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41. 发明授权

US08814369B2 Optical member with plate-crystal film, method for producing same, and optical system 有权
标题翻译：具有平板晶体膜的光学元件，其制造方法和光学系统
公开(公告)号：US08814369B2
公开(公告)日：2014-08-26
申请号：US13214614
申请日：2011-08-22
申请人： Akira Sakai , Tomonari Nakayama
发明人： Akira Sakai , Tomonari Nakayama
IPC分类号： G02B27/00
CPC分类号： G02B1/118 , G02B1/02 , G02B1/105 , G02B1/14 , G02B27/0018
摘要： An optical member includes a ray effective area, a ray ineffective area, at least one continuous protective film arranged over the ray effective area and at least part of the ray ineffective area, a light-shielding film arranged on the protective film located in the ray ineffective area, and a plate-crystal film arranged on the protective film located in the ray effective area, the plate-crystal film including mainly aluminum oxide and having a textured structure on a surface thereof, and an optical system includes the optical member.
摘要翻译：光学构件包括射线有效区域，射线无效区域，布置在射线有效区域和至少一部分射线无效区域上的至少一个连续保护膜，布置在位于射线中的保护膜上的光屏蔽膜无效区域和布置在位于射线有效区域中的保护膜上的平板状膜，其主要包括氧化铝的板状膜和在其表面上具有纹理结构，并且光学系统包括光学构件。

42. 发明申请

US20100247758A1 PRECURSOR SOL OF ALUMINUM OXIDE AND METHOD FOR PRODUCING OPTICAL MEMBER 有权
标题翻译：氧化铝前驱体和生产光学部件的方法
公开(公告)号：US20100247758A1
公开(公告)日：2010-09-30
申请号：US12748926
申请日：2010-03-29
申请人： Tomonari Nakayama , Kenji Makino
发明人： Tomonari Nakayama , Kenji Makino
IPC分类号： B05D5/06 , C09D5/00
CPC分类号： C09D1/00 , B05D5/02 , B82Y30/00 , C01F7/02 , C01F7/36 , C01P2002/02 , C01P2002/84 , C01P2004/20 , C01P2004/52 , C01P2004/64 , C03C1/008 , C03C17/007 , C03C2217/214 , C03C2217/425 , C03C2217/465 , C03C2217/732 , C03C2217/77 , C03C2218/113 , C03C2218/116 , C03C2218/32 , C09D5/00 , G02B1/02 , G02B1/113 , G02B1/118
摘要： A precursor sol of aluminum oxide includes a solvent and particles containing a hydrolysate of an aluminum compound and/or a condensate of the hydrolysate, in which the particles have an average particle size of 2.5 nm to 7 nm. A method for producing an optical member includes the steps of feeding the precursor sol of aluminum oxide described above onto a base to form an aluminum oxide film and immersing the aluminum oxide film in hot water with a temperature of 60° C. to 100° C. to form a textured structure comprising aluminum oxide boehmite.
摘要翻译：氧化铝的前体溶胶包括溶剂和含有铝化合物的水解物和/或水解产物的缩合物的颗粒，其中颗粒的平均粒径为2.5nm至7nm。制造光学部件的方法包括以下步骤：将上述氧化铝前体溶胶进料到基底上以形成氧化铝膜，并将氧化铝膜浸入温度为60℃至100℃的热水中以形成包含氧化铝勃姆石的纹理结构。

