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41. 发明申请

US20120171847A1 THIN-FILM DEVICES FORMED FROM SOLID PARTICLES 失效
标题翻译：从固体颗粒形成的薄膜装置
公开(公告)号：US20120171847A1
公开(公告)日：2012-07-05
申请号：US13311483
申请日：2011-12-05
申请人： Matthew R. Robinson , Chris Eberspacher , Jeroen K. J. Van Duren
发明人： Matthew R. Robinson , Chris Eberspacher , Jeroen K. J. Van Duren
IPC分类号： H01L21/20
CPC分类号： C09D11/52 , H01L21/02568 , H01L21/02628 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541
摘要： Methods and devices are provided for forming thin-films from solid group IIIA-based particles. In one embodiment of the present invention, a method is described comprising of providing a first material comprising an alloy of a) a group IIIA-based material and b) at least one other material. The material may be included in an amount sufficient so that no liquid phase of the alloy is present within the first material in a temperature range between room temperature and a deposition or pre-deposition temperature higher than room temperature, wherein the group IIIA-based material is otherwise liquid in that temperature range. The other material may be a group IA material. A precursor material may be formulated comprising a) particles of the first material and b) particles containing at least one element from the group consisting of: group IB, IIIA, VIA element, alloys containing any of the foregoing elements, or combinations thereof.
摘要翻译：提供了用于从基于固体IIIA的颗粒形成薄膜的方法和装置。在本发明的一个实施方案中，描述了一种方法，其包括提供包含a）基于IIIA族的材料和b）至少一种其它材料的合金的第一材料。可以以足够的量包含材料，使得在室温和高于室温的沉积或预沉积温度之间的温度范围内，第一材料中不存在液相，其中基于IIIA族的材料在该温度范围内为液体。另一种材料可以是IA族材料。可以配制前体材料，其包括：a）第一材料的颗粒，和b）含有至少一种元素的颗粒，所述元素包括：IB，IIIA族，VIA族元素，含有任何上述元素的合金，或其组合。

42. 发明申请

US20100003781A1 ROLL-TO-ROLL NON-VACUUM DEPOSITION OF TRANSPARENT CONDUCTIVE ELECTRODES 失效
标题翻译：透明导电非极性非真空沉积
公开(公告)号：US20100003781A1
公开(公告)日：2010-01-07
申请号：US12396435
申请日：2009-03-02
申请人： Jeroen K.J. Van Duren , Matthew R. Robinson , James R. Sheats
发明人： Jeroen K.J. Van Duren , Matthew R. Robinson , James R. Sheats
IPC分类号： H01L31/18
CPC分类号： H01L31/0322 , H01L31/18 , H01L31/1884 , Y02E10/50
摘要： Methods and devices are provided for improved photovoltaic devices. Non-vacuum deposition of transparent conductive electrodes in a roll-to-roll manufacturing environment is disclosed. In one embodiment, a method is provided for forming a photovoltaic device. The method comprises processing a precursor layer in one or more steps to form a photovoltaic absorber layer; depositing a smoothing layer to fill gaps and depression in the absorber layer to reduce a roughness of the absorber layer; adding an insulating layer over the smooth layer; and forming a web-like layer of conductive material over the insulating layer. By way of nonlimiting example, the web-like layer of conductive material comprises a plurality of carbon nanotubes. In some embodiments, the absorber layer is a group IB-IIIA-VIA absorber layer.
摘要翻译：为改进的光伏器件提供了方法和装置。透明导电电极在卷对卷制造环境中的非真空沉积被公开。在一个实施例中，提供了一种用于形成光伏器件的方法。该方法包括在一个或多个步骤中处理前体层以形成光伏吸收层; 沉积平滑层以填充吸收层中的间隙和凹陷以减小吸收层的粗糙度; 在平滑层上添加绝缘层; 以及在所述绝缘层上形成网状的导电材料层。作为非限制性实例，导电材料的网状层包括多个碳纳米管。在一些实施例中，吸收层是IB-IIIA-VIA族吸收层。

