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31. 发明授权

US4647621A Thermoplastic molding material 失效
标题翻译：热塑性成型材料
公开(公告)号：US4647621A
公开(公告)日：1987-03-03
申请号：US625689
申请日：1984-06-28
申请人： Juergen Pohrt , Ruediger Matern , Helmut Jenne , Hermann Gausepohl , Karl Gerberding
发明人： Juergen Pohrt , Ruediger Matern , Helmut Jenne , Hermann Gausepohl , Karl Gerberding
IPC分类号： C08L53/02 , C08L5/00 , C08L5/04
CPC分类号： C08L53/02 , Y10S525/905
摘要： A thermoplastic molding material comprises copolymers I and II.Copolymer I is a high-impact (graft) copolymer which is derived from a monovinyl-aromatic monomer and a polymer or copolymer predominantly containing polymerized 1,3-diene units, and is present in a proportion of 0.1-1.0% by weight, based on the molding material.Copolymer II is a block copolymer with star-shaped branching, ie. a radial block copolymer, having an average of more than two branches per molecule. It is substantially derived from 55-80% by weight of a monovinyl-aromatic monomer and 20-45% by weight of a 1,3-diene monomer.The molding material may contain conventional assistants and is used for the production of blown film.
摘要翻译：热塑性成型材料包括共聚物I和II。共聚物I是衍生自单乙烯基 - 芳族单体和主要含有聚合的1,3-二烯单元的聚合物或共聚物的高冲击（接枝）共聚物，并且以按重量计为0.1-1.0％在成型材料上。共聚物II是具有星形分支的嵌段共聚物，即每个分子平均具有多于两个分支的径向嵌段共聚物。其基本上衍生自单乙烯基 - 芳族单体的55-80重量％和1,3-二烯单体的20-45重量％。成型材料可以包含常规助剂，并且用于生产吹塑薄膜。

32. 发明授权

US4567232A Continuous preparation of rubber-modified polymers of vinyl-aromatics 失效
标题翻译：连续制备乙烯基芳烃的橡胶改性聚合物
公开(公告)号：US4567232A
公开(公告)日：1986-01-28
申请号：US650568
申请日：1984-09-13
申请人： Adolf Echte , Hermann Gausepohl , Juergen Hambrecht , Karl Gerberding
发明人： Adolf Echte , Hermann Gausepohl , Juergen Hambrecht , Karl Gerberding
IPC分类号： C08F2/02 , C08F2/06 , C08F279/02 , C08F291/02
CPC分类号： C08F279/02 , C08F291/02
摘要： A process for the continuous preparation of rubber-modified polymers of vinyl-aromatics, wherein a mixture which contains a monomeric aromatic vinyl compound and from 3 to 30% by weight, based on the monomer, of an elastomeric polymer, with or without a solvent, is polymerized, in the presence of a free radical initiator and in the presence or absence of a mercaptan as chain transfer agent, at from 80.degree. to 180.degree. C., with stirring, in a cascade of two or more isothermally operated reaction zones and of one or more additional reaction zones which can be operated isothermally or with a rising temperature profile in such a way that the residence time of the reactants in the first reaction zone is .ltoreq.35 minutes. The polymer obtained is freed from vinyl-aromatic monomer, and from any solvent, in a devolatilization zone. The product is useful for the production of injection moldings.
摘要翻译：用于连续制备乙烯基芳族化合物的橡胶改性聚合物的方法，其中含有单体芳族乙烯基化合物和基于单体的3-30重量％的弹性体聚合物的混合物，具有或不具有溶剂在存在自由基引发剂的情况下，在作为链转移剂的硫醇存在或不存在下，在80-180℃下，在搅拌下，在两个或更多个等温操作的反应区的级联中聚合以及一个或多个另外的反应区，其可以等温或以升高的温度曲线操作，使得反应物在第一反应区中的停留时间为35分钟。获得的聚合物在脱挥发分区域中不含乙烯基芳族单体和任何溶剂。该产品可用于生产注射成型品。

