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41. 发明授权

US5139703A Neutral and electrically conductive poly(heterocyclic vinylenes) and processes for preparing same 失效
公开(公告)号：US5139703A
公开(公告)日：1992-08-18
申请号：US526254
申请日：1990-05-21
申请人： Kwan-Yue A. Jen , Ronald L. Elsenbaumer , Lawrence W. Shacklette
发明人： Kwan-Yue A. Jen , Ronald L. Elsenbaumer , Lawrence W. Shacklette
IPC分类号： C08G61/12 , H01B1/12
CPC分类号： H01B1/127 , C08G61/123 , H01B1/128
摘要： This invention relates to electrically conductive and non-conductive forms of poly(heterocyclic vinylenes) and to solutions of same. Another aspect of this invention relates to novel precursor polymers which can be converted into the poly(heterocyclic vinylenes) of this invention.

42. 发明授权

US5104752A Dual, series/parallel battery cell connects 失效
标题翻译：双，系列/并联电池连接
公开(公告)号：US5104752A
公开(公告)日：1992-04-14
申请号：US597911
申请日：1990-10-15
申请人： Ray H. Baughman , Charles Becht, IV , Lawrence W. Shacklette
发明人： Ray H. Baughman , Charles Becht, IV , Lawrence W. Shacklette
IPC分类号： H01M2/30 , H01M2/34 , H01M6/42
CPC分类号： H01M2/34 , H01M2/30 , H01M6/42
摘要： A cell has a body containing at least one electroactive material. The body has both a positive electrical connecting means and a negative electrical connecting means on each of opposite ends of said body. Each of the negative and positive electrical connecting means is positioned such that the cell can be alternatively directly connected electrically in series or in parallel to form a battery power source.
摘要翻译：电池具有包含至少一种电活性材料的主体。主体在所述主体的每个相对端上均具有正电连接装置和负电连接装置。负电连接装置和正电连接装置中的每一个被定位成使得电池可以交替地直接连接电连接或并联以形成电池电源。

43. 发明授权

US4963206A Method of making a thermal window glazing with conductive polymer coating to block radiative heating 失效
标题翻译：用导电聚合物涂层制成热窗玻璃以阻挡辐射加热的方法
公开(公告)号：US4963206A
公开(公告)日：1990-10-16
申请号：US347546
申请日：1989-05-04
申请人： Lawrence W. Shacklette , Kwan-Yue Jen , Helmut Eckhardt , Ronald L. Elsenbaumer , Ray H. Baughman
发明人： Lawrence W. Shacklette , Kwan-Yue Jen , Helmut Eckhardt , Ronald L. Elsenbaumer , Ray H. Baughman
IPC分类号： C03C17/32
CPC分类号： C03C17/32 , Y10T428/1036 , Y10T428/31649
摘要： A method is provided for minimizing radiative heat transfer and maximizing the transmission of visible light through a window having at least one pane. The method comprises the step of applying a transparent conductive polymer layer to a face of the pane, the polymer layer being reflective and absorptive in an infrared region of the electromagnetic spectrum and being transparent in the visible region of the spectrum, and having a transparancy ratio greater than 2.
摘要翻译：提供了一种用于使辐射热传递最小化并通过具有至少一个窗格的窗口使可见光的透射最大化的方法。该方法包括将透明导电聚合物层施加到玻璃板的表面上的步骤，聚合物层在电磁光谱的红外区域是反射和吸收的，并且在光谱的可见光区域是透明的，具有透明比大于2。

44. 发明授权

US4915985A Process for forming articles of filled intrinsically conductive polymers 失效
标题翻译：用于形成填充的本征导电聚合物的方法
公开(公告)号：US4915985A
公开(公告)日：1990-04-10
申请号：US895596
申请日：1986-08-15
申请人： MacRae Maxfield , Lawrence W. Shacklette , Sharon Gould
发明人： MacRae Maxfield , Lawrence W. Shacklette , Sharon Gould
IPC分类号： H01M4/02 , H01M4/04 , H01M4/36 , H01M4/40 , H01M4/48 , H01M4/60 , H01M4/62 , H01M4/66 , H01M4/74 , H01M6/14 , H01M10/36
CPC分类号： H01M10/05 , H01M10/36 , H01M4/0461 , H01M4/13 , H01M4/36 , H01M4/364 , H01M4/40 , H01M4/602 , H01M4/621 , H01M4/622 , H01M4/661 , H01M4/745 , H01M6/14 , H01M2004/027 , H01M2300/0025 , H01M4/485
摘要： A method of fabricating an electrode which comprises an intimate mixture of finely divided electroactive material in a matrix composed of a conjugated backbone polymer which comprises the steps of: derivatizing the surface of finely divided alkali-metal alloying metal, alkali metal cation inserting material or anion inserting material with active polymer catalyst; dispersing the derivatized metal or material having a desired small particle size in a gas, suspension or solution of a monomer or other precursor of the desired conjugated backbone polymer and polymerizing the monomer and/or precursor in the presence of the dispersed metal or material; and fabricating a cohesive solid by recovering the polymerization product from said gas, suspension or solution comprising derivatized metal or material coated with conjugated backbone polymer and forming same into a cohesive solid.
摘要翻译：一种制造电极的方法，其包括由共轭主链聚合物构成的基质中的细分散的电活性材料的紧密混合物，该方法包括以下步骤：将细分的碱金属合金金属，碱金属阳离子插入材料或阴离子的表面衍生化用活性聚合物催化剂插入材料; 将具有所需小粒径的衍生金属或材料分散在所需共轭主链聚合物的单体或其它前体的气体，悬浮液或溶液中，并在分散的金属或材料的存在下聚合单体和/或前体; 并通过从包含衍生的金属或涂覆有共轭主链聚合物的材料的所述气体，悬浮液或溶液中回收聚合产物并制成粘性固体，并将其形成粘结固体。

