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    • 44. 发明授权
    • Poly(arylene thioether-ketone) copolymer and production process thereof
    • 聚(亚芳基硫醚 - 酮)共聚物及其制备方法
    • US5391645A
    • 1995-02-21
    • US63822
    • 1993-05-20
    • Yoshikatsu SatakeYoshiyuki InagumaYasuhiro Suzuki
    • Yoshikatsu SatakeYoshiyuki InagumaYasuhiro Suzuki
    • C08G75/02C08K5/35
    • C08G75/024C08G75/0245
    • Disclosed herein are a poly(arylene thioether-ketone) copolymer comprising (A) at least one poly(arylene thioether-ketone) segment having predominant recurring units of the formula ##STR1## wherein the --CO-- and --S-- are in the para position to each other, and (B) at least one poly(arylene thioether) segment having predominant recurring units of the formula ##STR2## (a) the ratio of the total amount of the poly(arylene thioether) segment (B) to the total amount of the poly(arylene thioether-ketone) segment (A) ranging from 0.05 to 5 by weight, (b) the number-average polymerization degree of the poly(arylene thioether) segment (B) being higher than 1 but lower than 10, and (c) said copolymer having a melt viscosity of 2-100,000 poises as measured at 350.degree. C. and a shear rate of 1,200/sec as well as a production process of the poly(arylene thioether-ketone) copolymer.
    • 本文公开了一种聚(亚芳基硫醚 - 酮)共聚物,其包含(A)至少一种具有主要重复单元的式(IMAGE)的聚(亚芳基硫醚 - 酮)链段,其中-CO-和-S-在对位 (B)至少一种具有下列主题重复单元的主要重复单元的聚(亚芳基硫醚)链段:(a)聚(亚芳基硫醚)链段(B)的总量与 聚(亚芳基硫醚 - 酮)链段(A)的总量为0.05-5重量%,(b)聚(亚芳基硫醚)链段(B)的数均聚合度高于1但低于 10,和(c)所述共聚物在350℃下测得的熔融粘度为2-100,000泊,剪切速率为1200 /秒,以及聚(亚芳基硫醚 - 酮)共聚物的制备方法。
    • 45. 发明授权
    • Poly(arylene sulfide) resin composition
    • 聚(亚芳基硫醚)树脂组合物
    • US5380783A
    • 1995-01-10
    • US113473
    • 1993-08-30
    • Yoshikatsu SatakeToshihiko OnoYoshinobu ItohYukio Ichikawa
    • Yoshikatsu SatakeToshihiko OnoYoshinobu ItohYukio Ichikawa
    • C08K3/08C08K3/24C08L81/02C08L81/04C08K3/10
    • C08K3/08C08K3/24
    • A poly(arylene sulfide) resin composition in which the tendency of a poly(arylene sulfide) resin to cause metals making up molds, processing machinery, metal parts of inserts and the like to corrode has been inhibited, and which has good processability includes the poly(arylene sulfide) resin and, as a corrosion inhibitor, at least one substance selected from the group consisting of a metallic simple substance of molybdenum, oxoacids of molybdenum, alkali metal salts of the oxoacids of molybdenum, alkaline earth metal salts of the oxoacids of molybdenum, the ammonium salts of the oxoacids of molybdenum, the zinc salts of the oxoacids of molybdenum, a metallic simple substance of tungsten, oxoacids of tungsten, alkali metal salts of the oxoacids of tungsten, alkaline earth metal salts of the oxoacids of tungsten, the ammonium salts of the oxoacids of tungsten and the zinc salts of the oxoacids of tungsten. The corrosion inhibitor being incorporated in a proportion within a range of 0.01-10 parts by weight per 100 parts by weight of the poly(arylene sulfide) resin.
    • 聚酰亚胺硫化物树脂组合物中,聚(亚芳基硫醚)树脂使金属组成模具,加工机械,插入物等的金属部件等被腐蚀的倾向已经被抑制,并且具有良好的加工性包括 聚(亚芳基硫醚)树脂,作为腐蚀抑制剂,选自钼的金属单体,钼的含氧物,钼的含氧酸的碱金属盐,含氧酸的碱土金属盐, 的钼,钼的含氧酸的铵盐,钼的含氧酸的锌盐,钨的金属单体,钨的含碳酸,钨的含氧酸的碱金属盐,钨的含氧酸的碱金属盐 ,钨的含氧酸的铵盐和钨的含氧酸的锌盐。 该防腐蚀剂以相对于100重量份的聚(亚芳基硫醚)树脂为0.01〜10重量份的比例组合。
    • 46. 发明授权
    • Poly (arylene thioether-ketone-ketone) copolymer and production process
thereof
    • 聚(亚芳基硫醚 - 酮 - 酮)共聚物及其制备方法
    • US5374692A
    • 1994-12-20
    • US35770
    • 1993-03-23
    • Yoshikatsu SatakeYoshiyuki InagumaJiro Masuko
    • Yoshikatsu SatakeYoshiyuki InagumaJiro Masuko
    • C08G75/02C08G2/00
    • C08G75/024C08G75/0245
    • Disclosed herein is a poly(arylene thioether-ketone-ketone) copolymer comprising (A) at least one poly(arylene thioether-ketone-ketone) segment having predominant recurring units of the formula ##STR1## (B) at least one poly(arylene thioether) segment having predominant recurring units of the formula ##STR2## (a) the ratio of the total amount of the poly(arylene thioether) segment (B) to the total amount of the poly(arylene thioether-ketone-ketone) segment (A) ranging from 0.1 to 9 by weight, (b) the weight-average molecular weight of the poly(arylene thioether) segment (B) being at least 200 but lower than 1000, and (c) said copolymer having a melt viscosity of 2-100,000 poises as measured at 380.degree. C. and a shear rate of 1,200/sec as well as a production process of the poly(arylene thioether-ketone-ketone) copolymer. The copolymer has high crystallinity and heat resistance, uniform composition, and excellent melt stability, processability, handling properties, solvent resistance and moisture absorption resistance.
    • 本文公开了一种聚(亚芳基硫醚 - 酮 - 酮)共聚物,其包含(A)至少一种具有下列主题的重复单元的聚(亚芳基硫醚 - 酮 - 酮)链段:(B)至少一种聚(亚芳基 (a)聚(亚芳基硫醚)链段(B)的总量与聚(亚芳基硫醚 - 酮 - 酮)链段(B)的总量的比例(A)的主要重复单元, A)为0.1-9重量%,(b)聚(亚芳基硫醚)链段(B)的重均分子量为至少200但低于1000,和(c)所述共聚物的熔体粘度为 在380℃下测量的2-100,000泊,剪切速率为1200 /秒,以及聚(亚芳基硫醚 - 酮 - 酮)共聚物的制备方法。 共聚物具有高结晶度和耐热性,组成均匀性,以及优异的熔体稳定性,加工性,操作性,耐溶剂性和耐吸湿性。