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31. 发明授权

US4695308A Herbicidal substituted 5-amino-1-aryl-pyrazoles 失效
标题翻译：除草取代的5-氨基-1-芳基 - 吡唑
公开(公告)号：US4695308A
公开(公告)日：1987-09-22
申请号：US925845
申请日：1986-10-30
申请人： Reinhold Gehring , Markus Lindig , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Jorg Stetter
发明人： Reinhold Gehring , Markus Lindig , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Jorg Stetter
IPC分类号： A01N57/08 , A01N57/32 , C07F9/6503 , C07F9/6561 , C07F9/65
CPC分类号： C07F9/65037 , A01N57/32
摘要： Herbicidally active substituted 5-amino-1-aryl-pyrazoles of the formula ##STR1## in which R represents hydrogen, cyano, nitro or alkoxycarbonyl,R.sup.1 represents hydrogen or alkyl,R.sup.2 and R.sup.3 independently of one another in each case represent alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl, cycloalkyl, alkoxy or cycloalkoxy, or represent in each case optionally substituted aryl, aryloxy, aralkyl or aralkyloxy,X represents oxygen or sulphur andAr represents in each case optionally substituted phenyl or pyridyl,or salts thereof.
摘要翻译：其中R表示氢，氰基，硝基或烷氧羰基的除草活性取代的5-氨基-1-芳基 - 吡唑，R1代表氢或烷基，R2和R3各自独立地表示烷基，烯基，烷基，卤代烷基，烷氧基烷基，环烷基，烷氧基或环烷氧基，或在每种情况下表示任选取代的芳基，芳氧基，芳烷基或芳烷氧基，X表示氧或硫，Ar表示在任何情况下均为任选取代的苯基或吡啶基或其盐。

32. 发明授权

US4882437A Substituted 5-amino-1-phenylpyrazoles 失效
标题翻译：取代的5-氨基-1-苯基吡唑
公开(公告)号：US4882437A
公开(公告)日：1989-11-21
申请号：US248890
申请日：1988-09-23
申请人： Reinhold Gehring , Erich Klauke , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Erich Klauke , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , A01N20060101 , A01N47/02 , C07C67/00 , C07C253/00 , C07C255/66 , C07D20060101 , C07D231/38 , C07D231/40 , C07D231/44
CPC分类号： C07D231/38 , A01N43/56 , C07C243/00 , C07C255/00 , C07D231/40
摘要： A 5-aminopyrazole of the formula ##STR1## in which R.sup.1 represents alkoxycarbonyl, alkenyloxycarbonyl or alkinyloxycarbonyl, andR.sup.3, R.sup.4, R.sup.5, R.sup.6, and R.sup.7, which are identical or different, represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylsulphonyl, alkoxycarbonyl or a radical --(X)n--R.sup.8 whereinX represents oxygen, sulphur, sulphinyl or sulphyonyl,n represents 0 or 1 andR.sup.8 represents halogenoalkyl, with the proviso that at least one of the radicals R.sup.3, R.sup.4, R.sup.5, R.sup.6 or R.sup.7 represents a radical --(X).sub.n --R.sup.8, and R.sup.1 does not represent cyano if R.sup.1 represents trifluoromethyl,These compounds are intermediates useful in the preparation of herbicidally active substituted 5-acylamino-1-phenylpyrazoles.
摘要翻译：其中R 1表示烷氧基羰基，链烯氧基羰基或烷氧基羰基，R 3，R 4，R 5，R 6和R 7相同或不同的5-氨基吡唑代表氢，卤素，氰基，硝基，烷基，烷氧基，烷基磺酰基，烷氧基羰基或 - （X）n-R8基团，其中X表示氧，硫，亚磺酰基或磺酰基，n表示0或1，R8表示卤代烷基，条件是基团R3，R4，R5中的至少一个，R6或R7表示 - （X）n-R8基团，如果R1表示三氟甲基，则R1不表示氰基。这些化合物是可用于制备除草活性的取代的5-酰基氨基-1-苯基吡唑的中间体。

