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41. 发明授权

US08835694B2 Process for transformation of lignocellulosic biomass or cellulose by catalysts based on tin oxide and/or antimony oxide and a metal that is selected from the groups 8 to 11 有权
标题翻译：通过基于氧化锡和/或氧化锑的催化剂和选自第8〜11组的金属转化木质纤维素生物质或纤维素的方法
公开(公告)号：US08835694B2
公开(公告)日：2014-09-16
申请号：US13995518
申请日：2011-12-16
申请人： Flora Chambon , Nadine Essayem , Franck Rataboul , Catherine Pinel , Amandine Cabiac , Emmanuelle Guillon
发明人： Flora Chambon , Nadine Essayem , Franck Rataboul , Catherine Pinel , Amandine Cabiac , Emmanuelle Guillon
IPC分类号： C07C45/60 , C07C29/14 , C07C29/132
CPC分类号： C07C45/60 , C07C29/132 , C07C31/20 , C07C49/17
摘要： The invention relates to a process for transformation of lignocellulosic biomass or cellulose using heterogeneous catalysts that are based on tin oxide and/or antimony oxide, dispersed on a substrate and containing at least one element in the particular metal state. The use of these catalysts makes it possible to obtain directly upgradable products, in particular hydroxyacetone and propylene glycol with high selectivity.
摘要翻译：本发明涉及一种使用基于氧化锡和/或氧化锑的非均相催化剂转化木质纤维素生物质或纤维素的方法，其分散在基材上并含有至少一种特定金属状态的元素。使用这些催化剂使得可以以高选择性获得直接可升级的产物，特别是羟基丙酮和丙二醇。

42. 发明授权

US08624058B2 Process for transformation of lignocellulosic biomass or cellulose by tungsten-based solid lewis acids 有权
标题翻译：通过钨基固体路易斯酸转化木质纤维素生物质或纤维素的方法
公开(公告)号：US08624058B2
公开(公告)日：2014-01-07
申请号：US13577988
申请日：2011-02-01
申请人： Flora Chambon , Nadine Essayem , Franck Rataboul , Catherine Pinel , Amandine Cabiac , Emmanuelle Guillon
发明人： Flora Chambon , Nadine Essayem , Franck Rataboul , Catherine Pinel , Amandine Cabiac , Emmanuelle Guillon
IPC分类号： C07C51/00 , C07C59/08
CPC分类号： C07C51/00 , C07C59/08
摘要： The invention relates to a process for transformation of lignocellulosic biomass or cellulose that uses tungsten-based heterogeneous catalysts that are dispersed on an oxide-based substrate, preferably with a base of oxide(s) of aluminum and/or zirconium and/or titanium and/or niobium. The use of these catalysts makes it possible to obtain directly lactic acid with high selectivity while limiting the production of oligosaccharides and soluble polymers.
摘要翻译：本发明涉及一种转化木质纤维素生物质或纤维素的方法，该方法使用分散在基于氧化物的基质，优选具有铝和/或锆和/或钛的氧化物的碱的钨基非均相催化剂和 /或铌。使用这些催化剂使得可以以高选择性直接获得乳酸，同时限制寡糖和可溶性聚合物的生产。

43. 发明授权

US08309781B2 Process for the production of light olefins from ethanol in the presence of a macroporous catalyst that comes in the form of balls 有权
标题翻译：在大球形催化剂存在下从乙醇生产轻质烯烃的方法
公开(公告)号：US08309781B2
公开(公告)日：2012-11-13
申请号：US12851861
申请日：2010-08-06
申请人： Vincent Coupard , Emmanuelle Guillon , Sylvie Maury , Nicolas Cadran
发明人： Vincent Coupard , Emmanuelle Guillon , Sylvie Maury , Nicolas Cadran
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , C07C2529/40 , Y02P30/42 , C07C11/02
摘要： A process for the production of C3-C6 light olefins from ethanol is described, and said process comprises at least the passage of a feedstock that contains ethanol into at least one reaction unit that is provided with at least one catalyst that comes in the form of spherical balls with a diameter of between 1 and 3 mm, each of said spherical balls comprising at least one zeolite and at least one alumina-based substrate and having a pore distribution such that the macropore volume that is measured by mercury porosimetry is between 0.10 and 0.20 ml/g and the mesopore volume that is measured by mercury porosimetry is between 0.25 and 0.35 ml/g.
摘要翻译：描述了从乙醇制备C3-C6轻质烯烃的方法，并且所述方法至少包含含有乙醇的原料通入至少一个反应单元，该反应单元中提供有至少一种催化剂，其形式为每个所述球形球包含至少一种沸石和至少一种氧化铝基底，并且具有孔分布，使得通过水银孔率法测量的大孔体积在0.10至 0.20ml / g，通过水银孔率法测定的中孔体积为0.25〜0.35ml / g。

