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31. 发明授权

US06211415B1 Process for thermal decomposition of hexafluoropropylene oxide oligomers 有权
标题翻译：六氟环氧丙烷低聚物热分解方法
公开(公告)号：US06211415B1
公开(公告)日：2001-04-03
申请号：US09308587
申请日：1999-05-21
申请人： Shigeru Morita , Toshihiko Amano
发明人： Shigeru Morita , Toshihiko Amano
IPC分类号： C07C4311
CPC分类号： C07C59/135
摘要： A hexafluoropropylene oxide oligomer of the formula: RfO[CF(CF3)CF2O]nCF(CF3)COF in which Rf is a group represented by the formula: F(CF2)m— in which m is an integer of 1 to 8, or the formula: (CF3)2CF(CF2)q— in which q is an integer of 0 to 6, and n is a number of 3 to 20 is heated and thermally decomposed in a solvent at a temperature of at least 100° C. in the presence of a compound which generates a fluoride (F−) ion to obtain mainly the dimer, trimer and tetramer of hexafluoropropylene oxide. Thus, the valuable low molecular weight oligomers of hexafluoropropylene oxide can be obtained from high molecular weight oligomers of hexafluoropropylene oxide which have been discarded.
摘要翻译： Rf为CFF（CF 3）CF 2 O] n CF（CF 3）COF的六氟环氧丙烷低聚物，其中R f为由式F（CF 2）m - 表示的基团，其中m为1至8的整数，或式（CF3）2CF（CF2）q-其中q为0-6的整数，n为3至20的数，在溶剂中在至少100℃的温度下加热和热分解。在产生氟化物（F-）离子的化合物的存在下，主要得到六氟环氧丙烷的二聚体，三聚体和四聚体。因此，六氟环氧丙烷的有价值的低分子量低聚物可以从被丢弃的六氟环氧丙烷的高分子量低聚物获得。

32. 发明授权

US06806393B2 Multimetal cyanide compounds, their preparation and their use 失效
标题翻译：多金属氰化合物，其制备及其用途
公开(公告)号：US06806393B2
公开(公告)日：2004-10-19
申请号：US10447521
申请日：2003-05-29
申请人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
发明人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
IPC分类号： C07C4311
CPC分类号： C08G65/2663 , B01J27/26 , B01J35/023
摘要： In multimetal cyanide complexes, more than 30% by weight of the primary particles have a platelet-like habit, i.e. the length and width of the primary particles is at least three times the thickness of the particles.
摘要翻译：在多金属氰化物络合物中，超过30重量％的初级颗粒具有血小板样习惯，即一次颗粒的长度和宽度至少为颗粒厚度的三倍。

