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41. 发明授权

US5077426A Preparation of alpha-formylamino nitriles 失效
标题翻译：阿尔法 - 甲酰胺硝酸盐的制备
公开(公告)号：US5077426A
公开(公告)日：1991-12-31
申请号：US627022
申请日：1990-12-13
申请人： Rolf Fikentscher , Michael Kroener
发明人： Rolf Fikentscher , Michael Kroener
IPC分类号： C07C253/30 , C07C255/29 , C07C255/60
CPC分类号： C07C255/29
摘要： A process for preparing .alpha.-formylamino nitriles of the formula Ia ##STR1## and Ib ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and each is hydrogen or unsubstituted or substituted, with substituents which are inert under the reaction conditions, aliphatic or heteroaliphatic radicals with 1 to 10, cycloaliphatic or heterocycloaliphatic radicals with 3 to 6, araliphatic radicals with 7 to 12, heteroaraliphatic radicals with 4 to 12, aromatic radicals with 6 to 10 or heteroarometic radicals with 3 to 10 carbon atoms, with the priviso that at least one of R.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 is hydrogen, comprises reacting an iminodiacetonitrile of the formula II ##STR3## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the abovementioned meanings, with formamide of the formula III ##STR4## in the presence of formic acid or with a compound which provides formic acid, in the presence of acids.
摘要翻译：制备式Ia Ia和Ib Ib的α-甲酰氨基腈的方法，其中R 1，R 2，R 3和R 4相同或不同，各自为氢或未取代或取代的取代基，反应条件，具有1-10个脂环族或杂脂肪族基团的脂族或杂脂族基团，具有3至6个，具有7至12个芳脂族基团，具有4至12个杂脂肪族基团，6至10个芳族基团或具有3至10个碳原子的杂芳族基团其中R 1和R 2或R 3和R 4中的至少一个是氢，包括使式II II的亚氨基二乙腈与式III的甲酰胺反应，其中R 1，R 2，R 3和R 4具有上述含义在甲酸存在下或在酸存在下与提供甲酸的化合物反应。

42. 发明授权

US4880497A Preparation of water-soluble copolymers containing vinylamine units, and their use as wet strength agents and dry strength agents for paper 失效
标题翻译：含有乙烯胺单元的水溶性共聚物的制备及其作为湿强度剂和用于纸的干强度剂的用途
公开(公告)号：US4880497A
公开(公告)日：1989-11-14
申请号：US187929
申请日：1988-04-29
申请人： Sigberg Pfohl , Michael Kroener , Heinrich Hartmann , Walter Denzinger
发明人： Sigberg Pfohl , Michael Kroener , Heinrich Hartmann , Walter Denzinger
IPC分类号： C08F8/12 , C08F16/16 , C08F18/02 , C08F20/52 , C08F26/00 , C08F26/06 , C08F216/16 , C08F216/18 , C08F218/02 , C08F218/04 , C08F218/08 , C08F218/10 , C08F220/00 , C08F220/02 , C08F220/10 , C08F220/18 , C08F220/42 , C08F220/56 , C08F226/02 , C08F226/10 , D21H17/34 , D21H17/36 , D21H17/37 , D21H17/45 , D21H21/18
CPC分类号： D21H17/45 , C08F226/02 , C08F8/44 , D21H17/34 , D21H17/36 , D21H17/37 , C08F2810/50 , D21H21/18
摘要： Water-soluble copolymers containing copolymerized vinylamine units are prepared by copolymerizing (a) from 95 to 10 mol % of N-vinylformamide and (b) from 5 to 90 mol % of an ethylenically unsaturated monomer from the group consisting of vinyl acetate, vinyl propionate, C.sub.1 -C.sub.4 -alkyl vinyl ethers, the esters, nitriles and amides of acrylic acid and methacrylic acid and N-vinylpyrrolidone, and then eliminating from 30 to 100 mol % of the formyl groups from the copolymer. Preferred copolymers are copolymers of N-vinylformamide and vinyl acetate, in which from 30 to 100 mol % of the monomer units are hydrolyzed. The copolymers are used in papermaking to increase the dry strength and wet strength of the paper.
摘要翻译：含有共聚乙烯基胺单元的水溶性共聚物通过（a）95〜10摩尔％的N-乙烯基甲酰胺和（b）5〜90摩尔％的乙烯基乙酸酯，丙酸乙烯酯，，C1-C4烷基乙烯基醚，丙烯酸和甲基丙烯酸和N-乙烯基吡咯烷酮的酯，腈和酰胺，然后从共聚物中除去30-100mol％的甲酰基。优选的共聚物是N-乙烯基甲酰胺和乙酸乙烯酯的共聚物，其中30-100mol％的单体单元被水解。该共聚物用于造纸，以提高纸张的干强度和湿强度。