44. 发明授权

US08183172B2 Dual zeolite catalyst comprising a group VIII metal and a group IIIA metal, and its use in isomerization of aromatic C8 compounds 有权
标题翻译：包含VIII族金属和IIIA族金属的双重沸石催化剂及其在芳族C8化合物的异构化中的用途
公开(公告)号：US08183172B2
公开(公告)日：2012-05-22
申请号：US12158534
申请日：2006-11-03
申请人： Emmanuelle Guillon , Eric Sanchez , Sylvie Lacombe
发明人： Emmanuelle Guillon , Eric Sanchez , Sylvie Lacombe
IPC分类号： B01J29/06 , C07C5/22
CPC分类号： B01J29/80 , B01J29/18 , B01J29/22 , B01J29/40 , B01J29/44 , B01J29/70 , B01J29/7007 , B01J29/74 , B01J29/7415 , B01J2229/186 , B01J2229/20 , B01J2229/37 , B01J2229/42 , C07C5/2708 , Y02P20/52 , C07C15/08
摘要： A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite selected from IM-5 zeolite and zeolites with structure type MFI, MOR, BEA and MTW, at least one group VIII metal, at least one group IIIA metal and at least one porous mineral matrix. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.
摘要翻译：描述了一种催化剂，其包含至少一种结构类型为EUO的沸石，至少一种选自IM-5沸石的沸石和结构型MFI，MOR，BEA和MTW的沸石，至少一种VIII族金属，至少一种IIIA族金属和至少一种多孔矿物基质。本发明的催化剂用于使包含每个分子含有8个碳原子的芳族化合物的进料异构化的方法。

45. 发明申请

US20110042270A1 CATALYST COMPRISING AT LEAST ONE PARTICULAR ZEOLITE AND AT LEAST ONE SILICA-ALUMINA, AND PROCESS FOR HYDROCRACKING HYDROCARBON FEEDS USING SAID CATALYST 审中-公开
标题翻译：至少包含一种特殊的沸石和至少一种二氧化硅的催化剂，以及使用合适的催化剂水解烃类进料的方法
公开(公告)号：US20110042270A1
公开(公告)日：2011-02-24
申请号：US12811636
申请日：2008-12-10
申请人： Emmanuelle Guillon , Christophe Bouchy , Johan Martens
发明人： Emmanuelle Guillon , Christophe Bouchy , Johan Martens
IPC分类号： B01J29/06 , C10G11/05
CPC分类号： B01J29/80 , B01J21/12 , B01J29/04 , B01J29/65 , B01J29/70 , B01J29/7042 , B01J29/7046 , B01J29/72 , B01J29/74 , B01J29/76 , B01J29/78 , B01J35/10 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C10G47/20
摘要： The invention describes a catalyst comprising at least one hydrodehydrogenating metal selected from the group formed by metals from group VIB and metals from group VIII and a support comprising at least one silica-alumina, and at least one COK-7 zeolite alone, or mixed with at least one ZBM-30 zeolite, as well as a process for hydrocracking hydrocarbon feeds employing said catalyst.
摘要翻译：本发明描述了一种催化剂，其包含至少一种选自组VIB的金属和来自VIII族的金属形成的氢化金属和包含至少一种二氧化硅 - 氧化铝的载体和至少一种单独的COK-7沸石或与至少一种ZBM-30沸石，以及使用所述催化剂加氢裂解烃进料的方法。

