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    • 41. 发明授权
    • Pigment dispersions with polymeric dispersants having pending chromophore groups
    • 具有悬浮发色团的聚合物分散剂的颜料分散体
    • US08759441B2
    • 2014-06-24
    • US11995330
    • 2006-06-23
    • Johan LoccufierWojciech JaunkyGeert DerooverLambertus Groenendaal
    • Johan LoccufierWojciech JaunkyGeert DerooverLambertus Groenendaal
    • C08L67/00C08L67/02C08L73/00C08L77/00C08L81/00C08G18/06C09D11/10
    • C09B69/106C09B67/0033C09B67/0036C09B67/0051C09B67/0063C09B67/009C09B69/10C09B69/109C09D11/101C09D11/326
    • A pigment dispersion includes a color pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group, wherein the at least one pending chromophore group is a derivative from a color pigment selected from the group consisting of monoazo pigments, disazo pigments, β-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindolinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacridone pigments, diketopyrrolo-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminum pigment lakes, dioxazine pigments, triarylcarbonium pigments, and quinophthalone pigments; the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; the polymeric dispersant has a polymeric backbone with a polymerization degree between 5 and 1,000; and at most 30 % of the monomer units of the polymeric backbone have a pending chromophore group. The pigment dispersion can be advantageously used in inkjet inks. Also disclosed is a method for preparing the pigment dispersion including the step of preparing the polymeric dispersant by copolymerizing a monomer already containing the pending chromophore group.
    • 颜料分散体包括着色颜料和聚合物分散剂,其具有通过连接基团与聚合物分散剂的聚合物主链共价结合的至少一个待处理的发色团,其中所述至少一个未完成的发色团是来自选自以下的颜色颜料的衍生物: 由单偶氮颜料,双偶氮颜料,萘酚颜料,萘酚AS颜料,偶氮颜料湖,苯并咪唑酮颜料,双偶氮缩合颜料,金属络合颜料,异吲哚啉酮颜料,异吲哚啉颜料,酞菁颜料,喹吖啶酮颜料,二酮吡咯并 - 吡咯 颜料,硫靛颜料,蒽醌颜料,蒽嘧啶颜料,阴丹酮颜料,黄烷酮酮颜料,吡喃酮颜料,蒽醌颜料,异卤蒽酮颜料,铝颜料湖,二恶嗪颜料,三芳基碳鎓颜料和喹酞酮颜料; 至少一个未决发色团组是作为聚合物主链上的侧基而不是聚合物主链本身中的基团发生或仅作为聚合物主链的端基发生的发色团。 连接基团由聚合物主链和芳族基团的第一个原子之间的所有原子组成,待处理的发色团通过该原子连接到聚合物主链上; 聚合物分散剂具有聚合度为5至1,000的聚合物主链; 并且至多30%的聚合物主链的单体单元具有未决的发色团组。 颜料分散体可以有利地用于喷墨油墨中。 还公开了一种制备颜料分散体的方法,其包括通过使已经含有未完成发色团的单体共聚制备聚合物分散剂的步骤。
    • 44. 发明申请
    • LED CURABLE COMPOSITIONS
    • LED固化组合物
    • US20130176370A1
    • 2013-07-11
    • US13820208
    • 2011-10-04
    • Johan Loccufier
    • Johan Loccufier
    • C09D11/00
    • C09D11/30B41J2/2107B41J11/002C08F2/50C08F216/125C08F220/38C08F220/40C09D11/101C09D11/40
    • A radiation curable composition includes a) at least one monomer comprising at least one vinyl ether group and at least one (meth)acrylate group; and b) at least one diffusion hindered photoinitiator selected from the group consisting of a polymeric photoinitiator, a multifunctional photoinitiator and a polymerizable photoinitiator characterized in that the diffusion hindered photoinitiator includes at least one structural moiety according to Formula (I): wherein: R1 and R2 are independently selected from the group consisting of a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkaryl group, a substituted or unsubstituted aryl or heteroaryl group, a halogen, an ether, a thioether, an aldehyde, a ketone, an ester, an amide, an amine and a nitro group; R1 and R2 may represent the necessary atoms to form a five to eight membered ring; and the dotted line represents the covalent bond of the structural moiety according to Formula (I) to the diffusion hindered photoinitiator.
    • 辐射固化组合物包括:a)至少一种包含至少一个乙烯基醚基团和至少一个(甲基)丙烯酸酯基团的单体; 和b)至少一种选自聚合光引发剂,多官能光引发剂和可聚合光引发剂的扩散受阻光引发剂,其特征在于扩散受阻光引发剂包括至少一个根据式(I)的结构部分:其中:R1和 R 2独立地选自氢,取代或未取代的烷基,取代或未取代的烯基,取代或未取代的炔基,取代或未取代的芳烷基,取代或未取代的烷芳基,取代或未取代的烷芳基, 未取代的芳基或杂芳基,卤素,醚,硫醚,醛,酮,酯,酰胺,胺和硝基; R1和R2可以表示必要的原子以形成五至八元环; 而虚线表示根据式(I)的结构部分与扩散受阻光引发剂的共价键。