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31. 发明申请

US20090298963A1 METHOD FOR PRODUCTION OF MODIFIED WATER ABSORBENT RESIN 审中-公开
标题翻译：生产改性吸水树脂的方法
公开(公告)号：US20090298963A1
公开(公告)日：2009-12-03
申请号：US11721285
申请日：2005-12-09
申请人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Andreas Flohr , Torsten Lindner
发明人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Andreas Flohr , Torsten Lindner
IPC分类号： C08J3/28 , C08F20/06
CPC分类号： C08L33/02 , C08F8/44 , C08J3/28 , C08J2300/14 , C08J2333/02 , C08F20/06 , C08L2666/04
摘要： This invention is to provide a method for producing a modified water absorbent resin excelling in water absorbing properties. This invention relates to a method for producing a modified water absorbent resin, which comprises a) mixing a water absorbent resin and a water-soluble radical polymerization initiator or a heat-degradable radical polymerization initiator without addition of an ethylenically unsaturated monomer and b) irradiating the resultant mixture with active energy rays. The method is particularly capable of exalting the absorbency against pressure and the saline flow conductivity.
摘要翻译：本发明提供一种制造吸水性优异的改性吸水性树脂的方法。本发明涉及一种改性吸水性树脂的制造方法，该方法包括：a）在不加入烯属不饱和单体的情况下，将吸水性树脂与水溶性自由基聚合引发剂或热降解自由基聚合引发剂混合，b）照射所得的具有活性能量射线的混合物。该方法特别能够提高抗压力和盐水流动导电性的吸收性。

32. 发明申请

US20080221229A1 WATER-ABSORBING AGENT AND PRODUCTION METHOD THEREOF 有权
标题翻译：吸水剂及其生产方法
公开(公告)号：US20080221229A1
公开(公告)日：2008-09-11
申请号：US12041609
申请日：2008-03-03
申请人： Kazushi Torii , Yoshifumi Adachi , Taishi Kobayashi , Yusuke Watanabe , Hiroyuki Ikeuchi , Toshimasa Kitayama
发明人： Kazushi Torii , Yoshifumi Adachi , Taishi Kobayashi , Yusuke Watanabe , Hiroyuki Ikeuchi , Toshimasa Kitayama
IPC分类号： C08J9/16
CPC分类号： A61L15/60 , A61F13/53 , A61F2013/530481 , B01J20/267 , C08J3/245 , C08J2300/14 , C08L101/14
摘要： To provide a water absorbing agent which is excellent in balance between absorbency and liquid permeability against pressure and is excellent in flowability at the time of moisture absorption. The water absorbing agent comprises water absorbent resin particles and an organic surface additive, wherein: the organic surface additive having (i) a reactive group for a functional group of a surface of each water absorbent resin particle and (ii) a hydrophobic group exists on the surface of the water absorbent resin particle, and the hydrophobic group has a hydrocarbon group whose carbon number is 8 or more, and a ratio of an oxyalkylene group in a molecular mass of the organic surface additive is 0 or more and 25 mass % or less.
摘要翻译：提供一种吸水剂，其在吸收性和液体渗透性与压力之间的平衡方面优异，并且在吸湿时流动性优异。吸水剂包括吸水性树脂颗粒和有机表面添加剂，其中：（i）每个吸水性树脂颗粒的表面的官能团的反应性基团和（ii）疏水基团的有机表面添加剂存在于吸水性树脂颗粒的表面和疏水基团具有碳数为8以上的烃基，有机表面添加剂的分子量中的氧化烯基的比例为0以上且25质量％以下，或减。

33. 发明申请

US20060128827A1 Absorbent members comprising modified water absorbent resin for use in diapers 审中-公开
标题翻译：吸收剂构件包括用于尿布的改性吸水性树脂
公开(公告)号：US20060128827A1
公开(公告)日：2006-06-15
申请号：US11297965
申请日：2005-12-08
申请人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Andreas Flohr , Torsten Lindner
发明人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Andreas Flohr , Torsten Lindner
IPC分类号： C08J3/28
CPC分类号： C08J3/28 , A61L15/60 , C08J2333/02
摘要： An absorbent member for use in disposable diapers, wherein the absorbent member comprises a modified water absorbent resin. The modified water absorbent resin is made according to the method which comprises a) mixing a water absorbent resin and a water-soluble radical polymerization initiator or a heat-degradable radical polymerization initiator without addition of an ethylenically unsaturated monomer and b) irradiating the resultant mixture with active energy rays. The method is particularly capable of exalting the absorbency against pressure and the saline flow conductivity.
摘要翻译：一种用于一次性尿布的吸收件，其中吸收件包括改性吸水树脂。改性吸水性树脂根据以下方法制备：a）将混合吸水性树脂和水溶性自由基聚合引发剂或热降解自由基聚合引发剂混合，不加入烯属不饱和单体，b）照射所得混合物具有活跃的能量射线。该方法特别能够提高抗压力和盐水流动导电性的吸收性。

