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    • 35. 发明授权
    • Photoresist stripping solution and a method of stripping photoresists using the same
    • 光阻剥离溶液和使用其剥离光致抗蚀剂的方法
    • US08192923B2
    • 2012-06-05
    • US11898174
    • 2007-09-10
    • Shigeru YokoiKazumasa Wakiya
    • Shigeru YokoiKazumasa Wakiya
    • G03C11/12
    • G03F7/425G03F7/423G03F7/426H01L21/02071H01L21/31116
    • A photoresist stripping solution which comprises (a) a salt of hydrofluoric acid with a base free from metal ions, (b) a water-soluble organic solvent, (c) a mercapto group containing corrosion inhibitor, and (d) water, and a method of stripping photoresists with the use of the same are disclosed. In case of using ammonium fluoride as component (a), the photoresist stripping solution may further contain (e) a salt of hydrofluoric acid with a quaternary ammonium hydroxide, such as tetramethylammonium hydroxide, tetrapropylammonium hydroxide, etc., and/or an alkanolamine. The photoresist stripping solution of the present invention has an excellent effect of protecting both Al- and Cu-based metal wiring conductors from corrosion, of efficiently stripping photoresist films and post-ashing residues, and is free from the precipitation of the corrosion inhibitor.
    • 一种光致抗蚀剂剥离溶液,其包含(a)不含金属离子的碱的氢氟酸盐,(b)水溶性有机溶剂,(c)含巯基的缓蚀剂,和(d)水,和 公开了使用其剥离光致抗蚀剂的方法。 在使用氟化铵作为组分(a)的情况下,光致抗蚀剂剥离溶液还可以含有(e)氢氟酸盐与季铵氢氧化物如四甲基氢氧化铵,四丙基氢氧化铵等和/或链烷醇胺。 本发明的光致抗蚀剂剥离溶液具有优异的保护Al和Cu基金属布线导体免受腐蚀,有效地剥离光致抗蚀剂膜和后灰化残留物的作用,并且没有腐蚀抑制剂的沉淀。
    • 36. 发明授权
    • Cleaning liquid used in process for forming dual damascene structure and a process for treating substrate therewith
    • 用于形成双镶嵌结构的工艺中使用的清洁液和用于处理底物的方法
    • US08158568B2
    • 2012-04-17
    • US12801452
    • 2010-06-09
    • Shigeru YokoiKazumasa Wakiya
    • Shigeru YokoiKazumasa Wakiya
    • C11D3/34C11D3/44C11D1/62
    • H01L21/31144C11D7/32C11D11/0047H01L21/31138H01L21/76807
    • It is disclosed a cleaning liquid used in a process for forming a dual damascene structure comprising steps of etching a low dielectric layer (low-k layer) accumulated on a substrate having thereon a metallic layer to form a first etched-space; charging a sacrifice layer in the first etched-space; partially etching the low dielectric layer and the sacrifice layer to form a second etched-space connected to the first etched-space; and removing the sacrifice layer remaining in the first etched-space with the cleaning liquid, wherein the cleaning liquid comprises (a) 1-25 mass % of a quaternary ammonium hydroxide, such as TMAH and choline (b) 30-70 mass % of a water soluble organic solvent, and (c) 20-60 mass % of water. The cleaning liquid attains in a well balanced manner such effects that a sacrifice layer used for forming a dual damascene structure is excellently removed, and a low dielectric layer is not damaged upon formation of a metallic wiring on a substrate having a metallic layer (such as a Cu layer) and the low dielectric layer formed thereon.
