DE VALORISATION DE LA RECHERCHE 19 Dec 1974 [21 Dec 1973] 54902/74 Heading C2C [Also in division A5] Novel quaternary ammonium salts of malic acid of Formula I where R is a saturated or unsaturated C 8 -C 20 monovalent aliphatic hydrocarbon radical; and R 1 , R 2 and R 3 which may be the same or different are C 1 -C 4 alkyl or aryl radicals, are prepared by reacting malic acid with the corresponding hydroxide of the quaternary ammonium salt in an aqueous medium in the presence of ethanol or isopropanol. The hydroxide may be formed in situ by reaction of the corresponding halide of the quaternary ammonium salt with an excess of silver hydroxide. The compounds of Formula I are used in cosmetic compositions.

42. 发明专利

GB1426137A PROCESS FOR PRODUCING L-MALIC ACID ANIONS OF L-MALIC ACID OR SALTS OF L-MALIC ACID 未知
公开(公告)号：GB1426137A
公开(公告)日：1976-02-25
申请号：GB1219874
申请日：1974-03-19
申请人： SNAM PROGETTI
IPC分类号： C12N11/04 , C12N11/08 , C12N11/12 , C12P7/42 , C12P7/46 , C12R1/01 , C12R1/38 , D01F1/10 , C07C59/12
摘要： Filamentary structures containing encapsulated fumarase are used for the enzymatic preparation of l-malic acid from solutions of fumaric acid salts. The fibres encapsulating the fumarase are obtained from polymers which can form fibres and are selected from esterified, nitrated cellulosics, polyolefins, polymers and copolymers of acrylonitrile, acrylates, methacrylates, vinyl esters, vinyl chloride, vinylidene chloride, styrene, polyamides or polyvinyl butyral, especially polymers of cellulose triacetate. The process makes it possible to achieve the enzymatic hydration of fumaric acid to give l-malic acid with remarkable ease; since the enzyme is immobilised, it can be used more than once and does not contaminate the product.

43. 发明专利

AU6692974A L-MALIC ACID 未知
公开(公告)号：AU6692974A
公开(公告)日：1975-09-25
申请号：AU6692974
申请日：1974-03-21
申请人： SNAM PROGETTI
发明人： BETTONTE MARIO , MORISI FRANCO , MOSTI ROSANNA
IPC分类号： C12N11/04 , C12N11/08 , C12N11/12 , C12P7/42 , C12P7/46 , C12R1/01 , C12R1/38 , D01F1/10 , C07B29/02 , C07C59/12 , C12D13/10

44. 发明专利

DE2459993A1 未知
公开(公告)号：DE2459993A1
公开(公告)日：1975-07-03
申请号：DE2459993
申请日：1974-12-18
申请人： ANVAR
发明人： GRIGNARD ROBERT
IPC分类号： C07C59/245 , A61K20060101 , A61K8/00 , A61K8/30 , A61K8/36 , A61K8/365 , A61K8/40 , A61K8/41 , A61Q5/00 , A61Q5/02 , A61Q19/00 , C07C20060101 , C07C51/00 , C07C67/00 , C07C209/00 , C07C211/63 , C07C211/64 , C07C59/12 , A61K7/48
摘要： Quaternary ammonium salts of malic acid having the formula: R1+OO+R1 ¦ PARALLEL PARALLEL ¦ R-N-R2 O-C-CHOH-CH2-O-O R-N-R2 ¦¦ R3R3 where: R is a monovalent aliphatic hydrocarbon radical, saturated or unsaturated, of from 8 to 20 carbon atoms but preferably of 12 to 18 carbon atoms; R1, R2, R3 may be identical or different and each represents a lower alkyl radical or an aryl radical. The salts find use in cosmetics as a source of the malic ions necessary to the energy process in cellular metabolism. These salts insure a better intracellular penetration of malic ion and improve the stability of creams and other cosmetic emulsions.

45. 发明专利

SE7416074A 未知
公开(公告)号：SE7416074A
公开(公告)日：1975-06-23
申请号：SE7416074
申请日：1974-12-19
申请人： ANVAR
发明人： GRIGNARD R
IPC分类号： C07C59/245 , A61K20060101 , A61K8/00 , A61K8/30 , A61K8/36 , A61K8/365 , A61K8/40 , A61K8/41 , A61Q5/00 , A61Q5/02 , A61Q19/00 , C07C20060101 , C07C51/00 , C07C67/00 , C07C209/00 , C07C211/63 , C07C211/64 , C07C59/12
CPC分类号： A61K8/365 , A61K8/416 , A61Q5/00 , A61Q5/02 , A61Q19/00 , Y10S514/97

