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41. 发明申请

US20050054532A1 Combination of crop protection agents with hydrogen bond-forming polymers 审中-公开
标题翻译：作物保护剂与氢键形成聚合物的组合
公开(公告)号：US20050054532A1
公开(公告)日：2005-03-10
申请号：US10942235
申请日：2004-09-16
申请人： Jean Kocur , Gerhard Frisch , Jochen Wurtz , Udo Bickers , Erwin Hacker , Hans Huff , Gerhard Schnabel
发明人： Jean Kocur , Gerhard Frisch , Jochen Wurtz , Udo Bickers , Erwin Hacker , Hans Huff , Gerhard Schnabel
IPC分类号： A01N25/10 , A01N47/36
CPC分类号： A01N25/10 , A01N47/36 , A01N2300/00
摘要： The present invention describes the combination of an agrochemically active compound with a polymer with formation of hydrogen bonds for the controlled release of this active compound. Both the polymer and active compound have functional groups which permit the formation of hydrogen bonds.
摘要翻译：本发明描述了农药化学活性化合物与形成氢键的聚合物的组合以控制该活性化合物的释放。聚合物和活性化合物都具有允许形成氢键的官能团。

42. 发明申请

US20050033047A1 Processes for preparing aminophenylsulfonylureas, and intermediates therefor 失效
标题翻译：制备氨基苯磺酰脲的方法及其中间体
公开(公告)号：US20050033047A1
公开(公告)日：2005-02-10
申请号：US10936180
申请日：2004-09-08
申请人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
发明人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
IPC分类号： C07D251/16 , A01N47/36 , A01P13/00 , A01P21/00 , C07C309/89 , C07C311/39 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/52 , C07D251/42 , C07D251/44 , C07D251/46 , C07D521/00 , F21S4/00 , F21V31/00 , H01R33/06 , A01N43/54 , A01N43/90 , C07D239/02
CPC分类号： C07D521/00 , A01N47/36 , H01R33/06 , Y02A40/143
摘要： The invention relates to the preparation of compounds (I) in which A=H or acyl and R1, R2, R3, R, n, X, Y and Z are as defined in claim 1 by halogenation and rearrangement of compounds (II) (optionally salt) to give compounds (III) R*═OH, R**═NR1R2 (II) R*═NR1R2, R**═Cl (III) R*═NR1R2, R**═NH2 (IV) a) ammonolysis of (III) to (IV), reduction of the nitro group and reaction with carbamate (salts) (VI) of the formula Ar—OCO—N(M)-Het, where Ar=phenyl, M=H or cation and Het=heterocycle from formula (I), to give compounds (I) (A=H), or b) ammonolysis of (III) to (IV), reaction with carbamate (salt) (VI) and reduction of resulting compounds (VII) at the NO2 group to give compounds (I) (A=H), or c) reaction of (III) with cyanates and amines (V) of the formula HNR3−Het and reduction of the resulting compound (VII) at the NO2 group to give compounds (I) (A=H) and optional acylation if A is to be other than H. Compounds of the formulae (I) (A=H), (III), (IV), (V), (VI) (M=cation) and (VII) are novel.
摘要翻译：本发明涉及其中A = H或酰基和R 1，R 2，R 3，R 3，n，X，Y和Z如权利要求1中所定义的化合物（I）的制备，化合物（II）（任选盐）的卤化和重排，得到化合物（III）R * = OH，R ** = NR 1 R 2（II）R * = NR 1 R 2， R ** = Cl（III）R * = NR 1 R 2，R ** = NH 2（IV）a）（III）至（IV）的氨解，硝基还原和与氨基甲酸酯反应其中Ar =苯基，M = H或阳离子和Het =来自式（I）的杂环的式Ar-OCO-N（M）-Het的化合物（I）（A = H），或b）（III）至（IV）的氨解，与氨基甲酸酯（盐）（VI）的反应和所得化合物（VII）在NO 2基团上的还原，得到化合物（I）（A = H），或c）（III）与式HNR <3-> Het的氰酸酯和胺（V）的反应，并且在NO 2基团上还原所得化合物（VII），得到化合物（I）（A = H），任选的酰化如果A 式（I）（A = H），（III），（IV），（V），（VI）（M = on）和（VII）是新颖的。

