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    • 45. 发明申请
    • Method for preparing bismuth-based high temperature superconductors
    • 制备铋基高温超导体的方法
    • US20020022577A1
    • 2002-02-21
    • US09916175
    • 2001-07-26
    • Sergey LeeSetsuko Tajima
    • H01F001/00H01B001/00
    • C04B35/4525C04B35/4521H01L39/2477Y10S505/737Y10S505/742
    • The invention provides means for stably preparing a bismuth-based high temperature superconductor of a Bi-2223 single-phase or a Bi/Pb-2223 single phase, wherein a second phase is not allowed to reside, at low cost and efficiently. With the means described above, mixed powders of raw materials (mixed powders of oxides and carbonates), obtained by mixing the raw materials such that a mixing ratio of constituents, Bi:Sr:Ca:Cu or (Bi, Pb):Sr:Ca:Cu, becomes identical to a stoichiometric ratio of a crystal of the superconductor Bi2Sr2Ca2Cu3Oz, or (Bi, Pb)2Sr2Ca2Cu3Oz, respectively, are used as raw material for sintering, and the sintering is applied thereto, using KCl as a flux. In this case, the raw material for the sintering as calcinated is preferably used, and the sintering is preferably applied at a sintering temperature kept at a constant level.
    • 本发明提供了以低成本和高效率稳定地制备Bi-2223单相或Bi / Pb-2223单相的铋基高温超导体的方法,其中不允许第二相存在。 使用上述方法,通过将原料混合使得成分Bi:Sr:Ca:Cu或(Bi,Pb):Sr:Cb的组分的混合比例混合得到的原料混合粉末(氧化物和碳酸盐的混合粉末) Ca:Cu分别与超导体Bi2Sr2Ca2Cu3Oz的晶体的化学计量比相同,或(Bi,Pb)2Sr2Ca2Cu3Oz分别作为烧结原料,使用KCl作为助熔剂进行烧结。 在这种情况下,优选使用煅烧的烧结原料,烧结温度优选在保持恒定水平的烧结温度下进行。
    • 46. 发明授权
    • Strongly-linked oxide superconductor and a method of its manufacture
    • 强连接氧化物超导体及其制造方法
    • US06310297B1
    • 2001-10-30
    • US08477456
    • 1995-06-07
    • Lawrence J. MasurEric R. Podtburg
    • Lawrence J. MasurEric R. Podtburg
    • H01B1200
    • C04B35/65C04B35/45H01L39/2419H01L39/2477Y10S505/704Y10S505/736Y10S505/74Y10S505/742Y10S505/776Y10S505/78Y10S505/813Y10T29/49014
    • A strongly-linked polycrystalline oxide superconductor article includes an oxide superconductor selected from the group consisting 124-type and 247-type oxide superconductors having fine, highly aligned oxide superconductor grains less than &mgr;m long a longest dimension. The oxide superconductor article has at least a 25% retention of critical current density in a 0.1 Tesla field. A method for preparing a strongly-linked oxide superconductor includes shaping a finely divided metallic precursor of an oxide superconductor; oxidizing the finely divided metallic precursor to produce a finely divided sub-oxide species while avoiding conversion of an appreciable amount of the sub-oxide species into the oxide superconductor, annealing and deforming the article, in either order, the annealing carried out at a temperature and for a time sufficient to convert some of the sub-oxide species into fine grains of the oxide superconductor thereby forming a mixture of sub-oxide species and oxide superconductor and the deformation carried out such that the fine grains of oxide superconductor are rotated into alignment parallel to an intended current carrying direction of the article without fracturing or pulverization of the oxide superconductor grains; alternating annealing and deformation of the article until no further improvement in alignment is observed; and subjecting the aligned grains to a final anneal in order to react any remaining sub-oxide species and maximize the growth and sintering of existing aligned grains.
