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31. 发明授权

US07879916B2 Hydrolysis resistant organomodified silylated ionic surfactants 有权
标题翻译：耐水解的有机改性的硅烷化离子表面活性剂
公开(公告)号：US07879916B2
公开(公告)日：2011-02-01
申请号：US11953167
申请日：2007-12-10
申请人： Mark D. Leatherman , George A. Policello , Wenqing Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： Mark D. Leatherman , George A. Policello , Wenqing Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： C09K3/00 , C07F7/08 , C07F7/04
CPC分类号： A61Q19/00 , A01N25/30 , A61K8/585 , C07F7/081 , C10G33/04 , C11D3/162 , D21C3/28 , D21H17/59 , D21H19/32 , D21H21/12
摘要： The present invention provides for a composition comprising a silane having the formula: (R1)(R2)(R3)Si—R4—Si(R5)(R6)(R7) wherein R1, R2, R3, R5, and R6 are each independently selected from the group consisting of 1 to 6 monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 7 to 10 carbons containing an aryl group; R4 is a hydrocarbon group of 1 to 3 carbons; R7 comprises an anionic, cationic or zwitterionic substituent. The silanes of the present invention exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：本发明提供一种组合物，其包含具有下式的（R 1）（R 2）（R 3）Si-R 4 -Si（R 5）（R 6）（R 7）的硅烷，其中R 1，R 2，R 3，R 5和R 6各自为独立地选自1至6个一价烃基，芳基和含有芳基的7至10个碳的烃基; R4是1〜3个碳原子的烃基; R7包含阴离子，阳离子或两性离子取代基。本发明的硅烷在宽的pH范围内表现出抗水解性。

32. 发明申请

US20110021644A1 HYDROLYSIS RESISTANT ORGANOMODIFIED TRISILOXANE IONIC SURFACTANTS 失效
标题翻译：耐水溶性有机硅氧烷离子表面活性剂
公开(公告)号：US20110021644A1
公开(公告)日：2011-01-27
申请号：US12810976
申请日：2008-12-26
申请人： Mark D. Leatherman , George A. Policello , Wenging N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajarman , Xia Zijun
发明人： Mark D. Leatherman , George A. Policello , Wenging N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajarman , Xia Zijun
IPC分类号： C09K3/00
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C11D3/3738 , C11D3/3742
摘要： The present invention provides for a composition comprising a siloxane having the formula: M1DM2 wherein M1=(R1)(R2)(R3)SiO1/2; M2=(R4)(R5)(R6)SiO1/2 and D=(R7)(Z)SiO2/2 where R1, R2, R3 R4, R5, R6 and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R8-RA, R9 Rc and R10-RZ; RA being an anionic substituent, Rc a cationic substituent or Rz a zwitterionic substituent on the D group wherein the composition is resistant to hydrolysis under either basic or acidic conditions.
摘要翻译：本发明提供包含具有下式的硅氧烷的组合物：M1DM2其中M1 =（R1）（R2）（R3）SiO1 / 2; M2 =（R4）（R5）（R6）SiO1 / 2和D =（R7）（Z）SiO2 / 2其中R1，R2，R3 R4，R5，R6和R7各自独立地选自1〜 4碳一价烃基，芳基和含有芳基的4至9个碳的烃基; Z是选自R8-RA，R9Rc和R10-RZ的侧链亲水性离子基团; RA为阴离子取代基，Rc为阳离子取代基或Rz为D基团上的两性离子取代基，其中所述组合物在碱性或酸性条件下对水解具有抗性。

