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    • 31. 发明授权
    • Highly-sensitive high-contrast photographic materials
    • 高度敏感的高对比度感光材料
    • US4311781A
    • 1982-01-19
    • US165823
    • 1980-07-03
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraNobuo Sakai
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraNobuo Sakai
    • C07C67/00C07C241/00C07C243/28C07C243/38C07C253/00C07C255/57G03C1/06G03C1/08G03C1/10G03C1/28G03C5/30
    • C07C243/00C07C243/38G03C1/061G03C1/28Y10S430/15
    • A silver halide photographic material providing very high contrast and negative image photographic characteristics comprising a support having thereon at least one silver halide photographic emulsion layer containing substantially surface latent image type mono-dispersed silver halide grains and providing a negative image, at least one hydrophilic colloid layer of the photographic material containing a compound represented by the general formula (I)R.sup.1 NHNHCOR.sup.2 (I)whereinR.sup.1 represents an aryl group and R.sup.2 represents a hydrogen atom, a phenyl group, or an unsubstituted alkyl group having 1 to 3 carbon atoms;and a compound represented by the general formula (II) or (III) ##STR1## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6, which may be the same or different, each represents a hydrogen atom, an alkyl group which may be substituted, an aryl group which may be substituted, an amino group which may be substituted, a hydroxyl group, an alkoxy group, an alkylthio group, a carbamoyl group which may be substituted, a halogen atom, a cyano group, a carboxyl group, an alkoxycarbonyl group, or a heterocyclic group; wherein R.sup.3 and R.sup.4 or R.sup.4 and R.sup.5 may combine and form a 5-membered or 6-membered ring and at least one of R.sup.3 and R.sup.5 represents a hydroxyl group and developing said photographic light-sensitive material with a developing solution containing a developing agent selected from the group consisting of a phenylenediamine compound and a combination of a 3-pyrazolidone compound with a hydroquinone compound.
    • 提供非常高的对比度和负影像照相特征的卤化银照相材料,包括其上具有至少一个含有基本上表面潜影型单分散卤化银颗粒并提供负像的卤化银照相乳剂层的载体,至少一种亲水胶体 含有通式(I)R1NHNHCOR2(I)表示的化合物的照相材料层,其中R1表示芳基,R2表示氢原子,苯基或未取代的碳原子数1〜3的烷基; 和由通式(II)或(III)表示的化合物,其中可以相同或不同的R 3,R 4,R 5和R 6各自表示氢原子, 可以被取代的烷基,可以被取代的芳基,可以被取代的氨基,羟基,烷氧基,烷硫基,可被取代的氨基甲酰基,卤素原子,氰基 基团,羧基,烷氧基羰基或杂环基; 其中R3和R4或R4和R5可以组合并形成5元或6元环,并且R 3和R 5中的至少一个表示羟基,并用含有显影剂的显影溶液显影所述照相感光材料 由苯二胺化合物和3-吡唑烷酮化合物与氢醌化合物的组合组成。