43. 发明授权

US07604843B1 Metallic dispersion 失效
标题翻译：金属色散
公开(公告)号：US07604843B1
公开(公告)日：2009-10-20
申请号：US11081163
申请日：2005-03-16
申请人： Matthew R. Robinson , Martin R. Roscheisen
发明人： Matthew R. Robinson , Martin R. Roscheisen
IPC分类号： B05D3/04 , H01L31/00
CPC分类号： H01L31/0322 , C23C18/02 , C23C18/1216 , C23C18/1258 , H01L31/03928 , H01L31/0749 , Y02E10/541 , Y02P70/521 , Y10S977/786 , Y10S977/81
摘要： A compound film may be formed by formulating a mixture of elemental nanoparticles composed of the Ib, the IIIa, and, optionally, the VIa group of elements having a controlled overall composition. The nanoparticle mixture is combined with a suspension of nanoglobules of gallium to form a dispersion. The dispersion may be deposited onto a substrate to form a layer on the substrate. The layer may then be reacted in a suitable atmosphere to form the compound film. The compound film may be used as a light-absorbing layer in a photovoltaic device.
摘要翻译：可以通过配制由Ib，IIIa和任选的具有受控整体组成的元素的VIa族组成的元素纳米颗粒的混合物来形成复合膜。将纳米颗粒混合物与镓的纳米金属的悬浮液组合以形成分散体。可以将分散体沉积在基底上以在基底上形成层。然后可以在合适的气氛中反应该层以形成化合物膜。复合膜可以用作光伏器件中的光吸收层。

44. 发明申请

US20130277625A1 TRANSPARENT CONDUCTORS INCORPORATING ADDITIVES AND RELATED MANUFACTURING METHODS 审中-公开
标题翻译：包含添加剂的透明导体及相关制造方法
公开(公告)号：US20130277625A1
公开(公告)日：2013-10-24
申请号：US13919833
申请日：2013-06-17
申请人： Arjun Daniel Srinivas , Matthew R. Robinson , Michael Eugene Young
发明人： Arjun Daniel Srinivas , Matthew R. Robinson , Michael Eugene Young
IPC分类号： H01B1/02 , H01B13/30
CPC分类号： H01B1/02 , G02F1/13439 , G06F3/044 , G06F3/045 , H01B13/30 , H01L51/0021 , H01L51/5206 , H01L2251/5369
摘要： A transparent conductor includes a film of a conductive ceramic and conductive additives at least partially incorporated into the film and localized within a region of the film. A thickness of the region is less than an overall thickness of the film, and at least one of the conductive additives has an aspect ratio of at least 3. The transparent conductor has a sheet resistance that is less than an intrinsic sheet resistance of the film.
摘要翻译：透明导体包括导电陶瓷膜和至少部分地结合到膜中并且定位在膜的区域内的导电添加剂。该区域的厚度小于膜的总厚度，并且至少一种导电添加剂的长宽比至少为3.透明导体的薄层电阻小于膜的本征薄层电阻。

45. 发明授权

US08530262B2 Roll-to-roll non-vacuum deposition of transparent conductive electrodes 失效
标题翻译：透明导电电极的卷对卷非真空沉积
公开(公告)号：US08530262B2
公开(公告)日：2013-09-10
申请号：US12396435
申请日：2009-03-02
申请人： Jeroen K. J. Van Duren , Matthew R. Robinson , James R. Sheats
发明人： Jeroen K. J. Van Duren , Matthew R. Robinson , James R. Sheats
IPC分类号： H01L21/00
CPC分类号： H01L31/0322 , H01L31/18 , H01L31/1884 , Y02E10/50
摘要： Methods and devices are provided for improved photovoltaic devices. Non-vacuum deposition of transparent conductive electrodes in a roll-to-roll manufacturing environment is disclosed. In one embodiment, a method is provided for forming a photovoltaic device. The method comprises processing a precursor layer in one or more steps to form a photovoltaic absorber layer; depositing a smoothing layer to fill gaps and depression in the absorber layer to reduce a roughness of the absorber layer; adding an insulating layer over the smooth layer; and forming a web-like layer of conductive material over the insulating layer. By way of nonlimiting example, the web-like layer of conductive material comprises a plurality of carbon nanotubes. In some embodiments, the absorber layer is a group IB-IIIA-VIA absorber layer.
摘要翻译：为改进的光伏器件提供了方法和装置。透明导电电极在卷对卷制造环境中的非真空沉积被公开。在一个实施例中，提供了一种用于形成光伏器件的方法。该方法包括在一个或多个步骤中处理前体层以形成光伏吸收层; 沉积平滑层以填充吸收层中的间隙和凹陷以减小吸收层的粗糙度; 在平滑层上添加绝缘层; 以及在所述绝缘层上形成网状的导电材料层。作为非限制性实例，导电材料的网状层包括多个碳纳米管。在一些实施例中，吸收层是IB-IIIA-VIA族吸收层。

