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    • 31. 发明授权
    • N-(2-nitrophenyl)-N-pyrimidin-2-ylureas
    • N-(2-硝基苯基)-N-嘧啶-2-基脲
    • US4999046A
    • 1991-03-12
    • US333377
    • 1989-04-05
    • Hermann Rempfler
    • Hermann Rempfler
    • A01N47/36C07D239/42
    • C07D239/42
    • The present invention relates to novel N-(2-nitrophenyl)-N-pyrimidin-2-ylureas having a herbicidal and plant growth-regulating activity, to agrochemical compositions containing those substances as active ingredients, to the use of the novel ureas for controlling weeds or for regulating plant growth, and to processes for the preparation of the novel compounds. The invention also relates to novel intermediates and to processes for the preparation thereof.The novel compounds correspond to formula I ##STR1## in which R.sup.1 is hydrogen, methyl, fluorine, chlorine or bromine,R.sup.2 is C.sub.1 -C.sub.2 haloalkyl having at least 2 fluorine atoms, andR.sup.3 is C.sub.1 -C.sub.4 alkyl,with the proviso that R.sup.2 is not trifluoromethyl when R.sup.3 is methyl.
    • 本发明涉及具有除草和植物生长调节活性的新型N-(2-硝基苯基)-N-嘧啶-2-基脲,含有这些物质作为活性成分的农用化学组合物,用于新颖的脲用于控制 杂草或调节植物生长,以及制备新化合物的方法。 本发明还涉及新型中间体及其制备方法。 所述新化合物对应于其中R 1为氢,甲基,氟,氯或溴的式I(I),R 2为具有至少2个氟原子的C 1 -C 2卤代烷基,且R 3为C 1 -C 4烷基,条件是 当R 3为甲基时,R 2不是三氟甲基。
    • 33. 发明授权
    • Microbicidal and growth-regulating compositions
    • 杀菌和生长调节组合物
    • US4758670A
    • 1988-07-19
    • US567998
    • 1984-01-04
    • Urs MullerHermann RempflerHans Tobler
    • Urs MullerHermann RempflerHans Tobler
    • A01N43/50A01N43/653C07D233/60C07D249/08C07D405/06C07D521/00A01N43/64
    • C07D231/12A01N43/50A01N43/653C07D233/56C07D249/08
    • Fluoroazolylpropane derivatives of the formula I ##STR1## are described, in which Az is imidazolyl or triazolyl, R.sup.1 is hydrogen, alkyl or aralkyl which is unsubstituted or substituted by halogen, alkyl, alkoxy, halogenoalkyl, nitro, cyano, carboxyl or alkoxycarbonyl, R.sup.2 is C.sub.1 -C.sub.10 -alkyl which is unsubstituted or substituted by alkoxy, aralkoxy or phenyl, it being possible for the aromatic nuclei of aralkoxy and phenyl in turn to be unsubstituted or substituted by halogen, alkyl, alkoxy, halogenoalkyl, cyano, carboxyl or alkoxycarbonyl, R.sup.3 is hydrogen, alkyl, alkylcarbonyl or aralkyl which is unsubstituted or substituted by halogen, alkoxy, alkyl, halogenoalkyl, cyano, carboxyl or alkoxycarbonyl, R.sup.5 is an unsubstituted or monosubstituted or polysubstituted radical selected from the series comprising C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, phenyl, naphthyl, biphenyl, benzylphenyl, benzyloxyphenyl, phenoxyphenyl and aralkyl, and X is oxygen or sulfur; including the acid addition salts, quaternary azolium salts and metal complexes.Methods of preparing these products are also disclosed, as are agrochemical compositions containing one of these compounds as the active substance. A process for controlling phytopathogenic microorganisms and/or for regulating plant growth by means of these substances is also described.