43. 发明授权

US4814505A Purification of n-vinylformamide 失效
标题翻译：正乙烯基甲酰胺的纯化
公开(公告)号：US4814505A
公开(公告)日：1989-03-21
申请号：US008171
申请日：1987-01-29
申请人： Michael Kroener , Willi Schmidt , Alfred Oftring , Theo Proll , Heinrich Hartmann
发明人： Michael Kroener , Willi Schmidt , Alfred Oftring , Theo Proll , Heinrich Hartmann
IPC分类号： C07C231/24 , C07C67/00 , C07C231/00 , C07C233/00 , C07C233/03 , C08F26/00 , C08F126/02 , C07C102/00 , C07C103/34 , C07C103/365
CPC分类号： C07C233/00
摘要： N-Vinylformamide is purified by fractional distillation in the presence of formamide in a column under from 0.5 to 30 mbar by a method in which the distillation is controlled so that N-vinylformamide containing from 0.1 to 15% by weight of formamide is obtained as the distillate. Homopolymers having particularly high molecular weights can be prepared from the N-vinylformamide purified in this manner.
摘要翻译： N-乙烯基甲酰胺通过在甲酰胺存在下，在0.5至30毫巴的柱中通过分馏进行纯化，其中控制蒸馏的方法使得得到含有0.1-15％（重量）甲酰胺的N-乙烯基甲酰胺作为馏出物具有特别高分子量的均聚物可以由以这种方式纯化的N-乙烯基甲酰胺制备。

44. 发明授权

US4774285A Preparation of water-soluble copolymers containing vinylamine units, and their use as wet strength agents and dry strength agents for paper 失效
标题翻译：含有乙烯胺单元的水溶性共聚物的制备及其作为湿强度剂和用于纸的干强度剂的用途
公开(公告)号：US4774285A
公开(公告)日：1988-09-27
申请号：US907222
申请日：1986-09-15
申请人： Sigberg Pfohl , Michael Kroener , Heinrich Hartmann , Walter Denzinger
发明人： Sigberg Pfohl , Michael Kroener , Heinrich Hartmann , Walter Denzinger
IPC分类号： C08F8/12 , C08F16/16 , C08F18/02 , C08F20/52 , C08F26/00 , C08F26/06 , C08F216/16 , C08F216/18 , C08F218/02 , C08F218/04 , C08F218/08 , C08F218/10 , C08F220/00 , C08F220/02 , C08F220/10 , C08F220/18 , C08F220/42 , C08F220/56 , C08F226/02 , C08F226/10 , D21H17/34 , D21H17/36 , D21H17/37 , D21H17/45 , D21H21/18
CPC分类号： D21H17/45 , C08F226/02 , C08F8/44 , D21H17/34 , D21H17/36 , D21H17/37 , C08F2810/50 , D21H21/18
摘要： Water-soluble copolymers containing copolymerized vinylamine units are prepared by copolymerizing (a) from 95 to 10 mol % of N-vinylformamide and (b) from 5 to 90 mol % of an ethylenically unsaturated monomer from the group consisting of vinyl acetate, vinyl propionate, C.sub.1 -C.sub.4 -alkyl vinyl ethers, the esters, nitriles and amides of acrylic acid and methacrylic acid and N-vinylpyrrolidone, and then eliminating from 30 to 100 mol % of the formyl groups from the copolymer. Preferred copolymers are copolymers of N-vinylformamide and vinyl acetate, in which from 30 to 100 mol % of the monomer units are hydrolyzed. The copolymers are used in papermaking to increase the dry strength and wet strength of the paper.
摘要翻译：含有共聚乙烯基胺单元的水溶性共聚物通过（a）95〜10摩尔％的N-乙烯基甲酰胺和（b）5〜90摩尔％的乙烯基乙酸酯，丙酸乙烯酯，，C1-C4烷基乙烯基醚，丙烯酸和甲基丙烯酸和N-乙烯基吡咯烷酮的酯，腈和酰胺，然后从共聚物中除去30-100mol％的甲酰基。优选的共聚物是N-乙烯基甲酰胺和乙酸乙烯酯的共聚物，其中30-100mol％的单体单元被水解。该共聚物用于造纸，以提高纸张的干强度和湿强度。