46. 发明授权

US08440498B2 Thin-film devices formed from solid particles 失效
标题翻译：由固体颗粒形成的薄膜器件
公开(公告)号：US08440498B2
公开(公告)日：2013-05-14
申请号：US13311483
申请日：2011-12-05
申请人： Matthew R. Robinson , Chris Eberspacher , Jeroen K. J. Van Duren
发明人： Matthew R. Robinson , Chris Eberspacher , Jeroen K. J. Van Duren
IPC分类号： H01L21/00
CPC分类号： C09D11/52 , H01L21/02568 , H01L21/02628 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541
摘要： Methods and devices are provided for forming thin-films from solid group IIIA-based particles. In one embodiment of the present invention, a method is described comprising of providing a first material comprising an alloy of a) a group IIIA-based material and b) at least one other material. The material may be included in an amount sufficient so that no liquid phase of the alloy is present within the first material in a temperature range between room temperature and a deposition or pre-deposition temperature higher than room temperature, wherein the group IIIA-based material is otherwise liquid in that temperature range. The other material may be a group IA material. A precursor material may be formulated comprising a) particles of the first material and b) particles containing at least one element from the group consisting of: group IB, IIIA, VIA element, alloys containing any of the foregoing elements, or combinations thereof.
摘要翻译：提供了用于从基于固体IIIA的颗粒形成薄膜的方法和装置。在本发明的一个实施方案中，描述了一种方法，其包括提供包含a）基于IIIA族的材料和b）至少一种其它材料的合金的第一材料。可以以足够的量包含材料，使得在室温和高于室温的沉积或预沉积温度之间的温度范围内，第一材料中不存在液相，其中基于IIIA族的材料在该温度范围内为液体。另一种材料可以是IA族材料。可以配制前体材料，其包括：a）第一材料的颗粒，和b）含有至少一种元素的颗粒，所述元素包括：IB，IIIA族，VIA族元素，含有任何上述元素的合金，或其组合。

47. 发明授权

US08414961B1 Solution deposited transparent conductors 失效
标题翻译：溶液沉积透明导体
公开(公告)号：US08414961B1
公开(公告)日：2013-04-09
申请号：US11956322
申请日：2007-12-13
申请人： Matthew R. Robinson , Chris Eberspacher
发明人： Matthew R. Robinson , Chris Eberspacher
IPC分类号： B05D5/12
CPC分类号： H01L31/0465 , H01L31/022466 , H01L31/03928 , H01L31/0749 , H01L31/1884 , H01L51/442 , Y02E10/541 , Y02E10/549 , Y02P70/521
摘要： Methods and devices are provided for improved photovoltaic devices. In one embodiment, a method is provided for forming a photovoltaic device. The method comprises processing a precursor layer in one or more steps to form a photovoltaic absorber layer; depositing a smoothing layer to fill gaps and depression in the absorber layer to reduce a roughness of the absorber layer; adding an insulating layer over the smooth layer; and forming a web-like layer of conductive material over the insulating layer. By way of nonlimiting example, the web-like layer of conductive material comprises a plurality of carbon nanotubes. In some embodiments, the absorber layer is a group IB-IIIA-VIA absorber layer.
摘要翻译：为改进的光伏器件提供了方法和装置。在一个实施例中，提供了一种用于形成光伏器件的方法。该方法包括在一个或多个步骤中处理前体层以形成光伏吸收层; 沉积平滑层以填充吸收层中的间隙和凹陷以减小吸收层的粗糙度; 在平滑层上添加绝缘层; 以及在所述绝缘层上形成网状的导电材料层。作为非限制性实例，导电材料的网状层包括多个碳纳米管。在一些实施例中，吸收层是IB-IIIA-VIA族吸收层。

