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31. 发明授权

US07893155B2 Material or curable solvent-based topcoating material, and coating material and coating film comprising or formed from the same 有权
标题翻译：可固化溶剂型涂层材料的材料，以及包含或由其形成的涂料和涂膜
公开(公告)号：US07893155B2
公开(公告)日：2011-02-22
申请号：US12662128
申请日：2010-03-31
申请人： Kohzo Ito , Jun Araki , Tatsuya Suzuki , Masahiko Yamanaka , Kentarou Watanabe
发明人： Kohzo Ito , Jun Araki , Tatsuya Suzuki , Masahiko Yamanaka , Kentarou Watanabe
IPC分类号： C08G63/48
CPC分类号： C09D105/16 , C08B37/0015 , C08G83/007 , C09D167/04 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935
摘要： To provide a coating material for a curable solvent-based topcoating material, having excellent marring resistance, chipping resistance, producing no crack and excellent in performances such as weatherability, stain resistance, adhesion and the like, and a curable solvent-type topcoating material using such a material.A coating material is blended preferably in an amount of 60 to 90% by mass relative to paint film forming components thereby to form a curable solvent-based topcoating material. The coating material includes an oleophilic polyrotaxane which includes a cyclic molecule, a linear molecule including the cyclic molecule with piercing through the cyclic molecule, and blocking groups which are placed at both end terminals of the linear molecule to prevent the cyclic molecule from leaving from the linear molecule, at least one of the above-mentioned liner molecule and the cyclic molecule having hydrophobic modification group.
摘要翻译：为了提供一种固化性溶剂型面涂材料的涂布材料，具有优异的耐剥离性，耐崩裂性，不产生裂纹，性能优异，耐候性，耐污染性，粘合性等优异的涂布材料，以及使用这样的材料。相对于漆膜形成成分，涂料优选以60〜90质量％的量配合，从而形成可固化的溶剂型面涂层材料。该涂料包括亲油性聚轮烷，其包含环状分子，包含穿过环状分子的环状分子的直链状分子，以及位于该直链状分子的两端末端的阻断基，以防止环状分子离开线性分子，至少一种上述内分子和具有疏水性改性基团的环状分子。

32. 发明申请

US20110040024A1 NANOPARTICLE AND NANOPARTICLE COMPOSITE 有权
标题翻译：纳米和纳米复合材料
公开(公告)号：US20110040024A1
公开(公告)日：2011-02-17
申请号：US12910739
申请日：2010-10-22
申请人： Hideaki YAEGASHI , Shoko Kano , Masahiko Yamanaka , Kentarou Watanabe , Hiroshi Yokohama , Hideo Sawada
发明人： Hideaki YAEGASHI , Shoko Kano , Masahiko Yamanaka , Kentarou Watanabe , Hiroshi Yokohama , Hideo Sawada
IPC分类号： C08L83/04 , C08F283/12 , B82Y30/00
CPC分类号： C07F7/21
摘要： A nanoparticle includes a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at its opposite terminals, a three-dimensional silica network section, and an organic chain having fluorine or silicon, and is represented by the following formula (2): where R′ is independent H or independent alkyl group; X is the hydrophilic group and is selected from the group consisting of an OH group, an NCO group, an NH2 group, an NHR group (where R is alkyl group) and a COY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is selected from the group consisting of an O, O═C—O, NH—C═O and NR—C═O (where R is alkyl group); E is O, O═C—O, NH—C═O or NR—C═O (where R is alkyl group); L is (CH2O)l—[Si(CH3)2O]k—(CH2O)l-α, (CF2)j-α or (CF2O)h-α where α is COY group (where Y is hydrophilic group), NCO group, NH2 group, NHR group (R is alkyl group), R group (or alkyl group) or H; n is 1≦n≦10; m is 1≦m≦n; k is 1≦k≦500; l is 0≦1≦10; j is 0≦j≦20; and h is 1≦h≦20.
摘要翻译：纳米颗粒包括在其相对端具有亲水基团和氟代烷基的链寡聚体部分，三维二氧化硅网络部分和具有氟或硅的有机链，并由下式（2）表示：其中R '是独立的H或独立的烷基; X是亲水基团，选自OH基团，NCO基团，NH 2基团，NHR基团（其中R是烷基）和COY基团（其中Y是亲水基团）; RF是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B选自O，O = C-O，NH-C = O和NR-C = O（其中R是烷基）; E是O，O = C-O，NH-C = O或NR-C = O（其中R是烷基）; L是（CH 2 O）1- [Si（CH 3）2 O] k - （CH 2 O）1-α，（CF 2）j-α或（CF 2 O）h-α，其中α是COY基团（其中Y是亲水基团）基团，NH 2基，NHR基（R为烷基），R基（或烷基）或H; n为1＆nlE; n＆nlE; 10; m为1＆nlE; m＆nlE; n; k是1＆nlE; k＆nlE; 500; l为0＆nlE; 1＆nlE; 10; j为0＆nlE; j＆nlE; 20; h为1＆nlE; h＆nlE; 20。