45. 发明授权

US4543215A .alpha.-iminodiacetonitriles and their preparation 失效
标题翻译： α-亚氨基二乙腈及其制备方法
公开(公告)号：US4543215A
公开(公告)日：1985-09-24
申请号：US547851
申请日：1983-11-02
申请人： Fritz Brunnmueller , Michael Kroener
发明人： Fritz Brunnmueller , Michael Kroener
IPC分类号： C07C255/24 , C07C255/26 , C07C121/42 , C07C121/78
CPC分类号： C07C255/00
摘要： Novel .alpha.-iminodiacetonitriles are prepared by a process in which an aldehyde-cyanohydrin or a haloacetonitrile is reacted with an aminonitrile, the reaction being carried out in the presence of a lower alkanol in the case of the preparation of symmetric .alpha.-iminodiacetonitriles, and in the presence of an auxiliary base in the case of the preparation employing a haloacetonitrile. The .alpha.-iminodiacetonitriles obtainable by the process of the invention are useful starting materials for the preparation of dyes, fungicides, bactericides, herbicides, textile assistants, anticorrosion agents, complex-forming agents, stabilizers in electroplating baths and inhibitors for antifreezes.
摘要翻译：通过将醛 - 羟腈或卤代乙腈与氨基腈反应的方法制备新的α-亚氨基二乙腈，该反应在制备对称的α-亚氨基二乙腈的情况下在低级烷醇的存在下进行，并且在在使用卤代乙腈的制备的情况下存在辅助碱。通过本发明方法可获得的α-亚麻子二腈是用于制备染料，杀真菌剂，杀菌剂，除草剂，纺织助剂，防腐剂，络合物形成剂，电镀浴中的稳定剂和防冻剂抑制剂的起始材料。

46. 发明授权

US08407275B2 Fast floating point compare with slower backup for corner cases 有权
标题翻译：快速浮点与较慢的备份角落比较
公开(公告)号：US08407275B2
公开(公告)日：2013-03-26
申请号：US12255968
申请日：2008-10-22
申请人： Maarten J. Boersma , Michael Kroener , Silvia M. Mueller , Jochen Preiss
发明人： Maarten J. Boersma , Michael Kroener , Silvia M. Mueller , Jochen Preiss
IPC分类号： G06F7/02
CPC分类号： G06F9/30021 , G06F9/30025
摘要： A floating point processor unit executes a floating point compare instruction with two operands of the same or different precision by comparing the two operands in integer format, which speeds up the execution of the floating point compare instruction significantly. The floating point processor now executes the floating point compare instruction at least twice as fast or faster (e.g., two clock cycles instead of five clock cycles in the prior art) for nearly most operand cases (e.g., 99% of all cases). Only the rare corner cases require additional operations on one of the operands and thus require additional cycles of execution time because the integer compare operation will not work for these corner cases. This is due to the fact that one operand is a single precision subnormal number in an unnormalized representation (i.e., has two representations) and the other operand is in the SP subnormal range such that the integer compare operation will fail.
摘要翻译：浮点处理器单元通过比较整数格式的两个操作数来执行具有相同或不同精度的两个操作数的浮点比较指令，这显着地加快了浮点比较指令的执行。浮点处理器现在对于几乎大多数操作数情况（例如，所有情况的99％），至少执行两倍快或更快（例如，现有技术中的两个时钟周期而不是五个时钟周期）的浮点比较指令。只有罕见的角落情况需要在其中一个操作数上进行额外的操作，因此需要额外的执行周期，因为整数比较操作将不适用于这些角色。这是由于一个操作数是非正规化表示中的单精度子正规数（即，具有两个表示），另一个操作数处于SP子正常范围，使得整数比较操作将失败。

