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41. 发明授权

US08318864B2 Functionalized ethylene/α-olefin interpolymer compositions 有权
公开(公告)号：US08318864B2
公开(公告)日：2012-11-27
申请号：US13031339
申请日：2011-02-21
申请人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
发明人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
IPC分类号： C08F10/02 , C08F230/08 , C08L53/00
CPC分类号： B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
摘要： The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.

42. 发明授权

US08211982B2 Functionalized ethylene/α-olefin interpolymer compositions 有权
标题翻译：官能化乙烯/α-烯烃互聚物组合物
公开(公告)号：US08211982B2
公开(公告)日：2012-07-03
申请号：US13031406
申请日：2011-02-21
申请人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
发明人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
IPC分类号： C08F297/02 , C08F297/00
CPC分类号： C08F297/086 , C08F210/16 , C08F295/00 , C08F297/083 , C08L23/08 , C08F210/14 , C08F2500/03 , C08F2500/20 , C08F2500/12 , C08F2500/11 , C08F2500/21
摘要： The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.
摘要翻译：本发明涉及衍生自基础烯烃互聚物的官能化互聚物，其通过聚合一种或多种单体或单体混合物如乙烯和一种或多种共聚单体而制备，以形成具有独特物理性质的互聚物产物。官能化的烯烃互聚物含有两个或多个不同的区域或链段（嵌段），产生独特的加工和物理性能。

43. 发明申请

US20120116021A1 POLYMER COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME 有权
标题翻译：聚合物组合物，其制备方法和由其制备的制品
公开(公告)号：US20120116021A1
公开(公告)日：2012-05-10
申请号：US13377916
申请日：2010-07-14
申请人： Wenbin Liang , Brian W. Walther , Timothy E. Clayfield , Arnis U. Paeglis , Sherrika D. Daniel , Larry A. Meiske
发明人： Wenbin Liang , Brian W. Walther , Timothy E. Clayfield , Arnis U. Paeglis , Sherrika D. Daniel , Larry A. Meiske
IPC分类号： C08L47/00
CPC分类号： C08L23/16 , C08F297/06 , C08L2205/02 , C08L2666/08 , C08L2666/06
摘要： The invention provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has an [(ML(1+4, 125° C.))/Mw(conv)]*1000 greater than 0.429 mole/g. The invention also provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has a Mooney Viscosity (ML, 1+4, 125° C.) greater than, or equal to, 70, and has a low shear viscosity (11 at 0.1 rad/sec) less than, or equal to, 100,000 Pa·sec. The invention also provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has a Mooney Viscosity (ML(1+4, 125° C.)) greater than, or equal to, 70, and has an [Mw(abs)]/[Mw(conv)] less than 1.2.
摘要翻译：本发明提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）第一共聚物，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中所述第一组合物具有大于0.429摩尔/ g的[（ML（1 + 4,125℃））/ Mw（conv）] * 1000。本发明还提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第一共聚体; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中第一组合物具有大于或等于70的门尼粘度（ML，1 + 4，125℃），并且具有小于或等于70的低剪切粘度（11弧度/秒），100,000Pa·秒。本发明还提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第一共聚体; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中第一组合物具有大于或等于70的门尼粘度（ML（1 + 4，125℃）），并且具有小于1.2的[Mw（abs）] / [Mw（conv））。

44. 发明授权

US5798410A Aqueous dispersions of linear olefin copolymers 失效
标题翻译：线性烯烃共聚物的水分散体
公开(公告)号：US5798410A
公开(公告)日：1998-08-25
申请号：US702824
申请日：1996-08-23
申请人： Brian W. Walther , James R. Bethea
发明人： Brian W. Walther , James R. Bethea
IPC分类号： C08J3/05 , C08K5/41 , C08K5/42 , C08L23/04 , C08J27/00
CPC分类号： C08L23/04 , C08K5/41 , C08K5/42
摘要： Artificial latexes that are film forming at room temperature can be prepared from a copolymer of ethylene and a C.sub.3 -C.sub.20 .alpha.-olefin. The copolymer is characterized by having a polydispersity index not greater than 2.5; random distribution of comonomer units along the polymer backbone; and a homogeneity index of at least 75. The copolymer preferably contains no polar substituents, which are generally necessary to make useful latexes from polyethylene.
摘要翻译：在室温下成膜的人造胶乳可以由乙烯和C 3 -C 20α-烯烃的共聚物制备。共聚物的特征在于多分散指数不大于2.5; 共聚单体沿着聚合物主链的随机分布; 并且均匀性指数为至少75.共聚物优选不含极性取代基，这通常是从聚乙烯制备有用的胶乳所必需的。