43. 发明申请

US20090304929A1 OPTICAL MEMBER, OPTICAL SYSTEM USING THE OPTICAL MEMBER, AND METHOD OF MANUFACTURING AN OPTICAL MEMBER 有权
标题翻译：光学部件，使用光学部件的光学系统和制造光学部件的方法
公开(公告)号：US20090304929A1
公开(公告)日：2009-12-10
申请号：US12544271
申请日：2009-08-20
申请人： Tomonari Nakayama , Masayuki Yamada
发明人： Tomonari Nakayama , Masayuki Yamada
IPC分类号： B05D3/10
CPC分类号： G02B1/118 , C03C1/006 , C03C17/42 , C03C2217/425 , C03C2217/465 , C03C2217/73 , C03C2217/77 , C09D171/00 , C09D179/08 , G02B1/02 , G02B1/111 , Y10T428/24612 , Y10T428/24942 , Y10T428/265 , Y10T428/269 , Y10T428/31504 , Y10T428/31616 , Y10T428/31623 , Y10T428/31663 , Y10T428/31667 , Y10T428/31681 , Y10T428/31721
摘要： Provided is an optical member capable of keeping a high performance antireflection effect over a long period of time with respect to an arbitrary substrate. The optical member has plural layers on a substrate, and includes at least one metal oxide layer having a void, and at least one layer containing an organic resin as a main component formed between the substrate and the metal oxide layer. The metal oxide layer is a plate crystal layer formed of a plate crystal containing aluminum oxide as a main component and a surface of the plate crystal layer has an uneven profile. The organic resin has an aromatic ring and/or a hetero ring in at least a part thereof.
摘要翻译：提供一种能够相对于任意基板在长时间内保持高性能的防反射效果的光学部件。光学构件在基板上具有多层，并且包括至少一个具有空隙的金属氧化物层，以及在基板和金属氧化物层之间形成有至少一层含有有机树脂作为主要成分的层。金属氧化物层是由含有氧化铝作为主要成分的板状晶体形成的板状结晶层，该板状结晶层的表面具有不均匀的形状。有机树脂的至少一部分具有芳环和/或杂环。

44. 发明授权

US06677099B1 Positive type photosensitive polyimide resin composition 有权
标题翻译：正型光敏聚酰亚胺树脂组合物
公开(公告)号：US06677099B1
公开(公告)日：2004-01-13
申请号：US10148396
申请日：2002-05-30
申请人： Kazuhisa Ishii , Tomonari Nakayama , Takayasu Nihira , Hiroyoshi Fukuro
发明人： Kazuhisa Ishii , Tomonari Nakayama , Takayasu Nihira , Hiroyoshi Fukuro
IPC分类号： G03F7023
CPC分类号： H01L21/02118 , C08K5/20 , C08K5/28 , C08L79/08 , G03F7/0233 , H01L21/312
摘要： A positive type photosensitive resin composition which can be developed by an aqueous alkaline solution and which is excellent in the developability and the adhesion to a substrate, is presented. Namely, the present invention presents a positive type photosensitive polyimide resin composition characterized by comprising 100 parts by weight of a solvent-soluble polyimide having repeating units represented by the formula (1) and from 1 to 50 parts by weight of a polyimide precursor having repeating units represented by the formula (2), and by further containing an o-quinonediazide compound in an amount of from 1 to 100 parts by weight per 100 parts by weight of the total amount of the repeating units represented by the formula (1) and the repeating units represented by the formula (2): (wherein R1 and R3 are bivalent organic groups, from 1 to 90 mol % of R1 is a bivalent organic group having one or plural groups of at least one type selected from the group consisting of a phenolic hydroxyl group, a carboxyl group, a thiophenol group and a sulfonic group, and from 10 to 99 mol % is a bivalent organic group having no phenolic hydroxyl, carboxylic, thiophenol or sulfonic group, and R2 and R4 are tetravalent organic groups constituting a tetracarboxylic acid or its derivative).
摘要翻译：本发明提供一种正极型感光性树脂组合物，其可以通过碱性水溶液显影，并且显影性和对基材的粘附性优异。即，本发明提供一种正型感光性聚酰亚胺树脂组合物，其特征在于，含有100重量份具有式（1）表示的重复单元的溶剂可溶性聚酰亚胺和1〜50重量份具有重复由式（2）表示的单元，并且还包含相对于由式（1）表示的重复单元的总量和每100重量份的由式（1）表示的重复单元的总量为1至100重量份的邻醌二叠氮化合物和由式（2）表示的重复单元:(其中R 1和R 3是二价有机基团，1至90摩尔％的R 1是具有一个或多个基团的二价有机基团选自酚羟基，羧基，苯硫酚基和磺酸基的至少一种，10〜99摩尔％为无酚羟基，羧基，苯硫酚或磺酸基的二价有机基团， R 2和R 4是构成四羧酸或其衍生物的四价有机基团）。