33. 发明授权

US06693222B2 Process for splitting water-soluble ethers 失效
标题翻译：分离水溶性醚的方法
公开(公告)号：US06693222B2
公开(公告)日：2004-02-17
申请号：US10136083
申请日：2002-04-29
申请人： Thomas Haas , Christian Ronge , Torsten Hahn
发明人： Thomas Haas , Christian Ronge , Torsten Hahn
IPC分类号： C07C4311
CPC分类号： C07C29/10 , C07C29/141 , C07C2601/14 , C12C11/02 , C07C31/202 , C07C35/14 , C07C33/03 , C07C31/08 , C07C31/10 , C07C31/20 , C07C31/04 , C07C31/22 , C07C31/205
摘要： A process for production of 1,3-propanediol including the steps: (a) hydrating acrolein in the presence of an acid hydration catalyst; (b) catalytically hydrogenating the reaction mixture of step (a), which reaction mixture comprises 3-hydroxypropionaldehyde and is freed of unreacted acrolein; (c) refining the reaction mixture of step (b) containing water, 1,3-propanediol and the by-products boiling higher than 1,3-propanediol; and, (d) treating 4-oxa-1,7-heptanediol to form 1,3-propanediol by (1) removing a boiler sump comprising 4-oxa-1,7-heptanediol from the refining step (c), (2) treating the boiler sump in an aqueous solution in the presence of an acid catalyst at about 200 to about 300° C. to form a solution comprising 1,3-propanediol, (3) neutralizing the solution obtained is step (2), and returning the neutralized solution from step (3) to the refining step (c). In addition, a process for splitting oligomeric water-soluble ether comprising: (a) treating an aqueous solution comprising oligomeric water-soluble ether in the presence of homogeneous acid catalyst at a temperature of from about 200 to about 300° C. to form the monomer of the oligomeric water-soluble ether; and (b) neutralizing the solution obtained in step (a),
摘要翻译：一种制备1,3-丙二醇的方法，包括以下步骤：（a）在酸性水合催化剂存在下水合丙烯醛; （b）催化氢化步骤（a）的反应混合物，该反应混合物包含3-羟基丙醛，并且不含未反应的丙烯醛; （c）精制含有水，1,3-丙二醇和沸点高于1,3-丙二醇的副产物的步骤（b）的反应混合物; （d）通过（1）从精制步骤（c），（2）中除去包含4-氧杂-1,7-庚二醇的锅炉贮槽，处理4-氧杂-1,7-庚二醇以形成1,3-丙二醇在约200〜约300℃的酸催化剂存在下，在水溶液中处理锅炉池，形成含有1,3-丙二醇的溶液，（3）中和得到的溶液是步骤（2），和将中和的溶液从步骤（3）返回到精制步骤（c）。另外，一种分解低聚水溶性醚的方法，包括：（a）在均聚酸催化剂存在下，在约200至约300℃的温度下处理包含低聚水溶性醚的水溶液，以形成低聚水溶性醚的单体; 和（b）中和步骤（a）中获得的溶液，

34. 发明授权

US06664428B2 Method of producing polyetherpolyols 有权
标题翻译：生产聚醚多元醇的方法
公开(公告)号：US06664428B2
公开(公告)日：2003-12-16
申请号：US10204293
申请日：2002-08-20
申请人： Thomas Ostrowski , Kathrin Harre , Georg Heinrich Grosch , Gerd Höppner , Peter de Vocht , Dirk Leys , Jürgen Winkler , Stephan Bauer
发明人： Thomas Ostrowski , Kathrin Harre , Georg Heinrich Grosch , Gerd Höppner , Peter de Vocht , Dirk Leys , Jürgen Winkler , Stephan Bauer
IPC分类号： C07C4311
CPC分类号： C08G65/2696 , C08G65/2663
摘要： A process for the preparation of polyetherpolyols by reacting diols or polyols with ethylene oxide, propylene oxide, butylene oxide or a mixture thereof in the presence of a multimetal cyanide complex catalyst is proposed, the reaction being carried out in a stirred kettle reactor and the reaction mixture being circulated via an external heat exchanger by means of a pump.
摘要翻译：提出了在多金属氰化物配合物催化剂存在下，通过二醇或多元醇与环氧乙烷，环氧丙烷，环氧丁烷或其混合物反应制备聚醚多元醇的方法，该反应在搅拌釜反应器中进行，反应混合物通过泵通过外部热交换器循环。