33. 发明授权

US07825283B2 Nanoparticle and nanoparticle composite 有权
标题翻译：纳米颗粒和纳米颗粒复合材料
公开(公告)号：US07825283B2
公开(公告)日：2010-11-02
申请号：US11715496
申请日：2007-03-08
申请人： Hideaki Yaegashi , Shoko Kano , Masahiko Yamanaka , Kentarou Watanabe , Hiroshi Yokoyama , Hideo Sawada
发明人： Hideaki Yaegashi , Shoko Kano , Masahiko Yamanaka , Kentarou Watanabe , Hiroshi Yokoyama , Hideo Sawada
IPC分类号： C07C27/10
CPC分类号： C07F7/21
摘要： A nanoparticle includes a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at its opposite terminals, a three-dimensional silica network section, and an organic chain having fluorine or silicon, and is represented by the following formula (1): where R′ is independent H or independent alkyl group; X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group or the like; RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O or the like; E is O, O═C—O, NH—C═O or the like; G is [(CH2O)1—[Si(CH3)2O]k—(CH2O)1] or the like.
摘要翻译：纳米颗粒包括在其相对端分别具有亲水基团和氟代烷基的链寡聚体部分，三维二氧化硅网络部分和具有氟或硅的有机链，并由下式（1）表示：其中R '是独立的H或独立的烷基; X是亲水基团，独立的OH基团，独立的NCO基团，独立的NH2基团等; RF是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O，独立的O = C-O等; E是O，O = C-O，NH-C = O等; G是[（CH 2 O）1- [Si（CH 3）2 O] k - （CH 2 O）1]等。

34. 发明申请

US20100129677A1 Material for Curable Aqueous Overcoating Material and Coating Material Using Same 审中-公开
标题翻译：用于可固化水性涂层材料和使用其的涂料的材料
公开(公告)号：US20100129677A1
公开(公告)日：2010-05-27
申请号：US12083150
申请日：2006-10-05
申请人： Kohzo Ito , Jun Araki , Tatsuya Suzuki , Masahiko Yamanaka , Kentarou Watanabe
发明人： Kohzo Ito , Jun Araki , Tatsuya Suzuki , Masahiko Yamanaka , Kentarou Watanabe
IPC分类号： C09D105/16 , B32B27/00
CPC分类号： C08G65/3331 , B05D7/14 , B05D7/57 , B05D2202/10 , C08B37/0015 , C08G65/33396 , C08G83/007 , C08L3/02 , C08L71/02 , C09D105/16 , Y10T428/31971 , C08L2666/26
摘要： There is provided a curable aqueous overcoating composition containing 1 to 90 mass % of hydrophilic polyrotaxane with respect to the coating film forming component, where the hydrophilic polyrotaxane has a cyclic molecule, a linear molecule included in the cyclic molecule in a skewered manner and blocking groups arranged on opposite ends of the linear molecule to prevent elimination of the cyclic molecule from the linear molecule and at least one of the linear molecule and the cyclic molecule has a hydrophilic modifying group.
摘要翻译：提供了相对于涂膜形成成分含有1〜90质量％的亲水性聚轮烷的可固化水性外涂层组合物，其中亲水性聚轮烷具有环状分子，串联包含在环状分子中的直链状分子和封端基排列在线性分子的相对端上以防止环状分子从线性分子中消除，并且至少一个直链分子和环状分子具有亲水性改性基团。