45. 发明授权

US4814242A Elastomeric binders for battery electrodes 失效
标题翻译：用于电池电极的弹性粘合剂
公开(公告)号：US4814242A
公开(公告)日：1989-03-21
申请号：US107313
申请日：1987-10-13
申请人： MacRae Maxfield , Taiguang R. Jow , Lawrence W. Shacklette
发明人： MacRae Maxfield , Taiguang R. Jow , Lawrence W. Shacklette
IPC分类号： H01M4/13 , H01M4/36 , H01M4/62 , H01M10/05 , H01M4/60
CPC分类号： H01M10/05 , H01M4/13 , H01M4/36 , H01M4/621
摘要： This invention relates to a novel anode for use in batteries, and to batteries containing the anode, which anode comprises one or more anode active materials and an elastomeric binder.
摘要翻译：本发明涉及一种用于电池的新型阳极和含阳极的电池，该阳极包含一种或多种阳极活性材料和弹性体粘合剂。

46. 发明授权

US4804594A Predoped conductive polymers as battery electrode materials 失效
标题翻译：预制导电聚合物作为电池电极材料
公开(公告)号：US4804594A
公开(公告)日：1989-02-14
申请号：US107312
申请日：1987-10-13
申请人： Taiguang R. Jow , Lawrence W. Shacklette
发明人： Taiguang R. Jow , Lawrence W. Shacklette
IPC分类号： H01M4/60 , H01M10/05 , H01M10/40
CPC分类号： H01M10/05 , H01M4/60
摘要： This invention relates to novel electrodes for use in batteries, and to batteries containing the electrodes, which electrodes comprise a conjugated backbone polymer which has been predoped with an anionic or cationic dopant prior to fabrication into a battery.
摘要翻译：本发明涉及用于电池的新型电极和含有电极的电池，该电极包括在制造成电池之前已经用阴离子或阳离子掺杂物预先表示的共轭主链聚合物。

47. 发明授权

US4695521A Conjugated polymer as substrate for the plating of alkali metal in a nonaqueous secondary battery 失效
标题翻译：共轭聚合物作为非水二次电池中碱金属电镀的底物
公开(公告)号：US4695521A
公开(公告)日：1987-09-22
申请号：US749325
申请日：1985-06-27
申请人： Lawrence W. Shacklette , James E. Toth , Ronald L. Elsenbaumer
发明人： Lawrence W. Shacklette , James E. Toth , Ronald L. Elsenbaumer
IPC分类号： H01M4/137 , H01M4/36 , H01M4/60 , H01M10/05 , H01M10/40
CPC分类号： H01M4/137 , H01M10/05 , H01M4/36 , H01M4/60
摘要： This invention relates to a novel anode for use in batteries, and to batteries containing the anode, which anode comprises of an electronically conductive n-doped conjugated backbone polymer having finely divided elemental alkali metal particles dispersed therein.
摘要翻译：本发明涉及一种用于电池的新型阳极，以及含有该阳极的电池，该阳极由其中分散有细分的元素碱金属颗粒的电子导电n掺杂共轭主链聚合物组成。

48. 发明授权

US4668596A Negative electrodes for non-aqueous secondary batteries composed on conjugated polymer and alkali metal alloying or inserting material 失效
标题翻译：由共轭聚合物和碱金属合金化或插入材料组成的非水二次电池的负极
公开(公告)号：US4668596A
公开(公告)日：1987-05-26
申请号：US875526
申请日：1986-06-20
申请人： Lawrence W. Shacklette , Taiguang R. Jow , James E. Toth , MacRae Maxfield
发明人： Lawrence W. Shacklette , Taiguang R. Jow , James E. Toth , MacRae Maxfield
IPC分类号： H01M4/02 , H01M4/04 , H01M4/36 , H01M4/40 , H01M4/48 , H01M4/60 , H01M4/62 , H01M4/66 , H01M4/74 , H01M6/14 , H01M10/36 , H01M6/16
CPC分类号： H01M10/05 , H01M10/36 , H01M4/0461 , H01M4/13 , H01M4/36 , H01M4/364 , H01M4/602 , H01M4/621 , H01M4/622 , H01M4/661 , H01M4/745 , H01M6/14 , H01M2004/027 , H01M2300/0025 , H01M4/40 , H01M4/485
摘要： This invention relates to a novel anode for use in batteries, and to batteries containing the anode, which anode comprises a mixture of a conjugated backbone polymer and another electroactive material selected from the group consisting of metals which alloy with alkali metals and alkali metal cation inserting materials as for example transition metal chalcogenides.
摘要翻译：本发明涉及一种用于电池的新型阳极和含阳极的电池，所述阳极包括共轭骨架聚合物和另一种电活性材料的混合物，该电极活性材料选自与碱金属和碱金属阳离子插入材料例如过渡金属硫族化物。

