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31. 发明授权

US4073750A Method for preparing a highly dispersed supported nickel catalyst 失效
标题翻译：制备高度分散的负载型镍催化剂的方法
公开(公告)号：US4073750A
公开(公告)日：1978-02-14
申请号：US688154
申请日：1976-05-20
申请人： David J. C. Yates , Lawrence L. Murrell
发明人： David J. C. Yates , Lawrence L. Murrell
IPC分类号： C10G35/06 , B01J23/755 , B01J37/02 , C07B31/00 , C07B61/00 , C07C1/00 , C07C4/06 , C07C4/10 , C07C5/10 , C07C9/04 , C07C13/18 , C07C67/00 , C10G49/04 , B01J29/14 , B01J23/74
CPC分类号： C07C4/10 , B01J23/755 , C07C5/10 , B01J35/0053 , B01J35/006 , B01J35/0066 , B01J37/0203 , C07C2101/14 , C07C2521/04 , C07C2521/08 , C07C2523/755 , Y10S502/506 , Y10S502/509 , Y10S502/513
摘要： This invention relates to a method for making supported nickel catalysts which are characterized as having the nickel in a highly dispersed state, the catalysts and use thereof in hydrogenation, reforming and hydrocarbon synthesis reactions, for example, Fischer-Tropsch reactions. Catalysts prepared by the method of the instant invention, wherein nonaqueous solutions are used in preparing the catalyst, are characterized as having a degree of dispersion of at least 10% greater than similar catalysts prepared by the prior art aqueous impregnation techniques and in some instances show an improved degree of dispersion of more than 50% over the catalysts prepared by the prior art methods. In the method of the instant invention the catalyst is prepared by slurrying a nickel metal precursor dissolved in a nonaqueous organic solvent with a high surface area support, for example, a refractory inorganic oxide, preferably selected from the group consisting of silica and alumina, removing the solvent to obtain a composite of said nickel metal precursor and said support and activating said composite by reducing in hydrogen at conditions sufficient to convert substantially all the nickel metal precursor to nickel metal. The nonaqueous solvent is preferably selected from the group consisting of aldehydes, ketones, ethers and organic nitrogen compounds, for example, acetone, acetonitrile, N,N-dimethyl formamide, hexamethyl phosphoramide, diethylether, tetrahydrofuran, dioxane, methylethyl ketone and acetaldehyde.
摘要翻译：本发明涉及一种制备负载镍催化剂的方法，其特征在于镍处于高度分散状态，催化剂及其在氢化，重整和烃合成反应中的用途，例如费 - 托反应。通过本发明方法制备的催化剂，其中非水溶液用于制备催化剂，其特征在于具有比现有技术的含水浸渍技术制备的类似催化剂大至少10％的分散度，并且在某些情况下显示出与现有技术方法制备的催化剂相比，分散度提高了超过50％。在本发明的方法中，催化剂是通过将溶解在非水有机溶剂中的镍金属前体与高表面积的载体如耐火无机氧化物，优选选自二氧化硅和氧化铝，除去溶剂，以获得所述镍金属前体和所述载体的复合物，并通过在足以将基本上所有镍金属前体转化为镍金属的条件下还原氢而活化所述复合物。非水溶剂优选选自醛，酮，醚和有机氮化合物，例如丙酮，乙腈，N，N-二甲基甲酰胺，六甲基磷酰胺，二乙醚，四氢呋喃，二恶烷，甲基乙基酮和乙醛。

32. 发明授权

US07495143B2 Hydrocarbon conversion using nanocrystalline zeolite Y 失效
标题翻译：使用纳米晶体沸石Y进行烃转化
公开(公告)号：US07495143B2
公开(公告)日：2009-02-24
申请号：US12072180
申请日：2008-02-25
申请人： Xingtao Gao , Johannes Hendrik Koegler , Lawrence L. Murrell , Philip J. Angevine
发明人： Xingtao Gao , Johannes Hendrik Koegler , Lawrence L. Murrell , Philip J. Angevine
IPC分类号： C07C2/58
CPC分类号： B01J29/088 , B01J29/084 , B01J35/023 , B01J37/08 , B01J2229/40 , B01J2229/42 , B01J2229/64 , C01B39/04 , C01B39/24 , C07C2/58 , C07C2/66 , C07C6/126 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2529/08 , C07C2529/12 , C07C2529/14 , C07C2529/16 , C10G29/205 , C10G2300/1081 , C10G2300/1088 , C10G2300/1096 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , C10G2400/30 , Y02P20/52 , C07C9/14 , C07C15/073 , C07C15/085
摘要： A process for alkylation of a hydrocarbon compound includes providing a catalyst including a zeolite Y having a crystal size of no more than 100 nm, and reacting an alkylatable hydrocarbon with an alkylating agent in the presence of the catalyst under alkylation reaction conditions to provide a gasoline product having a Research Octane Number of over 99.5.
摘要翻译：烃化合物的烷基化方法包括提供包含结晶尺寸不超过100nm的沸石Y的催化剂，并且在烷基化反应条件下在催化剂存在下使烷基化烃与烷基化剂反应以提供汽油研究辛烷值超过99.5的产品。