    • 描述了式I的氟唑基丙烷衍生物,其中Az是咪唑基或三唑基,R1是氢,未被取代或被卤素,烷基,烷氧基,卤代烷基,硝基,氰基,羧基或烷氧基羰基取代的烷基或芳烷基,R2 是未被取代或被烷氧基,芳烷氧基或苯基取代的C 1 -C 10 - 烷基,芳烷氧基和苯基的芳族核可能是未被取代的或被卤素,烷基,烷氧基,卤代烷基,氰基,羧基或烷氧基羰基 R 3是未取代的或被卤素,烷氧基,烷基,卤代烷基,氰基,羧基或烷氧基羰基取代的烷基,烷基,烷基羰基或芳烷基,R 5是未取代的或单取代的或多取代的基团,其选自包括C 1 -C 8烷基, C 3 -C 8 - 环烷基,C 3 -C 6 - 烯基,C 3 -C 6炔基,苯基,萘基,联苯基,苄基苯基,苄氧基苯基,苯氧基苯基和芳烷基,X是氧或硫; 包括酸加成盐,季铵盐和金属络合物。 还公开了制备这些产物的方法,以及含有这些化合物之一作为活性物质的农药组合物。 还描述了通过这些物质控制植物病原微生物和/或调节植物生长的方法。
    • 35. 发明授权
    • Triazolylalkenes as fungicides and plant growth regulants
    • 三唑基烯烃作为杀真菌剂和植物生长调节剂
    • US4497647A
    • 1985-02-05
    • US466825
    • 1983-02-16
    • Alfred MeyerWalter KunzLudwig MaierHermann Rempfler
    • Alfred MeyerWalter KunzLudwig MaierHermann Rempfler
    • A01N43/653A01N47/06A01N47/12C07D233/60C07D249/08C07D521/00C07F9/6518A01N43/50A01N43/64
    • C07D231/12A01N43/653C07D233/56C07D249/08C07F9/65181
    • The invention relates to novel azolyl-olefin derivatives of the general formula I ##STR1## wherein R.sub.1 is an azolyl group,R.sub.2 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.4 alkyl substituted by unsubstituted or substituted phenyl, C.sub.1 -C.sub.4 alkoxycarbonyl or C.sub.2 -C.sub.6 alkenyl, or is C.sub.3 -C.sub.8 cycloalkyl which is substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl groups,R.sub.3 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl which is substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl groups, or is the --C(R.sub.4)(R.sub.5)--[CH(R.sub.4)].sub.n --X--R.sub.6 group, wherein n is 0 or 1 andR.sub.4 and R.sub.5, each independently of the other, are hydrogen or C.sub.1 -C.sub.4 alkyl,X is oxygen or sulfur,R.sub.6 is a radical selected from the group consisting of C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, phenyl, naphthyl, biphenyl, benzylphenyl, benzoxyphenyl, phenoxyphenyl and aralkyl, which radical is substituted by one or more of halogen, cyano, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.5 alkoxy, C.sub.1 -C.sub.5 haloalkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 haloalkylthio, nitro, --COOR.sub.7 or --CON(R.sub.8)(R.sub.9), whereinR.sub.7 is C.sub.1 -C.sub.4 alkyl andR.sub.8 and R.sub.9, each independently of the other, are hydrogen or C.sub.1 -C.sub.4 alkyl, and the acid addition salts quaternary azolium salts and metal complexes thereof.The invention also describes methods of preparing these compounds as well as agrochemical compositions which contain one of said compounds as active ingredient. The invention further describes a method of controlling phytopathogenic microorganisms and/or of regulating plant growth which comprises the use of the novel compounds.
