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41. 发明授权

US08461092B2 Home care compositions comprising hydrolysis resistant organomodified disiloxane surfactants 有权
标题翻译：包含耐水解的有机改性的二硅氧烷表面活性剂的家庭护理组合物
公开(公告)号：US08461092B2
公开(公告)日：2013-06-11
申请号：US12621774
申请日：2009-11-19
申请人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaramaran
发明人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaramaran
IPC分类号： C11D17/04
CPC分类号： A61Q19/00 , A61K8/585 , C09D163/00 , C08L2666/44
摘要： Compositions comprising disiloxane surfactant compositions comprising a silicone composition comprising a silicone having the formula: MM′ where M=R1R2R3SiO1/2; M′=R4R5R6SiO1/2; with R1 selected from the group consisting of branched monovalent hydrocarbon radical of from 3 to 6 carbon atoms and R7, where R7 has the formula: R8R9R10SiR12 with R8, R9, and R10 each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and monovalent aryl or alkaryl hydrocarbon radicals having from 6 to 13 carbon atoms and R12 is a divalent hydrocarbon radical having from 1 to 3 carbon atoms, R2 and R3 are each independently selected from the group of from 1 to 6 carbon atom monovalent hydrocarbon radicals or R1, with R4 an alkylpolyalkyleneoxide of the general formula: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 where R13 is a divalent linear or branched hydrocarbon radical having the structure: —CH2—CH(R15)(R16)dO— where R15 is H or methyl; R16 is a divalent alkyl radical of 1 to 6 carbons where the subscript d may be 0 or 1; R14 is selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl where the subscripts a, b and c are zero or positive and satisfy the following relationships: 2≦a+b+c≦20 with a≧2, and R5 and R6 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms or R4 that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：包含二硅氧烷表面活性剂组合物的组合物，其包含硅氧烷组合物，其包含具有式MM的其中M = R 1 R 2 R 3 SiO 1/2的硅氧烷; M'= R4R5R6SiO1 / 2; 其中R 1选自3至6个碳原子的支化一价烃基和R 7，其中R 7具有下式：R 8 R 9 R 10 SiR 12，其中R 8，R 9和R 10各自独立地选自具有1至 6个碳原子和具有6至13个碳原子的单价芳基或烷芳基烃基，R 12是具有1至3个碳原子的二价烃基，R 2和R 3各自独立地选自1至6个碳原子的单价烃基或R 1，其中R 4是具有通式R 13（C 2 H 4 O）a（C 3 H 6 O）b（C 4 H 8 O）c R 14的烷基聚环氧烷，其中R 13是具有以下结构的二价直链或支链烃基：-CH 2 -CH（R 15））dO-，其中R 15是H或甲基; R16是1至6个碳的二价烷基，其中下标d可以是0或1; R 14选自H，1至6个碳原子的一价烃基和乙酰基，其中下标a，b和c为零或正，并且满足以下关系：2 @ a + b + c @ 20与 a> = 2，R 5和R 6各自独立地选自具有1至6个碳原子的一价烃基或在宽pH范围内表现出抗水解性的R4。

42. 发明授权

US08183317B2 Coating compositions comprising hydrolysis resistant organomodified disiloxane surfactants 失效
标题翻译：包含耐水解的有机改性的二硅氧烷表面活性剂的涂料组合物
公开(公告)号：US08183317B2
公开(公告)日：2012-05-22
申请号：US12621755
申请日：2009-11-19
申请人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaramaran
发明人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaramaran
IPC分类号： C08L83/12
CPC分类号： A61Q19/00 , A61K8/585 , C09D163/00 , C08L2666/44
摘要： A coating composition includes a silicone and a coating resin. The silicone has the formula MM′ where M=R1R2R3SiO1/2 and M′=R4R5R6SiO1/2. R1 can be a branched monovalent hydrocarbon radical of from 3 to 6 carbon atoms or R7, where R7 has the formula R8R9R10SiR12 wherein R8, R9, and R10 can independently be monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and monovalent aryl or alkaryl hydrocarbon radicals having from 6 to 13 carbon atoms. R12 is a divalent hydrocarbon radical having from 1 to 3 carbon atoms. R2 and R3 can be from 1 to 6 carbon atom monovalent hydrocarbon radicals or R1, with R4 being an alkylpolyalkyleneoxide. And R5 and R6 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms or R4 that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：涂料组合物包括硅树脂和涂料树脂。硅氧烷具有式M'，其中M = R1R2R3SiO1 / 2和M'= R4R5R6SiO1 / 2。 R 1可以是具有3至6个碳原子的支链一价烃基或R 7，其中R 7具有式R 8 R 9 R 10 SiR 12，其中R 8，R 9和R 10可以独立地为具有1至6个碳原子的一价烃基和单价芳基或烷芳基具有6至13个碳原子的基团。 R 12是具有1至3个碳原子的二价烃基。 R2和R3可以是1至6个碳原子的单价烃基或R1，R4是烷基聚环氧烷。并且R 5和R 6各自独立地选自具有1至6个碳原子的一价烃基或在宽pH范围内表现出抗水解性的R4。

