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    • 42. 发明授权
    • Flame retardant for halogen-containing vinyl resins
    • 含卤乙烯基树脂的阻燃剂
    • US5190700A
    • 1993-03-02
    • US574606
    • 1990-08-29
    • Yoshitane WatanabeKeitaro SuzukiKouji ShishidoMasayuki TeranishiMasuo Shindo
    • Yoshitane WatanabeKeitaro SuzukiKouji ShishidoMasayuki TeranishiMasuo Shindo
    • C08K3/16C08K3/22C08K13/02
    • C08K3/2279C08K13/02C08K3/16
    • The present invention provides a power flame retardant for a halogen-containing vinyl resin, which comprises the following Components A, B and C. (A) 5 to 30 parts by weight of at least one of alkali metal compound of lithium, sodium and potassium calculated as the formula M.sub.2 O where M is an alkali metal; (B) 0.2 to 10 parts by weight of a perchloric acid radical in the form of the acid or a salt or amine thereof, calculated as perchloric acid radical; and (C) 1 to 50 parts by weight of a hydrophobic dispersing agent having a boiling point or a decomposition temperature of 200.degree. C. or higher. All the parts by weight are based on 100 parts by weight of antimony pentoxide (Sb.sub.2 O.sub.5). The flame retardant of the present invention does not impair transparency of the halogen-containing vinyl resin, and also does not worsen various physical properties such as thermal stability and weathering resistance. The invention also provides (1) flame retardant halogen containing resins and (2) a process for preparing the powdered flame retardant.
    • 本发明提供含卤乙烯基树脂的电力阻燃剂,其包含以下组分A,B和C.(A)5至30重量份的锂,钠和钾的碱金属化合物 按公式M2O计算,其中M为碱金属; (B)0.2至10重量份以酸或其盐或胺形式的高氯酸基团,其计为高氯酸根; 和(C)1〜50重量份的沸点或分解温度为200℃以上的疏水性分散剂。 所有重量份均基于100重量份的五氧化二锑(Sb 2 O 5)。 本发明的阻燃剂不会损害含卤乙烯基树脂的透明性,也不会使各种物理性质如热稳定性和耐候性恶化。 本发明还提供(1)阻燃卤素树脂和(2)制备阻燃剂的方法。
    • 44. 发明授权
    • Binders for manufacture of precision casting molds
    • 用于制造精密铸造模具的粘合剂
    • US4769076A
    • 1988-09-06
    • US881274
    • 1986-07-02
    • Yoshitane WatanabeAkira KitajimaKeiko TasakiIsamu Yuuki
    • Yoshitane WatanabeAkira KitajimaKeiko TasakiIsamu Yuuki
    • B22C1/18B22C1/20B28B7/28
    • B22C1/205
    • Binders for manufacture of precision casting molds are provided, which are highly stable and are advantageous in that these may impart a high strength to the green molds as obtained by forming an accumulative refractory coat layer on a water-soluble pattern and then taking off the pattern from the coat layer, that no interlayer cleavage occurs in the accumulative coat layer when the pattern is taken off in the formation of the green mold, that the binders may impart a high strength to fired molds, that the castings as obtained by the use of the present fired molds are free from the surface roughness and other surface faults and that the dimension accuracy of the castings is not deteriorated at all by the use of the present binders.The binders of the present invention are characterized by containing the following components (a), (b) and (c) and optionally (d):(a) an organo-silicasol capable of providing 5-50 parts by weight of SiO.sub.2 in the binder;(b) 1-50 parts by weight of an alkyl silicate, an alkoxy-organosilane or a mixture thereof in the binder;(c) 1-30 parts by weight of a binder-soluble amine in the binder;(d) 1-30 parts by weight of an alkoxide of Ti, Zr, Sn, Al or In or a mixture thereof in the binder.
    • 提供了用于制造精密铸造模具的粘合剂,其是高度稳定的,并且有利的是这些可以赋予生坯模具高的强度,所述模具通过在水溶性图案上形成累积的耐火涂层,然后脱模 在涂层形成时,当在模具的形成中取出图案时,在累积涂层中不发生层间剥离,粘合剂可赋予烧结模具高的强度,通过使用 本发明的模具没有表面粗糙度和其他表面缺陷,并且通过使用本发明的粘合剂,铸件的尺寸精度根本不劣化。 本发明的粘合剂的特征在于含有以下组分(a),(b)和(c)和任选的(d):(a)能够提供5-50重量份SiO 2的有机二氧化硅 粘合剂 (b)1-50重量份的粘合剂中的硅酸烷基酯,烷氧基 - 有机硅烷或它们的混合物; (c)粘合剂中1-30重量份的粘合剂可溶性胺; (d)1-30重量份的Ti,Zr,Sn,Al或In的醇盐或它们在粘合剂中的混合物。
    • 45. 发明授权
    • Positively charged antimony pentoxide sol and preparation thereof
    • 正电荷五氧化二锑溶胶及其制备
    • US4731198A
    • 1988-03-15
    • US846580
    • 1986-03-31
    • Yoshitane WatanabeMasayuki TeranishiKeitaro Suzuki
    • Yoshitane WatanabeMasayuki TeranishiKeitaro Suzuki
    • C08K3/22C01G30/00C01G35/00C01G37/00C08K3/00C08K3/24C08K9/02C09C1/00B01J13/00
    • C09C1/0096C08K9/02C01P2006/12C01P2006/22C01P2006/80
    • Disclosed is a positively charged antimony pentoxide sol, comprising colloidal particles of antimony pentoxide sol coated on their surfaces with at least one of trivalent and tetravalent metals, the content of the metals being 1 to 50% by weight in terms of the metal oxide based on antimony pentoxide in the antimony pentoxide sol.When the positively charged antimony pentoxide sol of this invention is mixed with a cationic resin emulsion or an aqueous solution of a cationic water-soluble polymer, no agglomeration occurs and also, when it is added into an aqueous solution of an inorganic acid such as hydrochloric acid, sulfuric acid, nitric acid, etc., or an organic acid such as acetic acid, propionic acid, oxalic acid, maleic acid, etc., an aqueous solution of a metal salt or amine salts of these acids or an organic solvent such as an alcohol, no agglomeration occurs but it is well dispersed therein, and therefore it can be applicable for fields in which the antimony pentoxide sol of the prior art cannot satisfactorily be used.
    • 公开了一种带正电的五氧化二锑溶胶,其包含五氧化二锑溶胶表面上用至少一种三价和四价金属涂覆的胶体颗粒,金属含量为基于金属氧化物换算为1至50重量% 五氧化二锑中的五氧化二锑。 当将本发明的带正电荷的五氧化二锑溶胶与阳离子树脂乳液或阳离子水溶性聚合物的水溶液混合时,不发生附聚,并且当将其加入到无机酸如盐酸 酸,硫酸,硝酸等,或有机酸如乙酸,丙酸,草酸,马来酸等,这些酸的金属盐或胺盐的水溶液或有机溶剂如 作为醇,不发生凝聚,但是其分散良好,因此可以适用于现有技术的五氧化二锑溶胶不能令人满意地使用的领域。