46. 发明授权

US07771703B2 IZM-1 crystalline solid and a process for its preparation 失效
标题翻译： IZM-1结晶固体及其制备方法
公开(公告)号：US07771703B2
公开(公告)日：2010-08-10
申请号：US12022585
申请日：2008-01-30
申请人： Emmanuelle Guillon , Johan Mariens , Nicolas Bais , Antoine Fecant
发明人： Emmanuelle Guillon , Johan Mariens , Nicolas Bais , Antoine Fecant
IPC分类号： C01B39/48 , C01B39/04
CPC分类号： C01B37/02 , B01J20/18 , B01J29/035 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C01B39/48
摘要： The invention concerns a crystalline solid designated IZM-1, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base in terms of moles of oxides by the formula XO2: aY2O3; bM2/nO where X represents at least one tetravalent element, Y represents at least one trivalent element and M is an alkali metal and/or an alkaline-earth metal with valency n, a and b respectively representing the number of moles of Y2O3 and M2/nO; a is in the range 0 to 0.02 and b is in the range 0 to 1.
摘要翻译：本发明涉及一种称为IZM-1的结晶固体，其具有以下给出的X射线衍射图。所述固体具有通过式XO 2：a Y 2 O 3以氧化物的摩尔数表示为无水碱的化学组成; bM2 / nO其中X表示至少一种四价元素，Y表示至少一种三价元素，M表示碱金属和/或碱土金属，其价数n，a和b分别表示Y2O3和M2的摩尔数 /没有; a在0至0.02的范围内，b在0至1的范围内。

47. 发明申请

US20090299115A1 DUAL ZEOLITE CATALYST COMPRISING A GROUP VIII METAL AND A GROUP IIIA METAL, AND ITS USE IN ISOMERIZATION OF AROMATIC C8 COMPOUNDS 有权
标题翻译：包含第VIII族金属和第IIIA族金属的双沸腾催化剂及其在芳族C8化合物的异构化中的用途
公开(公告)号：US20090299115A1
公开(公告)日：2009-12-03
申请号：US12158534
申请日：2006-11-03
申请人： Emmanuelle Guillon , Eric Sanchez , Sylvie Lacombe
发明人： Emmanuelle Guillon , Eric Sanchez , Sylvie Lacombe
IPC分类号： C07C5/22 , B01J29/064
CPC分类号： B01J29/80 , B01J29/18 , B01J29/22 , B01J29/40 , B01J29/44 , B01J29/70 , B01J29/7007 , B01J29/74 , B01J29/7415 , B01J2229/186 , B01J2229/20 , B01J2229/37 , B01J2229/42 , C07C5/2708 , Y02P20/52 , C07C15/08
摘要： A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite selected from IM-5 zeolite and zeolites with structure type MFI, MOR, BEA and MTW, at least one group VIII metal, at least one group IIIA metal and at least one porous mineral matrix. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.
摘要翻译：描述了一种催化剂，其包含至少一种结构类型为EUO的沸石，至少一种选自IM-5沸石的沸石和结构型MFI，MOR，BEA和MTW的沸石，至少一种VIII族金属，至少一种IIIA族金属和至少一种多孔矿物基质。本发明的催化剂用于使包含每个分子含有8个碳原子的芳族化合物的进料异构化的方法。

48. 发明申请

US20090093661A1 CATALYST COMPRISING AN EUO ZEOLITE, A 10 MR ZEOLITE AND A 12 MR ZEOLITE, AND ITS USE IN ISOMERIZING AROMATIC C8 COMPOUNDS 有权
标题翻译：包含EUO ZEOLITE，10 MR ZEOLITE和12 MR ZEOLITE的催化剂及其在异氰酸酯化合物中的应用
公开(公告)号：US20090093661A1
公开(公告)日：2009-04-09
申请号：US12158753
申请日：2006-12-01
申请人： Emmanuelle Guillon , Eric Sanchez , Sylvie Lacombe
发明人： Emmanuelle Guillon , Eric Sanchez , Sylvie Lacombe
IPC分类号： C07C5/22
CPC分类号： B01J29/80 , B01J29/084 , B01J29/126 , B01J29/18 , B01J29/22 , B01J29/40 , B01J29/44 , B01J29/70 , B01J29/7007 , B01J29/74 , B01J29/7415 , B01J2229/186 , B01J2229/20 , B01J2229/37 , B01J2229/42 , C07C5/2708 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2529/80 , C07C2529/88 , Y02P20/52 , C07C15/08
摘要： A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite having channels the opening to which is defined by a ring of 10 oxygen atoms (10 MR), at least one zeolite having channels the opening to which is defined by a ring of 12 oxygen atoms (12 MR) and at least one porous mineral matrix. Said catalyst optionally also contains at least one group VIII metal. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.
摘要翻译：描述了一种催化剂，其包含至少一种结构类型为EUO的沸石，至少一种沸石，其通道的开口由10个氧原子（10MR）的环，至少一个具有通道开口的沸石由12个氧原子（12 MR）的环和至少一个多孔矿物基质定义。所述催化剂任选地还含有至少一种VIII族金属。本发明的催化剂用于使包含每个分子含有8个碳原子的芳族化合物的进料异构化的方法。