45. 发明授权

US5567760A Films from aqueous dispersions of block copolymers having hydrogenated conjugated diene block 失效
标题翻译：具有氢化共轭二烯嵌段的嵌段共聚物的水性分散体的膜
公开(公告)号：US5567760A
公开(公告)日：1996-10-22
申请号：US339862
申请日：1994-11-15
申请人： Brian W. Walther , Gary R. Marchand
发明人： Brian W. Walther , Gary R. Marchand
IPC分类号： C08J3/07 , C08J5/18 , C08L53/02 , C08J3/03 , B29D7/00 , C08K5/01 , C08L53/00
CPC分类号： C08J5/18 , C08J3/07 , C08L53/02 , C08J2353/02
摘要： Aqueous dispersions, and films prepared therefrom, comprising an organic phase of block copolymers and optional extenders wherein the block copolymers corresponds to the formula:A-B-X.sub.m -(B-A).sub.nwherein each A is a polymer block of a monovinylidene aromatic monomer and conjugated dienes, each B is a polymer block of one or more conjugated dienes and, optionally, one or more monovinylidene aromatic monomers, X is the remnant of a multifunctional coupling agent, m is 0 or 1, and n is an integer from 1 to 5. Each A polymer block has a weight average molecular weight from 4,000 to 15,000 Daltons. Each B polymer block has a weight average molecular weight from 20,000 to 200,000 Daltons. The total monovinylidene monomer content is from 6 to 30 percent by weight of the organic phase. The effective phase volume of the A polymer block in the organic phase is from 8 to 20 percent. Thin elastomeric articles prepared from the emulsions have improved tensile strength properties. Also claimed is a process for the preparation of such films.
摘要翻译：水分散体和由其制备的膜包含嵌段共聚物和任选的增量剂的有机相，其中嵌段共聚物对应于下式：AB-Xm-（BA）n，其中每个A是单亚乙烯基芳族单体和共轭二烯的聚合物嵌段，每个B是一种或多种共轭二烯和任选的一种或多种单亚乙烯基芳族单体的聚合物嵌段，X是多官能偶联剂的残余物，m是0或1，n是1至5的整数。聚合物嵌段具有4,000至15,000道尔顿的重均分子量。每个B聚合物嵌段的重均分子量为20,000至200,000道尔顿。总亚乙烯基单体含量为有机相重量的6至30％。有机相中的A聚合物嵌段的有效相体积为8〜20％。由乳液制备的薄弹性制品具有改进的拉伸强度性能。还要求的是制备这种膜的方法。

46. 发明授权

US5286457A Reactor with surface agitator for solution polymerization process 失效
标题翻译：具有表面搅拌器的反应器用于溶液聚合过程
公开(公告)号：US5286457A
公开(公告)日：1994-02-15
申请号：US858812
申请日：1992-03-27
申请人： Gary L. Woodson , Brian W. Walther , Brian G. Witt , Gary R. Marchand
发明人： Gary L. Woodson , Brian W. Walther , Brian G. Witt , Gary R. Marchand
IPC分类号： B01J19/00 , B01J19/18 , C08F2/26 , B01F7/18 , B01F7/32
CPC分类号： B01J19/002 , B01J19/18 , B01J2219/00094 , B01J2219/00768 , B01J2219/185
摘要： A reactor for the solution polymerization of volatile monomers equipped with an agitator to cause splashing and droplet formation to reduce volatile monomer accumulation in the vapor space.
摘要翻译：用于溶液聚合的反应器，用于配备搅拌器的挥发性单体以引起飞溅和液滴形成，以减少挥发性单体在蒸气空间中积累。

47. 发明授权

US5225493A Anionic polymerization process 失效
标题翻译：阴离子聚合工艺
公开(公告)号：US5225493A
公开(公告)日：1993-07-06
申请号：US936188
申请日：1992-08-26
申请人： Gary R. Marchand , Brian W. Walther , Warren R. Rose
发明人： Gary R. Marchand , Brian W. Walther , Warren R. Rose
IPC分类号： C08F2/42 , C08F6/02
CPC分类号： C08F2/42 , C08F6/02
摘要： A process for anionic polymerization of polymerizable monomers with an organo lithium initiator followed by polymerization termination characterized in that terminated reaction products are neutralized by contacting with sulfuric acid, phosphoric acid or a mixture thereof.
摘要翻译：一种可聚合单体与有机锂引发剂进行阴离子聚合的方法，随后进行聚合终止，其特征在于通过与硫酸，磷酸或其混合物的接触中和终止的反应产物。

48. 发明授权

US5120805A Reactor with surface agitator for solution polymerization process 失效
标题翻译：具有表面搅拌器的反应器用于溶液聚合过程
公开(公告)号：US5120805A
公开(公告)日：1992-06-09
申请号：US710632
申请日：1991-06-05
申请人： Gary L. Woodson , Brian W. Walther , Brian G. Witt , Gary R. Marchand
发明人： Gary L. Woodson , Brian W. Walther , Brian G. Witt , Gary R. Marchand
IPC分类号： B01J19/00 , B01J19/18 , C08F2/26
CPC分类号： B01J19/002 , B01J19/18 , B01J2219/00094 , B01J2219/00768 , B01J2219/185
摘要： A process for the solution polymerization of volatile monomers in a reactor equipped with an agitator to cause splashing and droplet formation to reduce volatile monomer accumulation in the vapor space.
摘要翻译：在装有搅拌器的反应器中使挥发性单体溶液聚合以引起飞溅和液滴形成以减少挥发性单体在蒸气空间中积累的方法。

49. 发明授权

US5089572A Blanking process for reaction mixture 失效
标题翻译：反应混合物的消隐方法
公开(公告)号：US5089572A
公开(公告)日：1992-02-18
申请号：US395176
申请日：1989-08-18
申请人： Gary R. Marchand , Joseph G. Schell, Jr. , Brian W. Walther , Corwin J. Bredeweg
发明人： Gary R. Marchand , Joseph G. Schell, Jr. , Brian W. Walther , Corwin J. Bredeweg
IPC分类号： C07B61/00 , C08F4/60 , C08F8/42
CPC分类号： C07B61/00 , C08F8/42 , Y10S526/912
摘要： A process for blanking a reaction mixture utilizing as a blanking agent a difunctional lithium composition.
摘要翻译：使用二官能锂组合物作为消隐剂冲洗反应混合物的方法。

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