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41. 发明授权

US07090928B2 Binuclear compounds 有权
标题翻译：双核化合物
公开(公告)号：US07090928B2
公开(公告)日：2006-08-15
申请号：US10404785
申请日：2003-04-01
申请人： Mark E. Thompson , Bert Alleyne , Peter Djurovich
发明人： Mark E. Thompson , Bert Alleyne , Peter Djurovich
IPC分类号： H01L51/54 , H05B33/14 , C09K11/06
CPC分类号： H01L51/009 , H01L51/006 , H01L51/0071 , H01L51/0077 , H01L51/0087 , H01L51/5016 , H01L51/5036 , Y10S428/917
摘要： Devices are provided having an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode. The emissive layer includes an emissive material having more than one metal center. In one embodiment, first and second metal centers are independently selected from the group consisting of d7, d8 and d9 metals. A bridging ligand is coordinated to the first metal center and to the second metal center. In one embodiment, the first and second metal centers each have coordination numbers of at least 3, and more preferably each have coordination numbers of 4. In one embodiment, photoactive ligands are coordinated to the first and second metal centers. In one embodiment, there are no photoactive ligands. In one embodiment, a charge neutral bi-nuclear emissive material is provided. In one embodiment the first and metal centers have a co-facial configuration, and preferably a square planar co-facial configuration. In one embodiment, the metal centers are selected from metals having an atomic number greater than or equal to 40.
摘要翻译：提供了具有阳极，阴极和布置在阳极和阴极之间并与之电连接的发射层的器件。发射层包括具有多于一个金属中心的发光材料。在一个实施方案中，第一和第二金属中心独立地选自d7，d8和d9金属。桥连配体与第一金属中心和第二金属中心配位。在一个实施方案中，第一和第二金属中心各自具有至少3的配位数，并且更优选地各自具有4的配位数。在一个实施方案中，光活性配体与第一和第二金属中心配位。在一个实施方案中，不存在光活性配体。在一个实施例中，提供电荷中性双核发射材料。在一个实施例中，第一和金属中心具有共面配置，并且优选地是正方形平面协同配置。在一个实施方案中，金属中心选自原子序数大于或等于40的金属。

42. 发明申请

US20050119485A1 Organometallic compounds for use in electroluminescent devices 有权
标题翻译：用于电致发光器件的有机金属化合物
公开(公告)号：US20050119485A1
公开(公告)日：2005-06-02
申请号：US11002188
申请日：2004-12-03
申请人： Cory Brown , David Knowles , Raymond Kwong , Yeh-Jiun Tung , Robert Walters , Peter Djurovich , Mark Thompson
发明人： Cory Brown , David Knowles , Raymond Kwong , Yeh-Jiun Tung , Robert Walters , Peter Djurovich , Mark Thompson
IPC分类号： C07F15/00 , C09K11/06 , H01L51/30 , H01L51/50 , H05B33/14
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/185 , H01L51/0085 , H01L51/5016 , Y10S428/917
摘要： An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer further comprising an emissive material having the structure: M is a metal having an atomic weight greater than 40. R5 is an aromatic group. The emissive material itself is also provided. The emissive material provides an improved stability and efficiency.
摘要翻译：提供有机发光装置。该器件具有阳极，阴极和布置在阳极和阴极之间的发射层。发射层还包括具有以下结构的发射材料：M是原子量大于40的金属.R 5是芳族基团。还提供了发射材料本身。发光材料提供了改进的稳定性和效率。