    • 强连接的多晶氧化物超导体制品包括选自124型和247型氧化物超导体的氧化物超导体,其具有小于长度最长尺寸的妈妈的精细高度排列的氧化物超导体晶粒。 氧化物超导体制品在0.1特斯拉场中具有至少25%的临界电流密度保留。 一种制备强连接的氧化物超导体的方法包括使细分的氧化物超导体的金属前体成形; 氧化细碎的金属前体以产生细碎的亚氧化物物质,同时避免将大量的次氧化物物质转化为氧化物超导体,退火和使制品变形,以任何顺序,在温度下进行退火 并且足以将一些氧化物物质转化为氧化物超导体的细晶粒的时间,从而形成次氧化物种类和氧化物超导体的混合物,并进行变形,使得氧化物超导体的细晶粒旋转成对准 平行于制品的预期电流输送方向,而不会破坏或粉碎氧化物超导体晶粒; 交替退火和变形,直到观察不到进一步改善; 并使对准的晶粒进行最终退火,以使任何剩余的亚氧化物物质反应并使现有对准晶粒的生长和烧结最大化。
    • 47. 发明授权
    • Superconducting metal-ceramic laminate
    • 超导金属陶瓷层压板
    • US6037068A
    • 2000-03-14
    • US107904
    • 1998-06-19
    • L. Pierre de RochemontMichael J. SuscavageDaniel F. Ryder, Jr.Mikhail Klugerman
    • L. Pierre de RochemontMichael J. SuscavageDaniel F. Ryder, Jr.Mikhail Klugerman
    • C23C16/40C23C16/56H01L39/02H01L39/14H01L39/24B32B9/00
    • H01L39/143C23C16/408C23C16/56H01L39/02H01L39/2451H01L39/2477Y10S428/93Y10S505/701Y10S505/702Y10S505/703Y10S505/704Y10T428/2929Y10T428/2931
    • This invention permits superconducting ceramics, as well as other ceramic materials, to be spray deposited onto indefinitely large sheets of metallic substrate from a carboxylic acid salt solution. Elemental metal precursors of the superconductor are introduced into the solution as carboxylic acid salts. The deposit formed on the malleable metallic substrate is then thermomechanically calcined to form c-axis textured metal-superconductor composite sheet structures. These composite sheet structures can be formed by pressing together two ceramic-substrate structures, ceramic face-to-face, to form a metal-ceramic-metal sheet structure, or by overlaying a metal sheet over the deposited structure. Once the structure has been thermomechanically calcined, the c-axis of the superconductor is oriented parallel to the vector defining the plane of the metal sheet, i.e., perpendicular to the surface of the plane. These sheets of c-axis textured superconductor can then be mechanically worked as continuous superconducting filaments into larger composite structures with predetermined c-axis orientation. The fact that the c-axis of the superconductor is given predetermined orientation allows surface topologies to be mechanically constructed from these sheets that maximize the performance of the superconductor for a predetermined application or magnetic field environment.
    • 本发明允许将超导陶瓷以及其它陶瓷材料从羧酸盐溶液喷涂到无限大的金属基材片上。 将超导体的元素金属前体作为羧酸盐引入溶液中。 然后将在韧性金属基材上形成的沉积物进行热机械煅烧以形成c轴织构的金属 - 超导体复合片材结构。 这些复合片材结构可以通过将两个陶瓷 - 衬底结构陶瓷面对面地组合在一起形成金属 - 陶瓷 - 金属片结构,或者通过在沉积结构上覆盖金属片来形成。 一旦结构被热力学煅烧,超导体的c轴平行于限定金属板的平面,即垂直于平面的表面的向量取向。 然后可以将这些c轴纹理超导体片材作为连续超导细丝机械加工成具有预定c轴取向的更大的复合结构。 超导体的c轴被给定为预定取向的事实允许表面拓扑结构由这些片材机械地构造,以使预定应用或磁场环境中的超导体的性能最大化。