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    • 43. 发明授权
    • Seal for electrochromic devices
    • 电致变色装置的密封
    • US06195193B1
    • 2001-02-27
    • US09540219
    • 2000-03-31
    • John S. AndersonWilliam L. TonarKevin L. AshThomas F. Guarr
    • John S. AndersonWilliam L. TonarKevin L. AshThomas F. Guarr
    • G02F115
    • G02F1/161
    • An improved seal member is provided as a part of an electrochromic device to bond two glass elements together in a spaced-apart relationship. In one embodiment the seal member provides improved adhesion to a reflector/electrode on the third surface of an electrochromic mirror, or to a layer of metal on the second or third surface for an electrochromic light filter. This seal member comprises a mixture of an organic resin scaling system and an adhesion promoter, where the adhesion promotor comprises a first and a second region, where the first region interacts with the reflector/electrode or the metal layer, and a second region that interacts with the organic resin sealing system, and may even chemically react with the organic resin sealing system. In another embodiment the seal member is provided with a coefficient of thermal expansion that is closer to glass than a standard epoxy sealing system.
    • 提供改进的密封构件作为电致变色装置的一部分,以将间隔开的关系将两个玻璃元件结合在一起。 在一个实施例中,密封构件对电致变色镜的第三表面上的反射器/电极或用于电致变色光过滤器的第二或第三表面上的金属层提供改进的粘附。 该密封构件包括有机树脂缩放系统和粘合促进剂的混合物,其中粘合促进剂包括第一和第二区域,其中第一区域与反射器/电极或金属层相互作用,第二区域与 与有机树脂密封系统,甚至可能与有机树脂密封系统发生化学反应。 在另一个实施例中,密封构件具有比标准环氧树脂密封系统更接近玻璃的热膨胀系数。
    • 44. 发明授权
    • Tristate electrochromic device
    • 三态电致变色装置
    • US07835059B2
    • 2010-11-16
    • US11096470
    • 2005-04-01
    • Punam GiriThomas F. Guarr
    • Punam GiriThomas F. Guarr
    • G02F1/15G02F1/153
    • G02F1/153G02F1/1521G02F1/163G02F2203/11
    • An electrochromic medium for use in a tristate electrochromic device, comprising: (a) at least one solvent; (b) at least one anodic material; (c) at least one cathodic material, wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic; (d) wherein, in a first state, the electrochromic medium exhibits a maximum light transmission; (e) wherein, in a second state, variable attenuation occurs to a significant extent in one of visible radiation or near-infrared radiation without significant attenuation in the other; and (f) wherein, in a third state, variable attenuation occurs to a significant extent in the other spectral region.
    • 一种用于三级电致变色装置的电致变色介质,包括:(a)至少一种溶剂; (b)至少一种阳极材料; (c)至少一种阴极材料,其中阳极和阴极材料都是电活性的,阳极和阴极材料中的至少一种是电致变色的; (d)其中,在第一状态下,所述电致变色介质表现出最大光透射率; (e)其中,在第二状态下,在可见辐射或近红外辐射之一中显着地发生可变衰减,而在另一个状态下没有显着的衰减; 和(f)其中,在第三状态下,可变衰减在另一光谱区域中显着地发生。
    • 47. 发明授权
    • Electrochromic device having a current-reducing additive
    • 具有减少电流的添加剂的电致变色装置
    • US06525861B1
    • 2003-02-25
    • US10012937
    • 2001-12-10
    • Kathy E. RobertsThomas F. Guarr
    • Kathy E. RobertsThomas F. Guarr
    • G02F115
    • G02F1/1521
    • An electrochromic medium for use in an electrochromic device comprising: at least one solvent; an anodic electroactive material; a cathodic electroactive material, wherein at least one of the anodic and cathodic electroactive materials is electrochromic; and a current-reducing additive, wherein the current-reducing additive comprises a polymer present in an effective concentration to materially reduce the current of the electrochromic medium upon application of an electrical potential, relative to an electrochromic medium without the current-reducing additive, while maintaining an electrochromic medium viscosity which facilitates acceptable production rates without a problematic degree of seal or other device component failure.
    • 一种用于电致变色装置的电致变色介质,包括:至少一种溶剂; 阳极电活性材料; 阴极电活性材料,其中所述阳极和阴极电活性材料中的至少一种是电致变色的; 和电流还原添加剂,其中所述电流还原添加剂包含以有效浓度存在的聚合物,以相对于不具有电流还原添加剂的电致变色介质,在施加电势时物理降低电致变色介质的电流,同时 保持电致变色介质粘度,其有利于可接受的生产率而没有密封程度或其他器件部件故障。
    • 50. 发明授权
    • Substituted metallocenes for use as anodic electrochromic materials, and electrochromic media and devices comprising the same
    • 用作阳极电致变色材料的取代的金属茂,以及电致变色介质和包含其的器件
    • US06392783B1
    • 2002-05-21
    • US09677689
    • 2000-10-02
    • Jeffrey R. LompreyThomas F. Guarr
    • Jeffrey R. LompreyThomas F. Guarr
    • G02F115
    • G02F1/1521C07F17/02C09K9/02
    • An electrochromic device comprising at least one substantially transparent substrate having an electrically conductive material associated therewith, and an electrochromic medium which comprises a solvent, a cathodic material, and an anodic electrochromic material represented by the formula: wherein R1-R10 are the same or different and at least three of R1-R10 are the same or different and comprise a straight or branched alkyl, aryl, alkaryl, or aralkyl group containing approximately 1 to approximately 40 carbon atom(s), and/or a silyl or siloxyl group containing approximately 1 to approximately 40 silicon atom(s), wherein the carbon or silicon atom(s) may be a linking group to, or part of, one or more functional groups comprising nitrites; nitro constituents; sulfoxides; sulfonates; phosphonium constituents; phosphonates; phosphonites; ammonium constituents; viologens, including bipyridinyl constituents; carbonyls, including carbonates, carbamates; ketones; esters; and amides; ethers, including polyethers; amines, including tertiary amines; alkenes; alkynes; and mixtures thereof; wherein any remainder of R1-R10 comprise H; and wherein M comprises a transition metal.
    • 一种电致变色装置,包括至少一个具有与之相关的导电材料的基本上透明的基底,以及电致变色介质,其包含溶剂,阴极材料和由下式表示的阳极电致变色材料:其中R1-R10相同或不同 并且R1-R10中的至少三个相同或不同,并且包含含有约1至约40个碳原子的直链或支链烷基,芳基,烷芳基或芳烷基,和/或含有约1至约40个碳原子的甲硅烷基或硅氧烷基 1至约40个硅原子,其中碳或硅原子可以是与一个或多个包含亚硝酸根的官能团的一部分或部分的连接基团; 硝基成分; 亚砜 磺酸盐; 鏻成分; 膦酸盐 亚膦酸盐 铵成分; 紫罗兰,包括联吡啶成分; 羰基,包括碳酸酯,氨基甲酸酯; 酮类 酯类 和酰胺; 醚,包括聚醚; 胺,包括叔胺; 烯烃 炔烃 及其混合物; 其中R 1 -R 10的任何其余部分包括H; 并且其中M包含过渡金属。