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    • 41. 发明授权
    • Chemical amplification type positive resist composition
    • 化学放大型正光刻胶组合物
    • US06696218B2
    • 2004-02-24
    • US10107488
    • 2002-03-28
    • Kunihiro IchimuraTsugio OkudairaMasumi SuetsuguYasunori UetaniKatsuhiko Namba
    • Kunihiro IchimuraTsugio OkudairaMasumi SuetsuguYasunori UetaniKatsuhiko Namba
    • G03F7038
    • G03F7/0045G03F7/0392G03F7/0397Y10S430/106
    • A chemical amplification type positive resist composition that enables a resist pattern free from deformation in a side wall thereof and excellent in evenness and is excellent in sensitivity as well as resolution is provided and the chemical amplification type positive resist composition comprises a resin which has a polymerization unit derived from p-hydroxystyrene and a polymerization unit having a group unstable against acid, and is insoluble or hardly soluble in an alkaline medium itself but becoming alkaline-soluble after the acid-unstable group being cleaved by the action of the generated acid; an acid generating agent; and a compound represented by the following formula (I): wherein R1 and R2 each independently represents an alkyl group having 1 to 15 carbon atoms, an alkyl group having 1 to 8 carbon atoms wherein at least 3 hydrogen atoms are substituted by fluorine atoms, or an aryl group having 6 to 10 carbon atoms.
    • 化学增幅型正性抗蚀剂组合物使得能够在其侧壁中没有变形的抗蚀剂图案具有优异的均匀性并且具有优异的灵敏度和分辨率,并且化学放大型正性抗蚀剂组合物包含具有聚合性的树脂 衍生自对羟基苯乙烯的单元和具有对酸不稳定的基团的聚合单元,并且在酸性不稳定基团被所产生的酸的作用下裂解后,在碱性介质中本身不溶或几乎不溶解,但变得碱溶性; 酸产生剂; 和由下式(I)表示的化合物:其中R 1和R 2各自独立地表示具有1至15个碳原子的烷基,具有1至8个碳原子的烷基,其中至少3个氢原子 被氟原子取代,或具有6〜10个碳原子的芳基。
    • 43. 发明授权
    • Chemically amplified positive resist composition
    • 化学放大正光刻胶组合物
    • US06579659B2
    • 2003-06-17
    • US09824227
    • 2001-04-03
    • Yasunori UetaniAiri YamadaYoshiko MiyaYoshiyuki Takata
    • Yasunori UetaniAiri YamadaYoshiko MiyaYoshiyuki Takata
    • G03F7004
    • G03F7/039G03F7/0045Y10S430/106Y10S430/111
    • A chemical amplification type positive resist composition excellent in balance of properties such as resolution, profile, sensitivity, dry etching resistance, adhesion and the like which comprises a resin which has the following polymeric units (A), (B) and (C); and an acid generating agent. (A): At least one polymeric unit of an alicyclic lactcone selected from polymeric units represented by the following formulae (Ia) and (Ib): (B): At least one polymeric unit selected from a polymeric unit of 3-hydroxy-1-adamantyl (meth)acrylate represented by the following formula (II), a polymeric unit of a combination of a unit represented by the following formula (III) and a unit derived from unsaturated dicarboxylic acid anhydride selected from maleic anhydride and itaconic anhydride and a polymeric unit of (&agr;)&bgr;-(meth)acryloyloxy-&ggr;-butyrolactone represented by the following formula (IV):
