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31. 发明授权

US4640923A Methods of combatting fungi employing 2,4-diamino-6-halogeno-5-alkylthio-pyrimidines 失效
标题翻译：使用2,4-二氨基-6-卤代-5-烷硫基 - 嘧啶杀真菌的方法
公开(公告)号：US4640923A
公开(公告)日：1987-02-03
申请号：US816936
申请日：1986-01-08
申请人： Michael Schwamborn , Engelbert Kuhle , Erich Klauke , Ludwig Eue , Robert R. Schmidt , Hans-Joachim Santel , Gerd Hanssler
发明人： Michael Schwamborn , Engelbert Kuhle , Erich Klauke , Ludwig Eue , Robert R. Schmidt , Hans-Joachim Santel , Gerd Hanssler
IPC分类号： A01N43/54 , C07D239/38 , C07D239/48
CPC分类号： C07D239/48 , A01N43/54 , C07D239/38
摘要： 2,4-Diamino-6-halogeno-5-alkylthio-pyrimidines of the general formual (I) ##STR1## in which X represents halogen,R.sup.1 represents alkyl which is optionally substituted by halogen,R.sup.2 represents hydrogen or alkyl,R.sup.3 represents hydrogen, alkyl or alkoxyalkyl,R.sup.4 represents hydrogen or alkyl,Z represents a branched or straight-chain alkylene group andR.sup.5 represents alkyl,process for their preparation and their use as plant protecting agent, particularly as herbicides and fungicides.
摘要翻译：其中X表示卤素，R 1表示任选被卤素取代的烷基，R 2表示氢或烷基，R 2表示氢，烷基， R3表示氢，烷基或烷氧基烷基，R4表示氢或烷基，Z表示支链或直链亚烷基，R5表示烷基，其制备方法及其作为植物保护剂的用途，特别是作为除草剂和杀真菌剂。

32. 发明授权

US4627872A 2,4-diaminopyrimidines 失效
标题翻译： 2,4-二氨基嘧啶
公开(公告)号：US4627872A
公开(公告)日：1986-12-09
申请号：US806053
申请日：1985-12-05
申请人： Michael Schwamborn , Engelbert Kuhle , Ludwig Eue , Robert R. Schmidt , Hans-Joachim Santel
发明人： Michael Schwamborn , Engelbert Kuhle , Ludwig Eue , Robert R. Schmidt , Hans-Joachim Santel
IPC分类号： A01N43/54 , C07D239/42 , C07D239/48
CPC分类号： C07D239/42 , A01N43/54 , C07D239/48
摘要： New herbicidally active 2,4-diamino pyrimidines of the formula ##STR1## wherein R.sup.1 is hydrogen or halogen, R.sup.2 is an optionally halogen-substituted alkyl or is halogen or alkoxy; R.sup.3 is hydrogen or alkyl; Y is oxygen or sulfur; and Z is a branched or unbranched alkylene.
摘要翻译：新的除草活性的2,4-二氨基嘧啶，其结构式为：其中R 1为氢或卤素，R 2为任选卤素取代的烷基或为卤素或烷氧基; R3是氢或烷基; Y是氧或硫; Z是支链或非支链亚烷基。

33. 发明授权

US4585471A Novel substituted 5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy-acetic acid amide herbicides 失效
标题翻译：新的取代的5-三氟甲基-1,3,4-噻二唑-2-基 - 氧 - 乙酸酰胺除草剂
公开(公告)号：US4585471A
公开(公告)日：1986-04-29
申请号：US733662
申请日：1985-05-10
申请人： Heinz Forster , Wolfgang J. Hofer, deceased , Robert R. Schmidt , Ludwig Eue
发明人： Heinz Forster , Wolfgang J. Hofer, deceased , Robert R. Schmidt , Ludwig Eue
IPC分类号： A01N43/82 , A01N43/824 , C07D211/00 , C07D215/00 , C07D285/00 , C07D285/12 , C07D285/13 , C07D417/12
CPC分类号： C07D285/12 , A01N43/82 , C07D285/13 , C07D417/12
摘要： Substituted 5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxyacetic acid amides of the formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and each represent alkyl, alkenyl, alkinyl, alkoxy, aralkyl, cycloalkyl, cycloalkenyl or aryl, each of which is optionally substituted, or a nitrogen-containing heterocyclic radical, or, together with the nitrogen atom to which they are bonded, form an optionally substituted, optionally partially unsaturated and optionally benzo-fused monocyclic or bicyclic structure which optionally contains further hetero atoms, with the proviso that R.sub.1 does not represent methyl when R.sup.2 represents phenyl, which possess herbicidal activity.
摘要翻译：式（I）的取代的5-三氟甲基-1,3,4-噻二唑-2-基 - 氧基乙酸酰胺，其中R 1和R 2相同或不同，并且各自表示烷基，烯基，炔基，烷氧基，芳烷基，环烷基，环烯基或芳基，其各自任选被取代，或含氮杂环基，或与它们所键合的氮原子一起形成任选取代的，任选地部分不饱和的和任选的苯并稠合的单环或任选地含有另外的杂原子的双环结构，条件是当R 2表示具有除草活性的苯基时，R 1不表示甲基。

