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31. 发明授权

US06528683B1 Method for producing shell catalysts for the catalytic vapor-phase oxidation of aromatic hydrocarbons and catalysts obtained in such a manner 失效
标题翻译：用于生产用于芳烃的催化气相氧化的壳催化剂和以这种方式获得的催化剂的方法
公开(公告)号：US06528683B1
公开(公告)日：2003-03-04
申请号：US09701517
申请日：2000-11-30
申请人： Thomas Heidemann , Frank Rosowski , Gerd Linden , Michael Seufert , Gerhard Hefele , Peter Michael Lorz
发明人： Thomas Heidemann , Frank Rosowski , Gerd Linden , Michael Seufert , Gerhard Hefele , Peter Michael Lorz
IPC分类号： C07C5116
CPC分类号： B01J37/0232 , B01J23/22 , B01J37/0219 , B01J37/0223 , C07C51/265 , Y10T428/31935 , C07C63/16
摘要： The invention relates to a method for producing shell catalysts for the catalytic vapor-phase oxidation of aromatic carboxylic acids and/or carboxylic acid anhydrides comprised of a supporting core and of catalytically active metal oxides which are deposited in a shell-shaped manner on said supporting core. The inventive catalysts are obtained by spraying an aqueous active mass suspension, said suspension containing the active metal oxides, at higher temperatures onto the hot supporting material which has a temperature ranging from 50 to 450° C. The aqueous active mass suspension contains 1 to 10 wt. %, with regard to the solid content of the active mass suspension, a binding agent comprised of A) a polymerizate obtained by radical polymerization, containing 5 to 100 wt. % of monomers (a) in the form of ethylenically unsaturated acid anhydrides or ethylenically unsaturated dicarboxylic acids whose carboxyl groups can form an anhydride and containing 0 to 95 wt. % monoethylenically unsaturated monomers (b) with the provision that the monomers (a) and (b) comprise, on average, a maximum of 6 carbon atoms which are not functionalized with groups containing oxygen, and of B) an alkanolamine having at least 2 OH groups, a maximum of 2 nitrogen atoms and a maximum of 8 C-atoms, whereby the weight ratio A:B ranges from 1:0.05 to 1:1.
摘要翻译：本发明涉及一种用于制备用于催化气相氧化芳族羧酸和/或羧酸酐的壳催化剂的方法，所述芳族羧酸和/或羧酸酐由支撑芯和催化活性金属氧化物组成，其以壳形方式沉积在所述支撑核心。本发明的催化剂是通过将含水活性物质悬浮液（含有活性金属氧化物的悬浮液）在较高温度下喷洒到温度为50-450℃的热支撑材料上而获得的。水性活性悬浮液含有1至10 重量％，关于活性悬浮液的固体含量，结合剂由A）通过自由基聚合获得的聚合物，其含有5〜100重量％％的烯属不饱和酸酐或烯属不饱和二羧酸形式的单体（a），其羧基可以形成酸酐并含有0至95重量％％单烯属不饱和单体（b），条件是单体（a）和（b）平均包含不含有氧的基团不被官能化的最多6个碳原子，和B）具有至少2个的链烷醇胺 OH基团，最多2个氮原子和最多8个C原子，其中重量比A:B的范围为1:0.05至1:1。

32. 发明授权

US08318982B2 Catalyst and process for preparing an amine 有权
标题翻译：催化剂和制备胺的方法
公开(公告)号：US08318982B2
公开(公告)日：2012-11-27
申请号：US12958597
申请日：2010-12-02
申请人： Petr Kubanek , Wolfgang Mägerlein , Johann-Peter Melder , Thomas Heidemann
发明人： Petr Kubanek , Wolfgang Mägerlein , Johann-Peter Melder , Thomas Heidemann
IPC分类号： C07C209/16 , C07D265/30 , C07D295/03 , C07D241/04 , B01J31/00 , B01J23/10
CPC分类号： B01J23/83 , B01J23/835 , B01J37/031 , B01J37/18 , C07C209/16 , C07C209/26 , C07C213/02 , C07D295/088 , C07C217/08
摘要： A process for preparing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of ammonia and primary and secondary amines, in the presence of a supported copper-, nickel- and cobalt-containing catalyst, wherein the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises oxygen compounds of aluminum, of copper, of nickel, of cobalt and of tin, and in the range from 0.2 to 5.0% by weight of oxygen compounds of yttrium, of lanthanum, of cerium and/or of hafnium, each calculated as Y2O3, La2O3, Ce2O3 and Hf2O3 respectively, and catalysts as defined above.
摘要翻译：在负载的铜，镍和钴的存在下，使伯醇或仲醇，醛和/或酮与氢和选自氨和伯胺和仲胺的氮化合物反应制备胺的方法其中所述催化剂的催化活性材料在用氢还原之前包含铝，铜，镍，钴和锡的氧化合物，并且其含量为0.2-5.0重量％分别以Y2O3，La2O3，Ce2O3和Hf2O3分别计算的铈和/或铪的镧，镧，铪和/或铪的氧化合物和催化剂。