43. 发明授权

US06693063B2 Herbicidal composition 失效
标题翻译：除草成分
公开(公告)号：US06693063B2
公开(公告)日：2004-02-17
申请号：US10023323
申请日：2001-12-18
申请人： Gerhard Schnabel , Jean Kocur , Hans-Peter Krause , Julio Martinez de Una , Hans Philipp Huff , Udo Bickers
发明人： Gerhard Schnabel , Jean Kocur , Hans-Peter Krause , Julio Martinez de Una , Hans Philipp Huff , Udo Bickers
IPC分类号： A01N2528
CPC分类号： A01N37/40 , A01N25/30 , A01N2300/00
摘要： The present invention relates to a herbicidal composition, comprising A) one or more compounds of the formula (I) in which Hal1 and Hal2 are identical or different halogen atoms, R1 is H, a cation or a C1-C20-carbon-containing radical and B) one or more surfactants, comprising as structural element at least 12 alkylene oxide units.
摘要翻译：本发明涉及除草组合物，其包含A）一种或多种式（I）化合物，其中H 1和Hal 2是相同或不同的卤素原子，R 1是H，阳离子或C 1 -C 20 - 碳的基团和B）一种或多种表面活性剂，其包含至少12个环氧烷单元作为结构元素。

44. 发明授权

US5936085A Process for the preparation of herbicidal sulfonylureas and of N-(pyrimidinyl or triazinyl)-carbamates as intermediate products 失效
标题翻译：用于制备除草磺酰脲和N-（嘧啶基或三嗪基） - 氨基甲酸酯作为中间产物的方法
公开(公告)号：US5936085A
公开(公告)日：1999-08-10
申请号：US678127
申请日：1996-07-11
申请人： Gerhard Schnabel , Harald Knorr , Klemens Minn , Jan Vermehren
发明人： Gerhard Schnabel , Harald Knorr , Klemens Minn , Jan Vermehren
IPC分类号： C07D239/42 , A01N47/36 , A01P13/00 , C07D239/46 , C07D239/47 , C07D251/16 , C07D251/42 , C07D521/00 , C07D251/46 , C07D239/69 , C07D401/12 , C07D403/12
CPC分类号： C07D521/00 , A01N47/36 , C07D251/16
摘要： Disclosed and claimed is a process for the preparation of a carbamate (IV)Ar--O--CO--NR--B (IV)by reaction of a saltM.sup..sym. .crclbar.NR--B (II-S)with a diaryl carbonate(ArO).sub.2 CO (III).The carbamate can be reacted, without any necessity of intermediate isolation, with a sulfonamide A--SO.sub.2 NH.sub.2 (V) to give a sulfonylurea (I) or salts thereofA--SO.sub.2 --NH--CO--NR--B (I).And thus, disclosed and claimed too is a process for the preparation of sulfonylurea (I) by (i) contacting a salt (II-S) with a diaryl carbonate (III) to form a carbamate (IV), and (ii) contacting carbamate (IV) from step (i) with or without intermediate isolation, with a sulfonamide (V). These processes avoid the use of alkali metal hydrides as a base. And, these processes can additionally include the preparation of salt (II-S) from a compound H--NR--B (II) and base M.sup..sym. Base.sup..crclbar..
摘要翻译：公开并要求保护的是通过盐M（+）（ - ）NR-B（II-S）与碳酸二芳酯反应制备氨基甲酸酯（Ⅳ）Ar-O-CO-NR-B（Ⅳ）的方法（ArO）2 CO（III）。氨基甲酸酯可以与磺酰胺A-SO 2 NH 2（V）反应而不需要中间分离，得到磺酰脲（I）或其盐.A-SO 2 -NH-CO-NR-B （I）。因此，也公开和要求的是通过（i）使盐（II-S）与碳酸二芳酯（III）接触以形成氨基甲酸酯（IV）来制备磺酰脲（I）的方法，以及（ⅱ）与或不与中间分离的氨磺酸（Ⅳ）与磺酰胺（Ⅴ）接触。这些方法避免使用碱金属氢化物作为碱。而且，这些方法还可以包括从化合物H-NR-B（II）和碱M（+）碱（ - ）制备盐（II-S）。