33. 发明授权

US4791212A 4-Alkenylaminocarbonyl- and 4-alkinylaminocarbonyl-1-phenyl-5-pyrazolamines 失效
标题翻译： 4-烯基氨基羰基和4-链烯基氨基羰基-1-苯基-5-吡唑胺
公开(公告)号：US4791212A
公开(公告)日：1988-12-13
申请号：US947667
申请日：1986-12-30
申请人： Reinhold Gehring , Erich Klauke , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Erich Klauke , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , A01N20060101 , A01N47/02 , C07C67/00 , C07C253/00 , C07C255/66 , C07D20060101 , C07D231/38 , C07D231/40 , C07D231/44
CPC分类号： C07D231/38 , A01N43/56 , C07C243/00 , C07C255/00 , C07D231/40
摘要： A 5-aminopyrazole of the formula ##STR1## in which R.sup.1 represents alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, alkenylaminocarbonyl or alkinylaminocarbonyl andR.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7, which are identical or different, represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylsulphonyl, alkoxycarbonyl or a radical --(X)n--R.sup.8whereinX represents oxygen, sulphur, sulphinyl or sulphonyl,n represents 0 or 1 andR.sup.8 represents halogenoalkyl, with the proviso that at least one of the radicals R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 represents a radical --(X).sub.n --R.sup.8, but R.sup.1 does not represent cyano if R.sup.1 represents trifluoromethyl.These compounds are intermediates useful in the preparation of herbicidally active substituted 5-acylamino-1-phenylpyrazoles.
摘要翻译：其中R 1表示烷氧基羰基，烯氧基羰基，烷氧基羰基，链烯基氨基羰基或烷基氨基羰基的R 5，R 5，R 5，R 6和R 7相同或不同，表示氢，卤素，氰基，硝基，烷基，烷氧基，烷基磺酰基，烷氧基羰基或基团 - （X）n -R 8，其中X表示氧，硫，亚磺酰基或磺酰基，n表示0或1，并且R 8表示卤代烷基，条件是至少一个基团R 3，R 4 ，R 5，R 6和R 7表示基团 - （X）n -R 8，但如果R 1表示三氟甲基，则R 1不表示氰基。这些化合物是可用于制备除草活性的取代的5-酰基氨基-1-苯基吡唑的中间体。

34. 发明授权

US4770692A 4-cyano(nitro)-5-oxy(thio)-pyrazole derivatives, composition containing them, and herbicidal and plant growth regulating methods of using them 失效
标题翻译： 4-氰基（硝基）-5-氧（硫代） - 吡唑衍生物，含有它们的组合物，以及使用它们的除草和植物生长调节方法
公开(公告)号：US4770692A
公开(公告)日：1988-09-13
申请号：US73555
申请日：1987-07-14
申请人： Jorg Stetter , Reinhold Gehring , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Jorg Stetter , Reinhold Gehring , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/18 , C07D231/20 , C07D231/22 , C07D231/26 , C07D401/04 , C07D401/12 , A01N43/40
CPC分类号： C07D401/12 , C07D231/18 , C07D231/20 , C07D231/22 , C07D231/26
摘要： Novel herbicidal and plant-growth regulating pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl or halogenoalkyl,R.sup.2 represents nitro or cyano,R.sup.3 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkinyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl or optionally substituted aryl,Ar represents phenyl which is substituted twice or more, or optionally substituted pyridyl, andY represents O, S, SO or SO.sub.2.Several intermediates therefor are also new.
摘要翻译：新颖的除草和植物生长调节式为“IMAGE”的吡唑，其中R 1表示氢，烷基或卤代烷基，R 2表示硝基或氰基，R 3表示任选取代的烷基，任选取代的烯基，任选取代的炔基，任选取代的环烷基，环烷基烷基，任选取代的芳烷基或任选取代的芳基，Ar表示被取代两次或更多个或任选取代的吡啶基的苯基，Y表示O，S，SO或SO 2。其中的几个也是新的。