    • 包含具有以下聚合单元(A),(B)和(C)的树脂的性能如分辨率,轮廓,灵敏度,耐干蚀刻性,粘附性等的平衡优异的化学增幅型正光刻胶组合物; (A):选自由下式(Ia)和(Ib)表示的聚合单元的脂环族内聚焦的至少一种聚合单元:( B):至少一种选自聚合单元的聚合单元 由下式(II)表示的3-羟基-1-金刚烷基(甲基)丙烯酸酯,由下式(III)表示的单元的组合的单体和来自选自马来酸酐的不饱和二羧酸酐的单元 酸酐和衣康酸酐以及由下式(IV)表示的(α)β-(甲基)丙烯酰氧基-γ-丁内酯的聚合单元:
    • 44. 发明授权
    • Chemical amplification type positive resist composition
    • 化学放大型正光刻胶组合物
    • US06548221B2
    • 2003-04-15
    • US10003441
    • 2001-12-06
    • Yasunori UetaniHiroki Inoue
    • Yasunori UetaniHiroki Inoue
    • G03F7004
    • G03F7/039G03F7/0045Y10S430/106Y10S430/115Y10S430/122
    • A positive resist composition is provided which comprises a resin having 2-alkyl-2-adamantyl (meth)acrylate polymerization unit represented by the following formula (I): wherein R1 represents hydrogen or methyl and R2 represents an alkyl, and being insoluble or barely soluble in alkali, but being converted to soluble in alkali by the action of an acid; and an acid generator represented by the following formula (V): wherein Q1, Q2 and Q3 independently represent hydrogen, a hydroxyl group, an alkyl having 1 to 6 carbon atoms or an alkoxy having 1 to 6 carbon atoms, and n is an integer of 4 to 8; and gives a good resolution upon exposure by ArF excimer laser and has little substrate dependency.
    • 提供一种正型抗蚀剂组合物,其包含具有由下式(I)表示的(甲基)丙烯酸2-烷基-2-金刚烷基酯聚合单元的树脂:其中R1表示氢或甲基,R2表示烷基,并且不溶或几乎不溶 可溶于碱,但通过酸的作用转化为可溶于碱;和由下式(V)表示的酸发生剂:其中Q1,Q2和Q3独立地表示氢,羟基,具有1〜 6个碳原子或1〜6个碳原子的烷氧基,n为4〜8的整数。 并且通过ArF准分子激光曝光时给出良好的分辨率,并且基板依赖性很小。
    • 45. 发明授权
    • Resist composition
    • 抗蚀组成
    • US06245478B1
    • 2001-06-12
    • US09398998
    • 1999-09-17
    • Yasunori UetaniIchiki Takemoto
    • Yasunori UetaniIchiki Takemoto
    • G03F7023
    • G03F7/0045G03F7/0085G03F7/0226G03F7/038G03F7/039Y10S430/121
    • A resist composition exhibiting an improved profile performance without impairing the resolution, the sensitivity, etc. which comprises a binder component; a radiation-sensitive component; and a succinimide compound represented by the following formula (I): wherein Q1 represents an alkyl group which may be optionally substituted with alkoxy, halogen or nitro, an alicyclic hydrocarbon residue, an aryl group, or an aralkyl group; and Q2, which may be the same as or different from Q1, represents hydrogen, an alkyl group which may be optionally substituted with alkoxy, halogen or nitro, an alicyclic hydrocarbon residue, an aryl group, or an aralkyl group.