43. 发明申请

US20060269785A1 Binuclear compounds 有权
标题翻译：双核化合物
公开(公告)号：US20060269785A1
公开(公告)日：2006-11-30
申请号：US11435210
申请日：2006-05-15
申请人： Mark Thompson , Bert Alleyne , Peter Djurovich
发明人： Mark Thompson , Bert Alleyne , Peter Djurovich
IPC分类号： H01L51/54 , H05B33/14
CPC分类号： H01L51/009 , H01L51/006 , H01L51/0071 , H01L51/0077 , H01L51/0087 , H01L51/5016 , H01L51/5036 , Y10S428/917
摘要： Devices are provided having an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode. The emissive layer includes an emissive material having more than one metal center. In one embodiment, first and second metal centers are independently selected from the group consisting of d7, d8, and d9 metals. A bridging ligand is coordinated to the first metal center and to the second metal center. In one embodiment, the first and second metal centers each have coordination numbers of at least 3, and more preferably each have coordination numbers of 4. In one embodiment, photoactive ligands are coordinated to the first and second metal centers. In one embodiment, there are no photoactive ligands. In one embodiment, a charge neutral bi-nuclear emissive material is provided. In one embodiment the first and metal centers have a co-facial configuration, and preferably a square planar co-facial configuration. In one embodiment, the metal centers are selected from metals having an atomic number greater than or equal to 40.
摘要翻译：提供了具有阳极，阴极和布置在阳极和阴极之间并与之电连接的发射层的器件。发射层包括具有多于一个金属中心的发光材料。在一个实施方案中，第一和第二金属中心独立地选自d7，d8和d9金属。桥连配体与第一金属中心和第二金属中心配位。在一个实施方案中，第一和第二金属中心各自具有至少3的配位数，并且更优选地各自具有4的配位数。在一个实施方案中，光活性配体与第一和第二金属中心配位。在一个实施方案中，不存在光活性配体。在一个实施例中，提供电荷中性双核发射材料。在一个实施例中，第一和金属中心具有共面配置，并且优选地是正方形平面协同配置。在一个实施方案中，金属中心选自原子序数大于或等于40的金属。

44. 发明申请

US20050260447A1 Cyclometallated iridium carbene complexes for use as hosts 有权
标题翻译：用作主体的环金属铱卡宾配合物
公开(公告)号：US20050260447A1
公开(公告)日：2005-11-24
申请号：US11032836
申请日：2005-01-10
申请人： Jason Brooks , Xiao-Chang Li , Bert Alleyne , Mark Thompson , Peter Djurovich , Arnold Tamayo
发明人： Jason Brooks , Xiao-Chang Li , Bert Alleyne , Mark Thompson , Peter Djurovich , Arnold Tamayo
IPC分类号： C09K11/06 , C25B3/00 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14
CPC分类号： H05B33/14 , C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0059 , H01L51/0078 , H01L51/0081 , H01L51/0085 , H01L51/5016
摘要： An organic light emitting device is provided. The device has an anode, a cathode and an organic layer disposed between the anode and the cathode. The organic layer comprises a host and a dopant, and the host comprises a compound having at least one carbene atom coordinated to iridium, and the compound has the structure:
摘要翻译：提供有机发光装置。该器件具有阳极，阴极和设置在阳极和阴极之间的有机层。有机层包括主体和掺杂剂，并且主体包含具有与铱配位的至少一个卡宾原子的化合物，该化合物具有以下结构：

45. 发明申请

US20050164031A1 Dual emitting dyads of heavy metal complexes as broad band emitters for organic LEDs 审中-公开
标题翻译：重金属配合物的双发射二极管作为有机LED的宽带发射器
公开(公告)号：US20050164031A1
公开(公告)日：2005-07-28
申请号：US10807739
申请日：2004-03-24
申请人： Mark Thompson , Biwu Ma , Peter Djurovich
发明人： Mark Thompson , Biwu Ma , Peter Djurovich
IPC分类号： C07F15/00 , C09K11/06 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14
CPC分类号： C09K11/06 , C07F15/0033 , C07F15/0086 , C07F15/0093 , C09K2211/185 , H01L51/0085 , H01L51/0087 , H01L51/009 , H01L51/5016 , H05B33/14
摘要： An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode. The emissive layer further comprises a compound having two metal centers, in which each metal has an atomic weight greater than 40. A bridging ligand, small molecule, or polymer is coordinated to both metal centers, and at least one photoactive ligand is bound to each metal. In one embodiment, the transition dipole moment of the photoactive ligand bound to the first metal is orthogonal to the photoactive ligand bound to the second metal. In another embodiment, the first metal center and the atoms of the bridging ligand that are coordinated to the first metal center form a plane and the atoms of the bridging ligand that are coordinated to the second metal center form another plane, and the planes form an angle that is between about 80 degrees and 100 degrees. In another embodiment, the bridging ligand is diacetylacetonate. In another embodiment, a polymer or small molecule is coordinated to both metals, and the metal-ligand complex for the first metal center is different from the metal-ligand complex for the second metal center.
摘要翻译：提供有机发光装置。该装置具有阳极，阴极和布置在阳极和阴极之间并电连接到阳极和阴极的发射层。发射层还包括具有两个金属中心的化合物，其中每个金属的原子量大于40。桥连配体，小分子或聚合物与两个金属中心配位，并且至少一个光活性配体结合到每个金属。在一个实施方案中，与第一金属结合的光活性配体的跃迁偶极矩与与第二金属结合的光活性配体正交。在另一个实施方案中，与第一金属中心配位的桥接配体的第一金属中心和原子形成平面，并且与第二金属中心配位的桥连配体的原子形成另一平面，并且平面形成角度在大约80度和100度之间。在另一个实施方案中，桥连配体是二乙酰丙酮化物。在另一个实施方案中，聚合物或小分子与两种金属配位，第一金属中心的金属 - 配体络合物不同于第二金属中心的金属 - 配体络合物。

