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31. 发明授权

US3607843A Process for making poly (phenylene sulfide) polymers of increased molecular weight 失效
标题翻译：制备增加分子量的聚（苯乙烯）聚合物的方法
公开(公告)号：US3607843A
公开(公告)日：1971-09-21
申请号：US3607843D
申请日：1969-05-16
申请人： PHILLIPS PETROLEUM CO
发明人： VIDAURRI FERNANDO C
IPC分类号： C08G75/02 , C08G75/06 , C08G23/00
CPC分类号： C08G75/0286 , C08G75/0254 , C08G75/0295 , Y02P20/582
摘要： The inherent viscosity of poly(phenylene sulfide) polymers is substantially increased and the range narrowed by recycling to the reactor as one of the reaction ingredients previously produced poly(phenylene sulfide) polymer.

32. 发明申请

US20160200874A1 POLYARYLENE SULFIDE RESIN AND MANUFACTURING METHOD THEREFOR, POLY(ARYLENE SULFONIUM SALT) AND MANUFACTURING METHOD THEREFOR, AND SULFOXIDE 有权
标题翻译：聚亚烷基磺酸树脂及其制备方法，聚（亚乙基磺酸盐）及其制备方法及其制备方法
公开(公告)号：US20160200874A1
公开(公告)日：2016-07-14
申请号：US14915974
申请日：2014-09-02
申请人： DIC CORPORATION , NATIONAL UNIVERSITY CORPORATION IWATE UNIVERSITY
发明人： Hajime Watanabe , Takashi Furusawa , Satoshi Ogawa , Toshikazu Takata
IPC分类号： C08G75/14 , C07C317/22 , C07C321/30
CPC分类号： C08G75/0272 , C07C317/22 , C07C321/30 , C07C323/65 , C08G75/0286 , C08G75/12 , C08G75/14
摘要： The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: reacting a sulfoxide represented by the following formula (1) with a particular aromatic compound to obtain a poly(arylenesulfonium salt) having a particular constitutional unit; and dealkylating or dearylating the poly(arylenesulfonium salt) to obtain a polyarylene sulfide resin having a particular constitutional unit, wherein R1 represents an alkyl group having 1 to 10 carbon atoms, etc.; Ar1 and Ar2 each independently represent an arylene group optionally having a substituent; and Z represents a direct bond, etc.
摘要翻译：本发明涉及一种聚芳硫醚树脂的制造方法，其特征在于，将下述式（1）表示的亚砜与特定的芳香族化合物反应，得到具有特定的结构单元的聚（芳基亚磺酸盐）并使聚（芳基亚磺酸盐）脱烷基化或脱芳基化，得到具有特定结构单元的聚芳硫醚树脂，其中R1表示碳原子数1〜10的烷基等。 Ar 1和Ar 2各自独立地表示任选具有取代基的亚芳基; Z表示直接键合等。

33. 发明申请

US20150064609A1 IONOMERS WITH IONIC GROUPS IN THE SIDE CHAIN 审中-公开
标题翻译：离子在侧链上的离子组
公开(公告)号：US20150064609A1
公开(公告)日：2015-03-05
申请号：US14293904
申请日：2014-11-12
申请人： Thomas Häring , Rima Häring
发明人： Thomas Häring , Jochen Kerres , Martin Hein
IPC分类号： B01J39/18 , H01M8/02 , C08J5/22
CPC分类号： B01J39/185 , B01D67/0006 , B01D67/0093 , B01D71/68 , B01D71/82 , B01D2325/16 , B01J39/19 , C08G65/48 , C08G75/0286 , C08J5/2231 , C08J5/2256 , C08J2365/02 , C08J2381/06 , H01M8/0289 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , H01M2300/0082 , Y02E60/523 , Y02P70/56
摘要： Ionomers and ionomer membranes, consisting of a non-fluorinated or partly fluorinated non-, partly or fully-aromatic main chain and a non- or partly-fluorinated side chain with ionic groups or their non-ionic precursors, have a positive impact on the proton conductivity of the ionomers. Various processes produce these polymeric proton conductors.
摘要翻译：由非氟化或部分氟化的非部分或完全芳族主链和具有离子基团或其非离子前体的非或部分氟化的侧链组成的离聚物和离子交联聚合物膜对离聚物的质子电导率。各种方法产生这些聚合物质子导体。