33. 发明授权

US4412037A Thermoplastic molding materials 失效
标题翻译：热塑性成型材料
公开(公告)号：US4412037A
公开(公告)日：1983-10-25
申请号：US302040
申请日：1981-09-14
申请人： Franz Brandstetter , Adolf Echte , Hermann Gausepohl , Herbert Naarmann
发明人： Franz Brandstetter , Adolf Echte , Hermann Gausepohl , Herbert Naarmann
IPC分类号： C08L25/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08L61/04
CPC分类号： C08L51/04 , C08L71/123
摘要： Thermoplastic molding materials based on styrene polymers which have been made impact-resistant and on polyphenylene ethers, wherein the particles of the soft component of the styrene polymer which has been made impact-resistant have a mean diameter of more than 1 micron, and wherein the proportion of particles which have a diameter of less than 0.6 micron is not less than 40% by weight and the proportion of particles which have a diameter of from 0.6 to 3 microns is less than 3% by weight.
摘要翻译：基于已经制成抗冲击性的苯乙烯聚合物和聚苯醚的热塑性成型材料，其中已经制成抗冲击性的苯乙烯聚合物的软组分的颗粒具有大于1微米的平均直径，并且其中直径小于0.6微米的颗粒的比例不小于40重量％，直径为0.6至3微米的颗粒的比例小于3重量％。

34. 发明授权

US4330641A Impact-resistant thermoplastic molding materials with improved stress-cracking resistance 失效
标题翻译：耐冲击热塑性成型材料具有改善的耐应力开裂性
公开(公告)号：US4330641A
公开(公告)日：1982-05-18
申请号：US204527
申请日：1980-11-06
申请人： Adolf Echte , Hermann Gausepohl , Helmut Jenne , Hans Mittnacht
发明人： Adolf Echte , Hermann Gausepohl , Helmut Jenne , Hans Mittnacht
IPC分类号： C08F255/06 , C08F279/02 , C08F279/04 , C08F279/06
CPC分类号： C08F255/06 , C08F279/02
摘要： Thermoplastic molding materials which contain a copolymer which has been made impact-resistant with a rubber. The copolymer is produced by polymerizing a mixture of a monovinyl-aromatic compound and an acrylic acid derivative or methacrylic acid derivative in the presence of a rubber. The folding materials contain a specific proportion of soft component. The diameter of the particles of the soft component, and the swelling index of the soft component, lie within a specific range, and the tensile strength of the molding material is higher than the yield strength.
摘要翻译：含有已经用橡胶抗冲击的共聚物的热塑性成型材料。共聚物通过在橡胶存在下聚合单乙烯基 - 芳族化合物和丙烯酸衍生物或甲基丙烯酸衍生物的混合物来制备。折叠材料含有特定比例的软组分。软组分的颗粒直径和软组分的溶胀指数在特定范围内，成型材料的拉伸强度高于屈服强度。

35. 发明授权

US4200702A Self-extinguishing thermoplastic molding compositions 失效
标题翻译：自熄性热塑性成型组合物
公开(公告)号：US4200702A
公开(公告)日：1980-04-29
申请号：US912358
申请日：1978-06-05
申请人： Hermann Gausepohl , Herbert Naarmann , Klaus Penzien , Rudolf Stephan
发明人： Hermann Gausepohl , Herbert Naarmann , Klaus Penzien , Rudolf Stephan
IPC分类号： C08L25/12 , C08L25/18 , C08L51/04 , C08L55/02 , C08L51/00
CPC分类号： C08L25/12 , C08L51/04 , C08L55/02 , C08L25/18
摘要： Thermoplastic molding compositions based on rubber-modified styrene-acrylonitrile copolymers containing a halogenated styrene oligomer as the effective flame-proofing agent which is sufficiently heat-stable, does not interfere with processing on conventional machinery, does not corrode or cause coatings on such machinery, and has virtually no adverse effect on the impact strength of the polymers. The flameproofing agent as a rule has a degree of polymerization of from 3 to 200 and can be incorporated into the polymer by conventional methods; the polymer may or may not contain additional synergistic agents and processing auxiliaries, which are incorporated in the conventional manner and in the conventional amounts.
摘要翻译：含有卤代苯乙烯低聚物作为充分热稳定性的有效阻燃剂的橡胶改性苯乙烯 - 丙烯腈共聚物的热塑性模塑组合物不影响常规机械的加工，不会在这种机械上腐蚀或引起涂层，并且对聚合物的冲击强度几乎没有不利影响。通常防火剂的聚合度为3〜200，可以通过常规方法加入到聚合物中; 聚合物可以包含或可以不含有以常规方式和常规量掺入的其它协同剂和加工助剂。