35. 发明授权

US06653511B2 Perfluoropolyether primary bromides and iodides 有权
标题翻译：全氟聚醚一级溴化物和碘化物
公开(公告)号：US06653511B2
公开(公告)日：2003-11-25
申请号：US10237345
申请日：2002-09-09
申请人： Jon L. Howell , Erik W. Perez , Alfred Waterfeld , Chadron Mark Friesen , Joseph Stuart Thrasher , Ireneusz Nowak
发明人： Jon L. Howell , Erik W. Perez , Alfred Waterfeld , Chadron Mark Friesen , Joseph Stuart Thrasher , Ireneusz Nowak
IPC分类号： C07C4311
CPC分类号： C07C41/14 , C07C41/18 , C07C41/22 , C07C43/126
摘要： A perfluoropolyether and a composition comprising the perfluoropolyether are provided in which the perfluoropolyether comprises at least one bromine or iodine atom at the primary position of the perfluoropolyether. Also provided is a process for producing the composition in which the process comprises contacting a perfluoropolyether acid fluoride moiety with a metal bromide or metal iodide or a suitable polyether secondary iodide under a condition sufficient to effect the production of a perfluoropolyether comprising at least one bromine or iodine at the primary position.
摘要翻译：提供全氟聚醚和包含全氟聚醚的组合物，其中全氟聚醚在全氟聚醚的主要位置包含至少一个溴或碘原子。还提供了一种制备组合物的方法，其中该方法包括使全氟聚醚酰氟部分与金属溴化物或金属碘化物或适当的聚醚二碘化物在足以产生包含至少一种溴或全氟聚醚的全氟聚醚的条件下接触碘在主要位置。

36. 发明授权

US06653441B2 Method for production of polyether alcohols 有权
公开(公告)号：US06653441B2
公开(公告)日：2003-11-25
申请号：US10130846
申请日：2002-05-21
申请人： Kathrin Harre , Gerd Höppner , Georg Heinrich Grosch , Stephan Bauer , Jürgen Winkler , Els Paredis , Reinhard Lorenz , Inge Rotermund
发明人： Kathrin Harre , Gerd Höppner , Georg Heinrich Grosch , Stephan Bauer , Jürgen Winkler , Els Paredis , Reinhard Lorenz , Inge Rotermund
IPC分类号： C07C4311
CPC分类号： C08G65/2663 , C08G18/485 , C08G65/2696
摘要： In a process for preparing polyether alcohols by catalytic addition of at least two alkylene oxides onto H-functional initiator substances, at least one multimetal cyanide compound is used as catalyst and the addition of the alkylene oxides onto the initiator substance includes incorporation of at least one oxyalkylene block during whose formation at least two alkylene oxides are metered in together and the ratio of the alkylene oxides to one another in the mixture is changed during the joint introduction.

37. 发明授权

US06642423B2 Polymerization of ethylene oxide using metal cyanide catalysts 失效
公开(公告)号：US06642423B2
公开(公告)日：2003-11-04
申请号：US10131900
申请日：2002-04-24
申请人： Katherine S. Clement , Louis L. Walker , Richard M. Wehmeyer , Robert H. Whitmarsh , David C. Molzahn , William P. Dianis , David E. Laycock , John W. Weston , Richard J. Elwell
发明人： Katherine S. Clement , Louis L. Walker , Richard M. Wehmeyer , Robert H. Whitmarsh , David C. Molzahn , William P. Dianis , David E. Laycock , John W. Weston , Richard J. Elwell
IPC分类号： C07C4311
CPC分类号： C08G65/2609 , B01J27/26 , B01J37/0223 , C08G65/2603 , C08G65/2615 , C08G65/2618 , C08G65/2663 , C08G65/2693 , C08G65/2696
摘要： Ethoxylations of various initiator compounds are performed in the presence of metal cyanide catalysts. The catalysts surprisingly form a wide variety of polyether products that in most cases contain only small amounts of high molecular weight poly(ethylene oxide).

38. 发明授权

US06620975B2 Process for making butyl ethers of glycols 失效
公开(公告)号：US06620975B2
公开(公告)日：2003-09-16
申请号：US09844442
申请日：2001-04-30
申请人： Benjamin Patrick Gracey
发明人： Benjamin Patrick Gracey
IPC分类号： C07C4311
CPC分类号： C07C41/06 , C07C41/42 , Y02P20/582 , C07C43/178
摘要： Processes are described for the preparation of glycol butyl ethers involving reaction of butadiene with saturated aliphatic glycols, separating the thus formed n- and sec-butenyl glycol ethers and hydrogenating the n-butenyl glycol ethers. Additional features are the use in the first step of heterogeneous catalyst modified by alkylpyridinium quaternary ammonium, quaternary arsonium quaternary phosphonium counterions and/or the conversion of sec-butenyl glycol ethers to butadiene and saturated aliphatic glycols.