34. 发明授权

US4540430A Herbicidally active novel substituted 3-trichloromethyl-1,2,4-thiadiazol-5-yl-oxyacetamides 失效
标题翻译：除草活性新型取代的3-三氯甲基-1,2,4-噻二唑-5-基 - 氧乙酰胺
公开(公告)号：US4540430A
公开(公告)日：1985-09-10
申请号：US515082
申请日：1983-07-18
申请人： Heinz Forster , Hans-Joachim Diehr , Jorg Stetter , Ludwig Eue , Robert R. Schmidt
发明人： Heinz Forster , Hans-Joachim Diehr , Jorg Stetter , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N43/82 , A01N43/836 , C07D285/08 , C07D417/12
CPC分类号： C07D285/08 , A01N43/82 , C07D417/12
摘要： A substituted 3-trichloromethyl-1,2,4-thiadiazol-5-yl-oxyacetamide of the formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and individually represent optionally substituted alkyl, alkenyl, alkinyl, alkoxy, aralkyl, cycloalkyl, cycloalkenyl, aryl or a nitrogen-containing heterocyclic radical, or, together with the nitrogen atom to which they are bonded, form an optionally substituted, optionally partially unsaturated and optionally benzo-fused monocyclic or bicyclic structure which optionally contains further heteroatoms,which possesses herbicidal activity.
摘要翻译：其中R1和R2相同或不同并且各自代表任选取代的烷基，烯基，炔基，烷氧基，芳烷基，环烷基的取代的3-三氯甲基-1,2,4-噻二唑-5-基 - 氧乙酰胺，环烯基，芳基或含氮杂环基，或与它们所键合的氮原子一起形成任选取代的，任选地部分不饱和的和任选的苯并稠合单环或双环结构，其任选地含有另外的杂原子，其具有除草活性。

