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31. 发明专利

JP2013239353A Inorganic magnesium solid electrolyte, magnesium battery, and inorganic magnesium solid electrolyte manufacturing method 有权
标题翻译：无机镁固体电解质，镁电池和无机磁固体电解液制造方法
公开(公告)号：JP2013239353A
公开(公告)日：2013-11-28
申请号：JP2012111899
申请日：2012-05-15
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HIGASHI SHOGO , AOKI MASAKAZU
IPC分类号： H01B1/06 , C01B6/15 , H01B13/00 , H01M4/46 , H01M6/18 , H01M10/054 , H01M10/0562 , H01M12/06
CPC分类号： H01M10/0562 , C01B6/003 , C01B6/15 , C01B21/092 , C01P2002/72 , H01M10/054 , H01M2300/0068
摘要： PROBLEM TO BE SOLVED: To provide a novel inorganic magnesium solid electrolyte for conducting magnesium ions.SOLUTION: A magnesium battery 10 according to the present invention comprises: a positive electrode 12; a negative electrode 14 having a negative electrode active material containing magnesium; and an inorganic magnesium solid electrolyte 16 interposed between the positive electrode 12 and the negative electrode 14, including a compound having a complex ion structure containing magnesium and hydrogen, and conducting magnesium ions. The inorganic magnesium solid electrolyte 16 may contain a compound containing at least one of boron and nitrogen. The inorganic magnesium solid electrolyte may be manufactured a manufacturing method including a heat treatment step of mixing and heating Mg(BH)and Mg(NH), and forming a compound having a complex ion structure containing magnesium and hydrogen.
摘要翻译：要解决的问题：提供用于导电镁离子的新型无机镁固体电解质。解决方案：根据本发明的镁电池10包括：正电极12; 具有含镁的负极活性物质的负极14; 以及插入在正极12和负极14之间的无机镁固体电解质16，包括具有含有镁和氢的复合离子结构的化合物和导电的镁离子。无机镁固体电解质16可以含有含有硼和氮中的至少一种的化合物。可以制造无机镁固体电解质的制造方法，其包括混合和加热Mg（BH）和Mg（NH）的热处理步骤，并形成具有含镁和氢的复合离子结构的化合物。

32. 发明专利

JP2013159852A Hydrogen storage alloy 有权
标题翻译：氢储存合金
公开(公告)号：JP2013159852A
公开(公告)日：2013-08-19
申请号：JP2012025584
申请日：2012-02-08
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： TOWATA SHINICHI , AOKI MASAKAZU , NORITAKE TATSUO , MIWA KAZUTOSHI
IPC分类号： C22C27/02 , B22F1/00 , B22F9/04 , C22C27/06 , C22C30/00
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen storage alloy which can store and release hydrogen near a normal temperature, which has a high rechargeable hydrogen storage capacity, which requires a low cost, and which is excellent in cycle durability.SOLUTION: A hydrogen storage alloy includes a bcc structure phase represented by TiCrVNbFe(1.5≤y/x
摘要翻译：要解决的问题：提供一种能够在常温下储存和释放氢的储氢合金，其具有高的可再充电氢储存能力，这需要低成本，并且循环耐久性优异。解决方案：氢存储合金包括由TiCrVNbFe（1.5≤y/ x <3，15≤z<65,1≤v≤10,0≤w<5和x + y + z + v + w = 100）表示的bcc结构相作为主要阶段 y / x优选在1.6和2.8之间; v优选为1.5〜8.5。

33. 发明专利

JP2014130687A Solid electrolyte, method for producing the same, and electricity storage device 审中-公开
标题翻译：固体电解质，其制造方法和电力存储装置
公开(公告)号：JP2014130687A
公开(公告)日：2014-07-10
申请号：JP2012286550
申请日：2012-12-28
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： AOKI MASAKAZU , NORITAKE TATSUO , ORIMO SHINICHI , MATSUO MOTOAKI
IPC分类号： H01M10/0562 , C01D15/00 , H01B1/06 , H01B13/00 , H01G11/56
摘要： PROBLEM TO BE SOLVED: To provide a solid electrolyte high in ionic conductivity.SOLUTION: In an electricity storage device 20, a conductive layer 22 is formed on a substrate 21, and a positive electrode 24 including a positive electrode active material, a solid electrolyte 26 and a negative electrode 28 including a negative electrode active material are sequentially stacked and formed on the conductive layer 22. A collector lead 23 is connected to the conductive layer 22, and a collector lead 29 is connected to the negative electrode 28. In the electricity storage device 20, the solid electrolyte 26 contains a compound represented by a general formula: LiBNH(1≤x≤3), and contains an M component that is at least one of Co and Ni.
摘要翻译：要解决的问题：提供高离子电导率的固体电解质。解决方案：在蓄电装置20中，在基板21上形成导电层22，并且将正极24包括正极活性物质，固体电解质 26和包含负极活性物质的负极28依次层叠并形成在导电层22上。集电极引线23与导电层22连接，集电极引线29与负极28连接。在蓄电装置20中，固体电解质26含有由通式LiBNH（1≤x≤3）表示的化合物，并含有作为Co和Ni中的至少一种的M成分。