36. 发明授权

US06916885B2 Method for breaking a chain during anionic polymerisation 失效
标题翻译：在阴离子聚合过程中断链的方法
公开(公告)号：US06916885B2
公开(公告)日：2005-07-12
申请号：US10399228
申请日：2001-10-26
申请人： Konrad Knoll , Hermann Gausepohl , Josef Richard Wünsch , Paul Naegele , Jürgen Koch
发明人： Konrad Knoll , Hermann Gausepohl , Josef Richard Wünsch , Paul Naegele , Jürgen Koch
IPC分类号： C08F2/38 , C08F12/00 , C08F12/08
CPC分类号： C08F12/08 , C08F2/42
摘要： A process for the preparation of linear polymers or block copolymers of styrene by anionic polymerization comprises carrying out the chain termination with an n-alkyl glycidyl ether or a dialkyl ketone.
摘要翻译：通过阴离子聚合制备苯乙烯的线性聚合物或嵌段共聚物的方法包括用正烷基缩水甘油醚或二烷基酮进行链终止。

37. 发明授权

US06369160B1 Polymer mixtures comprised of styrene polymers 有权
标题翻译：由苯乙烯聚合物组成的聚合物混合物
公开(公告)号：US06369160B1
公开(公告)日：2002-04-09
申请号：US09623179
申请日：2000-08-29
申请人： Konrad Knoll , Norbert Niessner , Josef Wünsch , Hermann Gausepohl
发明人： Konrad Knoll , Norbert Niessner , Josef Wünsch , Hermann Gausepohl
IPC分类号： C08L5302
CPC分类号： C08J5/18 , C08J2325/06 , C08J2353/02 , C08L25/06 , C08L53/02 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2666/24 , C08L2666/04
摘要： Polymer mixtures comprise P1) from 1 to 85% by weight of an elastomeric block copolymer which has been built up from hard blocks S made from vinylaromatic monomers and from random soft blocks B/S made up from dienes and from vinylaromatic monomers, and which contains at least the block structure S-B/S-S, where the diene content is less than 50 percent by weight and the proportion of the soft phase formed from the blocks B/S is at least 60 percent by weight, based in each case on the entire block copolymer, P2) from 5 to 89% by weight of a block copolymer differing from P1) and made from vinylaromatic monomers and from dienes, P3) from 10 to 94% by weight of glass-clear or impact-modified polystyrene or mixtures thereof, and P4) from 0 to 84% by weight of other additives, where the total of components P1) to P4) is 100%.
摘要翻译：聚合物混合物包含1至85重量％的弹性体嵌段共聚物，其由由乙烯基芳族单体制成的硬块S和由二烯和乙烯基芳族单体组成的无规软嵌段B / S构成，并且其包含至少块结构SB / SS，其中二烯含量小于50重量％，并且由块B / S形成的软相的比例为至少60重量％，基于每种情况下在整个嵌段共聚物，P2）5至89重量％的不同于P1的嵌段共聚物，并由乙烯基芳族单体和二烯制成P3）10至94重量％的玻璃透明或冲击改性的聚苯乙烯或其混合物，和P 4 ）0〜84重量％的其他添加剂，其中组分P1）至P4的总量）为100％。

38. 发明授权

US06346572B1 Impact-resistant molding compound made of styrene polymers 失效
标题翻译：由苯乙烯聚合物制成的耐冲击模塑料
公开(公告)号：US06346572B1
公开(公告)日：2002-02-12
申请号：US08981424
申请日：1997-12-23
申请人： Wolfgang Loth , Konrad Knoll , Hermann Gausepohl
发明人： Wolfgang Loth , Konrad Knoll , Hermann Gausepohl
IPC分类号： C08L2508
CPC分类号： C08F287/00 , C08L25/02 , C08L53/02 , C08L2666/24
摘要： A molding material as based on from 60 to 98% by weight of a hard matrix A comprising polymerized or copolymerized units of at least one vinylaromatic monomer or at least one vinylaromatic monomer and at least one polar comonomer and from 2 to 40% by weight, the percentages in each case being based on the molding material comprising A and B, of a soft phase B formed from a hydrogenated or unhydrogenated block copolymer prepared by anionic polymerization and comprising a vinylaromatic monomer V and a diene D, having at least one random or quasi-random block (V/D) of vinylaromatic monomer and diene and containing from 10 to 80% by weight, based on the soft phase B, of occlusions of matrix material (a) formed during the polymerization of the hard matrix A in the presence of the block rubber, and said molding material is used for the production of films, sheets or moldings.
摘要翻译：基于60至98重量％的包含至少一种乙烯基芳族单体或至少一种乙烯基芳族单体和至少一种极性共聚单体的聚合或共聚单元和2至40重量％的硬质基质A的成型材料，每种情况下的百分比均基于包含A和B的由通过阴离子聚合制备的包含乙烯基芳族单体V和二烯D的氢化或未氢化嵌段共聚物形成的软相B的模塑材料，所述乙烯基芳族单体V和二烯D具有至少一个随机或乙烯基芳族单体和二烯的准随机嵌段（V / D）和基于软相B含有10至80重量％的基质材料（a）在硬质基体A的聚合过程中形成的闭塞块状橡胶的存在和所述成型材料用于制造薄膜，片材或模制品。