33. 发明申请

US20120004482A1 METHOD FOR REACTING NATURAL GAS TO AROMATICS WHILE ELECTROCHEMICALLY REMOVING HYDROGEN AND ELECTROCHEMICALLY REACTING THE HYDROGEN WATER 有权
标题翻译：在电化学去除氢气和电化学反应氢气时将天然气反应成芳族化合物的方法
公开(公告)号：US20120004482A1
公开(公告)日：2012-01-05
申请号：US13256536
申请日：2010-03-29
申请人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
发明人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
IPC分类号： C07C2/00
CPC分类号： C01B3/38 , C01B3/503 , C01B3/56 , C01B5/00 , C01B2203/02 , C01B2203/0405 , C01B2203/041 , C01B2203/043 , C01B2203/048 , C01B2203/062 , C01B2203/1241 , C07C2/76 , C10G50/00 , C10G2400/30 , Y02P20/52 , C07C15/00 , C07C15/04
摘要： The invention relates to a process for converting aliphatic hydrocarbons having from 1 to 4 carbon atoms into aromatic hydrocarbons, which comprises the steps: a) reaction of a feed stream E comprising at least one aliphatic hydrocarbon having from 1 to 4 carbon atoms in the presence of a catalyst under nonoxidative conditions to give a product stream P comprising aromatic hydrocarbons and hydrogen and b) electrochemical removal of at least part of the hydrogen formed in the reaction from the product stream P by means of a gastight membrane-electrode assembly comprising at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane on the permeate side, reacted with oxygen to form water over the cathode catalyst, with the oxygen originating from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane.
摘要翻译：本发明涉及一种将具有1至4个碳原子的脂族烃转化为芳族烃的方法，其包括以下步骤：a）在存在的情况下使包含至少一种具有1至4个碳原子的脂族烃的进料流E反应的催化剂，以产生包含芳族烃和氢的产物流P和b）通过气密的膜 - 电极组合物从产物流P电化学去除反应中形成的氢的至少一部分，该气密膜电极组件至少包括一个选择性质子传导膜和至少一个电极催化剂在膜的每一侧上，其中至少部分氢被氧化成在膜的滞留侧上的阳极催化剂上的质子，质子在通过渗透物侧的膜与氧反应，在阴极催化剂上形成水，氧气源自氧-co 令人惊奇的流O与膜的渗透侧接触。

34. 发明申请

US20100312031A1 METHOD FOR OLIGOMERIZING ALKENES 审中-公开
标题翻译：低聚物的方法
公开(公告)号：US20100312031A1
公开(公告)日：2010-12-09
申请号：US12865272
申请日：2009-01-28
申请人： Thomas Heidemann
发明人： Thomas Heidemann
IPC分类号： C07C2/24
CPC分类号： C07C2/08 , C07C2/10 , C07C11/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/755 , C07C2527/02 , Y02P20/582
摘要： The present invention relates to a process for the oligomerization of alkenes, in which an alkene-comprising feed is provided and is subjected to an oligomerization in two successive reaction zones.
摘要翻译：本发明涉及烯烃低聚的方法，其中提供含烯烃的进料并在两个连续的反应区中进行低聚。

35. 发明申请

US20100286458A1 METHOD FOR ISOMERIZING OLEFINS 审中-公开
标题翻译：异烯烃方法
公开(公告)号：US20100286458A1
公开(公告)日：2010-11-11
申请号：US12738034
申请日：2008-10-15
申请人： Stefan Iselborn , Thomas Heidemann
发明人： Stefan Iselborn , Thomas Heidemann
IPC分类号： C07C5/03 , C07C5/25
CPC分类号： C07C11/06 , C07C5/2512 , C07C6/04 , C07C2521/04 , C07C2523/85 , C07C2523/885 , C07C2523/888 , C07C11/08
摘要： The present invention relates to a process for isomerizing olefins in olefin-comprising hydrocarbon mixtures having from 4 to 20 carbon atoms at temperatures of from 20 to 200° C. and pressures of from 1 to 200 bar in the liquid phase in the presence of a heterogeneous catalyst, wherein a catalyst comprising from 1 to 20% by weight of nickel in oxidic form and from 1 to 20% by weight of at least one element of group VIB on an aluminum oxide support is used.
摘要翻译：本发明涉及一种使含烯烃的烃混合物中的烯烃异构化的方法，该烃混合物在20〜200℃的温度和1〜200巴的压力下，在液相中，在使用非均相催化剂，其中使用包含1至20重量％的氧化物形式的镍和1至20重量％的至少一种氧化铝载体上VIB族元素的催化剂。