33. 发明申请

US20110021460A1 SELECTIVE HYDROSILYLATION METHOD AND PRODUCT 审中-公开
标题翻译：选择性氢化方法和产品
公开(公告)号：US20110021460A1
公开(公告)日：2011-01-27
申请号：US12891886
申请日：2010-09-28
申请人： David D. Farris , Chauncey J. Rinard , Mark D. Leatherman
发明人： David D. Farris , Chauncey J. Rinard , Mark D. Leatherman
IPC分类号： A01N55/10 , C07F7/08 , A01P3/00 , A01P7/04
CPC分类号： C08G77/38 , C08G77/46 , Y10S424/10
摘要： An asymmetric siloxane is made by reacting a silicone having the formula MHDxM′H where MH is R1R2HSiO1/2, M′H is R4R5HSiO1/2 and x is an integer 0≦x≦10 under selective hydrosilylation conditions in the presence of a precious metal hydrosilylation catalyst, with a first olefinic compound and in a second step, a monohydridosiloxane produced in the first step is reacted under hydrosilylating conditions with another olefinic compound different from the first olefinic compound.
摘要翻译：通过在贵金属存在下，在选择性氢化硅烷化条件下使具有式MHDxM'H的硅酮，其中MH为R1R2HSiO1 / 2，M'H为R4R5HSiO1 / 2，x为0和n1E; x和n1E为10，氢化硅烷化催化剂与第一烯属化合物反应，在第二步中，在氢化硅烷化条件下使第一步生产的单氢硅氧烷与另一种不同于第一种烯烃化合物的烯属化合物反应。

34. 发明申请

US20110015075A1 HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE IONIC SURFACTANTS 审中-公开
公开(公告)号：US20110015075A1
公开(公告)日：2011-01-20
申请号：US12834548
申请日：2010-07-12
申请人： Mark D. Leatherman , George A. Policello , Wenqing Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： Mark D. Leatherman , George A. Policello , Wenqing Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： A01N55/10 , C07F7/18 , A01N25/00 , A61K8/58 , A01P7/04 , A01P3/00 , A01P7/02 , A01P11/00 , A61Q9/02 , A61Q19/08 , A61Q1/02 , A61Q3/00 , C09D5/00 , C05F11/00
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C08G77/388 , C08G77/46 , C11D3/3738 , C11D3/3742
摘要： An asymmetric organomodified disiloxane surfactant having the formula: MM′ wherein M comprises branched hydrocarbon substituents and M′ comprises a cationic, anionic or zwitterionic substituent and a polyether substituent that may be combined as one moiety, wherein the disiloxane surfactant has an enhanced resistance to hydrolysis between a pH of about 3 to about 12.

35. 发明申请

US20110011308A1 HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE IONIC SURFACTANTS 有权
标题翻译：水解抗坏血酸的离子表面活性剂
公开(公告)号：US20110011308A1
公开(公告)日：2011-01-20
申请号：US12810967
申请日：2008-12-26
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Xia Zijun
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Xia Zijun
IPC分类号： C07F7/18 , C09D7/12
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C08G77/388 , C08G77/46 , C11D3/3738 , C11D3/3742
摘要： An asymmetric organomodified disiloxane surfactant having the formula: MM′ wherein M comprises branched hydrocarbon substituents and M′ comprises a cationic, anionic or zwitterionic substituent and a polyether substituent that may be combined as one moiety, wherein the disiloxane surfactant has an enhanced resistance to hydrolysis between a pH of about 3 to about 12.
摘要翻译：具有下式的不对称有机改性二硅氧烷表面活性剂：其中M包含支链烃取代基，M'包含阳离子，阴离子或两性离子取代基和可以作为一个部分结合的聚醚取代基，其中二硅氧烷表面活性剂具有增强的抗水解性在约3至约12的pH之间。