45. 发明授权

US08905559B2 Optical lens having sub-wavelength structure containing aluminum or aluminum oxide, method of manufacturing optical lens, and imaging optical system including optical lens 有权
标题翻译：含有铝或氧化铝的亚波长结构的光学透镜，制造光学透镜的方法和包括光学透镜的成像光学系统
公开(公告)号：US08905559B2
公开(公告)日：2014-12-09
申请号：US13006331
申请日：2011-01-13
申请人： Hiroshi Kawauchi , Masayuki Yamada , Takeharu Okuno , Ryo Ogawa , Tomonari Nakayama
发明人： Hiroshi Kawauchi , Masayuki Yamada , Takeharu Okuno , Ryo Ogawa , Tomonari Nakayama
IPC分类号： G02B27/00 , G02B1/11 , G02B5/00 , B29D11/00
CPC分类号： G02B5/003 , B29D11/00903 , G02B1/118
摘要： An optical element includes an optically effective area and an optically ineffective area partly or entirely coated with a coating opaque at wavelengths used. The opaque coating contains a cured product prepared from an epoxy resin and a curing agent containing an alicyclic acid anhydride. The alicyclic acid anhydride is preferably methylhexahydrophthalic anhydride or hexahydrophthalic anhydride.
摘要翻译：光学元件包括光学有效区域和光学无效区域，部分或全部涂覆有在所使用波长处不透明的涂层。不透明涂层含有由环氧树脂和含有脂环酸酐的固化剂制备的固化产物。脂环酸酐优选为甲基六氢邻苯二甲酸酐或六氢邻苯二甲酸酐。

46. 发明申请

US20120183730A1 OPTICAL MEMBER AND METHOD OF PRODUCING THE SAME 有权
标题翻译：光学部件及其制造方法
公开(公告)号：US20120183730A1
公开(公告)日：2012-07-19
申请号：US13349896
申请日：2012-01-13
申请人： Tomonari Nakayama , Kenji Makino
发明人： Tomonari Nakayama , Kenji Makino
IPC分类号： B32B3/00 , B05D5/06
CPC分类号： G02B1/04 , C08G73/10 , C08G73/101 , C08G73/1035 , C08G73/1042 , C08G73/106 , G02B1/111 , Y10T428/24355 , Y10T428/31623 , Y10T428/31721 , C08L79/08
摘要： Provided is an optical member where at least a layer having polyimide as a main component and a layer having a textured structure arising from a crystal containing aluminum oxide as a main component are stacked in this order. The polyimide includes a silane group in a side chain via an amide bond.
摘要翻译：提供了以至少具有聚酰亚胺为主要成分的层和由含有氧化铝作为主要成分的晶体产生纹理结构的层的光学构件。聚酰亚胺通过酰胺键包含侧链中的硅烷基。

47. 发明申请

US20110274878A1 PRECURSOR SOL OF ALUMINUM OXIDE, OPTICAL MEMBER, AND METHOD FOR PRODUCING OPTICAL MEMBER 有权
标题翻译：氧化铝前驱体SOL，光学部件，以及制造光学部件的方法
公开(公告)号：US20110274878A1
公开(公告)日：2011-11-10
申请号：US13101927
申请日：2011-05-05
申请人： Kenji Makino , Tomonari Nakayama , Keiko Abe , Norishige Kakegawa
发明人： Kenji Makino , Tomonari Nakayama , Keiko Abe , Norishige Kakegawa
IPC分类号： B32B3/30 , B05D5/06 , C09D7/12
CPC分类号： G02B1/118 , B05D5/063 , B05D2203/35 , B05D2401/10 , C03C1/008 , C03C17/007 , C03C17/25 , C03C17/28 , C03C2217/212 , C03C2217/213 , C03C2217/214 , C03C2217/425 , C03C2217/465 , C03C2217/73 , C03C2217/732 , C03C2217/77 , C03C2218/113 , C03C2218/116 , C03C2218/32 , C09D5/006 , G02B1/02 , G02B1/11 , G02B1/113 , Y10T428/24355
摘要： A precursor sol of aluminum oxide contains a polycondensate formed by the hydrolysis of an aluminum alkoxide or an aluminum salt, a solvent, and an organic aluminum compound having a specific structure. An optical member is produced by a process including a step of immersing an aluminum oxide film in a hot water with a temperature of 60° C. to 100° C. to form a textured structure made of aluminum oxide crystals, the aluminum oxide film being formed by feeding the precursor sol of aluminum oxide onto a base. A method for producing an optical member includes a step of immersing an aluminum oxide film in a hot water with a temperature of 60° C. to 100° C. to form a textured structure made of aluminum oxide crystals, the aluminum oxide film being formed by feeding the precursor sol of aluminum oxide onto a base.
摘要翻译：氧化铝的前体溶胶含有通过水解铝盐或铝盐，溶剂和具有特定结构的有机铝化合物形成的缩聚物。通过包括将氧化铝膜浸入温度为60℃至100℃的热水中以形成由氧化铝晶体制成的纹理结构的步骤的方法制造光学构件，所述氧化铝膜为通过将氧化铝的前体溶胶进料到基底上而形成。一种光学构件的制造方法包括将氧化铝膜浸入温度为60℃〜100℃的热水中，形成由氧化铝晶体构成的纹理结构的工序，形成氧化铝膜通过将氧化铝的前体溶胶进料到基底上。

