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41. 发明授权

US4967003A Propylamines, and their use as fungicides 失效
标题翻译：丙胺，以及它们作为杀真菌剂的用途
公开(公告)号：US4967003A
公开(公告)日：1990-10-30
申请号：US928006
申请日：1986-11-07
申请人： Costin Rentzea , Walter Himmele , Ernst Buschmann , Eberhard Ammermann , Ernst-Heinrich Pommer
发明人： Costin Rentzea , Walter Himmele , Ernst Buschmann , Eberhard Ammermann , Ernst-Heinrich Pommer
IPC分类号： A01N33/04 , A01N33/06 , A01N33/08 , A01N33/10 , A01N37/34 , A01N43/08 , A01N49/00 , C07C67/00 , C07C209/00 , C07C211/17 , C07C211/27 , C07C211/29 , C07C211/35 , C07C211/40 , C07C211/44 , C07C211/48 , C07C211/52 , C07C213/00 , C07C217/62 , C07C253/00 , C07C255/58 , C07D307/14 , C07D307/52
CPC分类号： C07C217/62 , A01N33/04 , A01N33/06 , A01N33/10 , A01N43/08 , A01N49/00 , C07D307/52
摘要： N-Arylpropyl-substituted secondary amines of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, alkyl, cycloalkyl, haloalkyl, alkoxy, chlorine, bromine or fluorine, m is 0, 1 or 2, R.sup.3 and R.sup.4 are each hydrogen or alkyl, and R.sup.5 is alkyl, cycloalkyl, cycloalkenyl, cycloalkylalkyl, alkenyl or an unsubstituted or substituted phenyl or phenylalkyl radical or methylfuran and the dashed bonds may be hydrogenated, and their salts, and fungicides containing these compounds.
摘要翻译：其中R 1和R 2各自为氢，烷基，环烷基，卤代烷基，烷氧基，氯，溴或氟，m为0,1或2，R 3和R 4各自为氢或烷基，R 5是烷基，环烷基，环烯基，环烷基烷基，烯基或未取代或取代的苯基或苯基烷基或甲基呋喃，虚线键可以被氢化，以及它们的盐和含有这些化合物的杀真菌剂。

42. 发明授权

US4929786A Preparation of 1-aryl-1-alkenes 失效
标题翻译： 1-芳基-1-烯烃的制备
公开(公告)号：US4929786A
公开(公告)日：1990-05-29
申请号：US264081
申请日：1988-10-28
申请人： Walter Himmele , Kaspar Bott , Klaus Bronstert
发明人： Walter Himmele , Kaspar Bott , Klaus Bronstert
IPC分类号： C07C1/00 , C07C1/24 , C07C15/44 , C07C15/50 , C07C17/00 , C07C17/35 , C07C22/04 , C07C25/24 , C07C41/00 , C07C41/18 , C07C43/166 , C07C67/00
CPC分类号： C07C41/18 , C07C1/24 , C07C17/35
摘要： Preparation of 1-aryl-1-alkenes by dehydration of 1-aryl-1-alkanols in the presence of a substance promoting elimination of water, the substance being a triester of phosphorous acid in which at least one of the radicals is an aryl group.The products are suitable as, inter al., initiators for anionic polymerization.
摘要翻译：在促进水分去除的物质存在下，通过1-芳基-1-链烷醇的脱水制备1-芳基-1-烯烃，该物质是其中至少一个基团是芳基的亚磷酸三酯。该产品适用于阴离子聚合的引发剂。