35. 发明授权

US4500341A Phenoxycarboxylic acid amide compounds and herbicidal compositions 失效
标题翻译：苯氧基羧酸酰胺化合物和除草组合物
公开(公告)号：US4500341A
公开(公告)日：1985-02-19
申请号：US313698
申请日：1981-10-21
申请人： Heinz Forster , Ludwig Eue , Robert R. Schmidt
发明人： Heinz Forster , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N39/02 , A01N39/04 , A01N43/56 , C07C67/00 , C07C231/00 , C07C231/02 , C07C235/20 , C07C235/24 , C07C237/06 , C07C237/12 , C07C237/22 , C07C313/00 , C07C323/41 , C07D211/16 , C07D231/12 , C07D231/20 , C07D249/08 , C07D295/185 , C07D521/00 , A01N37/20 , C07C103/75
CPC分类号： C07D295/185 , A01N39/02 , A01N39/04 , A01N43/56 , C07D231/12 , C07D233/56 , C07D249/08
摘要： Phenoxycarboxylic acid amide compound of the formula ##STR1## wherein R.sup.1 and R.sup.2 are individually selected from hydrogen and methyl,R.sup.3 is hydrogen or alkyl with from 1 to 5 carbon atomsR.sup.4 is optionally substituted alkoxycarbonylalkyl, aminocarbonylalkyl or dialkylaminocarbonylalkyl, phenyl, or substituted phenyl wherein the substituent is at least one of the group consisting of alkyl, alkoxy or alkylthio of from 1 to 4 carbon atoms, carbalkoxy of from 2 to 4 carbon atoms, halogen, and nitro; orR.sup.3 and R.sup.4, together with the adjacent nitrogen atom, form an mono- or bicyclic ring with up to 15 carbon atoms and which is optionally substituted by 1 to 3 alkyl groups of up to 4 carbon atoms each, and which ring may be partially unsaturated and/or benzo-fused; or a saturated mono-cyclic ring of up to 8 carbon atoms and containing a further hetero-atom selected from nitrogen, oxygen and sulfur, which ring is optionally substituted by one or two alkyl groups of up to 2 carbon atoms each; or an unsaturated 5-membered heterocyclic ring containing up to 4 ring nitrogen atoms and which ring is optionally substituted with at least one member of the group consisting of alkyl of up to 4 carbon atoms, alkoxy of up to 4 carbon atoms, alkylthio of up to 4 carbon atoms, phenyl, halogen, halomethyl, cyano, alkanoyl of up to 4 carbon atoms and carbalkoxy of from 2 to 4 carbon atoms; andX is hydrogen or chlorine;are outstandingly effective herbicides.
摘要翻译：式（I）的苯氧基羧酸酰胺化合物其中R 1和R 2分别选自氢和甲基，R 3是氢或具有1至5个碳原子的烷基R 4是任选取代的烷氧基羰基烷基，氨基羰基烷基或二烷基氨基羰基烷基，苯基或取代的苯基，其中取代基是1至4个碳原子的烷基，烷氧基或烷硫基，2至4个碳原子的烷氧基，卤素和硝基中的至少一个; 或R 3和R 4与相邻的氮原子一起形成具有至多15个碳原子的单环或双环，并且其任选被至多4个碳原子的1至3个烷基取代，并且该环可以是部分不饱和和/或苯并稠合; 或至多8个碳原子的饱和单环，并含有另外的选自氮，氧和硫的杂原子，该环任选被一个或两个至多2个碳原子的烷基取代; 或含有至多4个环氮原子的不饱和5元杂环，并且该环任选被至多一个由至多4个碳原子的烷基，至多4个碳原子的烷氧基，至少4个碳原子的烷硫基，至多4个碳原子，苯基，卤素，卤代甲基，氰基，至多4个碳原子的烷酰基和2至4个碳原子的烷氧基; X为氢或氯; 是非常有效的除草剂。

36. 发明授权

US4488895A N-Diazolyalkyl-haloacetanilide compounds and herbicidal compositions 失效
标题翻译： N-重氮基烷基 - 卤代乙酰苯胺化合物和除草组合物
公开(公告)号：US4488895A
公开(公告)日：1984-12-18
申请号：US343469
申请日：1982-01-28
申请人： Jorg Stetter , Klaus Ditgens , Rudolf Thomas , Ludwig Eue , Robert R. Schmidt
发明人： Jorg Stetter , Klaus Ditgens , Rudolf Thomas , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N43/653 , A01N43/82 , A01N43/836 , C07C233/07 , C07D249/08 , C07D249/10 , C07D249/12 , C07D249/14 , C07D271/06 , C07D285/08
CPC分类号： C07D271/06 , A01N43/653 , A01N43/82 , C07C233/07 , C07D285/08
摘要： Novel N-Diazolylalkyl-haloacetanilides of the formula ##STR1## wherein A is oxygen, sulphur or the grouping
摘要翻译：式（I）的新型N-二唑基烷基 - 卤代乙酰苯胺，其中A是氧，硫或NR