36. 发明申请

US20100016646A1 PROCESS FOR HYDROGENATING BUTADIYNE 有权
标题翻译：加氢丁二烯的方法
公开(公告)号：US20100016646A1
公开(公告)日：2010-01-21
申请号：US12485398
申请日：2009-06-16
申请人： Lucia KOENIGSMANN , Ekkehard Schwab , Piotr Makarczyk , Kai Rainer Ehrhardt , Maximilian Vicari , Thomas Heidemann , Dirk Grossschmidt , Gerrit Waters
发明人： Lucia KOENIGSMANN , Ekkehard Schwab , Piotr Makarczyk , Kai Rainer Ehrhardt , Maximilian Vicari , Thomas Heidemann , Dirk Grossschmidt , Gerrit Waters
IPC分类号： C07C7/167 , C07C5/09
CPC分类号： B01J23/44 , B01J21/04 , B01J23/40 , B01J35/08 , B01J35/1038 , B01J35/1061 , C07C5/08 , C07C5/09 , C07C7/167 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/44 , C07C9/10 , C07C11/08 , C07C11/24
摘要： In the process for hydrogenating butadiyne over a catalyst which comprises at least one platinum group metal on an inorganic metal oxide as a support, the hydrogenation is performed at a pressure in the range from 1 to 40 bar and a temperature in the range from 0 to 100° C., and from 0.05 to 5% by weight, based on the overall catalyst, of platinum group metal is present on the support.
摘要翻译：在包含在无机金属氧化物作为载体上的至少一种铂族金属的催化剂上氢化丁二炔的方法中，氢化在1至40巴的压力和0至 100℃，和0.05-5重量％，基于总催化剂，铂族金属存在于载体上。

37. 发明申请

US20090312583A1 PROCESS FOR CODIMERIZING OLEFINS 有权
标题翻译：用于编织烯烃的方法
公开(公告)号：US20090312583A1
公开(公告)日：2009-12-17
申请号：US12303527
申请日：2007-06-06
申请人： Marcus Sigl , Michael Triller , Thomas Heidemann
发明人： Marcus Sigl , Michael Triller , Thomas Heidemann
IPC分类号： C07C29/50 , C07C2/08 , C07C11/00
CPC分类号： C07C2/12 , C07C29/141 , C07C45/50 , C07C2529/06 , C12C11/02 , Y02P20/582 , C07C31/125 , C07C47/02
摘要： The present invention relates to a process for preparing olefin codimers, the olefin codimers which can be obtained by this process, a process for preparing alcohols in which such olefin codimers are subjected to hydroformylation and subsequent hydrogenation, the alcohol mixtures which can be obtained in this way and their use.
摘要翻译：本发明涉及一种制备烯烃共聚物的方法，可通过该方法获得的烯烃共聚物，一种制备醇的方法，其中这种烯烃共聚物经受加氢甲酰化和随后的氢化，可以在此获得的醇混合物方式和使用。

38. 发明授权

US07259285B1 Oligomerization catalyst, a method for production and the use thereof 有权
标题翻译：低聚催化剂，其制备方法及其应用
公开(公告)号：US07259285B1
公开(公告)日：2007-08-21
申请号：US10129981
申请日：2000-11-16
申请人： Marc Walter , Thomas Heidemann
发明人： Marc Walter , Thomas Heidemann
IPC分类号： C07C2/24 , C07C2/10 , C07C2/16 , B01J27/02 , B01J27/053
CPC分类号： C07C2/10 , B01J23/755 , B01J27/043 , B01J37/20 , C07C2521/04
摘要： An oligomerization catalyst for olefins having from 2 to 6 carbon atoms is produced by treating aluminum oxide with a nickel compound and a sulfur compound, either simultaneously or firstly with the nickel compound an then with the sulfur compound, and subsequently drying and calcining the resulting catalyst, wherein a molar ratio of sulfur to nickel in the finished catalyst of from 0.25:1 to 0.38:1 is set in this way. The catalyst and its use are also described.
摘要翻译：具有2至6个碳原子的烯烃的低聚催化剂是通过用镍化合物和硫化合物同时或首先用硫化合物与镍化合物一起处理氧化铝，然后干燥和煅烧所得到的催化剂其中，以这种方式设定成品催化剂中硫与镍的摩尔比为0.25:1至0.38:1。还描述了催化剂及其用途。