34. 发明申请

US20120245237A1 IONOMERS WITH IONIC GROUPS IN THE SIDE CHAIN 失效
标题翻译：离子在侧链上的离子组
公开(公告)号：US20120245237A1
公开(公告)日：2012-09-27
申请号：US13330614
申请日：2011-12-19
申请人： Thomas Häring , Jochen Kerres , Martin Hein
发明人： Thomas Häring , Jochen Kerres , Martin Hein
IPC分类号： B01J39/18
CPC分类号： B01J39/185 , B01D67/0006 , B01D67/0093 , B01D71/68 , B01D71/82 , B01D2325/16 , B01J39/19 , C08G65/48 , C08G75/0286 , C08J5/2231 , C08J5/2256 , C08J2365/02 , C08J2381/06 , H01M8/0289 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , H01M2300/0082 , Y02E60/523 , Y02P70/56
摘要： Ionomers and ionomer membranes with the ionic group on a flexible side chain have a positive impact on the proton conductivity of the ionomers. Various processes produce these polymeric proton conductors.
摘要翻译：在柔性侧链上具有离子基团的离子聚合物和离聚物膜对离聚物的质子传导性具有积极的影响。各种方法产生这些聚合物质子导体。

35. 发明申请

US20100075196A1 Polymer Electrolyte, Membrane Electrode Assembly and Fuel Cell 有权
标题翻译：聚合物电解质，膜电极组件和燃料电池
公开(公告)号：US20100075196A1
公开(公告)日：2010-03-25
申请号：US12565463
申请日：2009-09-23
申请人： Katsuyuki Kishi
发明人： Katsuyuki Kishi
IPC分类号： H01M8/10 , C08G75/00
CPC分类号： C08G75/0286 , C08G75/23 , C08J5/2275 , C08J2381/06 , H01B1/122 , H01M8/04291 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1088 , Y02P70/56
摘要： The present invention easily provides a polymer electrolyte that exhibits high proton conductivity under low humidity conditions and has a high level of durability and mechanical strength. The polymer electrolyte is produced by mixing proton-conducting sulfonated polyethersulfone C1, sulfonated polyphenylene sulfide C2 or sulfonated poly(4-phenoxybenzoyl-1,4-phenylene) C3 having a sulfonic acid group A as a protic acid group with 1,4-benzenedimethanol B as a crosslinking agent having a methylol group and heat-treating the mixture so that a reaction can be carried out. The polymer electrolyte includes a plurality of proton-conducting sulfonated polyethersulfone moieties C chemically bonded at their aromatic ring moieties other than the sulfonic acid group A to one another through a residue B′ of 1,4-benzenedimethanol.
摘要翻译：本发明容易提供在低湿度条件下具有高质子传导性并且具有高水平的耐久性和机械强度的聚合物电解质。聚合物电解质通过将具有磺酸基A作为质子酸的质子传导磺化聚醚砜C1，磺化聚苯硫醚C2或磺化聚（4-苯氧基苯甲酰基-1,4-亚苯基）C3与1,4-苯二甲醇 B作为具有羟甲基的交联剂，并对该混合物进行热处理以进行反应。聚合物电解质包括多个质子传导的磺化聚醚砜部分C，其通过1,4-苯二甲醇的残基B'在它们之外的芳族环部分以其磺酸基团A之间化学键合。

