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    • 50. 发明授权
    • Method of producing an integral skin polyurethane foam
    • 生产全身皮肤聚氨酯泡沫的方法
    • US3694530A
    • 1972-09-26
    • US3694530D
    • 1969-11-17
    • GOODYEAR TIRE & RUBBER
    • WOLFE JAMES D
    • B29C33/56B29C33/62B29C44/04C08J9/34B29D27/04C08G22/44
    • C08J9/34B29C33/56B29C33/62B29C44/04B29K2075/00B29K2105/043C08J2375/00Y10S264/05Y10S264/14Y10S264/18Y10S411/927Y10T428/24438Y10T428/24992Y10T428/31598
    • A method of producing integral skin polyurethane foams having densities as low as 1.0 to 3.0 lbs/ft3 and surfaces which may simulate grain leather. The mold surface is first coated with a release agent, then a skin forming agent and then the foamable polyurethane reaction mixture is cast in the coated mold. Representative examples of the skin forming agents are polyester polyether and polyhydrocarbon polyols of two to 10 hydroyxls, hydroxyl containing polymers having a hydrocarbon, polyester or polyether backbone. The above skin forming agents may be applied to the mold surface by incorporation in a suitable solvent such as a low boiling liquid hydrocarbon or ketone. Polyurethane catalysts may also be added to the film forming agent solution. Another group of film forming agents which may be used are particulate materials which have the ability to absorb at least 0.5 grams of water per gram of material. Representative examples are sodium chloride, diatomaceous earth and talc.
    • 一种生产密度低至1.0磅/立方英尺/立方厘米的整体表皮聚氨酯泡沫的方法和可以模拟谷物皮革的表面。 模具表面首先用脱模剂涂覆,然后涂覆成皮剂,然后将可发泡聚氨酯反应混合物浇铸在涂覆的模具中。 皮肤形成剂的代表性实例是聚酯聚醚和2至10个水溶性的多羟基多元醇,含羟基的聚合物具有烃,聚酯或聚醚主链。 上述皮肤成型剂可以通过掺入合适的溶剂如低沸点液体烃或酮中而施加到模具表面。 也可以将聚氨酯催化剂加入到成膜剂溶液中。 可以使用的另一组成膜剂是具有每克材料吸收至少0.5克水的能力的颗粒材料。 代表性的实例是氯化钠,硅藻土和滑石。