46. 发明授权

US08580394B2 3-coordinate copper(I)-carbene complexes 有权
标题翻译： 3-配位铜（I） - 碳烯配合物
公开(公告)号：US08580394B2
公开(公告)日：2013-11-12
申请号：US12948396
申请日：2010-11-17
申请人： Mark Thompson , Peter Djurovich , Valentina Krylova
发明人： Mark Thompson , Peter Djurovich , Valentina Krylova
IPC分类号： H01L51/54 , C09K11/06
CPC分类号： H01L51/0091 , C07F1/08 , C09K11/06 , C09K2211/188 , H01L51/5016
摘要： Novel phosphorescent trigonal copper carbene complexes are provided. The complex comprise a carbene ligand coordinated to a three coordinate copper atom. The complex may be used in organic light emitting devices. In particular, the complexes may be especially useful in OLEDs used for lighting applications.
摘要翻译：提供了新的磷光三角铜卡宾络合物。络合物包含与三配位铜原子配位的卡宾配体。该复合物可用于有机发光器件。特别地，复合物可能特别适用于用于照明应用的OLED。

47. 发明申请

US20120056529A1 3-COORDINATE COPPER(I)-CARBENE COMPLEXES 有权
标题翻译： 3-坐标铜（I） - 碳复合物
公开(公告)号：US20120056529A1
公开(公告)日：2012-03-08
申请号：US12948396
申请日：2010-11-17
申请人： Mark Thompson , Peter Djurovich , Valentina Krylova
发明人： Mark Thompson , Peter Djurovich , Valentina Krylova
IPC分类号： H01J1/63 , C07F1/08 , C07F5/02 , C07F9/6596
CPC分类号： H01L51/0091 , C07F1/08 , C09K11/06 , C09K2211/188 , H01L51/5016
摘要： Novel phosphorescent trigonal copper carbene complexes are provided. The complex comprise a carbene ligand coordinated to a three coordinate copper atom. The complex may be used in organic light emitting devices. In particular, the complexes may be especially useful in OLEDs used for lighting applications.
摘要翻译：提供了新的磷光三角铜卡宾络合物。络合物包含与三配位铜原子配位的卡宾配体。该复合物可用于有机发光器件。特别地，复合物可能特别适用于用于照明应用的OLED。

48. 发明申请

US20060257685A1 Organic light emitting devices having carrier transporting layers comprising metal complexes 有权
标题翻译：具有包含金属络合物的载流子传输层的有机发光器件
公开(公告)号：US20060257685A1
公开(公告)日：2006-11-16
申请号：US11408542
申请日：2006-04-20
申请人： Mark Thompson , Xiaofan Ren , Peter Djurovich , Haiping Hong , Stephen Forrest , Chihaya Adachi
发明人： Mark Thompson , Xiaofan Ren , Peter Djurovich , Haiping Hong , Stephen Forrest , Chihaya Adachi
IPC分类号： H01L51/54 , H05B33/12
CPC分类号： H01L51/5096 , C09K11/06 , C09K2211/1029 , C09K2211/1044 , C09K2211/185 , C09K2211/187 , C09K2211/188 , H01L51/002 , H01L51/0035 , H01L51/0037 , H01L51/0059 , H01L51/0062 , H01L51/007 , H01L51/0077 , H01L51/0079 , H01L51/008 , H01L51/0081 , H01L51/0083 , H01L51/0085 , H01L51/5016 , H01L51/5048 , H01L2251/552 , H05B33/14 , Y10S428/917 , Y10T428/24942
摘要： Light emitting devices having charge transporting layers comprising one or more metal complexes are provided. More particularly, devices include hole transporting layers comprising at least one organometallic complex are disclosed. The present devices can further comprise an electron blocking layer for improved efficiency.
摘要翻译：提供具有包含一种或多种金属络合物的电荷输送层的发光器件。更具体地，装置包括包含至少一种有机金属络合物的空穴传输层。本发明的器件还可以包括用于提高效率的电子阻挡层。