43. 发明授权

US4876275A 3,4-dihydro-2H-pyrans useful as pesticides 失效
标题翻译： 3,4-二氢-2H-吡喃可用作农药
公开(公告)号：US4876275A
公开(公告)日：1989-10-24
申请号：US176700
申请日：1988-04-01
申请人： Walter Himmele , Hans Theobald , Franz Merger , Ernst Hofmann , Christoph Kuenast , Peter Hofmeister
发明人： Walter Himmele , Hans Theobald , Franz Merger , Ernst Hofmann , Christoph Kuenast , Peter Hofmeister
IPC分类号： A01N43/16 , A01N43/28 , A01N43/30 , A01N43/32 , C07D309/30 , C07D407/12
CPC分类号： C07D407/12 , A01N43/16 , A01N43/28 , A01N43/30 , A01N43/32 , C07D309/30
摘要： 3,4-dihydro-2H-pyrans of the formula I ##STR1## where R.sup.1 is C.sub.4 -C.sub.20 -alkyl, C.sub.4 -C.sub.20 -alkoxyalkyl, aryl or C.sub.7 -C.sub.20 -arylalkyl, or is aryl or C.sub.7 -C.sub.20 -arylalkyl which bears from one to three substituents selected from the group consisting of halogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -haloalkyl, C.sub.1 -C.sub.8 -alkoxy or C.sub.1 -C.sub.8 -haloalkoxy, R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, R.sup.3 is aryl, or aryl bearing from one to three substituents selected from the group consisting of halogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -haloalkyl, C.sub.1 -C.sub.8 -alkoxy or C.sub.1 -C.sub.8 -haloalkoxy, or the radical ##STR2## where R.sup.4, R.sup.5 and R.sup.6 are hydrogen or C.sub.1 -C.sub.4 -alkyl, R.sup.7 is phenyl or benzoyl, or phenyl or benzoyl bearing from one to three substituents selected from the group consisting of halogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -haloalkyl, C.sub.1 -C.sub.8 -alkoxy and C.sub.1 -C.sub.8 -haloalkoxy, or a five- or six-membered heterocycle containing one or two oxygen atoms and which is either unsubstituted or substituted by one to three C.sub.1 -C.sub.8 -alkyl groups or one C.sub.3 -C.sub.6 -spirocycloalkyl, and l, m and n are 0 or 1, and their use for combating pests.
摘要翻译：其中R 1是C 4 -C 20烷基，C 4 -C 20烷氧基烷基，芳基或C 7 -C 20芳基烷基，或者是芳基或C 7 -C 20 - 芳基烷基， 1至3个选自卤素，C 1 -C 8 - 烷基，C 1 -C 8 - 卤代烷基，C 1 -C 8 - 烷氧基或C 1 -C 8 - 卤代烷氧基的取代基的芳基烷基，R 2为氢或C 1 -C 4烷基， R3是芳基或带有1至3个选自卤素，C 1 -C 8 - 烷基，C 1 -C 8 - 卤代烷基，C 1 -C 8 - 烷氧基或C 1 -C 8 - 卤代烷氧基的取代基的芳基或基团< 其中R 4，R 5和R 6是氢或C 1 -C 4 - 烷基，R 7是苯基或苯甲酰基，或苯基或苯甲酰基，其带有一至三个选自卤素，C 1 -C 8 - 烷基，C 1 -C 8 - ，C 1 -C 8 - 烷氧基和C 1 -C 8 - 卤代烷氧基，或含有一个或两个氧原子的五元或六元杂环，其未被取代或被一至三个C 1 -C 8烷基或一个C 3 -C 6 - 螺环烷基，l，m和n为0或1，用于防治害虫。

44. 发明授权

US4835171A Vinylureas, and fungicides containing these compounds 失效
标题翻译：乙烯基脲和含有这些化合物的杀真菌剂
公开(公告)号：US4835171A
公开(公告)日：1989-05-30
申请号：US717155
申请日：1985-03-28
申请人： Costin Rentzea , Wolfgang Spiegler , Walter Himmele , Eberhard Ammermann , Ernst-Heinrich Pommer
发明人： Costin Rentzea , Wolfgang Spiegler , Walter Himmele , Eberhard Ammermann , Ernst-Heinrich Pommer
IPC分类号： A01N47/38 , C07D231/12 , C07D231/16 , C07D233/56 , C07D233/60 , C07D233/68 , C07D249/08 , C07D249/10 , C07D521/00
CPC分类号： C07D231/12 , A01N47/38 , C07D233/56 , C07D249/08
摘要： Vinylureas of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or an unsubstituted or substituted alkyl or cycloalkyl radical, orR.sup.1 and R.sup.2 together form part of an unsubstituted or substituted carbocyclic ring,R.sup.3 is an unsubstituted or substituted alkyl or cycloalkyl radical,X is nitrogen or C--R.sup.6,Y is nitrogen or CH, andR.sup.4, R.sup.5 and R.sup.6 are each hydrogen, halogen or alkyl, and fungicides containing these compounds.
摘要翻译：式（I）的乙烯基脲其中R 1和R 2各自为氢或未取代或取代的烷基或环烷基，或者R 1和R 2一起形成未取代或取代的碳环的一部分，R 3为未取代或取代的烷基或环烷基，X是氮或C-R6，Y是氮或CH，R4，R5和R6各自是氢，卤素或烷基，以及包含这些化合物的杀真菌剂。