34. 发明申请

US20090239966A1 METHOD FOR SURFACE-TREATMENT OF WATER ABSORBENT RESIN 有权
标题翻译：表面处理吸水树脂的方法
公开(公告)号：US20090239966A1
公开(公告)日：2009-09-24
申请号：US11721293
申请日：2005-12-09
申请人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura
发明人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura
IPC分类号： C08F2/50
CPC分类号： C08F265/00 , C08F265/02 , C08J3/28 , C08J7/18 , C08J2300/14 , C08J2333/02 , C08L51/003 , C08L2666/02
摘要： This invention is to provide a method for surface-treatment of a water absorbent resin excelling in water absorption properties. This invention relates to a method for the surface-treatment of a water absorbent resin, which comprises: a) mixing 100 parts by weight of a water absorbent resin, 0.01-20 parts by weight of at least one radical polymerization initiator selected from the group-consisting of persulfates, hydrogen peroxide, and azo compounds, and a radically polymerizing compound and b) irradiating the resultant mixture with active energy rays. The treatment particularly exalts the absorption ratio against pressure and the saline flow conductivity.
摘要翻译：本发明提供一种吸水性树脂表面处理方法，其吸水性优异。本发明涉及一种表面处理吸水性树脂的方法，其包括：a）将100重量份的吸水性树脂，0.01-20重量份的至少一种选自下组的自由基聚合引发剂 - 过硫酸盐，过氧化氢和偶氮化合物，以及自由基聚合化合物，和b）用活性能量射线照射所得混合物。该处理特别提高了对压力和盐水流动传导率的吸收比。

35. 发明授权

US08252715B2 Water-absorbing agent and production method thereof 有权
标题翻译：吸水剂及其制备方法
公开(公告)号：US08252715B2
公开(公告)日：2012-08-28
申请号：US12041609
申请日：2008-03-03
申请人： Kazushi Torii , Yoshifumi Adachi , Taishi Kobayashi , Yusuke Watanabe , Hiroyuki Ikeuchi , Toshimasa Kitayama
发明人： Kazushi Torii , Yoshifumi Adachi , Taishi Kobayashi , Yusuke Watanabe , Hiroyuki Ikeuchi , Toshimasa Kitayama
IPC分类号： B01J20/285 , C08F20/02 , C08F16/28 , C08F32/00 , C08F120/00
CPC分类号： A61L15/60 , A61F13/53 , A61F2013/530481 , B01J20/267 , C08J3/245 , C08J2300/14 , C08L101/14
摘要： To provide a water absorbing agent which is excellent in balance between absorbency and liquid permeability against pressure and is excellent in flowability at the time of moisture absorption. The water absorbing agent comprises water absorbent resin particles and an organic surface additive, wherein: the organic surface additive having (i) a reactive group for a functional group of a surface of each water absorbent resin particle and (ii) a hydrophobic group exists on the surface of the water absorbent resin particle, and the hydrophobic group has a hydrocarbon group whose carbon number is 8 or more, and a ratio of an oxyalkylene group in a molecular mass of the organic surface additive is 0 or more and 25 mass % or less.
摘要翻译：提供一种吸水剂，其在吸收性和液体渗透性与压力之间的平衡方面优异，并且在吸湿时流动性优异。吸水剂包括吸水性树脂颗粒和有机表面添加剂，其中：（i）每个吸水性树脂颗粒的表面的官能团的反应性基团和（ii）疏水基团的有机表面添加剂存在于吸水性树脂颗粒的表面和疏水基团具有碳数为8以上的烃基，有机表面添加剂的分子量中的氧化烯基的比例为0以上且25质量％以下，或减。

36. 发明授权

US07879923B2 Method for surface-treatment of water absorbent resin 有权
标题翻译：吸水树脂表面处理方法
公开(公告)号：US07879923B2
公开(公告)日：2011-02-01
申请号：US11721293
申请日：2005-12-09
申请人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura
发明人： Makoto Matsumoto , Yoshiro Mitsukami , Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura
IPC分类号： C08J7/16 , C08J7/18 , A61L15/60 , C08L33/02
CPC分类号： C08F265/00 , C08F265/02 , C08J3/28 , C08J7/18 , C08J2300/14 , C08J2333/02 , C08L51/003 , C08L2666/02
摘要： This invention is to provide a method for surface-treatment of a water absorbent resin excelling in water absorption properties. This invention relates to a method for the surface-treatment of a water absorbent resin, which comprises: a) mixing 100 parts by weight of a water absorbent resin, 0.01-20 parts by weight of at least one radical polymerization initiator selected from the group consisting of persulfates, hydrogen peroxide, and azo compounds, and a radically polymerizing compound and b) irradiating the resultant mixture with active energy rays. The treatment particularly exalts the absorption ratio against pressure and the saline flow conductivity.
摘要翻译：本发明提供一种吸水性树脂表面处理方法，其吸水性优异。本发明涉及一种表面处理吸水性树脂的方法，其包括：a）将100重量份的吸水性树脂，0.01-20重量份的至少一种选自下组的自由基聚合引发剂由过硫酸盐，过氧化氢和偶氮化合物组成，和自由基聚合化合物，和b）用活性能量射线照射所得混合物。该处理特别提高了对压力和盐水流动传导率的吸收比。

