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    • 43. 发明授权
    • Carboamidoalkyl norbornanes, organoleptic uses thereof and process for
preparing same
    • 碳酰胺基烷基降冰片烷,感官用途及其制备方法
    • US4357949A
    • 1982-11-09
    • US268144
    • 1981-05-28
    • Philip T. KlemarczykFrederick L. SchmittEdward J. GrandaDomenick Luccarelli, Jr.
    • Philip T. KlemarczykFrederick L. SchmittEdward J. GrandaDomenick Luccarelli, Jr.
    • A24B15/34C07C45/62C07C45/69C07C47/347C07C47/445C07C61/13C11B9/00C11D3/50A24B3/12A24B15/30
    • C11D3/50A24B15/345C07C45/62C07C45/69C07C47/347C07C47/445C07C61/13C11B9/0046
    • Described are compounds having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and wherein R.sub.2 is methyl or hydrogen; R.sub.6 is methyl or hydrogen; R.sub.1, R.sub.3 or R.sub.7 represent methyl or hydrogen, with the proviso that one of R.sub.1, R.sub.3 and R.sub.7 represents methyl and the other two of R.sub.1, R.sub.3 and R.sub.7 represent hydrogen; wherein R.sub.4 and R.sub.5 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, dryer-added fabric softener articles, fabric brighteners and other perfumed articles and colognes). Also disclosed is a process for preparing such compounds according to the reaction scheme: ##STR2## wherein R" represents C.sub.1 C.sub.3 alkyl; m+n=3 with the further proviso that m is 1 or 2 and n is 1 or 2; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are as defined above.
    • 描述了具有通用结构的化合物:其中虚线表示碳 - 碳单键或碳 - 碳双键,其中R2是甲基或氢; R6是甲基或氢; R 1,R 3或R 7表示甲基或氢,条件是R 1,R 3和R 7中的一个表示甲基,R 1,R 3和R 7中的另外两个表示氢; 其中R 4和R 5相同或不同,各自表示氢或C 1 -C 3低级烷基。 此外,公开了这种化合物的感官用途,用于增强或增强消费材料的香味或味道,包括食品,口香糖,牙膏,药用产品,咀嚼烟草,烟草烟草,烟草制品,香水,香水制品(如液体 或固体阴离子,阳离子,非离子或两性离子洗涤剂,织物柔软剂,干燥剂添加的织物柔软剂制品,织物增白剂和其它香料制品和古龙水)。 还公开了根据反应方案制备这些化合物的方法:其中R“表示C 1 -C 3烷基; m + n = 3,进一步的条件是m为1或2,n为1或2; 并且其中R 1,R 2,R 3,R 4,R 5,R 6和R 7如上所定义。
    • 44. 发明授权
    • Carboamidoalkyl norbornanes and organoleptic use in detergents
    • 卡波酰胺基烷基降冰片烷和感官用于洗涤剂
    • US4331550A
    • 1982-05-25
    • US268117
    • 1981-05-28
    • Philip T. KlemarczykFrederick L. SchmittEdward J. GrandaDomenick Luccarelli, Jr.
    • Philip T. KlemarczykFrederick L. SchmittEdward J. GrandaDomenick Luccarelli, Jr.
    • A24B15/34C07C45/62C07C45/69C07C47/347C07C47/445C07C61/13C11B9/00C11D3/50A61K7/46
    • C11D3/50A24B15/345C07C45/62C07C45/69C07C47/347C07C47/445C07C61/13C11B9/0046
    • Described are compounds having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and wherein R.sub.2 is methyl or hydrogen; R.sub.6 is methyl or hydrogen; R.sub.1, R.sub.3 or R.sub.7 represent methyl or hydrogen, with the proviso that one of R.sub.1, R.sub.3 and R.sub.7 represents methyl and the other two of R.sub.1, R.sub.3 and R.sub.7 represent hydrogen; wherein R.sub.4 and R.sub.5 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, dryer-added fabric softener articles, fabric brighteners and other perfumed articles and colognes). Also disclosed is a process for preparing such compounds according to the reaction scheme: ##STR2## wherein R" represents C.sub.1 -C.sub.3 alkyl; m+n=3 with the further proviso that m is 1 or 2 and n is 1 or 2; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are as defined above.
    • 描述了具有通用结构的化合物:其中虚线表示碳 - 碳单键或碳 - 碳双键,其中R2是甲基或氢; R6是甲基或氢; R 1,R 3或R 7表示甲基或氢,条件是R 1,R 3和R 7中的一个表示甲基,R 1,R 3和R 7中的另外两个表示氢; 其中R 4和R 5相同或不同,各自表示氢或C 1 -C 3低级烷基。 此外,公开了这种化合物的感官用途,用于增强或增强消费材料的香味或味道,包括食品,口香糖,牙膏,药用产品,咀嚼烟草,烟草烟草,烟草制品,香水,香水制品(如液体 或固体阴离子,阳离子,非离子或两性离子洗涤剂,织物柔软剂,干燥剂添加的织物柔软剂制品,织物增白剂和其它香料制品和古龙水)。 还公开了根据反应方案制备这些化合物的方法:其中R“表示C 1 -C 3烷基; m + n = 3,进一步的条件是m为1或2,n为1或2; 并且其中R 1,R 2,R 3,R 4,R 5,R 6和R 7如上所定义。