45. 发明授权

US4618668A Preparation of polyphenylene ethers 失效
标题翻译：聚苯醚的制备
公开(公告)号：US4618668A
公开(公告)日：1986-10-21
申请号：US722154
申请日：1985-04-11
申请人： Volker Muench , Juergen Hambrecht , Walter Himmele , Adolf Echte , Johann Swoboda
发明人： Volker Muench , Juergen Hambrecht , Walter Himmele , Adolf Echte , Johann Swoboda
IPC分类号： C08G65/44 , C08G65/46
CPC分类号： C08G65/44
摘要： High molecular weight polyphenylene ethers are prepared from monohydric phenols by an oxidative coupling reaction with oxygen in the presence of a solvent and of a catalyst complex consisting of a copper salt and an organic amine of the general formula ##STR1## where R.sup.1 is C.sub.2 -C.sub.20 -alkylidene, preferably C.sub.2 -C.sub.12 -alkylidene, or alkenylidene, R.sup.2 is H or C.sub.1 -C.sub.12 -alkyl, preferably C.sub.1 -C.sub.4 -alkyl, or C.sub.5 -C.sub.8 -cycloalkyl, each of which is unsubstituted or substituted by functional groups, and n is an integer from 1 to 4, preferably 1 or 2. Preferred functional groups are --OR.sup.3, --NHR.sup.3 or --SR.sup.3, in which R.sup.3 is H C.sub.1 -C.sub.12 -alkyl or C.sub.5 -C.sub.8 -cycloalkyl, and the most suitable amines are 3-tert.-butoxypropylamine, 4-tert.-butoxybutylamine, 3-tert.-butoxy-2-methylpropylamine, 3-tert.-butoxy-2,3-dimethylpropylamine, 3-tert.-butoxy-2-methyloctylamine and N-methyl-N-(4-tert.-butoxybutyl)-amine. The polyphenylene ethers can be processed to moldings by a thermoplastic method.
摘要翻译：高分子量聚苯醚通过在溶剂存在下与氧气的氧化偶联反应和由通式为“IMAGE”的铜盐和有机胺组成的催化剂络合物由一元酚制备，其中R1为C2-C20 亚烷基，优选C 2 -C 12亚烷基或亚烯基，R 2是H或C 1 -C 12烷基，优选C 1 -C 4 - 烷基或C 5 -C 8 - 环烷基，其各自是未取代的或被官能团取代，n 是1至4的整数，优选1或2.优选的官能团是-OR 3，-NHR 3或-SR 3，其中R 3是H-C 1 -C 12 - 烷基或C 5 -C 8 - 环烷基，最合适的胺是3 叔丁氧基丙基胺，4-叔丁氧基丁胺，3-叔丁氧基-2-甲基丙胺，3-叔丁氧基-2,3-二甲基丙胺，3-叔丁氧基-2-甲基辛胺和N- 甲基-N-（4-叔丁氧基丁基） - 胺。可以通过热塑性方法将聚苯醚加工成模制品。