    • 本发明涉及通式Ⅰ(I)的新的唑基 - 烯烃衍生物,其中R1是唑基,R2是C1-C12烷基,C3-C8环烷基,被未取代或取代的苯基取代的C1-C4烷基,C1-C4烷氧基羰基 或C 2 -C 6烯基,或者是被1至4个C 1 -C 4烷基取代的C 3 -C 8环烷基,R 3是C 1 -C 12烷基,被1至4个C 1 -C 4烷基取代的C 3 -C 8环烷基,或者是-C )(R5) - [CH(R4)] nX-R6基团,其中n为0或1,R4和R5各自独立地为氢或C1-C4烷基,X为氧或硫,R6为自由基 选自C 1 -C 8烷基,C 3 -C 8环烷基,C 3 -C 6烯基,C 3 -C 6炔基,苯基,萘基,联苯基,苄基苯基,苯氧基苯基,苯氧基苯基和芳烷基,该基团被一个或多个卤素,氰基, C 1 -C 4烷基,C 1 -C 5烷氧基,C 1 -C 5卤代烷氧基,C 1 -C 3烷硫基,C 1 -C 3卤代烷基,C 1 -C 3卤代烷硫基,硝基,-COOR 7或-CON(R 8)(R 9) 9,各自独立地是氢或C 1 -C 4烷基,和酸加成盐季氮鎓盐及其金属络合物。 本发明还描述了制备这些化合物的方法以及含有所述化合物之一作为活性成分的农药组合物。 本发明还描述了一种控制植物病原微生物和/或调节植物生长的方法,其包括使用新化合物。
    • 37. 发明授权
    • Process for the manufacture of compounds containing vinyl groups
    • US4096154A
    • 1978-06-20
    • US673316
    • 1976-04-05
    • Hermann RempflerHans BosshardKurt Weber
    • Hermann RempflerHans BosshardKurt Weber
    • C07C309/29C07D307/91C07D333/46C09B69/06A01N9/00
    • C07D307/91C07C303/32C07D333/46C09B69/06
    • A novel process for the production of compounds of the formulaA--CH.dbd.CH--D--CH.dbd.CH--A.sub.1 (I)wherein A and A.sub.1, independently of one another, denote phenyl, naphthyl, diphenylyl, 2-phenyl-1,2,3-triazol-4-yl or pyridyl, it being possible for A and A.sub.1 to contain non-chromophoric substituents, and D denotes 4,4'-diphenylylene, 1,5- or 2,6-naphthylene, or a 9,10-dihydrophenanthrene or dibenzofurane radical which is bonded to the vinylene groups in the 2,7-position, which comprises reacting in a first stage a compound of the formulaX--CH.sub.2 --D--CH.sub.2--X (II)wherein X denotes halogen, especially chlorine or bromine, hydroxyl or a group ##STR1## wherein X.sub.1 represents an aliphatic cycloaliphatic or aromatic hydrocarbon radical, especially alkyl having 1 to 6 carbon atoms, or phenyl, and D has the indicated meaning, in a strongly acid medium, in a molar ratio of at least 1:2, with an organic sulphide containing 5 to 8 ring members, of the formula ##STR2## wherein B represents a polymethylene group of 4 to 7 methylene groups and wherein one of these methylene groups can be replaced by a hetero-atom and wherein these methylene groups can also contain alkyl groups with 1 to 4 carbon atoms as substituents, to give a sulphonium salt of the formula ##STR3## wherein M represents the anion of the strong acid used and n denotes the numbers 1 or 2; reacting, in a second stage, the resulting sulphonium salt with 2 mols of an aldehyde of the formulaA--CHO (V)orA.sub.1 --CHO (VI)or their mixture, in the presence of strong bases, in a strongly polar, protic or aprotic, water-miscible solvent to give a diepoxide of the formula ##STR4## and subjecting in a 3rd stage, the diepoxide of the formula (VII), thus obtained, to a reduction according to processes which are in themselves known for the reduction of epoxides with elimination of the epoxide oxygen and formation of vinylene groups.