39. 发明授权

US06482994B2 Ether-capped poly(oxyalkylated) alcohol surfactants 有权
标题翻译：醚封端的聚（烷氧基化）醇表面活性剂
公开(公告)号：US06482994B2
公开(公告)日：2002-11-19
申请号：US09485139
申请日：2000-02-02
申请人： William Michael Scheper , Mark Robert Sivik
发明人： William Michael Scheper , Mark Robert Sivik
IPC分类号： C07C4311
CPC分类号： C11D1/721 , C08G65/22 , C08G65/2609
摘要： Ether-capped poly(oxyalkylated) alcohol surfactants having superior grease cleaning abilities and improved spotting/filming benefits are provided. The alcohol surfactants have the formula: R1O[CH2CH(R3)O]x[CH2]kCH(OH)[CH2]jOR2 wherein R1 is linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having from 1 to 30 carbon atoms; R2 is linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having from 6 to 30 carbon atoms; R3 is H, or a linear aliphatic hydrocarbon radical having from 1 to 4 carbon atoms; x is an integer having an average value from 1 to 40, wherein when x is 2 or greater R3 may be the same or different and k and j are integers having an average value of from 1 to 12; further wherein when x is 15 or greater and R3 is H and methyl, at least four of R3 are methyl, further wherein when x is 15 or greater and R3 includes H and from 1 to 3 methyl groups, then at least one R3 is ethyl, propyl or butyl, further wherein R2 can optionally be alkoxylated, wherein said alkoxy is selected from ethoxy, propoxy, butyloxy and mixtures thereof.
摘要翻译：提供了具有优异的油脂清洁能力和改善的点样/成膜效益的具有醚封端的聚（烷氧基化）醇表面活性剂。醇表面活性剂具有下式：其中R 1是具有1至30个碳原子的直链或支链，饱和或不饱和的脂族或芳族烃基; R2是具有6至30个碳原子的直链或支链，饱和或不饱和的脂族或芳族烃基; R3是H或具有1至4个碳原子的直链脂族烃基; x是平均值为1至40的整数，其中当x为2或更大时，R 3可以相同或不同，k和j为平均值为1至12的整数; 进一步其中当x为15或更大且R 3为H和甲基时，R 3中的至少4个为甲基，此外，当x为15或更大且R 3包括H和1至3个甲基时，则至少一个R 3为乙基丙基或丁基，其中R 2可任选地被烷氧基化，其中所述烷氧基选自乙氧基，丙氧基，丁氧基及其混合物。

40. 发明授权

US06429342B1 Polymerization of ethylene oxide using metal cyanide catalysts 失效
标题翻译：使用金属氰化物催化剂聚合环氧乙烷
公开(公告)号：US06429342B1
公开(公告)日：2002-08-06
申请号：US09611499
申请日：2000-07-07
申请人： Katherine S. Clement , Louis L. Walker , Richard M. Wehmeyer , Robert H. Whitmarsh , David C. Molzahn , William P. Dianis , David E. Laycock
发明人： Katherine S. Clement , Louis L. Walker , Richard M. Wehmeyer , Robert H. Whitmarsh , David C. Molzahn , William P. Dianis , David E. Laycock
IPC分类号： C07C4311
CPC分类号： B01J27/26 , B01J37/0223 , C08G65/2615 , C08G65/2663 , C08G65/2693 , C08G65/2696
摘要： Ethoxylations of various initiator compounds are performed in the presence of metal cyanide catalysts. The catalysts surprisingly form a wide variety of polyether products that in most cases contain only small amounts of high molecular weight poly(ethylene oxide).
摘要翻译：各种引发剂化合物的乙氧基化在金属氰化物催化剂的存在下进行。催化剂令人惊奇地形成多种聚醚产物，其在大多数情况下仅含有少量的高分子量聚（环氧乙烷）。

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