46. 发明授权

US4568668A Oximinophosphoric acid derivatives, their preparation and their use for controlling pests 失效
标题翻译：肟基磷酸衍生物，其制备及其用于防治害虫的用途
公开(公告)号：US4568668A
公开(公告)日：1986-02-04
申请号：US572914
申请日：1984-01-23
申请人： Rainer Burstinghaus , Walter Himmele , Karl Kiehs , Heinrich Adolphi
发明人： Rainer Burstinghaus , Walter Himmele , Karl Kiehs , Heinrich Adolphi
IPC分类号： A01N57/08 , C07D309/04 , C07F9/09 , C07F9/165 , C07F9/24 , C07F9/40 , A01N57/16 , C07D307/06
CPC分类号： A01N57/08 , C07D309/04 , C07F9/097 , C07F9/1657 , C07F9/2445 , C07F9/4096
摘要： Oximinophosphoric acid derivatives of the formula I ##STR1## where R.sup.1 is a straight-chain or branched alkyl group of not more than 4 carbon atoms, R.sup.2 is a straight-chain or branched alkoxy or alkylthio group of not more than 4 carbon atoms, a straight-chain or branched alkyl group of not more than 3 carbon atoms, phenyl, amino, or a straight-chain or branched alkylamino or dialkylamino radical where each alkyl is of no more than 4 carbon atoms, X is oxygen or sulfur and n is 1 or 2, a process for their preparation, and their use for controlling pests.
摘要翻译：其中R 1是不大于4个碳原子的直链或支链烷基，R 2是不大于4个碳的直链或支链烷氧基或烷硫基。原子，不超过3个碳原子的直链或支链烷基，苯基，氨基或直链或支链烷基氨基或二烷基氨基，其中每个烷基不超过4个碳原子，X是氧或硫 n为1或2，其制备方法及其用于防治害虫的用途。

47. 发明授权

US4487965A Trans-3-(4'-tert.-Butylcyclohex-1'yl)-2-methyl-1-dialkylaminopropanes, their preparation and their use as drugs 失效
标题翻译：反式-3-（4'-叔丁基环己基-1'-基）-2-甲基-1-二烷基氨基丙烷，其制备及其作为药物的用途
公开(公告)号：US4487965A
公开(公告)日：1984-12-11
申请号：US508143
申请日：1983-06-27
申请人： Walter Himmele , Wolfgang Heberle , Friedrich-Wilhelm Kohlmann , Walter Wesenberg
发明人： Walter Himmele , Wolfgang Heberle , Friedrich-Wilhelm Kohlmann , Walter Wesenberg
IPC分类号： A61K31/13 , A61K20060101 , A61P31/04 , A61P31/10 , C07C67/00 , C07C209/00 , C07C209/72 , C07C211/17 , C07D20060101 , C07C85/24 , C07C87/36
CPC分类号： C07C211/17 , C07C2101/08 , C07C2101/14
摘要： Trans-3-(4'-tert.-Butylcyclohex-1'-yl)-2-methyl-1-dialkylaminopropanes of the formula I ##STR1## where R.sup.1 and R.sup.2 are each alkyl and the sum of the carbon atoms in R.sup.1 and R.sup.2 is 5, 6, or 7, and their salts with physiologically tolerated acids, and their preparation, are described. The novel compounds are useful as active compounds for drugs.
摘要翻译：式I的反-3-（4'-叔丁基环己-1'-基）-2-甲基-1-二烷基氨基丙烷其中R 1和R 2各自是烷基，R 1中的碳原子的总和并且R2是5,6或7，并且描述了它们与生理上耐受的酸的盐及其制备方法。新化合物可用作药物的活性化合物。