39. 发明授权

US06852898B2 Method for producing oligomers 失效
标题翻译：生产低聚物的方法
公开(公告)号：US06852898B2
公开(公告)日：2005-02-08
申请号：US10221168
申请日：2001-03-22
申请人： Ralf Schulz , Thomas Heidemann , Peter Schwab , Peter Zehner
发明人： Ralf Schulz , Thomas Heidemann , Peter Schwab , Peter Zehner
IPC分类号： B01J19/24 , C07B61/00 , C07C2/08 , C07C2/10 , C07C2/24 , C07C11/02 , C07C2/06
CPC分类号： C07C2/10 , B01J19/2465 , C07C2/08
摘要： In a process for preparing essentially unbranched oligomers of alkenes having from 4 to 6 carbon atoms starting from the alkenes or a hydrocarbon stream comprising such alkenes over a nickel-containing heterogeneous catalyst in an adiabatically operated reactor at from 20 to 300° C. and pressures of from 1 to 100 bar, a first substream of the output from the reactor is worked up to isolate the oligomers and the second substream is recirculated together with fresh alkene or a fresh hydrocarbon stream comprising such alkenes to the reactor.
摘要翻译：在从20-300℃绝热操作的反应器中，在烯烃或含有这种烯烃的含烃非均相催化剂的基础上制备基本上未分支的具有4-6个碳原子的烯烃低聚物的方法， 1至100巴，将来自反应器的输出的第一子流排除以分离低聚物，并将第二子流与新鲜的烯烃或包含这种烯烃的新鲜烃物流一起再循环到反应器中。

40. 发明授权

US06700000B1 Method for producing phthalic anhydride 有权
标题翻译：邻苯二甲酸酐的制造方法
公开(公告)号：US06700000B1
公开(公告)日：2004-03-02
申请号：US09700452
申请日：2000-11-15
申请人： Thomas Heidemann , Herbert Wanjek
发明人： Thomas Heidemann , Herbert Wanjek
IPC分类号： C07D30789
CPC分类号： B01J35/0006 , B01J23/002 , B01J27/198 , B01J37/0223 , B01J2523/00 , C07D307/89 , B01J2523/15 , B01J2523/47 , B01J2523/51 , B01J2523/53 , B01J2523/55
摘要： Phthalic anhydride is prepared by catalytic gas-phase oxidation of xylene and/or naphthalene by a gas comprising molecular oxygen in a fixed bed at elevated temperature and using at least three coated catalysts arranged in superposed zones, which catalysts have a layer of catalytically active metal oxides applied to a core of support material. In the process described, the catalyst activity rises from zone to zone from the gas inlet end to the gas outlet end and the activity of the catalysts of the individual zones is set such that the least active catalyst comprises a lower amount of active composition and, if desired, additionally more alkali metal selected from the group consisting of potassium, rubidium and cesium as dopant than the catalyst of the next zone and the subsequent even more active catalyst comprises the same amount of active composition and even less alkali metal as dopant or a greater amount of active composition and, if desired, less alkali metal as dopant than the catalyst of the second zone, with further conditions.
摘要翻译：邻苯二甲酸酐通过在固定床中在升高的温度下通过包含分子氧的气体二甲苯和/或萘的催化气相氧化制备，并且使用布置在重叠区中的至少三个涂覆的催化剂，该催化剂具有催化活性金属层施加到支撑材料的芯的氧化物。在所描述的方法中，催化剂活性从气体入口端到气体出口端从区域上升，并且各个区域的催化剂的活性被设定为使得最低活性催化剂包含较少量的活性组合物，如果需要，另外还有更多的选自钾，铷和铯作为掺杂剂的碱金属比下一个区域的催化剂和随后的甚至更活泼的催化剂包含相同量的活性组合物，甚至更少的碱金属作为掺杂剂或更多量的活性组合物和如果需要，具有比第二区域的催化剂更少的碱金属作为掺杂剂，具有进一步的条件。

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