36. 发明授权

US07700797B2 Use of hydrolysis resistant organomodified silylated surfactants 有权
标题翻译：使用耐水解的有机改性的甲硅烷基化表面活性剂
公开(公告)号：US07700797B2
公开(公告)日：2010-04-20
申请号：US11419634
申请日：2006-05-22
申请人： Mark D. Leatherman , Wenqing Peng , George A. Policello , Suresh K. Rajaraman , Roland Wagner , Zijun Xia
发明人： Mark D. Leatherman , Wenqing Peng , George A. Policello , Suresh K. Rajaraman , Roland Wagner , Zijun Xia
IPC分类号： C07F7/04 , C07F7/08
CPC分类号： A61K8/894 , A01N25/30 , A61Q19/00 , C09D7/45 , C11D3/3738
摘要： Organomodified silylated surfactant compositions that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：在宽pH范围内表现出抗水解性的有机改性的甲硅烷基化表面活性剂组合物。

37. 发明授权

US07652072B2 Hydrolysis resistant organomodified disiloxane surfactants 有权
标题翻译：耐水解的有机改性的二硅氧烷表面活性剂
公开(公告)号：US07652072B2
公开(公告)日：2010-01-26
申请号：US11427913
申请日：2006-06-30
申请人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaraman
发明人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaraman
IPC分类号： B01F3/00
CPC分类号： A61K8/894 , A61Q15/00 , A61Q19/00 , C07F7/0838 , Y10S516/906
摘要： Compositions comprising an asymmetric disiloxane surfactant composition comprising a silicone composition comprising a silicone having the formula: MM′ where M or M′ comprises an alkylpolyalkyleneoxide bearing substituent selected from the group consisting of: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 and R12SiR5R6(R13(C2H4O)a(C3H6O)b(C4H8O)cR14) that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：包含不对称二硅氧烷表面活性剂组合物的组合物，其包含硅氧烷组合物，其包含具有下式的MM的硅氧烷，其中M或M'包含带有取代基的烷基聚环氧烷烃，所述取代基选自：R 13（C 2 H 4 O）a（C 3 H 6 O）b（C 4 H 8 O）c R 14 和在宽pH范围内表现出抗水解性的R12SiR5R6（R13（C2H4O）a（C3H6O）b（C4H8O）cR14）。

38. 发明申请

US20090247649A1 Compositions using evaporable silicone carriers for cosmetics, cleaning and care product compositions 审中-公开
标题翻译：用于化妆品，清洁和护理产品组合物的可蒸发硅胶载体的组合物
公开(公告)号：US20090247649A1
公开(公告)日：2009-10-01
申请号：US12455737
申请日：2009-06-04
申请人： Suresh K. Rajaraman , Mark D. Leatherman , Roy U. Rojas-Wahl , John S. Razzano
发明人： Suresh K. Rajaraman , Mark D. Leatherman , Roy U. Rojas-Wahl , John S. Razzano
IPC分类号： A61K8/89 , C11D3/37
CPC分类号： A61K8/585 , A61Q5/02 , A61Q5/12 , A61Q17/04 , A61Q19/00
摘要： This invention describes cosmetic, cleaning and care products compositions made using an evaporable siloxane liquid support or carrier having the molecular formula: MvM′wDxTyQz where the subscripts may have the following values: x=0, 1, 2, 3, or 4; y=0. 1, or 2; z=0, 1, 2, 3, or 4; and v and w may be zero or a positive integer subject to the limitation that v+w≧1 where the components are defined as follows: M=(R1O)a(R2O)bR3cSiO1/2 where the subscripts may have the following values: a=1, 2, or 3; b=0, 1, or 2; c=0, 1, or 2; subject to the limitation that a+b+c=3 except when w+x+y+z=0 then a+b+c=4; M′=(R1O)d(R2O)eR4fSiO1/2 where the subscripts may have the following values: d=1, 2, or 3; e=0, 1, or 2; f=0, 1, or 2; subject to the limitation that d+e+f=3; D=R5R6SiO2/2; T=R7SiO3/2; and Q=SiO4/2; where R1 and R2 are selected from the group of linear or branched monovalent hydrocarbon radicals having from one to eight carbon atoms and where each R3, R4, R5, R6, and R7 is independently selected from the group of monovalent hydrocarbon radicals having from one to sixty carbon atoms; and mixtures thereof.
摘要翻译：本发明描述了使用具有以下分子式的可蒸发硅氧烷液体载体或载体制备的化妆品，清洁和护理产品组合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> MvM'wDxTyQz < ？in-line-formula description =“In-line Formulas”end =“tail”？>其中下标可以具有以下值：x = 0,1,2,3或4; y = 0。 1或2; z = 0,1,2,3或4; 并且v和w可以是零或正整数，其受到v + w> = 1的限制，其中组分定义如下：M =（R1O）a（R2O）bR3cSiO1 / 2其中下标可以具有以下值：a = 1,2或3; b = 0,1或2; c = 0,1或2; 受限于a + b + c = 3，除了当w + x + y + z = 0时，a + b + c = 4; M'=（R1O）d（R2O）eR4fSiO1 / 2其中下标可以具有以下值：d = 1,2或3; e = 0,1或2; f = 0,1或2; 受限于d + e + f = 3; D = R5R6SiO2 / 2; T = R7SiO3 / 2; 和Q = SiO4 / 2; 其中R 1和R 2选自具有1至8个碳原子的直链或支链一价烃基，其中每个R 3，R 4，R 5，R 6和R 7独立地选自具有一个至六十个碳原子; 及其混合物。