37. 发明授权

US4195181A 1,3,4-Thiadiazole compounds and herbicidal compositions 失效
标题翻译： 1,3,4-噻二唑化合物和除草组合物
公开(公告)号：US4195181A
公开(公告)日：1980-03-25
申请号：US771729
申请日：1977-02-24
申请人： Carl Metzger , Ludwig Eue , Robert R. Schmidt
发明人： Carl Metzger , Ludwig Eue , Robert R. Schmidt
IPC分类号： C07D285/12 , C07D285/135 , A01N9/12 , C07D417/04
CPC分类号： C07D285/135
摘要： New heterocyclic-substituted 1,3,4,-thiadiazole derivatives of the formula ##STR1## in which R.sup.1 is alkyl, alkenyl, haloalkyl, optionally substituted aralkyl, optionally substituted aryl, alkylthio, alkylsulfonyl, alkylsulfoxyl, aralkylthio, aralkylsulfonyl or aralkylsulfoxyl,R.sup.2 is methyl or ethyl, andn is 1 or 2,are surprisingly effective as herbicides and are particularly useful as selective herbicides for combating grasses, especially in crops of cereals or cotton.
摘要翻译：新的具有式（I）的杂环取代的1,3,4 - 噻二唑衍生物，其中R 1是烷基，烯基，卤代烷基，任选取代的芳烷基，任选取代的芳基，烷硫基，烷基磺酰基，烷基亚砜基，芳烷硫基，芳烷基磺酰基或芳烷基亚磺酰基，R 2为甲基或乙基，n为1或2，作为除草剂令人惊奇地有效，并且特别用作防治草，特别是谷类或棉花作物的选择性除草剂。

38. 发明授权

US4183742A 4,5-Dichloro-imidazole-1-carboxylic acid aryl esters and their use as plant protection agents 失效
标题翻译： 4,5-二氯 - 咪唑-1-羧酸芳基酯及其作为植物保护剂的用途
公开(公告)号：US4183742A
公开(公告)日：1980-01-15
申请号：US835092
申请日：1977-09-21
申请人： Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
发明人： Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N43/36 , A01N47/16 , A01N47/22 , A01P13/00 , C07D233/68 , C07D233/90 , C07D487/14 , C07D233/28 , A01N9/22
CPC分类号： C07D487/14 , A01N47/22 , C07D233/68 , C07D233/90
摘要： A 4,5-dichloro-imidazole-1-carboxylic acid aryl ester of the formula ##STR1## in which X represents trifluoromethyl, cyano or a group ##STR2## in which R.sup.1 represents an optionally substituted saturated or unsaturated aliphatic radical, R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group, R.sup.3 represents alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents, or R.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom form an optionally substituted 5- to 7-membered heterocyclic radical in which 1 to 3 ring members may be selected from oxygen, sulfur and nitrogen, Y represents halogen, alkyl with 1 to 6 carbon atoms, trifluoromethyl, alkoxy with 1 to 6 carbon atoms, nitro, cyano or a ##STR3## group, in which R.sup.4 represents alkyl with 1 to 6 carbon atoms and n represents 0, 1, 2, 3, 4, or 5, which possesses plant protection properties especially herbicidal and plant growth regulant properties.
摘要翻译：其中X表示三氟甲基，氰基或其中R 1表示任选取代的饱和或不饱和脂族基团的基团的4,5-二氯 - 咪唑-1-羧酸芳基酯，其中X表示三氟甲基， R 2表示氢，具有1至8个碳原子的烷基，具有至多8个碳原子的烯基或甲酰基，R 3表示具有1至8个碳原子的烷基或各自具有至多8个碳原子的链烯基或炔基，每个的这些烷基，烯基和炔基，以携带一个或多个取代基，或表示环中具有5至7个碳原子的环烷基，其任选被具有1至6个碳原子的烷基取代，或表示可以任选携带一个或多个取代基，或R2和R3与相邻的氮原子结合形成任选取代的5至7元杂环基，其中1至3个环成员可以选自氧，硫和氮，Y代表卤素，烷基与1至 6个碳原子，三氟甲基，具有1至6个碳原子的烷氧基，硝基，氰基或者IMAGE基团，其中R 4表示具有1至6个碳原子的烷基，n表示0,1,2,3,4或5个具有植物保护性，特别是除草和植物生长调节性。