48. 发明授权

US06875554B2 Positive photosensitive polyimide resin composition 有权
标题翻译：正光敏聚酰亚胺树脂组合物
公开(公告)号：US06875554B2
公开(公告)日：2005-04-05
申请号：US10381736
申请日：2001-10-03
申请人： Tadashi Hatanaka , Tomonari Nakayama , Takayasu Nihira
发明人： Tadashi Hatanaka , Tomonari Nakayama , Takayasu Nihira
IPC分类号： G03F7/037 , C08G73/10 , C08L79/08 , G03F7/022 , G03F7/023 , G03F7/004 , G03F7/038
CPC分类号： G03F7/0233
摘要： A positive photosensitive polyimide resin composition comprising: (a) a solvent-soluble polyimide comprised of from 1 to 100 mol % of a bivalent organic group derived from a diamine, that has at least one solvent solubilizing functional group, the polyimide having a reduced viscosity ranging from 0.05 to 5.0 dl/g, (b) a photosensitive orthoquinonediazide compound, and (c) from 0.1 to 50 wt %, based on the total weight of all polymers of the composition, of a component (c1) or (c2), wherein: component (c1) is a solvent-soluble polyimide comprised of from 1 to 100 mol % of a bivalent organic group derived from a diamine, that has at least one functional group selected from the group consisting of a long chain alkyl group having at least 6 carbon atoms and a fluorinated alkyl group, the polyimide having a reduced viscosity ranging from 0.05 to 5.0 dl/g, and component (c2) is a polyamic acid comprised of from 1 to 100 mol % of a bivalent organic group derived from a diamine, that has at least one functional group selected from the group consisting of a long chain alkyl group having at least 6 carbon atoms and a fluorinated alkyl group, the polyimide having a reduced viscosity ranging from 0.05 to 5.0 dl/g.
摘要翻译：一种正型光敏聚酰亚胺树脂组合物，其包含：（a）由1至100摩尔％的衍生自二胺的二价有机基团的溶剂可溶性聚酰亚胺，其具有至少一种溶剂增溶官能团，所述聚酰亚胺具有比浓粘度范围为0.05至5.0dl / g，（b）光敏正二叠氮化合物，和（c）基于组合物的所有聚合物的总重量，0.1至50重量％的组分（c1）或（c2）其中：成分（c1）是由1〜100摩尔％的来自二胺的二价有机基团构成的溶剂可溶性聚酰亚胺，其具有至少1个选自由以下组成的组中的官能团：长链烷基，至少6个碳原子和氟化烷基，所述聚酰亚胺的比浓粘度范围为0.05-5.0dl / g，组分（c2）是由1至100mol％的衍生自二胺，至少有o 选自具有至少6个碳原子的长链烷基和氟化烷基的官能团，所述聚酰亚胺的比浓粘度为0.05-5.0dl / g。