35. 发明申请

US20090281213A1 HYDROPHOBIC MODIFIED POLYROTAXANE AND CROSSLINKED POLYROTAXANE 有权
标题翻译：疏水性改性聚氨酯和交联聚氨酯
公开(公告)号：US20090281213A1
公开(公告)日：2009-11-12
申请号：US12065457
申请日：2006-08-23
申请人： Kohzo Ito , Jun Araki , Tatsuya Suzuki , Masahiko Yamanaka , Kentarou Watanabe
发明人： Kohzo Ito , Jun Araki , Tatsuya Suzuki , Masahiko Yamanaka , Kentarou Watanabe
IPC分类号： C08L5/16
CPC分类号： C08B37/0015 , C08G83/007
摘要： [Object] To provide a hydrophobic modified polyrotaxane soluble in an organic solvent, and a crosslinked polyrotaxane using this.[Solving Means] A hydrophobic modified polyrotaxane has a cyclic molecule, a linear molecule including the cyclic molecule with piercing through the cyclic molecule, and blocking groups which are placed at both end terminals of the linear molecule to prevent the cyclic molecule from leaving from the linear molecule. The cyclic molecule is cyclodextrin, and each of all or a part of the hydroxyl groups in the cyclodextrin is modified with a hydrophobic modification group.A crosslinked polyrotaxane is formed by combining this hydrophobic modified polyrotaxane and a polymer through the cyclic molecule.
摘要翻译：提供可溶于有机溶剂的疏水性改性聚轮烷，使用该聚轮烷的交联聚轮烷。 [解决方案]疏水性改性聚轮烷具有环状分子，包含贯穿环状分子的环状分子的直链状分子，以及配置在直链状分子两末端的封端基，以防止环状分子离开线性分子。环状分子是环糊精，并且环糊精中的全部或一部分羟基中的每一个都用疏水性修饰基团修饰。通过环状分子将该疏水性改性聚轮烷与聚合物结合而形成交联聚轮烷。

36. 发明申请

US20090047532A1 Material for Room Temperature Curable Solvent-Borne Overcoating Material,Coating Material Using Same and Coating Film 有权
标题翻译：室温固化溶剂涂层材料，使用相同涂层材料和涂膜的材料
公开(公告)号：US20090047532A1
公开(公告)日：2009-02-19
申请号：US12083099
申请日：2006-10-05
申请人： Kohzo Ito , Jun Araki , Tatsuya Suzuki , Masahiko Yamanaka , Kentarou Watanabe
发明人： Kohzo Ito , Jun Araki , Tatsuya Suzuki , Masahiko Yamanaka , Kentarou Watanabe
IPC分类号： B32B27/00 , C08G63/66 , C08L3/14 , C08L67/00
CPC分类号： C09D105/16 , B05D7/53 , B05D7/57 , C08B37/0015 , C08G83/007 , Y10T428/31511 , Y10T428/31786 , Y10T428/31935 , Y10T428/31971
摘要： [Object] To provide a coating material for a room temperature curable solvent-borne overcoating material having chipping resistance and not allowing occurrence of cracks, and a room temperature curable solvent-borne overcoating material using the same, the room temperature curable solvent-borne overcoating material being excellent in abrasion resistance and in performance such as weather resistance, contamination resistance and adhesion.[Solving Means] A coating material is formed of a lipophilic polyrotaxane including a cyclic molecule, a linear molecule piercing through the cyclic molecule to include it, and blocking groups disposed at both end terminals of the linear molecule to prevent departure of the cyclic molecule. In the lipophilic polyrotaxane, at least one of the linear molecule and the cyclic molecule has a hydrophobic modification group. A room temperature curable solvent-borne overcoating material is formed to contain the coating material preferably within a range of from 60 to 100% by mass relative to a film-forming component.
摘要翻译：本发明提供一种具有耐崩裂性且不产生裂纹的室温固化性溶剂型外涂层材料用涂料，以及使用该材料的室温固化型溶剂型外涂层材料，室温固化型溶剂型外涂层材料的耐磨性和耐候性，耐污染性和粘合性等性能优异。 [解决方案]涂料由包含环状分子的亲脂性聚轮烷，穿过环状分子的直链状分子包括在内的亲脂性聚轮烷，以及设置在该直链状分子的两端末端的阻聚基来形成，以防止环状分子脱离。在亲油性聚轮烷中，直链状分子和环状分子中的至少一种具有疏水性改性基团。形成室温固化型溶剂型外涂层材料，以相对于成膜成分优选为60〜100质量％的范围。