39. 发明授权

US4178166A 4,5-Dichloro-imidazole derivatives and their use as plant protection agents 失效
标题翻译： 4,5-二氯咪唑衍生物及其作为植物保护剂的用途
公开(公告)号：US4178166A
公开(公告)日：1979-12-11
申请号：US835095
申请日：1977-09-21
申请人： Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
发明人： Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N43/50 , A01P13/00 , C07D233/68 , C07D233/90 , C07D487/14 , A01N9/22
CPC分类号： C07D487/14 , A01N43/50 , C07D233/68 , C07D233/90
摘要： A 4,5-dichloro-imidazole derivative of the formula ##STR1## in which X represents trifluoromethyl, cyano or a ##STR2## in which R.sup.1 represents an optionally saturated or unsaturated aliphatic radical,R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group,R.sup.3 represents hydrogen, alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents, orR.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom for an optionally substituted 5-membered to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulphur and nitrogen, andR represents alkyl with 1 to 12 carbon atoms or alkenyl or alkynyl each with up to 12 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring or represents a phenyl radical which is at least disubstituted;and the use of such novel 4,5-dichloro-imidazole derivatives as plant protection agents especially as a herbicide, plant growth regulant, insecticide or acaricide.
摘要翻译：式（I）的4,5-二氯 - 咪唑衍生物，其中X表示三氟甲基，氰基或者其中R 1表示任选饱和或不饱和的脂族基团，R 2表示氢，烷基与1至 8个碳原子，具有至多8个碳原子的烯基或甲酰基，R3表示氢，具有1至8个碳原子的烷基或具有至多8个碳原子的链烯基或炔基，这些烷基，烯基和炔基中的每一个都是可能的自由基携带一个或多个取代基，或表示环中具有5至7个碳原子的环烷基，其任选被具有1至6个碳原子的烷基取代，或表示可任选地携带一个或多个取代基的苯基，或者R 2和R 3连接与相邻的氮原子一起用于任选取代的5元至7元杂环，其中1至3个环成员可以选自氧，硫和氮，R表示具有1至12个碳原子的烷基或烯基或炔基各自具有至多12个碳原子，这些烷基，烯基和炔基中的每一个可以携带一个或多个取代基，或代表环中具有5至7个碳原子的环烷基或代表至少为二取代; 以及这种新型的4,5-二氯 - 咪唑衍生物作为植物保护剂，特别是作为除草剂，植物生长调节剂，杀虫剂或杀螨剂的用途。

40. 发明授权

US4840661A Sulphonyliso(thio)urea derivatives and herbicidal use thereof 失效
标题翻译：磺酰基（硫）脲衍生物及其除草用途
公开(公告)号：US4840661A
公开(公告)日：1989-06-20
申请号：US769272
申请日：1985-08-23
申请人： Hans-Joachim Diehr , Christa Fest , Rolf Kristen , Joachim Kluth , Klaus-Helmut Muller , Theodor Pfister , Uwe Priesnitz , Hans-Jochem Riebel , Wolfgang Roy , Hans-Joachim Santel , Robert R. Schmidt , Ludwig Eue
发明人： Hans-Joachim Diehr , Christa Fest , Rolf Kristen , Joachim Kluth , Klaus-Helmut Muller , Theodor Pfister , Uwe Priesnitz , Hans-Jochem Riebel , Wolfgang Roy , Hans-Joachim Santel , Robert R. Schmidt , Ludwig Eue
IPC分类号： A01N47/42 , C07D521/00
CPC分类号： C07D521/00 , A01N47/42
摘要： The invention relates relates to new sulphonyliso(thio)-urea derivatives of the general formula (I) ##STR1## in which R.sup.1 represent an optionally substituted radical from the series comprising alkyl, aralkyl, aryl and heteroarylR.sup.2 represents an optionally substituted and/or optionally fused 6-membered aromatic heterocyclic radial containing at least one nitrogen atom,R.sup.3 represents an optically substituted aromatic or heteroaromatic radical,X represents oxygen or sulphur andM represents hydrogen or an equivalent of a metal, and adducts of compounds of the formula (I) with strong acids, processes for their prepartion, and their use as herbicides.
摘要翻译：本发明涉及通式（I）的新的磺酰基（硫代） - 脲衍生物，其中R 1表示包含烷基，芳烷基，芳基和杂芳基的系列中的任选取代的基团R 2表示任选取代的和/或任选稠合的含有至少一个氮原子的6元芳族杂环径流，R 3表示光学取代的芳族或杂芳族基团，X表示氧或硫，M表示氢或等价金属，以及具有强酸的式（I），其制备方法及其作为除草剂的用途。

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