49. 发明授权

US4522901A Secondary battery containing organoborate electrolyte 失效
标题翻译：二次电池含有机硼酸盐电解质
公开(公告)号：US4522901A
公开(公告)日：1985-06-11
申请号：US556721
申请日：1983-11-30
申请人： Lawrence W. Shacklette
发明人： Lawrence W. Shacklette
IPC分类号： H01M6/16 , H01M10/05 , H01M10/40
CPC分类号： H01M10/05 , H01M6/166
摘要： Secondary batteries with conjugated polymer anodes, such as polyacetylene, contain an electrolyte including a salt of the formula MB.sub.4-w-y-z R'.sub.w R".sub.y X.sub.z wherein M is an alkali metal, B is boron, R is alkyl, R' is aryl or alkyl-substituted aryl, R" is heterocycle, X is F, Cl, Br, I, CN, OCN, SCN, fluoroaryl or perfluoroalkyl-substituted aryl, w and y are integers of 0 to 4, and z is an integer of 0 to 4, provided that when X is solely F, Cl, I, Br, CN, OCN, SCN or perfluororalkyl, Z is not 4; with the sum x+y+z being equal to or less than 4. Exemplary salts are LiBMe.sub.4, LiBMe.sub.2 Ph.sub.2, LiBMe.sub.2 PhPy, LiBMe.sub.2 P.sub.y 2 and KBPh.sub.3 SCN (where M=methyl, Ph=phenyl and Py=pyrrolyl). Cathodes such as conjugated backbone polymers (e.g. polyacetylene) and transition-metal chalcogenides (e.g. TiS.sub.2) are disclosed. The battery can be charged to a state wherein the anode is in a reduced state of 0.1 V-0.5 V (relative to M/M.sup.+) where a voltage plateau exists in some instances.
摘要翻译：具有共轭聚合物阳极的二次电池，例如聚乙炔，含有包含式MB4-wy-zR'wR''yXz的盐的电解质，其中M是碱金属，B是硼，R是烷基，R'是芳基或烷基取代的芳基，R“是杂环，X是F，Cl，Br，I，CN，OCN，SCN，氟代芳基或全氟烷基取代的芳基，w和y是0-4的整数，z是 0至4，条件是当X仅为F，Cl，I，Br，CN，OCN，SCN或全氟烷基时，Z不为4; x + y + z的和x等于或小于4.示例性的盐是LiBMe4，LiBMe2Ph2，LiBMe2PhPy，LiBMe2Py2和KBPh3SCN（其中M =甲基，Ph =苯基和Py =吡咯基）。公开了诸如共轭主链聚合物（例如聚乙炔）和过渡金属硫族化物（例如TiS 2）的阴极。可以将电池充电到在某些情况下存在电压平台的情况下，阳极为0.1V-0.5V（相对于M / M +）的还原状态。

50. 发明授权

US4472489A Polymeric electrode coated with reaction product or organosulfur compound 失效
标题翻译：聚合电极涂覆有反应产物或有机硫化合物
公开(公告)号：US4472489A
公开(公告)日：1984-09-18
申请号：US556739
申请日：1983-11-30
申请人： MacRae Maxfield , Lawrence W. Shacklette , James F. Wolf , Suzanne M. Savner
发明人： MacRae Maxfield , Lawrence W. Shacklette , James F. Wolf , Suzanne M. Savner
IPC分类号： H01M4/02 , H01M4/60
CPC分类号： H01M4/60
摘要： Conjugated backbone polymer electrodes such as polyacetylene anodes are coated with the reaction product of the reduced polymer with a sultone or sulfonate. Such coating may have occurred by using a sultone such as propane sultone in the electrolyte of a battery with such an anode, or in electrode preparation. The coating improves the stability of the electrode, especially when the polymer is highly reduced during battery use, whether the sultone remains as all or part of the electrolyte, or the sultone is replaced by a solvent such as propylene carbonate in the electrolyte for the battery containing coated electrode.
摘要翻译：共轭骨架聚合物电极如聚乙炔阳极被还原的聚合物与磺内酯或磺酸盐的反应产物包被。这种涂层可能通过在具有这种阳极的电池的电解质中或在电极制备中使用诸如丙磺酸内酯的磺内酯而发生。涂层改善了电极的稳定性，特别是当电池使用期间聚合物被高度还原时，无论该磺基酮是全部还是部分电解质，或者在电解质中的溶剂如碳酸亚丙酯代替了磺内酯含电极。

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