35. 发明授权

US4740231A 1-aryl-5-alkoximinoalkylamino-pyrazoles, composition containing them, herbicidal and plant-growth regulating method of using them, and intermediates in the preparation of them 失效
标题翻译： 1-芳基-5-肟基烷基氨基 - 吡唑，含有它们的组合物，除草剂和植物生长调节方法及其制备中间体
公开(公告)号：US4740231A
公开(公告)日：1988-04-26
申请号：US866510
申请日：1986-05-22
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , A01N47/02 , C07D231/38 , C07D401/04 , C07D521/00 , C07D401/14
CPC分类号： C07D231/38 , A01N43/56 , A01N47/02 , C07D231/12 , C07D233/56 , C07D249/08 , C07D401/04
摘要： 1-Aryl-5-alkoximinoalkylamino-pyrazoles of the formula ##STR1## in which R represents cyano or nitro, or represents an optionally substituted heterocyclic radical,R.sup.1 represents hydrogen or alkyl,R.sup.2 represents hydrogen or alkyl, or represents optionally substituted aryl,R.sup.3 represents hydrogen, alkyl or alkenyl, or represents in each case optionally substituted aralkyl or aryl andAr represents optionally substituted phenyl or pyridyl,are active as herbicides and plant growth regulants. Compounds of the formula ##STR2## in which R" has the same definition as R other than cyano, are also active and useful as intermediates as well.
摘要翻译：其中R表示氰基或硝基，或表示任选取代的杂环基，R 1表示氢或烷基，R 2表示氢或烷基，或表示任选取代的芳基，R 3表示任选取代的芳基，或代表任意取代的芳烷基或芳基，Ar表示任意取代的苯基或吡啶基，作为除草剂和植物生长调节剂是有活性的。 R“具有与R不同于氰基的定义相同的式”IMAGE“的化合物也是有活性的并且也用作中间体。

36. 发明授权

US4681618A 1-aryl-5-halo-4-nitopyrazoles, herbicidal compositions containing them, and herbicidal method of using them 失效
标题翻译： 1-芳基-5-卤代-4-硝基吡唑，含有它们的除草组合物和使用它们的除草方法
公开(公告)号：US4681618A
公开(公告)日：1987-07-21
申请号：US816643
申请日：1986-01-06
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/14 , C07D231/16 , C07D231/22 , C07D231/32 , C07D231/38
CPC分类号： C07D231/16
摘要： Herbicidally effective 1-aryl-4-nitropyrazoles of the general formula (I) ##STR1## in which Hal represents halogen,R.sup.1 and R.sup.3 independently of one another represent cyano, nitro, halogen, alkyl, alkoxy, alkoxycarbonyl, halogenoalkyl, halogenoalkoxy or a radial --S(O).sub.n --R.sup.6 andR.sup.2, R.sup.4 and R.sup.5 independently of one another and independently of R.sup.1 and R.sup.3 represent the same radicals as R.sup.1 and R.sup.3, and additionally represent hydrogen,and whereinR.sup.6 represents alkyl, halogenoalkyl, amino, alkylamino or dialkylamino and n-represents the number 0, 1 or 2 are disclosed.
摘要翻译：其中Hal代表卤素，R1和R3彼此独立的通式（I）的除草有效的1-芳基-4-硝基吡唑代表氰基，硝基，卤素，烷基，烷氧基，烷氧基羰基，卤代烷基，卤代烷氧基或径向-S（O）n -R 6和R 2，R 4和R 5彼此独立地且独立地R 1和R 3表示与R 1和R 3相同的基团，并且另外表示氢，并且其中R 6表示烷基，卤代烷基，氨基，烷基氨基或二烷基氨基，n - 表示数字0,1或2。

37. 发明授权

US5104439A Herbicidal agents based on pyrazole derivatives 失效
标题翻译：基于吡唑衍生物的除草剂
公开(公告)号：US5104439A
公开(公告)日：1992-04-14
申请号：US569493
申请日：1990-08-20
申请人： Otto Schallner , Reinhold Gehring , Erich Klauke , Jorg Stetter , Heinz-Jurgen Wroblowsky , Robert R. Schmidt , Hans-Joachim Santel
发明人： Otto Schallner , Reinhold Gehring , Erich Klauke , Jorg Stetter , Heinz-Jurgen Wroblowsky , Robert R. Schmidt , Hans-Joachim Santel
IPC分类号： A01N43/56 , A01N47/02 , A01N47/18 , A01N47/22 , A01N47/36 , A01N53/00 , A01N57/22 , A01N57/24 , C07C67/00 , C07C253/00 , C07C255/66 , C07C317/32 , C07C317/48 , C07C323/48 , C07D231/38 , C07D231/40 , C07F9/40 , C07F9/6509
CPC分类号： C07D231/38 , A01N43/56 , A01N47/02 , A01N47/18 , A01N47/22 , A01N47/36 , A01N53/00 , A01N57/22 , C07D231/40 , C07F9/4015 , C07F9/650935
摘要： Herbicidally active 5-amino-1-phenyl-pyrazoles, most of which are new, of the formula ##STR1##