36. 发明申请

US20090233142A2 POLYMER HAVING OXOCARBON GROUP, AND USE THEREOF 审中-公开
标题翻译：具有OXOCARBON集团的聚合物及其用途
公开(公告)号：US20090233142A2
公开(公告)日：2009-09-17
申请号：US11568086
申请日：2006-10-19
申请人： Ken Yoshimura
发明人： Ken Yoshimura
IPC分类号： C08G85/00 , H01M8/10 , C08J5/20
CPC分类号： H01M4/926 , C08G65/48 , C08G75/0286 , C08J5/2256 , C08J2371/12 , C08J2381/02 , H01B1/122 , H01M4/92 , H01M8/1007 , H01M8/1027 , H01M8/1032 , H01M8/1067
摘要： Disclosed is a polymer having an oxocarbon group represented by the general formula (1). This polymer having an oxocarbon group is useful as a polymer electrolyte as the material for proton conductive membranes in solid polymer fuel cells which use a gas fuel such as a hydrogen gas or a liquid fuel such as methanol or dimethyl ether.
摘要翻译：公开了具有由通式（1）表示的氧碳基团的聚合物。具有氧碳基的聚合物可用作固体聚合物燃料电池中使用气体燃料如氢气或液体燃料如甲醇或二甲醚的质子传导膜的材料的聚合物电解质。

37. 发明授权

US5312880A Production processes of arylene thioether oligomer and copolymer 失效
标题翻译：亚芳基硫醚低聚物和共聚物的生产工艺
公开(公告)号：US5312880A
公开(公告)日：1994-05-17
申请号：US113471
申请日：1993-08-30
申请人： Hiroyuki Sato , Mitsuru Hoshino , Yukichika Kawakami
发明人： Hiroyuki Sato , Mitsuru Hoshino , Yukichika Kawakami
IPC分类号： C08G63/688 , C08G75/02 , C08G75/06 , C08F283/00 , C08G75/14
CPC分类号： C08G75/0286 , C08G63/688
摘要： Disclosed herein are a process for the preparation of a carboxylated arylene thioether oligomer, in which an alkali metal sulfide is caused to act on a poly(arylene thioether) so as to depolymerize the poly(arylene thioether), thereby preparing an alkali thiolate-containing oligomer, and a carboxylating agent is then caused to act on the alkali thiolate-containing oligomer, thereby forming the carboxylated arylene thioether oligomer, and a process for the production of an arylene thioether copolymer, wherein the carboxylated arylene thioether oligomer alone, which has been obtained in accordance with this preparation process, or a mixture of the carboxylated oligomer in an amount of at least 50 wt. % and another carboxylic compound in an amount less than 50 wt. % is reacted with an alkylenediol or an alkylenediol and a polyester or an alkylene diol and a lactone.
摘要翻译：本文公开了一种制备羧基化亚芳基硫醚低聚物的方法，其中使碱金属硫化物作用于聚（亚芳基硫醚）以使聚（亚芳基硫醚）解聚，从而制备含硫醇盐的碱然后使低聚物和羧化剂作用于含有含硫醇盐的低聚物，从而形成羧基化亚芳基硫醚低聚物，以及生产亚芳基硫醚共聚物的方法，其中单独的羧化亚芳基硫醚低聚物已经被根据该制备方法获得，或羧化低聚物的混合物的量为至少50wt。％和另一种少于50wt。％的羧酸化合物。％与亚烷基二醇或亚烷基二醇和聚酯或亚烷基二醇和内酯反应。