37. 发明申请

US20100009846A1 PARTICLE-SHAPED WATER ABSORBING AGENT AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：颗粒形吸水剂及其制造方法
公开(公告)号：US20100009846A1
公开(公告)日：2010-01-14
申请号：US12524989
申请日：2008-02-04
申请人： Hiroyuki Ikeuchi , Hirotama Fujimaru , Makoto Nagasawa , Kazuhiko Sakamoto , Shigeru Sakamoto , Kazushi Torii , Ryoko Tahara
发明人： Hiroyuki Ikeuchi , Hirotama Fujimaru , Makoto Nagasawa , Kazuhiko Sakamoto , Shigeru Sakamoto , Kazushi Torii , Ryoko Tahara
IPC分类号： B01J20/26 , C08F20/06 , B32B5/16
CPC分类号： C08F2/44 , A61F2013/530583 , C08F220/06 , C08F222/1006 , C08K5/0008 , C08L33/02 , C08L71/02 , Y10T428/2982 , C08L2666/22
摘要： An object of the present invention is to provide a particle-shaped water absorbing agent having a remarkably improved surface color and excellent water-absorbing properties (better water absorption capacity, and lower water soluble content and residual monomer content) at the same time. In order to attain the object, a particle-shaped water absorbing agent according to the present invention is a particle-shaped water absorbing agent whose main component is a polyacrylic acid and/or a salt thereof, the particle-shaped water absorbing agent having a surface color of Hunter b value in a range of −5 to 10, and having a cross-linking absorption property index (CPI) in a range of 1 to 100, the CPI defined by the following two equations: GEX=(GVs+17)/Ln (water soluble content) Equation 1; CPI=(GEX/residual monomer content)×100 Equation 3 where GVs is gel volume in saline, Ln (water soluble content) is a logarithm natural of water soluble content.
摘要翻译：本发明的目的是提供一种具有显着改善的表面颜色和优异的吸水性（更好的吸水能力，更低的水溶性含量和残留的单体含量）的颗粒状吸水剂。为了达到上述目的，本发明的颗粒状吸水剂是主要成分为聚丙烯酸和/或其盐的颗粒状吸水剂，该颗粒状吸水剂具有 Hunter b值的表面颜色在-5至10的范围内，并且交联吸收特性指数（CPI）在1至100的范围内，由以下两个等式定义的CPI：GEX =（GVs + 17 ）/ Ln（水溶性含量）等式1; CPI =（GEX /残留单体含量）×100等式3其中GV是盐水中的凝胶体积，Ln（水溶性含量）是水溶性含量的对数自然。

38. 发明授权

US08257610B2 Water absorbing agent and production method thereof 有权
标题翻译：吸水剂及其制备方法
公开(公告)号：US08257610B2
公开(公告)日：2012-09-04
申请号：US12674780
申请日：2008-09-26
申请人： Kazushi Torii , Taishi Kobayashi , Yoshifumi Adachi , Yusuke Watanabe , Toshimasa Kitayama
发明人： Kazushi Torii , Taishi Kobayashi , Yoshifumi Adachi , Yusuke Watanabe , Toshimasa Kitayama
IPC分类号： C09K3/00 , C09K3/32 , C09K21/14 , B01J20/26
CPC分类号： A61L15/60 , B01J20/26 , B01J20/267 , C08K5/09
摘要： The present invention provides a water absorbing agent, and a method for producing the water absorbing agent. The water absorbing agent includes water absorbent resin particles, an organic acid and/or salt thereof having carbon number of 10 or more and not more than 30 in its molecule, and a water-soluble polyvalent cation. The method includes the step (i) of mixing the water absorbent resin particles, the organic acid and/or salt thereof having carbon number of 10 or more and not more than 30 in its molecule, and the water-soluble polyvalent cation with one another.
摘要翻译：本发明提供一种吸水剂及其制造方法。吸水剂包括分子中碳数为10以上且30以下的吸水性树脂粒子，有机酸和/或其盐和水溶性多价阳离子。该方法包括在其分子中混合吸水性树脂颗粒，碳数为10以上至30以下的有机酸和/或其盐和水溶性多价阳离子之间的步骤（i）。