38. 发明授权

US4810283A Novel 1-aryl-4-nitro-pyrazole herbicides and plant growth regulators, compositions and use 失效
标题翻译：新型1-芳基-4-硝基 - 吡唑除草剂和植物生长调节剂，组合物和用途
公开(公告)号：US4810283A
公开(公告)日：1989-03-07
申请号：US925639
申请日：1986-10-30
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/38 , C07D231/40 , C07D401/04 , C07D231/16
CPC分类号： C07D231/38 , A01N43/56 , C07D401/04
摘要： Novel 1-aryl-4-nitro-pyrazoles which exhibit herbicidal and plant growth-regulating activity of the formula ##STR1## in which R.sup.1 represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl andR.sup.2 represents hydrogen, or represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl, or represents a radical ##STR2## or R.sup.1 and R.sup.2, together with the nitrogen atom to which they are bonded, represent a saturated heterocyclic radical, which can optionally contain further hetero atoms, andAr represents in each case optionally substituted phenyl or pyridyl,whereinX represents oxygen or sulphur andR.sup.3 represents hydrogen, alkyl, alkoxy, alkoxy-alkyl, alkylthio, alkylthioalkyl, alkylamino, di-alkylamino, halogenoalkyl, alkenyl or alkinyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl, or represents optionally substituted aryloxy, or represents optionally substituted arylthio, or represents optionally substituted arylamino,but wherein R.sup.2 only represents hydrogen or a radical ##STR3## if R.sup.1 does not simultaneously represent unsubstituted alkyl or represent alkyl which is substituted by an alkoximino radical.
摘要翻译：表现出式（IMAGE）的除草和植物生长调节活性的新型1-芳基-4-硝基 - 吡唑，其中R 1在每种情况下表示任选取代的烷基，烯基，炔基或环烷基，R 2表示氢，或每个或任选取代的烷基，烯基，炔基或环烷基，或者表示基团，或者R 1和R 2与它们所键合的氮原子一起代表饱和杂环基团，其可以任选地含有其它杂原子，Ar 在每种情况下表示任选取代的苯基或吡啶基，其中X表示氧或硫，R 3表示氢，烷基，烷氧基，烷氧基 - 烷基，烷硫基，烷硫基烷基，烷基氨基，二烷基氨基，卤代烷基，烯基或炔基，或表示任选取代的环烷基或表示任选取代的芳基，或表示任选取代的芳氧基，或表示任选取代的芳硫基，或表示任选的亚芳基取代的芳基氨基，但其中R 2仅代表氢或基团，如果R 1不同时表示未取代的烷基或代表被烷基肟基取代的烷基。

39. 发明授权

US4806144A 5-Sulphonamido-1-aryl-pyrazoles 失效
标题翻译： 5-磺酰氨基-1-芳基 - 吡唑
公开(公告)号：US4806144A
公开(公告)日：1989-02-21
申请号：US817181
申请日：1986-01-08
申请人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/38 , C07D231/42
CPC分类号： C07D231/42
摘要： A 5-sulphonamido-1-aryl-pyrazole of the formula (I) ##STR1## in which R.sup.1 represents hydrogen, nitro, nitroso or halogen,R.sup.2 represents hydrogen, alkyl or a radical R.sup.3 --SO.sub.2 --, or an inorganic or organic cation bonded in the form of a salt,R.sup.3 represents alkyl, alkenyl, cycloalkyl, halogeno-alkyl, hydroxyalkyl, alkoxyalkyl or unsubstituted or substituted aryl,R.sup.4 and R.sup.6 independently of one another represent cyano, nitro, halogen, alkyl, alkoxy, alkoxycarbonyl, halogenoalkyl, halogenoalkoxy or a radical --(O).sub.n --R.sup.9 andR.sup.5, R.sup.7 and R.sup.8 independently of one another and of R.sup.4 and R.sup.6 represent the same radicals as R.sup.4 and R.sup.6, and additionally represent hydrogen,whereinR.sup.9 represents alkyl, halogenoalkyl, amino, alkyl-amino or dialkylamino andn represents the number 0, 1 or 2.Such 5-sulphonamido-1-aryl-pyrazole being useful as a herbicide.
摘要翻译：式（I）的5-磺酰氨基-1-芳基 - 吡唑其中R 1表示氢，硝基，亚硝基或卤素，R 2表示氢，烷基或基团R 3 -SO 2 - 或无机或以盐形式键合的有机阳离子，R 3表示烷基，烯基，环烷基，卤代烷基，羟烷基，烷氧基烷基或未取代或取代的芳基，R 4和R 6彼此独立地表示氰基，硝基，卤素，烷基，烷氧基，烷氧基羰基，卤代烷基，卤代烷氧基或基团 - （O）n -R 9和R 5，R 7和R 8彼此独立地表示，并且R 4和R 6表示与R 4和R 6相同的基团，并且另外表示氢，其中R 9表示烷基，卤代烷基，氨基，烷基 - 氨基或二烷基氨基，n代表数字0,1或2.这种5-磺酰氨基-1-芳基 - 吡唑可用作除草剂。