49. 发明申请

US20060024526A1 Organic light emitting devices with electron blocking layers 有权
公开(公告)号：US20060024526A1
公开(公告)日：2006-02-02
申请号：US11230851
申请日：2005-09-19
申请人： Mark Thompson , Vadim Adamovich , Xiaofan Ren , Arnold Tamayo , Peter Djurovich
发明人： Mark Thompson , Vadim Adamovich , Xiaofan Ren , Arnold Tamayo , Peter Djurovich
IPC分类号： H05B33/12
CPC分类号： H01L51/0085 , C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0059 , H01L51/0062 , H01L51/0077 , H01L51/0081 , H01L51/0087 , H01L51/5096 , H01L2251/308 , H05B33/14 , Y10S428/917
摘要： The present invention relates to organic light emitting devices (OLEDs), and more specifically to efficient OLEDs having electron blocking layers. The devices of the present invention comprise at least one electron blocking layer which functions to confine electrons to specific regions of the light emitting devices. The present invention also relates to materials for use as electron blockers that show increased stability when incorporated into an organic light emitting device.

50. 发明申请

US20050260448A1 Novel organometallic compounds for use in electroluminescent devices 有权
标题翻译：用于电致发光器件的新型有机金属化合物
公开(公告)号：US20050260448A1
公开(公告)日：2005-11-24
申请号：US11032885
申请日：2005-01-10
申请人： Chun Lin , Jui-Yi Tsai , Jason Brooks , Bert Alleyne , Mark Thompson , Peter Djurovich , Arnold Tamayo , Tissa Sajoto , Robert Walters
发明人： Chun Lin , Jui-Yi Tsai , Jason Brooks , Bert Alleyne , Mark Thompson , Peter Djurovich , Arnold Tamayo , Tissa Sajoto , Robert Walters
IPC分类号： C09K11/06 , H01L51/00 , H01L51/50 , H05B33/14
CPC分类号： C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0059 , H01L51/0078 , H01L51/0081 , H01L51/0085 , H01L51/5016 , H05B33/14 , Y10S428/917
摘要： An organic light emitting device having an anode, a cathode and an organic layer between the anode and the cathode is provided. The organic layer comprises a carbene-metal complex having the structure: where R may be halo, hydrogen, alkyl, alkenyl, alkynyl, aralkyl, aryl, heteroaryl, substituted aryl, substituted heteroaryl, or a heterocyclic group; and additionally or alternatively, two or more R groups on the same ring form independently a 5 or 6-member cyclic group, which may be cycloalkyl, cycloheteroalkyl, aryl or heteroaryl; and which may be substituted by one or more substituents J; and J may be R′, CN, CF3, C(O)OR′, C(O)R′, C(O)NR′2, NR′2, NO2, OR′, SR′, SO2, SOR′, or SO3R′, and additionally or alternatively, two J groups on adjacent ring atoms form a fused 5- or 6-membered aromatic group; each R′ may be halo, H, alkyl, alkenyl, alkynyl, heteroalkyl, aralkyl, aryl and heteroaryl.
摘要翻译：提供了一种在阳极和阴极之间具有阳极，阴极和有机层的有机发光器件。有机层包含具有以下结构的卡宾金属络合物：其中R可以是卤素，氢，烷基，烯基，炔基，芳烷基，芳基，杂芳基，取代的芳基，取代的杂芳基或杂环基; 另外或替代地，相同环上的两个或更多个R基团独立地形成5或6元环基，其可以是环烷基，环杂烷基，芳基或杂芳基; 并且其可以被一个或多个取代基J取代; 并且J可以是R'，CN，CF 3，C（O）OR'，C（O）R'，C（O）NR'2，NR' 2'，2'，OR'，SR'，SO 2，SOR'或SO 3 R' ，另外或可选地，相邻环原子上的两个J基团形成稠合的5或6元芳族基团; 每个R'可以是卤素，H，烷基，烯基，炔基，杂烷基，芳烷基，芳基和杂芳基。

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