    • 公开了一种用于形成双镶嵌结构的方法中使用的清洗液,包括以下步骤:蚀刻积聚在其上具有金属层的基底上的低介电层(低k层),以形成第一蚀刻空间; 在第一蚀刻空间中填充牺牲层; 部分地蚀刻低介电层和牺牲层以形成连接到第一蚀刻空间的第二蚀刻空间; 并用清洗液除去残留在第一蚀刻空间中的牺牲层,其中清洗液包含(a)1-25质量%的季铵氢氧化物,如TMAH和胆碱(b),30-70质量% 水溶性有机溶剂,(c)20〜60质量%的水。 清洗液以良好平衡的方式达到这样的效果,即用于形成双镶嵌结构的牺牲层被极好地去除,并且在具有金属层的基底上形成金属布线时,低介电层不被损坏(例如 Cu层)和形成在其上的低电介质层。
    • 37. 发明申请
    • Cleaning liquid used in process for forming dual damascene structure and a process for treating substrate therewith
    • 用于形成双镶嵌结构的工艺中使用的清洁液和用于处理底物的方法
    • US20100051582A1
    • 2010-03-04
    • US12591210
    • 2009-11-12
    • Shigeru YokoiKazumasa Wakiya
    • Shigeru YokoiKazumasa Wakiya
    • B44C1/22C11D7/32
    • H01L21/31144C11D7/32C11D11/0047H01L21/31138H01L21/76807
    • It is disclosed a cleaning liquid used in a process for forming a dual damascene structure comprising steps of etching a low dielectric layer (low-k layer) accumulated on a substrate having thereon a metallic layer to form a first etched-space; charging a sacrifice layer in the first etched-space; partially etching the low dielectric layer and the sacrifice layer to form a second etched-space connected to the first etched-space; and removing the sacrifice layer remaining in the first etched-space with the cleaning liquid, wherein the cleaning liquid comprises (a) 1-25 mass % of a quaternary ammonium hydroxide, such as TMAH and choline, (b) 30-70 mass % of a water soluble organic solvent, and (c) 20-60 mass % of water. The cleaning liquid attains in a well balanced manner such effects that a sacrifice layer used for forming a dual damascene structure is excellently removed, and a low dielectric layer is not damaged upon formation of a metallic wiring on a substrate having a metallic layer (such as a Cu layer) and the low dielectric layer formed thereon.
    • 公开了一种用于形成双镶嵌结构的方法中使用的清洗液,包括以下步骤:蚀刻积聚在其上具有金属层的基底上的低介电层(低k层),以形成第一蚀刻空间; 在第一蚀刻空间中填充牺牲层; 部分地蚀刻低介电层和牺牲层以形成连接到第一蚀刻空间的第二蚀刻空间; 并用清洗液去除残留在第一蚀刻空间中的牺牲层,其中清洗液包含(a)1-25质量%的季铵氢氧化物,如TMAH和胆碱,(b)30-70质量% 的水溶性有机溶剂,(c)20〜60质量%的水。 清洗液以良好平衡的方式达到这样的效果,即用于形成双镶嵌结构的牺牲层被极好地去除,并且在具有金属层的基底上形成金属布线时,低介电层不被损坏(例如 Cu层)和形成在其上的低电介质层。
    • 40. 发明申请
    • Photoresist stripping solution and a method of stripping photoresists using the same
    • 光阻剥离溶液和使用其剥离光致抗蚀剂的方法
    • US20050019688A1
    • 2005-01-27
    • US10925978
    • 2004-08-26
    • Kazumasa WakiyaShigeru Yokoi
    • Kazumasa WakiyaShigeru Yokoi
    • C11D1/62C11D7/32C11D11/00G03F7/42G03C11/12
    • H01L21/02068C11D1/62C11D7/32C11D11/0047G03F7/425G03F7/426
    • A photoresist stripping solution comprising (a) a specified quaternary ammonium hydroxide, such as tetrabutylammonium hydroxide, tetrapropylammonium hydroxide, methyltributylammonium hydroxide or methyltripropylammonium hydroxide, (b) a water-soluble amine, (c) water, (d) a corrosion inhibitor and (e) a water-soluble organic solvent, the compounding ratio of component (a) to component (b) being in the range of from 1:3 to 1:10 by mass, as well as a method of stripping photoresists using the solution. The stripping solution of the invention assures effective protection of Al, Cu and other wiring metal conductors against corroding as well as efficient stripping of the photoresist film, post-ashing residues such as modified photoresist film and metal depositions. It also assures efficient stripping of Si-based residues and effective protection of the substrate (particularly the reverse side of a Si substrate) from corroding.
    • 光致抗蚀剂剥离溶液,其包含(a)特定的季铵氢氧化物,例如四丁基氢氧化铵,氢氧化四丙基铵,氢氧化甲基三丁基铵或甲基三氢丙基氢氧化铵,(b)水溶性胺,(c)水,(d)腐蚀抑制剂和( e)水溶性有机溶剂,组分(a)与组分(b)的混合比例在1:3至1:10的范围内,以及使用溶液剥离光致抗蚀剂的方法。 本发明的剥离溶液确保有效保护Al,Cu和其它布线金属导体免受腐蚀以及光致抗蚀剂膜的有效剥离,后灰化残留物如修饰的光致抗蚀剂膜和金属沉积。 它还确保有效剥离Si基残留物并有效保护基材(特别是Si基板的反面)免受腐蚀。