39. 发明授权

US6162866A Thermoplastic molding compositions based on star polymers with thermoplastic elastomers and polyarylene ethers 失效
标题翻译：基于具有热塑性弹性体和聚亚芳基醚的星形聚合物的热塑性模塑组合物
公开(公告)号：US6162866A
公开(公告)日：2000-12-19
申请号：US372809
申请日：1999-08-12
申请人： Josef Wunsch , Konrad Knoll , Hermann Gausepohl
发明人： Josef Wunsch , Konrad Knoll , Hermann Gausepohl
IPC分类号： C08F293/00 , C08K5/00 , C08L53/00 , C08L51/00
CPC分类号： C08L53/00
摘要： Thermoplastic molding compositions comprise:______________________________________ A) from 20 to 96% by weight of star polymers obtainable by polymerizing vinylaromatic monomers with a branched monomer building block which contains at least two vinylaromatic functions, B) from 3 to 50% by weight of copolymers comprising vinylaromatic monomers, 1,1-diphenylethylene and, if desired, dienes, C) from 1 to 15% by weight of polyarylene ethers, D) from 0 to 5% by weight of nucleating agents, E) from 0 to 5% by weight of antioxidants, F) from 0 to 5% by weight of stabilizers, and G) from 0 to 50% by weight of fibrous or particulate fillers. ______________________________________
摘要翻译：热塑性成型组合物包含：A）20至96重量％的星形聚合物，可通过将乙烯基芳族单体与含有至少两个乙烯基芳族官能团的支链单体结构单元聚合而获得，B）3至50％共聚物的重量包括 - 乙烯基芳族单体，1,1-二苯基乙烯，以及如果需要的话，二烯，-C）1至15重量％的聚亚芳基醚， - D）0-5重量％的成核剂， - E）0至5重量％的抗氧化剂， - F）0至5重量％的稳定剂， - 和 - G）0至50重量％的纤维或颗粒填料。 -

40. 发明授权

US6143847A Method for preparing (co) polymers by metal-free anionic polymerization in the presence of a phosphonium cation containing at least one annellated aromatic ring 失效
标题翻译：在含有至少一个环形芳环的鏻阳离子存在下通过无金属阴离子聚合制备（共）聚合物的方法
公开(公告)号：US6143847A
公开(公告)日：2000-11-07
申请号：US827906
申请日：1997-04-07
申请人： Thieo E. Hogen-Esch , Dimo K. Dimov , Stephan Jungling , Volker Warzelhan , Hermann Gausepohl
发明人： Thieo E. Hogen-Esch , Dimo K. Dimov , Stephan Jungling , Volker Warzelhan , Hermann Gausepohl
IPC分类号： C07F9/54 , C08F2/00 , C08F4/00
CPC分类号： C07F9/5442 , C08F4/00
摘要： The present invention concerns a novel method for preparing polymers (preferably (meth)acrylate polymers and copolymers) having a narrow molecular weight distribution by metal-free anionic polymerization in the presence of a phosphonium cation containing at least one annellated aromatic ring as substituent on the phosphorous atom.
摘要翻译：本发明涉及一种制备具有窄分子量分布的聚合物（优选（甲基）丙烯酸酯聚合物和共聚物）的新方法，其通过无金属阴离子聚合在含有至少一个环状芳环作为取代基的鏻阳离子存在下磷原子。

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