45. 发明授权

US5747421A Formylaminophenylsulfonylureas, preparation processes and use as herbicides and plant growth regulators 失效
标题翻译：甲酰氨基苯基磺酰脲，制备方法和用作除草剂和植物生长调节剂
公开(公告)号：US5747421A
公开(公告)日：1998-05-05
申请号：US453978
申请日：1995-05-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D251/16 , A01N47/36 , C07D239/42 , C07D251/46 , C07D251/50 , C07D405/12 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36
摘要： Formylaminophenylsulfonylureas; processes for their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) ##STR1## in which R.sup.1 is H, a substituted or unsubstituted hydrocarbon radical or an unsubstituted or substituted heterocyclic radical, R.sup.2 is H, (C.sub.1 -C.sub.6)-alkyl or (C.sub.1 -C.sub.6)-alkoxy, R.sup.3 is halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy, (C.sub.1 -C.sub.6)-haloalkyl, (C.sub.1 -C.sub.6)-haloalkoxy, NO.sub.2, CN, NH.sub.2, (C.sub.1 -C.sub.4) -mono- or dialkylamino, each independently of other radicals R.sup.3 if n is 2 or 3, n is 0, 1, 2 or 3, W is an oxygen atom or a sulfur atom, X and Y independently of one another are halogen, (C.sub.1 -C.sub.6)-alkyl, (C.sub.1 -C.sub.6)-alkoxy or (C.sub.1 -C.sub.6)-alkylthio, each of the three last-mentioned radicals being unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C.sub.1 -C.sub.4)-alkoxy and (C.sub.1 -C.sub.4)-alkylthio, or are (C.sub.3 -C.sub.6)-cycloalkyl, (C.sub.2 -C.sub.6)-alkenyl, (C.sub.2 -C.sub.6)-alkynyl, (C.sub.2 -C.sub.6)-alkenyloxy, (C.sub.2 -C.sub.6)-alkynyloxy, mono- or di�(C.sub.1 -C.sub.4 -alkyl)!amino, and Z is CH or N, are suitable as herbicides and plant growth regulators. The compounds (I) can be prepared by processes analogous to known processes whereby some novel intermediates of formula (II) are used.
摘要翻译：甲酰氨基苯基磺酰脲其制备方法及其作为除草剂和植物生长调节剂的用途式（I）取代烃基或未取代或取代的杂环基的化合物，R2是H，（C1-C6） - 烷基或（C1-C6） - 烷氧基，R 3为卤素，（C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基，（C 1 -C 6） - 卤代烷基，（C 1 -C 6） - 卤代烷氧基，NO 2，CN，NH 2，（C 1 -C 4）单或二烷基氨基，如果n为2或3，各自独立地为其它基团，n为0,1,2或3，W为氧原子或硫原子，X和Y彼此独立地为卤素，（C1 （C 1 -C 6） - 烷基，（C 1 -C 6） - 烷氧基或（C 1 -C 6） - 烷硫基，三个最后提到的基团中的每一个是未取代的或被一个或多个选自卤素，（C1- 或（C 1 -C 6） - 烷硫基，或者是（C 3 -C 6） - 环烷基，（C 2 -C 6） - 烯基，（C 2 -C 6） - 炔基，（C 2 -C 6） - 炔基氧基，（C 2 -C 6） C6） - 炔氧基，单或二[（C1-C4烷基）]氨基，Z为CH或N，适合作为除草剂和植物生长调节剂。化合物（I）可以通过类似于已知方法的方法制备，由此使用一些新的式（II）中间体。