48. 发明授权

US4464370A Cyclohexene containing morpholines and fungicidal use 失效
标题翻译：环己烯含有吗啉和杀真菌剂
公开(公告)号：US4464370A
公开(公告)日：1984-08-07
申请号：US380470
申请日：1982-05-20
申请人： Walter Gramlich , Walter Himmele , Christoph Martin , Ernst-Heinrich Pommer , Hardo Siegel
发明人： Walter Gramlich , Walter Himmele , Christoph Martin , Ernst-Heinrich Pommer , Hardo Siegel
IPC分类号： C07D295/02 , A01N43/40 , A01N43/84 , C07C45/69 , C07C45/74 , C07C47/225 , C07D211/14 , C07D265/30 , C07D295/033
CPC分类号： C07D295/033 , A01N43/40 , A01N43/84 , C07C45/69 , C07C45/74 , C07C47/225
摘要： Cyclohexene derivatives of the formula I ##STR1## where R.sup.1 and R.sup.2 are hydrogen or tert.-butyl and N and X are members of a heterocyclic ring in which X is an alkylene chain of four, five or six members, one of which may be a hetero-atom, such as oxygen, and where the alkylene radicals are unsubstituted or substituted by alkyl or by --CH.sub.2 OH or its acetyl or propionyl derivative, and their salts are used in fungicides.
摘要翻译：式I的环己烯衍生物其中R 1和R 2是氢或叔丁基，N和X是杂环的成员，其中X是四个，五个或六个成员的亚烷基链，其中之一可以是一个杂原子，如氧，其中亚烷基是未取代的或被烷基取代或被-CH 2 OH或其乙酰基或丙酰基衍生物取代，它们的盐用于杀真菌剂中。

49. 发明授权

US4410734A Optically active phenylpropane derivatives, their preparation and their use for the preparation of fungicides 失效
标题翻译：光学活性苯丙烷衍生物，其制备及其在制备杀真菌剂中的应用
公开(公告)号：US4410734A
公开(公告)日：1983-10-18
申请号：US213792
申请日：1980-12-08
申请人： Christoph Martin , Walter Himmele , Hardo Siegel
发明人： Christoph Martin , Walter Himmele , Hardo Siegel
IPC分类号： C12P7/40 , C07C27/00 , C07C33/18 , C07C33/20 , C07C33/24 , C07C41/00 , C07C43/20 , C07C43/23 , C07C43/303 , C07C51/00 , C07C57/30 , C07C59/64 , C07C67/00 , C07C69/612 , C07D295/02 , C07D295/03 , C12P7/22 , C12P7/24 , C12R1/865
CPC分类号： C07D295/03 , C07C33/20 , C07C33/24 , C07C43/23
摘要： S-Configurated phenylpropane derivatives of the formula ##STR1## where R.sup.1 is alkyl, aryl or alkoxy, R.sup.2 is hydrogen, alkyl, aryl or alkoxy, and R.sup.3 is carboxyl or esterified carboxyl, acetalized formyl, hydroxymethyl or esterified hydroxymethyl, their preparation by microbiological hydrogenation, and their use for the preparation of fungicidal compounds.
摘要翻译：其中R 1为烷基，芳基或烷氧基，R 2为氢，烷基，芳基或烷氧基，且R 3为羧基或酯化羧基，缩醛化甲酰基，羟甲基或酯化羟甲基的S-配位苯基丙烷衍生物，其制备方法为微生物氢化及其用于制备杀真菌化合物的用途。

50. 发明授权

US4220777A Naphthalimide derivatives 失效
标题翻译：邻苯二甲酰亚胺衍生物
公开(公告)号：US4220777A
公开(公告)日：1980-09-02
申请号：US961485
申请日：1978-11-17
申请人： Jochen Karg , Manfred Patsch , Walter Himmele
发明人： Jochen Karg , Manfred Patsch , Walter Himmele
IPC分类号： C09B57/08 , C07D221/14
CPC分类号： C07D221/14
摘要： Naphthalimide derivatives of the general formula ##STR1## where R.sup.1 is hydrogen or C.sub.1 - to C.sub.4 -alkyl,R.sup.2 is nitrile or a radical containing a carbonyl group or an acetalized carbonyl group andR.sup.3 and R.sup.4 are unsubstituted or substituted alkyl.The compounds are excellent optical brighteners, especially for synthetic fibers.
摘要翻译：其中R 1为氢或C 1〜C 4 - 烷基，R 2为腈或含有羰基或缩醛化羰基的基团，R 3和R 4为未取代或取代的烷基的通式为“IMAGE”的萘二甲酰亚胺衍生物。这些化合物是优异的荧光增白剂，特别是合成纤维。

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