43. 发明授权

US06890886B2 Agricultural compositions employing organosiloxanes containing polyhydric groups 失效
标题翻译：使用含有多羟基的有机硅氧烷的农业组合物
公开(公告)号：US06890886B2
公开(公告)日：2005-05-10
申请号：US09858708
申请日：2001-05-16
申请人： George A. Policello , Gerald J. Murphy
发明人： George A. Policello , Gerald J. Murphy
IPC分类号： C08L83/06 , A01N25/10 , A01N25/30 , A01N55/10 , C08K5/00 , C08L83/12 , A01N3/02 , A01N57/00
CPC分类号： A01N25/10 , A01N25/30
摘要： The present invention teaches polyhydric organosilicones and their use, a preferred of which is as adjuvants for pesticides. The polyhydric organosilicone have siloxane backbones with pendant, terminal or intermediate polyhydric groups. The polyhydric groups or the silioxane may be functionalized further with amine, alkyl and/or alkyleneoxide groups.
摘要翻译：本发明教导了多元有机硅氧烷及其用途，其优选作为农药助剂。多羟基有机硅氧烷具有具有侧基，末端或中间多羟基的硅氧烷主链。多羟基或硅氧烷可以进一步用胺，烷基和/或环氧烷基官能化。

44. 发明授权

US5861524A Oligomeric fluoroalkylsiloxanes as oil spreading agents 失效
标题翻译：低聚氟代烷基硅氧烷作为油扩散剂
公开(公告)号：US5861524A
公开(公告)日：1999-01-19
申请号：US844810
申请日：1997-04-22
申请人： Gerald J. Murphy , Seisaku Kumai , Jeffrey A. Cooke , Yutaka Furukawa , George A. Policello
发明人： Gerald J. Murphy , Seisaku Kumai , Jeffrey A. Cooke , Yutaka Furukawa , George A. Policello
IPC分类号： B01F17/54 , A01N25/02 , A01N25/30 , C07F7/08 , C07F7/12
CPC分类号： C07F7/085 , C07F7/0852 , Y10S424/08
摘要： Oligomeric fluoroalkylsiloxanes corresponding to the formula: ##STR1## wherein x is 0 to 3, y is 0, 1, or 2; z is 0 or 1; x+y>0, and R has the formula --C.sub.a H.sub.2a --O.sub.b --C.sub.d H.sub.2c --C.sub.d F.sub.2d+1 in which a is 2-4, b is 0 or 1, c is 0-8 and d is 4-12, and compositions thereof with an oil, are useful as spreading agents and in agricultural applications.
摘要翻译：对应于下式的低聚氟代烷基硅氧烷：其中x为0至3，y为0,1或2; z为0或1; x + y> 0，R具有式-CaH2a-Ob-CdH2c-CdF2d + 1，其中a为2-4，b为0或1，c为0-8且d为4-12，其组成为有油，可用作扩散剂和农业应用。