49. 发明授权

US08980401B2 Optical member and method of producing the same 有权
标题翻译：光学元件及其制造方法
公开(公告)号：US08980401B2
公开(公告)日：2015-03-17
申请号：US13349896
申请日：2012-01-13
申请人： Tomonari Nakayama , Kenji Makino
发明人： Tomonari Nakayama , Kenji Makino
IPC分类号： B32B3/00 , B05D5/06 , G02B1/04 , C08G73/10
CPC分类号： G02B1/04 , C08G73/10 , C08G73/101 , C08G73/1035 , C08G73/1042 , C08G73/106 , G02B1/111 , Y10T428/24355 , Y10T428/31623 , Y10T428/31721 , C08L79/08
摘要： Provided is an optical member where at least a layer having polyimide as a main component and a layer having a textured structure arising from a crystal containing aluminum oxide as a main component are stacked in this order. The polyimide includes a silane group in a side chain via an amide bond.
摘要翻译：提供了以至少具有聚酰亚胺为主要成分的层和由含有氧化铝作为主要成分的晶体产生纹理结构的层的光学构件。聚酰亚胺通过酰胺键包含侧链中的硅烷基。

50. 发明授权

US08580026B2 Precursor sol of aluminum oxide, optical member, and method for producing optical member 有权
标题翻译：氧化铝的前体溶胶，光学部件，以及光学部件的制造方法
公开(公告)号：US08580026B2
公开(公告)日：2013-11-12
申请号：US13101927
申请日：2011-05-05
申请人： Kenji Makino , Tomonari Nakayama , Keiko Abe , Norishige Kakegawa
发明人： Kenji Makino , Tomonari Nakayama , Keiko Abe , Norishige Kakegawa
IPC分类号： B05D5/06 , C03C17/25 , C03C17/28 , C09D5/00
CPC分类号： G02B1/118 , B05D5/063 , B05D2203/35 , B05D2401/10 , C03C1/008 , C03C17/007 , C03C17/25 , C03C17/28 , C03C2217/212 , C03C2217/213 , C03C2217/214 , C03C2217/425 , C03C2217/465 , C03C2217/73 , C03C2217/732 , C03C2217/77 , C03C2218/113 , C03C2218/116 , C03C2218/32 , C09D5/006 , G02B1/02 , G02B1/11 , G02B1/113 , Y10T428/24355
摘要： A precursor sol of aluminum oxide contains a polycondensate formed by the hydrolysis of an aluminum alkoxide or an aluminum salt, a solvent, and an organic aluminum compound of general formula (1): wherein R1 and R2 each represent an alkyl group having 1 to 6 carbon atoms, a perfluoroalkyl group, or an allyl group; R3 represents an alkyl group having 1 to 6 carbon atoms, a perfluoroalkyl group, an allyl group, or an aryl group; and n represents an integer of 1 to 3. An optical member is produced by a process including a step of immersing an aluminum oxide film in a hot water with a temperature of 60 Â° C. to 100 Â°C. to form a textured structure made of aluminum oxide crystals, the aluminum oxide film being formed by feeding the precursor sol of aluminum oxide onto a base. A method for producing an optical member includes a step of immersing an aluminum oxide film in a hot water with a temperature of 60 Â° C. to 100 Â° C. to form a textured structure made of aluminum oxide crystals, the aluminum oxide film being formed by feeding the precursor sol of aluminum oxide onto a base.
摘要翻译：氧化铝的前体溶胶含有通过水解铝醇盐或铝盐，溶剂和通式（1）的有机铝化合物形成的缩聚物：其中R1和R2各自表示具有1-6个碳原子的烷基碳原子，全氟烷基或烯丙基; R3表示碳原子数1〜6的烷基，全氟烷基，烯丙基或芳基。 n表示1〜3的整数。通过包括将氧化铝膜浸渍在温度为60℃〜100℃的热水中的工序的方法制造光学部件。为了形成由氧化铝晶体制成的纹理结构，通过将氧化铝的前体溶胶进料到基底上而形成氧化铝膜。一种光学构件的制造方法包括将氧化铝膜浸渍在温度为60℃〜100℃的热水中，形成由氧化铝晶体构成的纹理结构，氧化铝膜通过将氧化铝的前体溶胶进料到基底上而形成。

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