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    • 44. 发明授权
    • Method of polishing a substrate comprising polysilicon, silicon oxide and silicon nitride
    • 抛光包括多晶硅,氧化硅和氮化硅的衬底的方法
    • US08491808B2
    • 2013-07-23
    • US12724685
    • 2010-03-16
    • Yi GuoZhendong LiuKancharla-Arun Kumar ReddyGuangyun Zhang
    • Yi GuoZhendong LiuKancharla-Arun Kumar ReddyGuangyun Zhang
    • C03C15/00C03C25/68H01L21/302H01L21/461
    • H01L21/31053C09G1/02C09K3/1463
    • A method for chemical mechanical polishing of a substrate is provided, comprising: providing a substrate, wherein the substrate comprises polysilicon, silicon oxide and silicon nitride; providing a chemical mechanical polishing composition, comprising, as initial components: water; an abrasive; an alkyl aryl polyether sulfonate compound, wherein the alkyl aryl polyether sulfonate compound has a hydrophobic portion having an alkyl group bound to an aryl ring and a nonionic acyclic hydrophilic portion having 4 to 100 carbon atoms; and a substance according to formula I wherein each of R1, R2, R3, R4, R5, R6 and R7 is a bridging group having a formula —(CH2)n—, wherein n is an integer selected from 1 to 10; providing a chemical mechanical polishing pad with a polishing surface; moving the polishing surface relative to the substrate; dispensing the chemical mechanical polishing composition onto the polishing surface; and, abrading at least a portion of the substrate to polish the substrate; wherein at least some of the polysilicon is removed from the substrate; and, wherein at least some of the silicon oxide and silicon nitride is removed from the substrate.
    • 提供了一种用于基板的化学机械抛光的方法,包括:提供基板,其中所述基板包括多晶硅,氧化硅和氮化硅; 提供化学机械抛光组合物,其包含作为初始组分的水; 研磨剂 烷基芳基聚醚磺酸盐化合物,其中烷基芳基聚醚磺酸盐化合物具有与芳环结合的烷基的疏水部分和具有4至100个碳原子的非离子非环状亲水部分; 和根据式I的物质,其中R1,R2,R3,R4,R5,R6和R7中的每一个是具有式 - (CH 2)n - 的桥连基团,其中n是选自1至10的整数; 提供具有抛光表面的化学机械抛光垫; 相对于衬底移动抛光表面; 将化学机械抛光组合物分配到抛光表面上; 并且研磨所述衬底的至少一部分以抛光所述衬底; 其中所述多晶硅中的至少一些从所述衬底移除; 并且其中从所述衬底去除所述氧化硅和氮化硅中的至少一些。
    • 46. 发明申请
    • Method Of Polishing Chalcogenide Alloy
    • 抛光硫族化合物的方法
    • US20120003834A1
    • 2012-01-05
    • US12828441
    • 2010-07-01
    • Ja-Ho KooZhendong LiuKaveri SawantKancharla-Arun Kumar Reddy
    • Ja-Ho KooZhendong LiuKaveri SawantKancharla-Arun Kumar Reddy
    • H01L21/306
    • C09G1/02H01L45/06H01L45/144H01L45/1683
    • The invention provides a method for chemical mechanical polishing of a substrate. The invention comprises providing a substrate, wherein the substrate comprises a chalcogenide phase change alloy and providing a chemical mechanical polishing composition, wherein the chemical mechanical polishing composition comprises, by weight percent, water, 0.1 to 30 abrasive, at least one polishing agent selected from 0.05 to 5 halogen compound, 0.05 to 5 phthalic acid, 0.05 to 5 phthalic anhydride and salts, derivatives and mixtures thereof and wherein the chemical mechanical polishing composition has a pH of 2 to less than 7. A chemical mechanical polishing pad polishes the substrate with the chemical mechanical polishing pad and the chemical mechanical polishing composition to selectively or non-selectively remove the chalcogenide phase change alloy from the substrate.
    • 本发明提供了一种用于基材的化学机械抛光的方法。 本发明包括提供一种基材,其中该基材包括一种硫族化物相变合金并提供一种化学机械抛光组合物,其中该化学机械抛光组合物包含按重量百分比计的水,0.1至30种研磨剂,至少一种抛光剂, 0.05至5个卤素化合物,0.05至5邻苯二甲酸,0.05至5邻苯二甲酸酐及其盐,衍生物和混合物,其中化学机械抛光组合物的pH值为2至小于7.化学机械抛光垫用 化学机械抛光垫和化学机械抛光组合物,以从衬底中选择性或非选择性地除去硫族化物相变合金。
    • 47. 发明授权
    • Chemical mechanical polishing composition and methods relating thereto
    • 化学机械抛光组合物及其相关方法
    • US08071479B2
    • 2011-12-06
    • US12332816
    • 2008-12-11
    • Zhendong Liu
    • Zhendong Liu
    • H01L21/302
    • C09G1/02C09K3/1463H01L21/3212
    • A method for chemical mechanical polishing of a substrate comprising a barrier material in the presence of at least one of an interconnect metal and a low-k dielectric material using a chemical mechanical polishing composition comprising water; 1 to 40 wt % abrasive having an average particle size of ≦100 nm; 0.001 to 5 wt % quaternary compound; a material having a formula (I): wherein R is selected from C2-C20 alkyl, C2-C20 aryl, C2-C20 aralkyl and C2-C20 alkaryl; wherein x is an integer from 0 to 20; wherein y is an integer from 0 to 20; wherein x+y≧1; and, wherein the chemical mechanical polishing composition has a pH≦5.