37. 发明申请

US20080064904A1 Nanoparticle and nanoparticle composite 有权
标题翻译：纳米颗粒和纳米颗粒复合材料
公开(公告)号：US20080064904A1
公开(公告)日：2008-03-13
申请号：US11715496
申请日：2007-03-08
申请人： Hideaki Yaegashi , Shoko Kano , Masahiko Yamanaka , Kentarou Watanabe , Hiroshi Yokoyama , Hideo Sawada
发明人： Hideaki Yaegashi , Shoko Kano , Masahiko Yamanaka , Kentarou Watanabe , Hiroshi Yokoyama , Hideo Sawada
IPC分类号： C07C27/10
CPC分类号： C07F7/21
摘要： A nanoparticle includes a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at its opposite terminals, a three-dimensional silica network section, and an organic chain having fluorine or silicon, and is represented by the following formula (1): where R′ is independent H or independent alkyl group; X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group or the like; RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O or the like; E is O, O═C—O, NH—C═O or the like; G is [(CH2O)1—[Si(CH3)2O]k—(CH2O)1] or the like.
摘要翻译：纳米颗粒包括在其相对端分别具有亲水基团和氟代烷基的链寡聚体部分，三维二氧化硅网络部分和具有氟或硅的有机链，并由下式（1）表示：其中R '是独立的H或独立的烷基; X是亲水基团，是独立的OH基团，独立的NCO基团，独立的NH 2基团等; R F是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O，独立的O-C-O等; E是O，O-C-O，NH-C-O等; G是[（CH 2）2） - [Si（CH 3 3）2 O] （CH 2 O 2）1 ...等。

38. 发明申请

US20060124029A1 Clear paint composition and clear coat film using same 审中-公开
标题翻译：使用相同的清漆组合物和透明涂膜
公开(公告)号：US20060124029A1
公开(公告)日：2006-06-15
申请号：US11269708
申请日：2005-11-09
申请人： Hiroshi Yokoyama , Masahiko Yamanaka , Kentarou Watanabe , Tsunehiko Higuchi , Shigeki Hirabayashi
发明人： Hiroshi Yokoyama , Masahiko Yamanaka , Kentarou Watanabe , Tsunehiko Higuchi , Shigeki Hirabayashi
IPC分类号： C08L89/00 , D21H17/07 , C07D295/18 , C08L97/00
CPC分类号： D21H19/10 , C08K9/12 , C08L5/00 , C09D5/448 , C09D7/63 , C09D7/67 , C09D7/68 , C09D7/69
摘要： An industrial product is provided with a clear paint composition including a material of a clear paint. An information nucleic acid is contained in the material of the clear paint and includes a site having an arbitrary and known base sequence.
摘要翻译：工业产品具有透明涂料组合物，其包括透明涂料的材料。信息核酸包含在透明涂料的材料中，并且包括具有任意和已知碱基序列的位点。