    • 抗蚀剂组合物,其表现出改进的轮廓性能,而不损害包括粘结剂成分的分辨率,灵敏度等; 辐射敏感组件; 和由下式(I)表示的琥珀酰亚胺化合物:其中Q1表示可任选被烷氧基,卤素或硝基取代的烷基,脂环族烃残基,芳基或芳烷基; 和可以与Q1相同或不同的Q2表示氢,可以任选被烷氧基,卤素或硝基取代的烷基,脂环族烃残基,芳基或芳烷基。
    • 46. 发明授权
    • Positive resist composition
    • 正抗蚀剂组成
    • US6068962A
    • 2000-05-30
    • US934226
    • 1997-09-19
    • Yasunori UetaniHiroshi MoriumaJun Tomioka
    • Yasunori UetaniHiroshi MoriumaJun Tomioka
    • G03F7/022G03F7/023
    • G03F7/0226Y10S430/121Y10S430/127
    • A non-chemically enhanced type positive resist composition includes an alkali-soluble novolak resin, a quinonediazide type sensitizer and at least one of the following compounds (a) and (b):(a) an acid-generator which is decomposed by the action of an alkali developer and generates an acid, and(b) compounds represented by the following formula (IV) or (V): ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 independently represents hydrogen, halogen, hydroxy, alkyl, alkoxy, aryl or nitro, each of R.sup.9 and R.sup.10 independently represents hydrogen, halogen, alkyl, aryl, nitro, a group of --(CH.sub.2).sub.n --OR.sup.11 or a group of --(CH.sub.2).sub.n --COOR.sup.12 in which R.sup.11 represents hydrogen, alkyl, aryl or alkanoyl and R.sup.12 represents hydrogen, alkyl or aryl, and n is a number from 0 to 3 and R.sup.13 represents hydrogen, halogen, alkyl, alkoxy or aryl.
    • 非化学增强型正型抗蚀剂组合物包括碱溶性酚醛清漆树脂,醌二叠氮化物型增感剂和至少一种以下化合物(a)和(b)):(a)通过动作分解的酸发生剂 的碱显影剂,并产生酸,和(b)由下式(IV)或(V)表示的化合物:其中R1,R2,R3,R4,R5,R6,R7和R8各自独立地表示氢,卤素 ,羟基,烷基,烷氧基,芳基或硝基,R 9和R 10各自独立地表示氢,卤素,烷基,芳基,硝基, - (CH 2)n -OR 11或 - (CH 2)n -COOR 12基团 其中R 11表示氢,烷基,芳基或烷酰基,R 12表示氢,烷基或芳基,n为0至3的数,R 13表示氢,卤素,烷基,烷氧基或芳基。
    • 48. 发明授权
    • Positive type resist composition
    • 正型抗蚀剂组合物
    • US5326665A
    • 1994-07-05
    • US24499
    • 1993-03-01
    • Haruyoshi OsakiHiroshi MoriumaYasunori Uetani
    • Haruyoshi OsakiHiroshi MoriumaYasunori Uetani
    • C08G8/04G03F7/023G03F7/039H01L21/027G03F7/30
    • C08G8/04G03F7/0236
    • A positive type resist composition comprising an alkali-soluble resin and a quinonediazide compound, wherein the alkali-soluble resin containing resin (A) is obtainable through a condensation reaction with at least one phenol compound represented by the following general formula (I): ##STR1## wherein R.sub.1 to R.sub.3 independently of one another each represent a hydrogen atom or an alkyl or alkoxy group having 1-4 carbon atoms and k represents 1 or 2, at least one compound represented by the following general formula (II): ##STR2## wherein R.sub.4 represents a hydrogen atom, an alkyl group having 1-4 carbon atoms or a phenyl group, R.sub.5 to R.sub.7 independently of one another each represent a hydrogen atom or an alkyl or alkoxy group having 1-4 carbon atoms and n represents 1 or 2, and an aldehyde compound. This composition is excellent in the balance between performances such as sensitivity, heat resistance and profile, and is free from scum.
    • 包含碱溶性树脂和醌二叠氮化合物的正型抗蚀剂组合物,其中所述含碱树脂(A)的树脂可通过与至少一种由以下通式(I)表示的酚化合物的缩合反应获得: (I)其中R1至R3彼此独立地表示氢原子或具有1-4个碳原子的烷基或烷氧基,k表示1或2,至少一种由以下通式(II)表示的化合物: :其中R 4表示氢原子,具有1-4个碳原子的烷基或苯基,R 5至R 7彼此独立地表示氢原子或具有1-4个碳原子的烷基或烷氧基 碳原子,n表示1或2,醛化合物。 该组合物在灵敏度,耐热性和轮廓性能之间的平衡方面是优异的,并且没有浮渣。