46. 发明专利

DE2450137A1 Purer L-malic acid prodn - using a fumarase-forming microorganism immobilised in an acrylic matrix 未知
公开(公告)号：DE2450137A1
公开(公告)日：1975-04-24
申请号：DE2450137
申请日：1974-10-22
申请人： TANABE SEIYAKU CO
发明人： CHIBATA ICHIRO , TOSA TETSUYA , SATO TADASHI , YAMAMOTO KOZO , TAKATSUKI OSAKA
IPC分类号： C12N9/88 , C12N11/04 , C12N11/08 , C12P7/46 , C07C59/12 , C07G7/02
摘要： L-malic acid is produced using a fumarase-forming microorganism (I) by polymerising an acryloyl monomer in an aqs. suspension of (I) to immobilise it and then subjecting the prod. to reaction with fumarase. Formation of side-prods. (e.g. succinic acid) is avoided, the microorganism retains high fumarase activity over an extended period, the reaction product does not need further purifcn. and (I) is re-usable. (I) includes Brevibacterium ammoniagenes IAM 1641 (ATCC 6871) and IAM 1645 (ATCC 6872), Corynebacterium equi IAM 1038, E. coli ATCC 11303, Microbacterium flavum IAM 1642, Proteus vulgaris IFO 3045 and Pichia farinosa IFO 0574 and are used in amts. of 0.1-5, pref. 1-3 g per g acryloyl.

47. 发明专利

NL144596B 未知
公开(公告)号：NL144596B
公开(公告)日：1975-01-15
申请号：NL6511348
申请日：1965-08-31
申请人： STANDARD OIL CO
IPC分类号： C07C17/30 , C07C51/12 , C07C51/34 , C07D311/00 , C07D311/76 , C07D311/92 , C08F8/06 , C07C120/02 , C07B29/00 , C07C51/08 , C07C59/12 , C07C101/26 , C08F8/30

48. 发明专利

GB1371430A PROCESS FOR PREPARING HYDROXY CITRONELLYL ESTERS 未知
公开(公告)号：GB1371430A
公开(公告)日：1974-10-23
申请号：GB5085372
申请日：1972-04-27
申请人： RHONE POULENC SA
IPC分类号： C07C47/26 , C07C59/12 , C07C57/02 , C07C59/18
摘要： 1371430 Hydroxycitronellyl enol esters SOC DES USINES CHIMIQUES RHONEPOULENC 27 April 1972 [28 April 1971] 50853/72 Divided out of 1371429 Heading C2C Esters (I) and (II) are made by reacting the esters (III) and (IV) with 58-78% w/v aqueous H 2 SO 4 , R being C 1 -C 6 alkyl. The esters (III) and (IV) may be made by reacting citronellal with an aliphatic carboxylic anhydride in the presence of an alkali metal carboxylate.

49. 发明专利

GB1342360A DETERGENT COMPOSITIONS 未知
公开(公告)号：GB1342360A
公开(公告)日：1974-01-03
申请号：GB1342360D
申请日：1970-12-04
申请人： UNILEVER LTD
IPC分类号： C11D3/00 , C11D3/16 , C11D3/20 , C07C59/12 , C11D1/02 , C11D1/66 , C11D1/84
摘要： 1342360 Hexadecylsuccinic acid salts UNILEVER Ltd 1 Dec 1971 [4 Dec 1970] 57647/70 Addition to 1293753 Heading C2C [Also in Division C5] Disodium 5,6-dichloro hexadecylsuccinate is prepared by treating hexadecenyl succinic anhydride with chlorine and then with sodium hydroxide. Disodium 5,6-dihydroxy hexadecylsuccinate is prepared by treating hexadecenylsuccinic acid with formic acid and hydrogen peroxide followed by treatment with sodium hydroxide, acidification and further treatment with sodium hydroxide. Mixed 5- and 6-hydroxy disodium hexadecyl succinates are prepared by treating hexadecenyl succinic anhydride with cone. H 2 SO 4 and then with sodium hydroxide. Mixed disodium epoxy hexadecylsuccinates are prepared by treating hexadecenyl succinic anhydride with m-chloroperbenzoic acid, followed by sodium bisulphite and sodium carbonate. Disodium bromo-hydroxy hexadecyl succinate mixed with the dibromo compound is prepared by treating hexadecenyl succinic anhydride with bromine, followed by sodium hydroxide. Disodium hydroxyhexadecyl malonate is prepared by treating diethyl malonate with sodium and hexadecane 1,2-epoxide, followed by sodium hydroxide. Disodium nitro hexadecyl succinates (mixed 5-nitro and 6-nitro compounds) are prepared by treating hexadecenyl succinic anhydride with aqueous nitric acid and sodium nitrite and neutralizing with sodium hydroxide.

50. 发明专利

CH454825A Verfahren zur Herstellung von Äpfelsäure 未知
公开(公告)号：CH454825A
公开(公告)日：1968-04-30
申请号：CH1422065
申请日：1965-10-14
申请人： ALLIED CHEM
发明人： CARL ROBERT AHLGREN
IPC分类号： B01J19/00 , B01J19/02 , C07C51/367 , C22C14/00 , C22C16/00 , C22C27/02 , C07C51/00 , C07C59/12

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