40. 发明授权

US4772312A 5-amino-1-pyridyl-pyrazoles, composition containing them, and herbicidal method of using them 失效
标题翻译： 5-氨基-1-吡啶基 - 吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4772312A
公开(公告)日：1988-09-20
申请号：US866638
申请日：1986-05-22
申请人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56
摘要： Herbicidally active novel 5-amino-1-pyridyl-pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen or represents alkyl with 1 to 12 carbon atoms,R.sup.2 represents hydrogen, nitro, nitroso or halogen, or represents a radical ##STR2## wherein R.sup.5 represents hydrogen, hydroxyl, alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl or alkylthioalkyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl, or represents alkoxy or alkylthio, or represents optionally substituted aryloxy, or represents optionally substituted arylthio, or represents alkylamino or dialkylamino, or represents optionally substituted arylamino,R.sup.3 represents hydrogen, or represents a radical ##STR3## or represents a radical --S(O).sub.n --R.sup.7, R.sup.4 represents hydrogen, or represents alkyl, or represents a radical ##STR4## or represents a radical --S(O).sub.n --R.sup.7, and, in the case where R.sup.3 represents an --SO.sub.2 --R.sup.7 radical, also represents an inorganic or organic cation bonded in salt form, andR.sup.6 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl or alkylthioalkyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl, or represents alkoxy or alkylthio, or represents optionally substituted aryloxy, or represents optionally substituted arylthio, or represents alkylamino or dialkylamino, or represents optionally substituted arylamino,X represents oxygen or sulphur,n represents the number 0, 1 or 2,R.sup.7 represents alkyl, halogenoalkyl or optionally substituted aryl andPy represents substituted C-linked pyridyl.Some of the intermediates wherein the 5-position of the pyrazole carries a halogen atom are also new.
摘要翻译：其中R1代表氢或代表具有1-12个碳原子的烷基，R2代表氢，硝基，亚硝基或卤素的除草活性的新颖的5-氨基-1-吡啶基吡唑，其中R1代表氢或代表基团或代表任意取代的环烷基，或表示任意取代的芳基，或表示烷氧基或烷硫基，或表示任选取代的芳氧基，或表示任选取代的芳硫基，或表示任选取代的芳硫基，或或表示任选取代的芳基氨基，R 3表示氢，或表示基团，或表示基团-S（O）n -R 7，R 4表示氢，或表示烷基，或表示基团。或表示基团-S（O）n -R 7，并且在R 3表示-SO 2 -R 7基团的情况下，也表示以盐形式键合的无机或有机阳离子，R 6表示代表氢，烷基，烯基，炔基，卤代烷基，烷氧基烷基或烷硫基烷基，或表示任意取代的环烷基，或表示任意取代的芳基，或表示烷氧基或烷硫基，或表示任意取代的芳氧基，或表示任意取代的芳硫基，或表示烷基氨基或二烷基氨基，或表示任选取代的芳基氨基，X表示氧或硫，n表示0,1或2，R7表示烷基，卤代烷基或任意取代的芳基，Py表示取代的C-连接的吡啶基。其中吡唑的5-位带有卤素原子的一些中间体也是新的。

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