    • 在使用包含水的化学机械抛光组合物的介质金属和低k电介质材料中的至少一种的存在下,包括阻挡材料的基材的化学机械抛光的方法; 1至40重量%的平均粒度为& 100埃的研磨剂; 100纳米; 0.001〜5重量%的季铵化合物; 具有式(I)的材料:其中R选自C 2 -C 20烷基,C 2 -C 20芳基,C 2 -C 20芳烷基和C 2 -C 20烷芳基; 其中x是0至20的整数; 其中y是0至20的整数; 其中x +y≥1; 并且其中所述化学机械抛光组合物具有pH≦̸ 5。
    • 49. 发明授权
    • Selective barrier metal polishing method
    • 选择性屏障金属抛光方法
    • US07981316B2
    • 2011-07-19
    • US11975804
    • 2007-10-22
    • Zhendong LiuRoss E. Barker, II
    • Zhendong LiuRoss E. Barker, II
    • C09K13/00C09K13/04C09K13/06H01L21/302
    • C09G1/02C09K3/1409C09K3/1463C23F3/06H01L21/3212H01L21/7684
    • The polishing method uses a polishing solution for removing barrier materials in the presence of interconnect metals and dielectrics. The polishing solution comprises, by weight percent, 0.1 to 10 hydrogen peroxide, at least one pH adjusting agent selected from the group consisting of nitric acid, sulfuric acid, hydrochloric acid and phosphoric acid for adjusting a pH level of the polishing solution to less than 3, at least 0.0025 benzotriazole inhibitor for reducing removal rate of the interconnect metals, 0 to 10 surfactant, 0.01 to 10 colloidal silica having an average particle size of less than 50 nm and balance water and incidental impurities. The polishing solution has a tantalum nitride material to copper selectivity of at least 3 to 1 and a tantalum nitride to TEOS selectivity of at least 3 to 1.
    • 抛光方法使用在互连金属和电介质存在下去除阻挡材料的抛光溶液。 抛光溶液以重量百分比计包含0.1至10种过氧化氢,至少一种选自硝酸,硫酸,盐酸和磷酸的pH调节剂,用于将抛光溶液的pH值调节至小于 3,至少含有0.0025的苯并三唑抑制剂,用于降低互连金属的去除速率,0至10表面活性剂,0.01至10个平均粒度小于50nm的胶体二氧化硅,余量为水和附带杂质。 抛光溶液的氮化钽材料至铜选择性为至少3比1,氮化钽至TEOS选择性为至少3比1。
    • 50. 发明授权
    • Multi-component barrier polishing solution
    • 多组分屏障抛光液
    • US07842192B2
    • 2010-11-30
    • US11349863
    • 2006-02-08
    • Jinru BianZhendong Liu
    • Jinru BianZhendong Liu
    • C09K13/00
    • H01L21/3212C09G1/02
    • The polishing solution is useful for removing barrier materials in the presence of at least one nonferrous interconnect metal with limited erosion of dielectrics. The solution contains 0 to 20 weight percent oxidizer, at least 0.001 weight percent inhibitor for reducing removal rate of the nonferrous interconnect metals, 1 ppm to 4 weight percent organic-containing ammonium cationic salt formed with a quanternary ammonium structure, 1 ppm to 4 weight percent anionic surfactant, the anionic surfactant having 4 to 25 carbon atoms and the total carbon atoms in of the ammonium cationic salt plus the anionic surfactant being 6 to 40 carbon atoms, 0 to 50 weight percent abrasive and balance water; and the solution having a pH of less than 7.
    • 在至少一种具有有限的电介质腐蚀的有色互连金属的存在下,抛光溶液可用于去除阻挡材料。 该溶液含有0至20重量百分比的氧化剂,至少0.001重量%的用于降低有色互连金属去除速率的抑制剂,1ppm至4重量%的由铵季铵结构形成的含铵阳离子盐,1ppm至4重量% 阴离子表面活性剂,阴离子表面活性剂具有4至25个碳原子,铵阳离子盐加阴离子表面活性剂的总碳原子数为6至40个碳原子,0至50重量%的研磨剂和余量的水; 并且该溶液的pH值小于7。