47. 发明授权

US08278238B2 Triplet emitter having condensed five-membered rings 失效
标题翻译：具有稠合五元环的三重发射体
公开(公告)号：US08278238B2
公开(公告)日：2012-10-02
申请号：US12066144
申请日：2006-09-07
申请人： Hans-Hermann Johannes , Wolfgang Kowalsky , Sven Ammermann , Michael Kroener , Ute Jana Weinaug
发明人： Hans-Hermann Johannes , Wolfgang Kowalsky , Sven Ammermann , Michael Kroener , Ute Jana Weinaug
IPC分类号： B01J31/00 , H01L31/00
CPC分类号： C07F15/0033 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/104 , C09K2211/1044 , C09K2211/1051 , C09K2211/1059 , C09K2211/185 , H05B33/14 , Y10T428/31678
摘要： The present invention relates to light emitting compounds, especially to triplett emitters suitable for electrooptical applications. Compounds according to the invention are organometallic complexes of a metal, preferably Ir, having a backbone of one five-membered ring that is linked to a five- or six-membered ring, by an intermediate six-membered ring. These compounds are suitable for adaptation to the emission of light in the UV to NIR range by adaptation of atoms or groups within at least one of the five-membered or six-membered ring structures.
摘要翻译：本发明涉及发光化合物，特别涉及适用于电光应用的三重发射体。根据本发明的化合物是具有通过中间六元环连接至五元或六元环的五元环的主链的金属，优选Ir的有机金属络合物。这些化合物适用于通过适应五元或六元环结构中的至少一个中的原子或基团来适应UV到NIR范围内的光的发射。

48. 发明授权

US5554718A Catonic urea/formaldehyde resins, their preparation and their use in the paper industry 失效
标题翻译：阳离子脲/甲醛树脂，其制备及其在造纸工业中的应用。
公开(公告)号：US5554718A
公开(公告)日：1996-09-10
申请号：US775928
申请日：1991-11-06
申请人： Klaus Flory , Andreas Stange , Michael Kroener , Norbert Sendhoff
发明人： Klaus Flory , Andreas Stange , Michael Kroener , Norbert Sendhoff
IPC分类号： C08G12/12 , C08G12/46 , D21H17/49 , D21H17/50 , C08G2/26 , C08G14/02
CPC分类号： C08G12/46 , Y10T428/31949 , Y10T428/31964
摘要： Cationic urea/formaldehyde resins are obtainable by condensing urea and formaldehyde in a molar ratio of from 1:1.5 to 1:3 in the presence of polymers which contain not less than 1 mol % of polymerized vinylamine units and have Fikentscher K values of from 5 to 300, in an amount of from 5 to 50 g per mole of urea in the end product, where the mixture is first a) precondensed at a pH of from 8 to 14, then acidified and b) condensed at a pH of from 1 to 5 until gel formation begins, c) then from 0.3 to 1.5 moles of formaldehyde are added per mole of urea used, d) post-condensation is carried out and e) the resin solution is subsequently neutralized. The resins thus obtained are used in papermaking as assistants for increasing the dry and wet strength of paper and result in less dulling of the whiteness of the paper.
摘要翻译： PCT No.PCT / EP90 / 01399 Sec。 371日期1991年11月6日 102（e）1991年11月6日，PCT提交1990年8月22日PCT公布。出版物WO91 / 02762 日期1991年3月7日阳离子脲/甲醛树脂可通过在含有不少于1摩尔％的聚合乙烯胺单元的聚合物存在下将脲和甲醛以1:1.5至1:3的摩尔比缩合而得到，并具有Fikentscher K值为5至300，最终产物中每摩尔尿素为5至50g，其中混合物首先a）在8至14的pH下预缩合，然后酸化并b）在 pH为1至5，直到凝胶形成开始，c）然后每摩尔使用的尿素加入0.3至1.5摩尔的甲醛，d）进行后冷凝，e）随后中和树脂溶液。由此获得的树脂用于造纸中作为助剂以增加纸张的干湿强度，并且导致纸的白度较少的钝化。