46. 发明授权

US5723409A Intermediates for the preparation of phenylsulfonylurea herbicides and plant growth regulators 失效
公开(公告)号：US5723409A
公开(公告)日：1998-03-03
申请号：US430343
申请日：1995-04-28
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N47/36 , C07C311/47 , C07C311/65 , C07C335/28 , C07D521/00 , C07D239/64 , A01N43/54 , C07D401/12
CPC分类号： C07D521/00 , A01N47/36 , C07C311/47 , C07C311/65 , C07C335/28
摘要： The compounds of the formula (I) ##STR1## in which R.sup.1 -R.sup.4, W, X, Y and Z are as defined in claim 1 are suitable for controlling harmful plants in crops. Their preparation may employ the intermediates of the formulae II and III: ##STR2##

47. 发明授权

US10278385B2 Formulations and their use 有权
公开(公告)号：US10278385B2
公开(公告)日：2019-05-07
申请号：US13720035
申请日：2012-12-19
申请人： Stephan Hueffer , Alejandra Garcia Marcos , Paul Klingelhoefer , Gerhard Schnabel
发明人： Stephan Hueffer , Alejandra Garcia Marcos , Paul Klingelhoefer , Gerhard Schnabel
IPC分类号： A01N25/22 , A01N57/20
摘要： The use of formulations comprising (A) one or more aminocarboxylates, selected from among methylglycine diacetate (MGDA) and its alkali metal salts, glutamic acid diacetate (GLDA) and its alkali metal salts, iminodisuccinate, hydroxyethylimine diacetate and ethyleneiminodisuccinate and the corresponding alkali metal salts, (B) at least one organic compound selected from among organic phosphates, organic phosphonates and organic phosphites and salts of the abovementioned organic compounds, and (C) optionally water, for application to plants or the ground.

48. 发明申请

US20140336051A1 Methods of Controlling Undesirable Vegetation with Imidazolinone Herbicides and Adjuvants in Herbicide Resistant Crop Plants 审中-公开
标题翻译：防除除草剂作物植物中咪唑啉酮除草剂和佐剂的不良植被控制方法
公开(公告)号：US20140336051A1
公开(公告)日：2014-11-13
申请号：US14362271
申请日：2012-11-14
申请人： Gerhard Schnabel , Matthias Pfenning , Joerg Polzin , Hagen Bremer
发明人： Gerhard Schnabel , Matthias Pfenning , Joerg Polzin , Hagen Bremer
IPC分类号： A01N25/30 , A01N43/50
CPC分类号： A01N25/30 , A01N43/50 , A01N2300/00
摘要： A herbicidal composition comprising: a) a herbicide compound A, which is selected from the group of imidazolinones; and b) an adjuvant B, which is a surfactant selected from the groups b1 to b5: b1) a nonionic surfactant of the formula R1Xn and polyalkoxylated derivatives thereof, wherein R1 is selected from aliphatic or aromatic residues having at least eight carbon atoms; X is selected from hydroxy, —O—(C1-C6-alkyl), —O—(C3-C6-alkenyl), amine, amide, or ester; and n is 1, 2, 3, 4, 5 or 6; b2) an anionic surfactant of the formula R1Yn, wherein R1 is selected from aliphatic or aromatic residues having at least eight carbon atoms; Y is selected from carboxylate, sulfonate, sulfate, phosphate, or phosphonate; and n is 1, 2, 3, 4, 5 or 6; b3) a cationic surfactant; b4) a zwitterionic surfactant; or b5) a polymeric surfactant; and wherein the weight ratio of the herbicide compound A and the adjuvant B is from 2:1 to 1:60; and the use of the said compositions for controlling undesirable vegetation.
摘要翻译：一种除草组合物，其包含：a）除草剂化合物A，其选自咪唑啉酮; 和b）佐剂B，其为选自b1至b5族的表面活性剂：b1）式R1Xn的非离子表面活性剂和其聚烷氧基化衍生物，其中R1选自具有至少8个碳原子的脂族或芳族残基; X选自羟基，-O-（C 1 -C 6 - 烷基），-O-（C 3 -C 6 - 烯基），胺，酰胺或酯; n为1,2,3,4,5或6; b2）式R1Yn的阴离子表面活性剂，其中R 1选自具有至少8个碳原子的脂族或芳族残基; Y选自羧酸盐，磺酸盐，硫酸盐，磷酸盐或膦酸盐; n为1,2,3,4,5或6; b3）阳离子表面活性剂; b4）两性离子表面活性剂; 或b5）聚合物表面活性剂; 并且其中除草剂化合物A和佐剂B的重量比为2:1至1:60; 以及使用所述组合物来控制不期望的植被。