39. 发明申请

US20060084099A1 Product identification method 审中-公开
标题翻译：产品识别方法
公开(公告)号：US20060084099A1
公开(公告)日：2006-04-20
申请号：US11237884
申请日：2005-09-29
申请人： Hiroshi Yokoyama , Masahiko Yamanaka , Kentarou Watanabe , Tsunehiko Higuchi , Hidetoshi Hayashi
发明人： Hiroshi Yokoyama , Masahiko Yamanaka , Kentarou Watanabe , Tsunehiko Higuchi , Hidetoshi Hayashi
IPC分类号： C12Q1/68 , G06F19/00 , C12P19/34
CPC分类号： C12Q1/6816 , G16B30/00 , C12Q2563/185 , C12Q2521/101
摘要： A product identification method of one embodiment of the invention includes the steps of providing a product with an information nucleic acid having a segment of known base sequence randomly selected for the product, extracting the information nucleic acid from the product, amplifying the information nucleic acid by a polymerase chain reaction; and determining a base sequence of the information nucleic acid to identify the product by the base sequence of the information nucleic acid.
摘要翻译：本发明的一个实施方案的产品鉴定方法包括以下步骤：向产品提供具有随机选择用于产品的已知碱基序列的信息核酸，从产物中提取信息核酸，通过以下步骤扩增信息核酸：聚合酶链反应; 以及根据所述信息核酸的碱基序列确定所述信息核酸的碱基序列以鉴定所述产物。

40. 发明授权

US06635351B2 Clear coating composition, method of forming a coating film and multilayer coating film 失效
标题翻译：透明涂料组合物，形成涂膜的方法和多层涂膜
公开(公告)号：US06635351B2
公开(公告)日：2003-10-21
申请号：US09919531
申请日：2001-07-31
申请人： Tatsuya Ishihara , Masahiko Yamanaka , Tetsuji Mizuno , Takashi Moriwake , Hisaki Tanabe , Goro Nagao
发明人： Tatsuya Ishihara , Masahiko Yamanaka , Tetsuji Mizuno , Takashi Moriwake , Hisaki Tanabe , Goro Nagao
IPC分类号： B32B904
CPC分类号： B05D7/532 , C09D7/65 , Y10T428/31663
摘要： It is an object of the invention to provide a clear coating composition, which can give coating films showing good water repellency, in other words a factor giving a care-free and deluxe feeling to car owners, and which are excellent in non-sanding recoatability in recoating dirtied coatings after due repair, as well as a method of forming a coating film and a multilayerd coating film. The invention provides a clear coating composition which comprises (A) 100 parts by mass of the sum of a crosslinkable coating film-forming resin and a crosslinking agent on the solid basis and (B) 0.01 to 2 parts by mass of a ladder silicone copolymer obtainable by copolymerizing (b-1) a (meth)acryloxyalkyl-containing ladder silicone oligomer, (b-2) a crosslinkable functional group-containing ethylenically unsaturated monomer and optionally (b-3) another copolymerizable ethylenically unsaturated monomer.
摘要翻译：本发明的目的是提供一种透明的涂料组合物，其可以赋予具有良好防水性的涂膜，换句话说，对车主给予无忧无虑和豪华感的因素，并且非着色再涂性在经过适当修复后重涂污垢涂层，以及形成涂膜和多层涂膜的方法。本发明提供了一种透明涂料组合物，其包含（A）100质量份可交联涂膜形成的总和树脂和固体成分的交联剂，（B）0.01〜2质量份通过（b-1）含（甲基）丙烯酰氧基烷基的硅氧烷低聚物（b-2），交联性官能团基团的烯属不饱和单体和任选的（b-3）另一种可共聚的烯属不饱和单体。

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