34. 发明专利

JP2011020901A Hydride complex and hydrogen storage material 审中-公开
标题翻译：氢化复合物和氢储存材料
公开(公告)号：JP2011020901A
公开(公告)日：2011-02-03
申请号：JP2009168302
申请日：2009-07-16
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： MATSUMOTO MITSURU , AOKI MASAKAZU , NORITAKE TATSUO , TOWATA SHINICHI
IPC分类号： C01B3/00 , C01B6/04 , C01B6/21 , C01B21/092
CPC分类号： Y02E60/327
摘要： PROBLEM TO BE SOLVED: To provide a new hydride complex from which hydrogen can be extracted even at a temperature of 200°C or lower, and to provide a hydrogen storage material obtained by releasing hydrogen from the hydride complex.
SOLUTION: The hydride complex is obtained by mixing and pulverizing a mixture of a metal borohydride M(BH
4 )
n (where M represents at least one first metal element selected from alkali metals, alkaline earth metals and transition metals, and n represents an oxidation number of M), a metal amide M'(NH
2 )
n' (where M' represents at least one second metal element selected from alkali metals, alkaline earth metals and transition metals, and n' represents an oxidation number of M'), and a metal hydride M''H
n'' (where M'' represents at least one third metal element selected from alkali metals, alkaline earth metals and transition metals, and n'' represents an oxidation number of M''). The hydrogen storage material is obtained by wholly or partially releasing hydrogen included in the hydride complex.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：为了提供即使在200℃或更低的温度也能够提取氢的新的氢化物配合物，并提供通过从氢化物络合物中释放氢获得的储氢材料。解决方案：通过混合和粉碎金属硼氢化物M（BH 4 ） n （其中M表示至少一种第一金属元素选自碱金属，碱土金属和过渡金属，n表示氧化数M），金属酰胺M'（NH SB 2）SB'n'（其中M '表示选自碱金属，碱土金属和过渡金属中的至少一种第二金属元素，n'表示M'的氧化数），金属氢化物M'H n“ （其中M“表示选自碱金属，碱土金属和过渡金属中的至少一种第三金属元素，n”表示M“的氧化数）。通过完全或部分地释放包含在氢化物络合物中的氢气来获得储氢材料。版权所有（C）2011，JPO＆INPIT

35. 发明专利

JP2011011936A Hydride composite and hydrogen storage material 审中-公开
标题翻译：氢化复合材料和氢储存材料
公开(公告)号：JP2011011936A
公开(公告)日：2011-01-20
申请号：JP2009156394
申请日：2009-06-30
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： MATSUMOTO MITSURU , AOKI MASAKAZU , NORITAKE TATSUO , TOWATA SHINICHI
IPC分类号： C01B6/24 , B01J20/02 , C01B3/00 , H01M8/06
CPC分类号： Y02E60/327 , Y02P20/129
摘要： PROBLEM TO BE SOLVED: To provide a novel hydride composite from which hydrogen can be taken out, even at ≤200°C, and a hydrogen storage material that can be obtained by releasing the hydrogen from the hydride composite.SOLUTION: The hydride composite is obtained by mixing and pulverizing a mixture of a metal borohydride M(BH)(wherein M is a first metal element; and n is the oxidation number of M) and a metal aluminum hydride compound M'(AlH)(wherein M' is a second metal element; and n' is the oxidation number of M'). The hydrogen storage material is obtained by releasing all or a portion of the hydrogen contained in the hydride composite.
摘要翻译：要解决的问题：提供即使在≤200℃也可以从其中取出氢的新型氢化物复合物，以及可以通过从氢化物复合物中释放氢而获得的储氢材料。溶液：氢化物复合物通过混合并粉碎金属硼氢化物M（BH）（其中M是第一金属元素; n是M的氧化数）和金属氢化铝化合物M'（AlH）（其中M'是第二金属元素; n'是M'的氧化数）。通过释放氢化物复合材料中所含的全部或一部分氢来获得储氢材料。

36. 发明专利

JP2010265136A Hydride composite, imide material and method for producing hydrogen gas 审中-公开
标题翻译：氢化物复合材料，生产氢气的材料和方法
公开(公告)号：JP2010265136A
公开(公告)日：2010-11-25
申请号：JP2009117054
申请日：2009-05-13
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： AOKI MASAKAZU , MATSUMOTO MITSURU , TOWATA SHINICHI , NORITAKE TATSUO , KITAJIMA SATSUKI , SATO MASAHIRO
IPC分类号： C01B6/24 , C01B3/04 , C01B21/092
CPC分类号： Y02E60/364 , Y02P20/129
摘要： PROBLEM TO BE SOLVED: To provide a hydride composite from which hydrogen can be taken out even at ≤100°C, an imide compound that can be obtained by releasing hydrogen from the hydride composite material, and a method for producing hydrogen gas using the hydride composite. SOLUTION: The hydride composite comprises LiAlH x (NH 2 ) 4-x (wherein x=0 or 1) and LiAlH 4 . The imide material is obtained by releasing all or a portion of hydrogen contained in the hydride composite. The method for producing the hydrogen gas comprises a hydrogen releasing step of releasing hydrogen from the hydride composite. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：为了提供即使在≤100℃也可以取出氢的氢化物复合物，可以通过从氢化物复合材料中释放氢而获得的酰亚胺化合物，以及氢气的制造方法使用氢化物复合材料。解决方案：氢化物复合材料包含LiAlH x SB SB（4）x-x SB（x = 0或1）和LiAlH < SB> 4 。酰亚胺材料是通过释放氢化物复合材料中所含的全部或部分氢而获得的。制造氢气的方法包括从氢化物复合物中释放氢的氢释放步骤。版权所有（C）2011，JPO＆INPIT