39. 发明授权

US07507775B2 Hydrolysis resistant organomodified disiloxane surfactants 有权
标题翻译：耐水解的有机改性的二硅氧烷表面活性剂
公开(公告)号：US07507775B2
公开(公告)日：2009-03-24
申请号：US11300100
申请日：2005-12-13
申请人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaraman
发明人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaraman
IPC分类号： C07F7/08
CPC分类号： A61K8/891 , A61Q15/00 , A61Q19/00 , C07F7/0838
摘要： Disiloxane compounds of the formula MM′ Where M comprises either branched allyl hydrocarbon substituents or silanyl substituents and M′ comprises an alkylpolyalkyleneoxide substituent. The disiloxane compounds of the invention exhibit an enhanced resistance to hydrolysis outside a pH range ranging from 6 to 7.5, and are useful as surfactants.
摘要翻译：式中的二硅氧烷化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> MM'<？in-line-formula description =“In-line Formulas”end =“tail”？ >其中M包含支链烯丙基烃取代基或硅烷基取代基，M'包含烷基聚环氧烷烃取代基。本发明的二硅氧烷化合物在6至7.5的pH范围内具有增强的抗水解性，并且可用作表面活性剂。

40. 发明授权

US07399350B2 Fluorine-free disiloxane surfactant compositions for use in coatings and printing ink compositions 有权
标题翻译：用于涂料和印刷油墨组合物的无氟二硅氧烷表面活性剂组合物
公开(公告)号：US07399350B2
公开(公告)日：2008-07-15
申请号：US11582576
申请日：2006-10-17
申请人： Suresh K. Rajaraman , Alain Lejeune , Alexander Borovik , George A. Policello , Mark D. Leatherman
发明人： Suresh K. Rajaraman , Alain Lejeune , Alexander Borovik , George A. Policello , Mark D. Leatherman
IPC分类号： C09D11/02 , B01F17/54
CPC分类号： C09D183/12 , C09D7/47 , C09D11/0235 , C09D11/03 , C09D11/101 , C08L2666/04 , C08L2666/02 , C08L2666/14
摘要： The present invention relates to coating and printing ink compositions possessing silicone surfactants compositions comprising fluorine-free organomodified disiloxanes which are resistant to hydrolysis between a pH of about 3 to a pH of about 12. The coatings and printing ink composition of the present invention exhibit enhanced wetting, flow and leveling properties.
摘要翻译：本发明涉及具有包含无水有机改性二硅氧烷的硅氧烷表面活性剂组合物的涂料和印刷油墨组合物，其在约3至约pH约12之间的水解条件下具有抗水解性。本发明的涂料和印刷油墨组合物显示出增强的润湿，流动和流平性能。

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