49. 发明授权

US08840909B2 Multipurpose ant bait 有权
标题翻译：多用途蚂蚁诱饵
公开(公告)号：US08840909B2
公开(公告)日：2014-09-23
申请号：US13130654
申请日：2009-11-16
申请人： Claude Taranta , Thomas Bork , Gerhard Schnabel , Helmut Müller , Sarah Thompson , Clark D. Klein , Nigel Armes , Tiffany Hennessey
发明人： Claude Taranta , Thomas Bork , Gerhard Schnabel , Helmut Müller , Sarah Thompson , Clark D. Klein , Nigel Armes , Tiffany Hennessey
IPC分类号： A01N25/34 , A01N25/00 , A01N43/56 , A01N47/34
CPC分类号： A01N25/006 , A01N43/56 , A01N47/34 , A01N47/02 , A01N2300/00
摘要： Subject of the present invention is a solid ant bait comprising an insecticide and a bait composition. Another subject is a process for the preparation of said ant bait, comprising extruding a mixture, which contains the insecticide and the bait composition. Yet another subject is a method for controlling ants, comprising offering to said ants the ant bait according to the invention. Finally, a subject is a use of the ant bait according to the invention for controlling ants.
摘要翻译：本发明的主题是包含杀虫剂和诱饵组合物的固体蚂蚁诱饵。另一个主题是制备所述蚂蚁诱饵的方法，包括挤出含有杀虫剂和诱饵组合物的混合物。另一个主题是用于控制蚂蚁的方法，包括向所述蚂蚁提供根据本发明的蚂蚁诱饵。最后，受试者是使用根据本发明的蚂蚁诱饵来控制蚂蚁。

50. 发明申请

US20140080702A1 Copolymers of N-vinylcarboxamide and diallyldialkylammonium salt as dispersant for agrochemical formulations 审中-公开
标题翻译： N-乙烯基甲酰胺和二烯丙基二烷基铵盐的共聚物作为农业化学制剂的分散剂
公开(公告)号：US20140080702A1
公开(公告)日：2014-03-20
申请号：US14122469
申请日：2012-05-24
申请人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso
发明人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso
IPC分类号： A01N25/10 , C05G3/02 , A01N43/56
CPC分类号： A01N25/10 , A01N25/04 , A01N25/30 , A01N43/56 , A01N47/24 , C05G3/02 , A01N57/20 , A01N2300/00
摘要： The present invention relates to a composition comprising an agrochemical active substance and a copolymer which comprises an N-vinylcarboxamide and a diallyldialkylammonium salt incorporated into the polymer. The invention furthermore relates to a method of preparing this composition; to the use of this composition for dispersing agrochemical active substances; to a method of controlling phytopathogenic fungi and/or undesired plant growth and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the crop plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment; and furthermore to seed comprising the composition.
摘要翻译：本发明涉及包含农药活性物质和共聚物的组合物，其包含N-乙烯基甲酰胺和掺入聚合物中的二烯丙基二烷基铵盐。本发明还涉及一种制备该组合物的方法; 使用该组合物分散农药活性物质; 涉及一种控制植物病原真菌和/或不期望的植物生长和/或不期望的昆虫或螨攻击和/或调节植物生长的方法，其中允许组合物作用于相应的害虫，其环境或作物植物上在相应的有害生物，土壤和/或不需要的植物和/或作物植物和/或其环境上受到保护; 以及包含该组合物的种子。

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