45. 发明申请

US20120067586A1 AQUEOUS FOAMING COMPOSITIONS WITH HIGH TOLERANCE TO HYDROCARBONS 有权
标题翻译：具有高耐油性的水性泡沫组合物
公开(公告)号：US20120067586A1
公开(公告)日：2012-03-22
申请号：US12883368
申请日：2010-09-16
申请人： Kalman KOCZO , Oleg Tselnik , Benjamin Falk , George A. Policello
发明人： Kalman KOCZO , Oleg Tselnik , Benjamin Falk , George A. Policello
IPC分类号： E21B43/00 , C09K8/035 , C09K8/588
CPC分类号： C09K8/703 , C09K8/38
摘要： A composition for providing a stable foam with high tolerance to hydrocarbons includes (a) an aqueous liquid; (b) at least one water soluble or dispersible silicon-containing polyether foamant contained within the aqueous liquid; and (c) a non-aqueous liquid. The aqueous liquid includes water and brine. The non-aqueous liquid includes liquid hydrocarbons.
摘要翻译：用于提供对烃具有高耐受性的稳定泡沫的组合物包括（a）水性液体; （b）水性液体中含有的至少一种水溶性或分散性含硅聚醚发泡剂; 和（c）非水性液体。含水液体包括水和盐水。非水性液体包括液体烃。

46. 发明授权

US07851581B2 Film forming composition with spreading properties 失效
标题翻译：具有扩散性能的成膜组合物
公开(公告)号：US07851581B2
公开(公告)日：2010-12-14
申请号：US11840304
申请日：2007-08-17
申请人： Anna M. Czech , Benjamin Falk , John Nicholson , George A. Policello , Jo Anne Tully
发明人： Anna M. Czech , Benjamin Falk , John Nicholson , George A. Policello , Jo Anne Tully
IPC分类号： C08G77/60
CPC分类号： A61K8/585 , A01N25/04 , A01N25/24 , A01N25/30 , A61K8/0241 , A61K8/25 , A61K8/463 , A61K8/466 , A61K8/894 , A61K2800/412 , A61K2800/624 , A61K2800/652 , A61Q5/06 , A61Q19/00 , C11D1/143 , C11D1/146 , C11D1/22 , C11D1/29 , C11D1/342 , C11D1/345 , C11D1/37 , C11D3/124 , C11D3/373 , C11D3/3738 , C11D17/0013 , C11D17/0039 , Y10T428/2995
摘要： A film forming composition with spreading properties derived from an aqueous emulsion comprising (I) colloidal silica core/silicone shell particles consisting of (a) 90 wt % to 10 wt % cores of colloidal silica and (b) 10 wt % to 90 wt % shells of polyorganosiloxane; (II) a polyalkyleneoxide modified trisiloxane; (III) an emulsifier package consisting of at least one anionic surfactant, and (IV) the salt of an acidic polymerization catalyst. The composition may include optional ingredients useful in Personal Care, Hair Care, Skin Care, Agricultural, and Home Care applications.
摘要翻译：一种具有源自水乳液的铺展性的成膜组合物，其包含（I）由（a）90重量％至10重量％的胶体二氧化硅芯和（b）10重量％至90重量％聚有机硅氧烷壳; （II）聚氧化亚烷基改性的三硅氧烷; （III）由至少一种阴离子表面活性剂和（IV）酸性聚合催化剂的盐组成的乳化剂包。组合物可以包括用于个人护理，护发，护肤，农业和家庭护理应用中的任选成分。

47. 发明授权

US06673359B2 Terminally modified, amino, polyether siloxanes 失效
标题翻译：末端改性的氨基，聚醚硅氧烷
公开(公告)号：US06673359B2
公开(公告)日：2004-01-06
申请号：US09808603
申请日：2001-03-14
申请人： George A. Policello
发明人： George A. Policello
IPC分类号： A01N2500
CPC分类号： C07F7/0838
摘要： The present invention teaches the composition of terminally modified, amino, polyether, siloxanes, known henceforth as amino siloxane alkokylates, and their use as adjuvants. The amino siloxane alkoxylates of the present invention enhance the efficacy of agrichemicals on plants as compared to conventional TSE's alone. The amino siloxane alkoxylates have at one end, an amine functionality and at the other end, a polyalkyleneoxide functionality.
摘要翻译：本发明教导了末端改性的氨基，聚醚，硅氧烷的组成，以下称为氨基硅氧烷烷基酯，以及它们作为佐剂的用途。与单独的常规TSE相比，本发明的氨基硅氧烷烷氧基化物增强了农药对植物的功效。氨基硅氧烷烷氧基化物在一端具有胺官能团，另一端具有聚亚烷基氧化物官能团。