37. 发明专利

JP2010236084A Hydrogen storage alloy, method of preparing the same and hydrogen storage device 有权
标题翻译：氢存储合金，其制备方法和氢储存装置
公开(公告)号：JP2010236084A
公开(公告)日：2010-10-21
申请号：JP2009258344
申请日：2009-11-11
申请人： Toyota Central R&D Labs Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： AOKI MASAKAZU , TOWATA SHINICHI , NORITAKE TATSUO , ITO AKIO , WASHIO KOTA , ISHIKIRIYAMA MAMORU
IPC分类号： C22C27/02 , C01B3/00 , C22F1/00 , C22F1/18 , F17C11/00
CPC分类号： C22C27/02 , C01B3/0031 , C22C30/00 , C22F1/18 , Y02E60/327
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen storage alloy having a high initial effective hydrogen amount and excellent cycle durability, and to provide a method of preparing the same, and a hydrogen storage device using such a hydrogen storage alloy. SOLUTION: There are disclosed the hydrogen storage alloy having, as a main phase thereof, a bcc structure phase having a composition represented by Ti x Cr y V z X w , and a hydrogen generator using the alloy. The method of preparing the hydrogen storage alloy includes: a melting/casting process of melting/casting raw materials mixed to be the composition represented by Ti x Cr y V z X w ; a heat treatment process of heat-treating an ingot obtained in the melting/casting process; and an activation process of executing the treatment of storing/releasing hydrogen to the heat-treated ingot at least once, wherein 3/2≤y/x≤3/1, 50≤z≤75 mol%, 0≤x≤5 mol%, (x+y+z+w) is 100 mol%, and X is at least one selected from Al, Si and Fe. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供具有高初始有效氢量和优异的循环耐久性的储氢合金，并提供其制备方法和使用这种储氢合金的储氢装置。解决方案：公开了一种储氢合金，其具有作为其主相的具有由Ti X X V SB表示的组成的bcc结构相＆gt; z＆lt; SB＆gt; w＆lt; / SB＆gt;和使用该合金的氢发生器。制备储氢合金的方法包括：熔融/浇铸原料的熔融/铸造方法，所述原料混合成由Ti X V ž X 瓦特; 在熔融/铸造过程中获得的锭的热处理过程; 以及将经过热处理的锭储存/释放氢的处理进行至少一次的活化处理，其中3 /2≤y/x≤3/1,50≤z≤75摩尔％，0≤x≤5摩尔％，（x + y + z + w）为100摩尔％，X为选自Al，Si，Fe中的至少1种。版权所有（C）2011，JPO＆INPIT

38. 发明专利

JP2009023857A Hydrogen generation apparatus 有权
标题翻译：氢气发生装置
公开(公告)号：JP2009023857A
公开(公告)日：2009-02-05
申请号：JP2007186419
申请日：2007-07-18
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： AOKI MASAKAZU , OBA NOBUKO , MATSUMOTO MITSURU , WAKAYAMA HIROAKI
IPC分类号： C01B3/06 , C01B3/00 , C01B3/56
CPC分类号： Y02E60/324 , Y02E60/36
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen generation apparatus which applies a reaction for generating hydrogen from two or more kinds of material. SOLUTION: The hydrogen generation apparatus comprises a liquid material tank 12 for storing a liquid material; a second material tank 18 which is divided into a plurality of subtanks A-D, each of the subtanks A-D being filled with a second material for generating hydrogen by the reaction with the liquid raw material or its gas; a liquid material supplying means (V1 A -V1 D valves) for supplying the liquid material or its gas separately into the subtanks A-D; a hydrogen discharge means (V2 A -V2 B valves) for separately discharging a gas containing hydrogen from the subtanks A-D; and a control means for controlling both of the liquid material supply means and the hydrogen discharge means. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种从两种或更多种材料产生氢的反应的氢气产生装置。解决方案：氢气产生装置包括用于储存液体材料的液体料箱12; 被分成多个子容器A-D的第二材料槽18，每个副容器A-D填充有通过与液体原料或其气体的反应产生氢气的第二材料; 用于将液体材料或其气体分别供入到子容器A-D中的液体材料供给装置（V1 A -V1 D ）; 用于从副容器A-D分别排放含氢气体的氢气排出装置（V2 A -V2 B ）; 以及用于控制液体材料供应装置和氢气排出装置两者的控制装置。版权所有（C）2009，JPO＆INPIT

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