39. 发明授权

US08198209B2 Water absorbing agent, water absorbent core using the agent, and manufacturing method for water absorbing agent 有权
标题翻译：吸水剂，使用该吸水剂的吸水芯，以及吸水剂的制造方法
公开(公告)号：US08198209B2
公开(公告)日：2012-06-12
申请号：US12294328
申请日：2007-03-20
申请人： Kazushi Torii , Hirofumi Shibata , Kazuki Kimura , Yasuhisa Nakashima , Motohiro Imura , Hiroko Ueda , Katsuyuki Wada
发明人： Kazushi Torii , Hirofumi Shibata , Kazuki Kimura , Yasuhisa Nakashima , Motohiro Imura , Hiroko Ueda , Katsuyuki Wada
IPC分类号： B01J20/26 , B01J20/10 , B32B5/24
CPC分类号： A61L15/60 , A61L15/18 , B01J20/103 , B01J20/26 , B01J20/261 , B01J20/267 , B01J2220/46 , B01J2220/68 , C08K3/36 , C08L101/14 , Y10T428/253
摘要： A water absorbing agent of the present invention has an internal crosslinking structure obtained by polymerization of a water-soluble unsaturated monomer. The agent satisfies conditions (a) to (d): (a) the agent contains water-insoluble inorganic particles at an amount of from 10 ppm to 1,900 ppm inclusive; (b) the agent contains 5 mass % or less particles which have such a size that they can pass through a sieve having a mesh opening size of 150 μm; (c) the agent has an absorbency against a pressure of 4.83 kPa (AAP) of 18 g/g or more; and (d) the water-insoluble inorganic particles reside on a surface of the water absorbing resin or near the surface.
摘要翻译：本发明的吸水剂具有通过聚合水溶性不饱和单体获得的内部交联结构。该试剂满足条件（a）至（d）：（a）该试剂含有10ppm至1,900ppm含量的水不溶性无机颗粒; （b）该试剂含有5质量％以下的粒径，使其能够通过网孔大小为150μm的筛子; （c）该试剂具有相对于4.83kPa（AAP）的压力为18g / g以上的吸收性; 和（d）水不溶性无机颗粒驻留在吸水树脂的表面上或表面附近。

40. 发明申请

US20100093917A1 Water Absorbent Resin Production Method, Water Absorbent Resin, and Usage Thereof 审中-公开
标题翻译：吸水树脂生产方法，吸水树脂及其用途
公开(公告)号：US20100093917A1
公开(公告)日：2010-04-15
申请号：US12530957
申请日：2008-03-14
申请人： Kazushi Torii , Taishi Kobayashi
发明人： Kazushi Torii , Taishi Kobayashi
IPC分类号： C08J3/24 , C08L33/00
CPC分类号： C08J3/245 , B01J20/267 , C08F20/06 , C08J2333/02 , C08L33/02 , C08L71/02 , C08L2666/22
摘要： A method for producing a water absorbent resin comprises the steps of: (i) polymerizing a monomer including an unsaturated monomer containing a carboxyl group, in the presence of an internal cross-linking agent (A) having two or more radical polymerizable unsaturated groups in its single molecule and in the presence of a non-polymeric internal cross-linking agent (B) having in its single molecule two or more functional groups each of which allows formation of an ester bond or an amide bond by reacting with a carboxyl group, while crushing a cross-linked polymer hydrogel; and (ii) drying the cross-linked polymer hydrogel obtained in the step (i), wherein: an amount of the internal cross-linking agent (A) is 0.01 mol % or more and 0.2 mol % or less relative to an amount of the unsaturated monomer containing a carboxyl group, and a molar ratio (B)/(A) of the internal cross-linking agent (A) and the non-polymeric internal cross-linking agent (B) is 0.01 or more and 1.8 or less.
摘要翻译：一种吸水性树脂的制造方法，其特征在于：（i）在含有两个以上自由基聚合性不饱和基团的内部交联剂（A）的存在下，使含有羧基的不饱和单体的单体聚合，其单分子和在其单分子中具有两个或更多个官能团的非聚合内部交联剂（B）的存在下，每个可通过与羧基反应形成酯键或酰胺键，同时粉碎交联聚合物水凝胶; 和（ii）干燥步骤（i）中获得的交联聚合物水凝胶，其中：内部交联剂（A）的量相对于（i）的量为0.01摩尔％以上且0.2摩尔％以下含有羧基的不饱和单体和内部交联剂（A）与非聚合内部交联剂（B）的摩尔比（B）/（A）为0.01以上1.8以下。

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