    • 38. 发明授权
    • Microbicidal and growth regulating compositions
    • 杀菌和生长调节组合物
    • US4940481A
    • 1990-07-10
    • US468522
    • 1983-02-22
    • Urs MullerHans ToblerHermann RempflerAlfred Meyer
    • Urs MullerHans ToblerHermann RempflerAlfred Meyer
    • A01N43/50A01N43/653C07D233/60C07D249/08C07D521/00
    • C07D231/12A01N43/50A01N43/653C07D233/56C07D249/08
    • The invention relates to azolylpropane derivatives of the general formula I ##STR1## wherein R.sub.1 is an azolyl group,R.sub.2 and R.sub.3, each independently of the other, is hydrogen, alkyl, alkenyl, alkynyl, aralkyl, cyanoalkyl or alkoxycarbonylalkyl, and one of R.sub.2 and R.sub.3 always has a meaning other than hydrogen,R.sub.4 is C.sub.3 -C.sub.8 cycloalkyl, unsubstituted or substituted by alkyl; unsubstituted or substituted phenyl; or is C.sub.1 -C.sub.10 alkyl, unsubstituted or substituted by phenyl or substituted phenyl,R.sub.5 is an unsubstituted or a mono- or polysubstituted radical selected from the group consisting of C.sub.1 -C.sub.8 alky, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, phenyl, naphthyl, biphenyl, benzylphenyl, benzyloxyphenyl, phenoxyphenyl and aralkyl,R.sub.6 is hydrogen, alkyl or alkyl substituted by cyano, alkoxy or alkoxycarbonyl, or is an unsubstituted or substituted radical selected from the group consisting of alkylcarbonyl, phenylcarbonyl, carbamoyl, aralkyl, alkoxycarbonyl, alkylsulfonyl, phenylsulfonyl or sulfamoyl, andX is oxygen or sulfur,including the acid addition salts, quaternary azolium salts and metal complexes thereof.The invention further discloses methods of preparing these compounds as well as agrochemical compositions which contain one of said compounds as active component. The invention relates further to a method of controlling phytopathogenic microorganisms and/or of regulating plant growth with the compounds of formula I.
    • 本发明涉及通式Ⅰ(I)的吡唑基丙烷衍生物,其中R 1是唑基,R 2和R 3各自独立地是氢,烷基,烯基,炔基,芳烷基,氰基烷基或烷氧羰基烷基,和 R2和R3中的一个总是具有除氢之外的含义,R4是未被取代或被烷基取代的C3-C8环烷基; 未取代或取代的苯基; 或未被取代或被苯基或取代的苯基取代的C1-C10烷基,R5是未取代的或选自C1-C8烷基,C3-C8环烷基,C3-C6链烯基,C3-C6炔基,苯基, 萘基,联苯基,苄基苯基,苄氧基苯基,苯氧基苯基和芳烷基,R6是氢,被氰基,烷氧基或烷氧基羰基取代的烷基或烷基,或是选自烷基羰基,苯基羰基,氨基甲酰基,芳烷基,烷氧基羰基, 烷基磺酰基,苯基磺酰基或氨磺酰基,X是氧或硫,包括酸加成盐,季氮鎓盐及其金属络合物。 本发明还公开了制备这些化合物的方法以及含有所述化合物之一作为活性组分的农用化学组合物。 本发明还涉及用式I化合物控制植物病原微生物和/或调节植物生长的方法。
    • 39. 发明授权
    • Herbicidal epoxides
    • 除草环氧化物
    • US4849007A
    • 1989-07-18
    • US934298
    • 1986-11-24
    • Hermann RempflerWalter Kunz
    • Hermann RempflerWalter Kunz
    • A01N43/20C07D303/32
    • A01N43/20C07D303/32
    • The invention relates to a herbicidal and plant growth regulating composition which contains as active ingredient a 2-benzoyl-2-phenyloxirane of formula I; ##STR1## wherein each of m and n independently of the other is 0, 1, 2 or 3 and each of R and R' independently of the other is a halogen atom, a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl or C.sub.1 -C.sub.4 haloalkoxy group or the nitro or cyano group or a phenoxy group which is substituted by (R).sub.m, in the form of a racemate or an optically active enantiomer.Some oxiranes are known as intermediates for the preparation of fungicides and others are novel. The herbicidal composition has selective action in rice crops and is active against grasses.
    • 本发明涉及含有式I的2-苯甲酰基-2-苯基环氧乙烷作为活性成分的除草和植物生长调节组合物; (I)其中m和n彼此独立地为0,1,2或3,R和R'各自独立地为卤原子,C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4卤代烷基或C 1 -C 4卤代烷氧基或硝基或氰基或被(R)m取代的外消旋体或光学活性对映异构体形式的苯氧基。 一些环氧乙烷被称为制备杀真菌剂的中间体,而另一些则是新的。 除草组合物在水稻作物中具有选择性作用,并且对草有活性。