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    • 38. 发明授权
    • Process for the preparation of percarboxylic acid solutions
    • 过羧酸溶液的制备方法
    • US4344897A
    • 1982-08-17
    • US102817
    • 1979-12-13
    • Ralf GoedeckeWilli HofenHermann SeifertGerd Siekmann
    • Ralf GoedeckeWilli HofenHermann SeifertGerd Siekmann
    • C07C67/00C07C407/00C07C409/24C07C409/26C07C179/00B01D3/36
    • C07C407/003C07C407/00
    • In a process for the continuous preparation of pure organic solutions of percarboxylic acids having 2 to 5 carbon atoms, by(a) contacting aqueous hydrogen peroxide with a carboxylic acid containing 2 to 5 carbon atoms in the presence of an acid catalyst at a feed molar ratio of H.sub.2 O.sub.2 to carboxylic acid of 0.5:1 to 30:1,(b) isolating an extract essentially containing the percarboxylic acid and possibly the corresponding carboxylic acid not converted in stage (a), by extracting the reaction mixture obtained according to stage (a) with an organic solvent,(c) treating the extract with water or an aqueous solution in an extraction unit provided with one to ten theoretical separation stages and(d) dehydrating the solution of the percarboxylic acid and organic solvent obtained according to (c), by azeotropic distillation,the improvement wherein the organic phase of the top product of the azeotropic distillation, obtained during the dehydration according to (d), is entirely or partially recycled to stage (c) and/or entirely or partially recycled to stage (b).
    • 在连续制备具有2至5个碳原子的过羧酸的纯有机溶液的方法中,通过(a)在酸催化剂存在下,在进料摩尔浓度下使过氧化氢水与含2-5个碳原子的羧酸接触 H 2 O 2与羧酸的比例为0.5:1至30:1,(b)通过提取根据阶段(a)获得的反应混合物,分离基本上含有过羧酸的萃取物和可能的(a)阶段未转化的相应羧酸, (c)用有机溶剂处理提取物,(c)在提供有1到10个理论分离阶段的提取单元中用水或水溶液处理提取物,和(d)使根据(c)获得的过羧酸和有机溶剂的溶液脱水 ),通过共沸蒸馏,其中根据(d)在脱水期间获得的共沸蒸馏的顶部产物的有机相完全或部分地回收 循环到阶段(c)和/或完全或部分地循环到阶段(b)。