48. 发明授权

US5658852A Alkylsiloxanes as adjuvants for agriculture 失效
标题翻译：烷基硅氧烷作为农业辅助剂
公开(公告)号：US5658852A
公开(公告)日：1997-08-19
申请号：US449452
申请日：1995-05-24
申请人： Gerald J. Murphy , George A. Policello
发明人： Gerald J. Murphy , George A. Policello
IPC分类号： A01M1/20 , A01N25/02 , A01N25/04 , A01N25/10 , A01N25/30 , A01N55/00 , A01N55/10 , A01N61/02 , C07F7/18 , A01N25/24
CPC分类号： A01N55/00 , A01N25/30 , A01N61/02
摘要： Linear alkylsilicone compounds of the formula ##STR1## wherein x=0 to 20, preferably 0 to 10, most preferably 0 to 1; y=1 to 10, preferably 1 to 5, most preferably 1; and R is an alkyl or alkyl ester group containing 6 to 16 carbons, or cyclic alkylsilicone compounds of the formula ##STR2## where m is 0 to 4, preferably 0 to 2, most preferably 0, and n is 1 to 5, preferably 3 to 5, most preferably 4, provided that m+n=3 to 5, are adjuvants for agricultural applications of oil-containing compositions. Especially preferred alkylsilicone compounds have a degree of polymerization of .ltoreq.6 and an alkyl content of .ltoreq.50% by weight. The compounds potentiate spreading of mineral or vegetable oils or oil-containing emulsions in dormant spray oils, crop oil concentrates, pesticides, and the like on difficult-to wet surfaces such as waxy leaf cuticles and arthropod exoskeletons.
摘要翻译：其中x = 0至20，优选0至10，最优选0至1的直链烷基硅氧烷化合物。 y = 1〜10，优选1〜5，最优选1; 和R为含有6至16个碳原子的烷基或烷基酯基，或式“IMAGE”的环烷基硅氧烷化合物，其中m为0至4，优选0至2，最优选0，n为1至5，优选3 至5，最优选4，条件是m + n = 3至5，是用于含油组合物的农业应用的佐剂。特别优选的烷基硅氧烷化合物的聚合度为＆lt; 6＆gt;烷基含量为<50重量％。这些化合物加强了在难以湿润的表面如蜡状叶片角质层和节肢动物外骨骼上的休眠喷雾油，作物油浓缩物，农药等中的矿物油或植物油或含油乳剂的铺展。

49. 发明授权

US5104647A Surfactant blend of organosilicone and polyalkylene oxide polymers useful as an agricultural adjuvant 失效
标题翻译：有机硅氧烷和可用作农业助剂的聚环氧烷聚合物的表面活性剂共混物
公开(公告)号：US5104647A
公开(公告)日：1992-04-14
申请号：US541958
申请日：1990-06-22
申请人： George A. Policello
发明人： George A. Policello
IPC分类号： A01N25/30 , C08L71/02 , C08L83/06 , C08L83/12
CPC分类号： C08L71/02 , A01N25/30 , C08L83/06 , C08L83/12
摘要： A surfactant mixture for use as a pesticide adjuvant comprising an organosilicone compound and a polyalkyleneoxide copolymer.
摘要翻译：用作农药助剂的表面活性剂混合物，其包含有机硅氧烷化合物和聚环氧烷共聚物。

50. 发明授权

US5045225A Self hydrophobing silicone/hydrocarbon antifoam compositions 失效
标题翻译：自疏疏硅酮/烃消泡剂组合物
公开(公告)号：US5045225A
公开(公告)日：1991-09-03
申请号：US455875
申请日：1989-12-18
申请人： Michael P. Aronson , Samuel O. Lin , George A. Policello
发明人： Michael P. Aronson , Samuel O. Lin , George A. Policello
IPC分类号： B01D19/04 , C11D3/00
CPC分类号： C11D3/0026 , B01D19/0409
摘要： An antifoam composition and laundry detergent formulation including it. The antifoam composition comprises a selected alkylaminosilicone, finely divided filler particles and a hydrocarbon carrier oil. Optional ingredients include oil/water surfactants and silicone oils. The alkylaminosilicone reduces the surface tension of the hydrocarbon oil and renders the formulation self-hydrophobing.
摘要翻译：包含它的消泡剂组合物和衣物洗涤剂制剂。消泡剂组合物包含选择的烷基氨基硅氧烷，细分散的填料颗粒和烃载体油。可选配成分包括油/水表面活性剂和硅油。烷基氨基硅氧烷降低烃油的表面张力并使配方自我疏水。

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