38. 发明授权

US4820801A Polyphenylene sulfide containing covalently bonded chlorine in a reduced amount 失效
标题翻译：含有共价键合氯的聚苯硫醚减少量
公开(公告)号：US4820801A
公开(公告)日：1989-04-11
申请号：US924915
申请日：1986-10-29
申请人： Hiroshi Inoue , Toshikazu Kato , Masaaki Otsuru , Noriaki Emura
发明人： Hiroshi Inoue , Toshikazu Kato , Masaaki Otsuru , Noriaki Emura
IPC分类号： C08G75/02 , C08K5/37 , C08G75/14
CPC分类号： C08G75/0286 , C08G75/0281 , C08K5/37
摘要： A highly modified polyphenylene sulfide (hereinafter refer to as "PPS") which contains covalently bonded chlorine in a far less amount than conventional PPS's and is substantially free from ionically bonded chlorine and sodium, is produced by heat-treating a conventional PPS with at least one of organic, sulfur-containing compounds in a solvent capable of dissolving the PPS. Such a PPS is very useful as a coating or encapsulating material for electrical and electronic components, etc.
摘要翻译：通过将常规PPS至少具有热处理的方法制造出高度改性的聚苯硫醚（以下称为“PPS”），其含有远低于常规PPS的共价键，并且基本上不含离子键合氯和钠在能够溶解PPS的溶剂中的有机，含硫化合物之一。这样的PPS作为用于电气和电子部件等的涂层或封装材料是非常有用的

39. 发明授权

US4440915A Stabilized polyphenylene sulfide and method for producing same 失效
标题翻译：稳定的聚苯硫醚及其制备方法
公开(公告)号：US4440915A
公开(公告)日：1984-04-03
申请号：US443861
申请日：1982-11-22
申请人： Toshiyuki Asakura , Hiroaki Kobayashi , Yukio Noguchi
发明人： Toshiyuki Asakura , Hiroaki Kobayashi , Yukio Noguchi
IPC分类号： C08G75/02 , C08G75/06 , C08F283/00
CPC分类号： C08G75/0236 , C08G75/0213 , C08G75/0231 , C08G75/0286
摘要： A stabilized polyphenylene sulfide is provided which comprises a recurring unit ##STR1## wherein the average n between foreign units is greater than about 5, and about 0.05 to about 10 mole % per phenylene sulfide unit of an aromatic constituent chemically bonded with said polyphenylene sulfide chain, said aromatic constituent containing an electron attractive group selected from the group consisting of --SO.sub.2 --, --CO--, --NO.sub.2, --SO.sub.3 R, --COOR, wherein R is H, lower aliphatic hydrocarbon groups, aromatic hydrocarbon groups or alkaline metals, and --CONH--, and said stabilized polyphenylene sulfide has a melting point in the range of about 250.degree. C. to about 350.degree. C. Also provided is a method for preparing stabilized polyphenylene sulfide comprising preparing a polyphenylene sulfide consisting mainly of a recurring unit ##STR2## wherein the degree of polymerization of said recurring unit is greater than about 20, and reacting said polyphenylene sulfide with about 0.05 to about 20 mole % per said phenylene sulfide unit of a halogenated aromatic compound having an electron attractive group.
摘要翻译：提供了一种稳定的聚苯硫醚，其包含重复单元，其中外来单元之间的平均n大于约5至约10摩尔％，每个苯硫醚单元与所述聚苯硫醚链化学键合的芳族组分所述芳族成分含有选自-SO 2 - ， - CO - ， - O 2，-SO 3 R，-COOR的吸电子基团，其中R是H，低级脂族烃基，芳族烃基或碱金属，和 -CONH-，所述稳定化的聚苯硫醚的熔点在约250℃至约350℃的范围内。还提供了制备稳定的聚苯硫醚的方法，包括制备主要由重复单元组成的聚苯硫醚， IMAGE>其中所述重复单元的聚合度大于约20，并且使所述聚苯硫醚与约0.05至约20摩尔％具有吸电子基团的卤代芳族化合物的苯硫醚单元。

40. 发明授权

US3395132A Method for crosslinking polyphenylene sulfide resins 失效
标题翻译：交联聚苯硫醚树脂的方法
公开(公告)号：US3395132A
公开(公告)日：1968-07-30
申请号：US61079367
申请日：1967-01-23
申请人： DOW CHEMICAL CO
发明人： SMITH HARRY A
IPC分类号： C08G75/02
CPC分类号： C08G75/0286 , Y10S277/944

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