49. 发明授权

US07449421B2 Catalyst and its use for improving the pour point of hydrocarbon charges 失效
标题翻译：催化剂及其用于改善碳氢化合物装料倾点的用途
公开(公告)号：US07449421B2
公开(公告)日：2008-11-11
申请号：US10807459
申请日：2004-03-24
申请人： Eric Benazzi , Emmanuelle Guillon , Johan Martens
发明人： Eric Benazzi , Emmanuelle Guillon , Johan Martens
IPC分类号： B01J29/06 , B01J21/00 , B01J29/00 , B01J21/16 , C10G73/02 , C10G45/00
CPC分类号： C10G45/64 , B01J29/70 , B01J29/74 , B01J29/78 , B01J29/80 , B01J2229/42 , C10G65/043
摘要： A catalyst comprising at least one zeolite (molecular sieve) chosen from the group formed by the TON structure type zeolites (Theta-1, ZSM-22, ISI-1, NU-10 and KZ-2) and at least one zeolite chosen from the group formed by the zeolites (ZSM-48, EU-2, EU-11 and ZBM-30), at least one porous mineral matrix, at least one hydro-dehydrogenating element, preferably chosen from the elements of Group VIB and Group VIII of the periodic table, is used for the conversion of hydrocarbons, in particular for the reduction of the pour point of charges containing long (more than 10 carbon atoms) linear and/or slightly branched paraffins, in particular in order to convert, with a good yield, charges having high pour points to at least one cut having a low pour point and a high viscosity index for oil bases.
摘要翻译：包含选自由TON结构型沸石（Theta-1，ZSM-22，ISI-1，NU-10和KZ-2）形成的基团的至少一种沸石（分子筛）和至少一种选自由沸石（ZSM-48，EU-2，EU-11和ZBM-30）形成的基团，至少一种多孔矿物基质，至少一种加氢脱氢元素，优选选自VIB族和VIII族的元素的特别是用于降低含有长（大于10个碳原子）的线性和/或稍微支化的链烷烃的电荷的倾点，特别是为了转化，用良好的产率，具有高倾点的装料至少具有低倾点和油基高粘度指数的切割。

50. 发明申请

US20080275281A1 Process for Isomerizing an Aromatic C8 cut in the presence of a catalyst based on a Dealuminated Euo Zeolite 有权
标题翻译：在基于脱铝EuO沸石的催化剂存在下异构化芳族C8馏分的方法
公开(公告)号：US20080275281A1
公开(公告)日：2008-11-06
申请号：US12081870
申请日：2008-04-22
申请人： Emmanuelle Guillon , Eric Sanchez
发明人： Emmanuelle Guillon , Eric Sanchez
IPC分类号： C07C5/22
CPC分类号： B01J29/7246 , B01J29/7446 , B01J37/0009 , B01J2229/16 , B01J2229/20 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C5/2775 , C07C2529/70 , Y02P20/52 , C07C15/08
摘要： A process is described for isomerising an aromatic cut containing at least one aromatic compound containing eight carbon atoms per molecule, comprising bringing said cut into contact with a catalyst containing a zeolite with structure type EUO, said catalyst having been prepared using a process comprising at least the following steps: i) synthesizing at least one zeolite with structure type EUO having an overall Si/Al atomic ratio in the range 5 to 45; ii) dealuminating the zeolite obtained at the end of said step i) using at least one treatment with an aqueous solution of a mineral acid or an organic acid, such that at least 10% by weight of the aluminium atoms are extracted from said zeolite from said step i); iii) forming said dealuminated zeolite with a matrix; iv) depositing at least one metal from group VIII of the periodic table of the elements, the order of carrying out said steps iii) and iv) being inconsequential following on from said step ii).
摘要翻译：描述了一种方法，用于异构化含有至少一种每分子含有8个碳原子的芳族化合物的芳族切割，包括使所述切割物与含有结构类型为EUO的沸石的催化剂接触，所述催化剂已经使用至少包括以下步骤：i）合成至少一种具有总体Si / Al原子比在5至45范围内的结构类型EUO的沸石; ii）使所述步骤i）末端获得的沸石脱铝，使用无机酸或有机酸的水溶液进行至少一次处理，使得至少10重量％的铝原子从所述沸石中提取出来说步骤i）; iii）用基质形成所述脱铝沸石; iv）从所述元件的周期表的VIII族中沉积至少一种金属，执行所述步骤iii）和iv）的顺序在所述步骤ii）之后是无关紧要的。

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