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    • 35. 发明授权
    • Process for production of ammonium thiosulphate
    • 硫代硫酸铵生产工艺
    • US6159440A
    • 2000-12-12
    • US227058
    • 1999-01-07
    • Peter Schoubye
    • Peter Schoubye
    • C01B17/62C01B17/64C01B21/093C01C20060101C01C1/00C01C1/24
    • C01B17/64
    • A process for continuous production of ammonium thiosulphate from H.sub.2 S, SO.sub.2, and NH.sub.3 comprising steps of producing in a first absorption step a solution of ammonium hydrogen sulphite by contacting a first gas stream comprising S0.sub.2 with NH.sub.3 and an aqueous solution comprising ammonium hydrogen sulphite in one or more absorbers connected in series and withdrawing a vent gas from one of the absorbers, passing the solution produced in the first absorption step to a second absorption step in which a second gas stream comprising H.sub.2 S is contacted with NH.sub.3 and an aqueous solution of ammonium thiosulphate thereby producing a solution being rich in ammonium thiosulphate.
    • 一种用于从H 2 S,SO 2和NH 3连续生产硫代硫酸铵的方法,包括以下步骤:在第一吸收步骤中通过使包含SO 2的第一气流与NH 3和含有亚硫酸氢铵的水溶液在一个 或更多的吸收器,并且将从第一吸收步骤中产生的溶液通过第二吸收步骤,其中将包含H 2 S的第二气流与NH 3和硫代硫酸铵的水溶液接触, 从而产生富含硫代硫酸铵的溶液。
    • 38. 发明授权
    • Catalysts
    • 催化剂
    • US3644216A
    • 1972-02-22
    • US85143469
    • 1969-08-19
    • UGINE KUHLMANN
    • EGALON ROGERTELLA RAMIRO
    • B01J23/78B01J37/00C01C20060101C01C1/04B01J11/40
    • C01C1/0411B01J23/78B01J37/00B01J37/0009Y02P20/52
    • This invention relates to a method of preparing iron-promoted catalysts in a pelletized form for the synthesis of ammonia which comprises the steps of fusing a mixture consisting essentially of iron oxides of the approximate composition of magnetite together with additional oxides of promoter metals in a total proportion of the oxides of promoter metals of from about 1 percent to about 10 percent, rapidly cooling the fusion product, grinding the fusion product to give fine, regular granules, reducing substantially completely the fused granules, coarsely grinding the reduced fused granules, agglomerating the coarsely ground product into pellets by simple compression and recovering said catalyst in a pelletized form. The invention also relates to the catalysts so produced.
    • 本发明涉及一种制备用于合成氨的造粒形式的铁促进催化剂的方法,该方法包括以下步骤:将基本上由氧化铁组成的混合物组成的磁铁矿的大致组成与另外的助催化剂金属氧化物 促进剂金属氧化物的比例为约1%至约10%,快速冷却熔融产物,研磨熔融产物以得到精细的规则颗粒,基本上完全还原熔融颗粒,粗磨研磨还原的熔融颗粒,将 通过简单的压缩将粗磨产物转化成颗粒,并以成粒形式回收所述催化剂。 本发明还涉及如此生产的催化剂。