49. 发明授权

US5126395A Preparation of stable water-in-oil emulsions of hydrolyzed polymers of N-vinylamides 失效
标题翻译： N-乙烯基胺水解性聚合物稳定的水溶性乳液的制备
公开(公告)号：US5126395A
公开(公告)日：1992-06-30
申请号：US662622
申请日：1990-02-28
申请人： Lutz End , Walter Denzinger , Michael Kroener , Norbert Sendhoff , Enrique Freudenberg , Friedrich Linhart , Rolf Fikentscher , Heinrich Hartmann
发明人： Lutz End , Walter Denzinger , Michael Kroener , Norbert Sendhoff , Enrique Freudenberg , Friedrich Linhart , Rolf Fikentscher , Heinrich Hartmann
IPC分类号： C08F2/32 , C08F2/44 , C08F4/28 , C08F4/34 , C08F8/12 , C08F26/00 , C08F26/02 , C08K3/30 , C08K5/21 , D21H17/34 , D21H21/10
CPC分类号： D21H21/10 , C08F26/02 , C08F8/44 , C08K3/30 , C08K5/21 , D21H17/34
摘要： Stable water-in-oil emulsions of a hydrolyzed polymer of an N-vinylamide of the formula ##STR1## where R and R.sup.1 are each H or C.sub.1 -C.sub.6 -alkyl, are prepared by polymerizing a compound of the formula I, alone or as a mixture with other monoethylenically unsaturated monomers, in the form of a water-in-oil emulsion to give a water-in-oil polymer emulsion, and then hydrolyzing the polymer, hydrolysis of the polymer in the form of the water-in-oil polymer emulsion being carried out in the presence of an acid or base, and additives in the form of antioxidants, reducing agents or aldehyde acceptors being added for stabilization.
摘要翻译：式（Ⅰ）的N-乙烯基酰胺的水解聚合物的稳定的油包水乳液，其中R和R 1各自为H或C 1 -C 6 - 烷基，是通过将式I化合物，单独或作为与其它单烯键式不饱和单体的混合物，以油包水乳液的形式提供油包水聚合物乳液，然后水解聚合物，水解形式的聚合物，在酸或碱的存在下进行油包水聚合物乳液，以及为了稳定而加入抗氧化剂，还原剂或醛受体形式的添加剂。

50. 发明授权

US4978427A Water-soluble copolymers containing vinylamine units as wet strength and dry strength agent for paper 失效
标题翻译：含有乙烯胺单元作为湿强度的水溶性共聚物和用于纸的干强度剂
公开(公告)号：US4978427A
公开(公告)日：1990-12-18
申请号：US402564
申请日：1989-09-05
申请人： Sigberg Pfohl , Michael Kroener , Heinrich Hartmann , Walter Denzinger
发明人： Sigberg Pfohl , Michael Kroener , Heinrich Hartmann , Walter Denzinger
IPC分类号： C08F8/12 , C08F16/16 , C08F18/02 , C08F20/52 , C08F26/00 , C08F26/06 , C08F216/16 , C08F216/18 , C08F218/02 , C08F218/04 , C08F218/08 , C08F218/10 , C08F220/00 , C08F220/02 , C08F220/10 , C08F220/18 , C08F220/42 , C08F220/56 , C08F226/02 , C08F226/10 , D21H17/34 , D21H17/36 , D21H17/37 , D21H17/45 , D21H21/18
CPC分类号： D21H17/45 , C08F226/02 , C08F8/44 , D21H17/34 , D21H17/36 , D21H17/37 , C08F2810/50 , D21H21/18
摘要： Water-soluble copolymers containing copolymerized vinylamine units are prepared by copolymerizing (a) from 95 to 10 mol % of N-vinylformamide and (b) from 5 to 90 mol % of an ethylenically unsaturated monomer from the group consisting of vinyl acetate, vinyl propionate, C.sub.1 -C.sub.4 -alkyl vinyl ethers, the esters, nitriles and amines of acrylic acid and methacrylic acid and N-vinylpyrrolidone, and then eliminating from 30 to 100 mol % of the formyl groups from the copolymer. Preferred copolymers are copolymers of N-vinyl-formamide and vinyl acetate, in which from 30 to 100 mol % of the monomer units are hydrolyzed. The copolymers are used in papermaking to increase the dry strength and wet strength of the paper.

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