48. 发明申请

US20130056244A1 PATTERNED TRANSPARENT CONDUCTORS AND RELATED MANUFACTURING METHODS 有权
标题翻译：图形透明导体及相关制造方法
公开(公告)号：US20130056244A1
公开(公告)日：2013-03-07
申请号：US13594758
申请日：2012-08-24
申请人： Arjun Srinivas , Matthew R. Robinson , Alexander Chow Mittal , Michael Eugene Young , David Buchanan , Joseph George , Yuka Yoshioka
发明人： Arjun Srinivas , Matthew R. Robinson , Alexander Chow Mittal , Michael Eugene Young , David Buchanan , Joseph George , Yuka Yoshioka
IPC分类号： H05K1/02
CPC分类号： H05K1/0274 , B82Y30/00 , G06F3/041 , G06F2203/04103 , H05K1/0296 , H05K1/0298 , H05K1/09 , H05K3/0091 , H05K3/027 , Y10S977/932 , Y10T428/25 , Y10T428/254
摘要： A patterned transparent conductor includes a substrate and additives at least partially embedded into at least one surface of the substrate and localized adjacent to the surface according to a pattern to form higher sheet conductance portions. The higher sheet conductance portions are laterally adjacent to lower sheet conductance portions.
摘要翻译：图案化的透明导体包括基材和至少部分地嵌入基材的至少一个表面中并且根据图案邻近表面定位的添加剂，以形成更高的片状导电部分。较高的片材导电部分与下片材导电部分横向相邻。

49. 发明申请

US20130000952A1 TRANSPARENT CONDUCTORS INCORPORATING ADDITIVES AND RELATED MANUFACTURING METHODS 有权
标题翻译：包含添加剂的透明导体及相关制造方法
公开(公告)号：US20130000952A1
公开(公告)日：2013-01-03
申请号：US13536968
申请日：2012-06-28
申请人： Arjun Daniel Srinivas , Michael Eugene Young , Matthew R. Robinson
发明人： Arjun Daniel Srinivas , Michael Eugene Young , Matthew R. Robinson
IPC分类号： H01B5/00
CPC分类号： H01B1/02 , G02F1/13439 , G06F3/044 , G06F3/045 , H01B13/30 , H01L51/0021 , H01L51/5206 , H01L2251/5369
摘要： A transparent conductor includes a film of a conductive ceramic. Additives are at least partially incorporated into the film. The additives are at least one of electrically conductive and semiconducting, and at least one of the additives has an aspect ratio of at least 3.
摘要翻译：透明导体包括导电陶瓷膜。添加剂至少部分地并入到膜中。添加剂是导电和半导体中的至少一种，并且至少一种添加剂具有至少3的纵横比。

50. 发明申请

US20120295022A1 High-Throughput Printing of Chalcogen Layer 审中-公开
标题翻译：高通量印刷硫族元素层
公开(公告)号：US20120295022A1
公开(公告)日：2012-11-22
申请号：US13481994
申请日：2012-05-29
申请人： Jeroen K.J. Van Duren , Matthew R. Robinson , Craig Leidholm
发明人： Jeroen K.J. Van Duren , Matthew R. Robinson , Craig Leidholm
IPC分类号： B05D1/38 , B05D3/02 , B05D3/10
CPC分类号： C23C18/1283 , C23C18/1204 , C23C18/1225 , C23C18/1241 , C23C18/127 , H01L31/0322 , H01L31/06 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要： Methods and devices for high-throughput printing of a precursor material for forming a film of a group IB-IIIA-chalcogenide compound are disclosed. In one embodiment, the method comprises forming a precursor layer on a substrate, wherein the precursor layer comprises one or more discrete layers. The layers may include at least a first layer containing one or more group IB elements and two or more different group IIIA elements and at least a second layer containing elemental chalcogen particles. The precursor layer may be heated to a temperature sufficient to melt the chalcogen particles and to react the chalcogen particles with the one or more group IB elements and group IIIA elements in the precursor layer to form a film of a group IB-IIIA-chalcogenide compound.
摘要翻译：公开了用于形成IB-IIIA族硫族化合物化合物的膜的前体材料的高通量印刷的方法和装置。在一个实施例中，该方法包括在衬底上形成前体层，其中前体层包含一个或多个离散层。这些层可以包括至少包含一个或多个IB族元素和两个或更多个不同IIIA族元素的第一层和至少包含元素硫族元素颗粒的第二层。可以将前体层加热到足以熔化硫族元素颗粒的温度，并使硫族元素颗粒与前体层中的一种或多种IB族元素和IIIA族元素反应，以形成IB-IIIA族硫族化合物组合物。

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