33. 发明授权

US4708945A Catalysts comprising silica supported on a boehmite-like surface, their preparation and use 失效
标题翻译：包含负载在勃姆石状表面上的二氧化硅的催化剂，其制备和用途
公开(公告)号：US4708945A
公开(公告)日：1987-11-24
申请号：US815220
申请日：1985-12-31
申请人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr.
发明人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr.
IPC分类号： B01J21/04 , B01J21/08 , B01J21/12 , B01J37/02 , C04B41/87 , C10G11/04 , C10G47/02
CPC分类号： B01J21/12 , B01J37/024 , C10G11/04
摘要： Useful cracking catalysts and catalyst supports comprising silica supported on a boehmite-like surface are prepared by compositing particles of silica or hydrated silica with particles of porous boehmite and subjecting the resulting composite to high temperature steaming at a temperature of at least about 600.degree. C. for a time sufficient to disperse at least a portion of the silica over the boehmite surface as the boehmite converts to .gamma.-Al.sub.2 O.sub.3. The silica wets, spreads out and reacts with the surface hydroxyl groups of the transforming boehmite.
摘要翻译：通过将二氧化硅或水合二氧化硅的颗粒与多孔勃姆石的颗粒合并并将所得复合材料在至少约600℃的温度下进行高温蒸汽来制备包含负载在勃姆石样表面上的二氧化硅的有用的裂解催化剂和催化剂载体。足以在勃姆石转化为γ-Al 2 O 3时将至少一部分二氧化硅分散在勃姆石表面上。二氧化硅浸湿，展开并与转化勃姆石的表面羟基反应。

34. 发明授权

US4422926A Separating basic asphaltenes using Bronsted acid transition metal oxide acid catalysts 失效
标题翻译：使用布朗斯台德酸过渡金属氧化物酸催化剂分离碱性沥青质
公开(公告)号：US4422926A
公开(公告)日：1983-12-27
申请号：US305265
申请日：1981-09-24
申请人： Kenneth A. Gould , Dane C. Grenoble , Lawrence L. Murrell , Wim J. M. Pieters
发明人： Kenneth A. Gould , Dane C. Grenoble , Lawrence L. Murrell , Wim J. M. Pieters
IPC分类号： B01J23/00 , C10G25/00 , C10G11/04 , C10G25/12
CPC分类号： C10G25/003
摘要： Basic asphaltenes are selectively removed from asphaltene-containing hydrocarbon feeds by contacting the feed with a transition metal oxide solid acid catalyst exhibiting Bronsted acidity. The catalyst selectively adsorbs the basic asphaltenes. The catalysts will comprise a catalytic metal component selected from the group consisting essentially of oxides of (a) tungsten, niobium and mixtures thereof and (b) mixtures of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, supported on pyrogenic alumina. Asphalt-laden catalyst is separated from the feed, the asphaltenes adsorbed thereon are cracked off in the presence of steam and the catalyst is regenerated and recycled back to the adsorption zone.
摘要翻译：通过使进料与显示布朗斯台德酸度的过渡金属氧化物固体酸催化剂接触，基本沥青质从含沥青烯的烃进料中选择性地除去。催化剂选择性吸附碱性沥青质。催化剂将包括选自以下的催化金属组分：（a）钨，铌及其混合物的氧化物和（b）（a）与钽，铪，铬，钛，锆及其混合物的混合物，其被负载在致热氧化铝上。将含沥青的催化剂与进料分离，吸附在其上的沥青质在蒸汽存在下破裂，催化剂再生并再循环回吸附区。

35. 发明授权

US4220556A Silylhydrocarbyl phosphine transition metal complexes 失效
标题翻译：硅烷基烃基过渡金属络合物
公开(公告)号：US4220556A
公开(公告)日：1980-09-02
申请号：US4801
申请日：1979-01-19
申请人： Alexis A. Oswald , Lawrence L. Murrell
发明人： Alexis A. Oswald , Lawrence L. Murrell
IPC分类号： B01J31/24
CPC分类号： B01J31/2404 , B01J31/1633 , B01J31/24 , B01J21/08 , B01J2231/321 , B01J2531/80 , B01J2531/822 , B01J2531/824 , B01J2531/845
摘要： Novel heterogeneous silylhydrocarbyl phosphine transition metal complex catalysts and intermediates therefor are prepared by (a) the selective monoaddition of silane having chlorine, alkoxy or acyloxy groups to an .alpha., .omega.-diene, (b) followed by the addition of a phosphine to the resulting .omega.-alkenyl silanes to form the corresponding silylalkyl phosphines, (c) which are then covalently anchored as such or in the form of their transition metal complexes via condensation of their reactive silane substituents with hydroxy groups of silica and metal oxides, (d) optionally followed by complexing the free phosphine groups of anchored silylalkyl phosphines with transition metal compounds.
摘要翻译：新型异构甲硅烷基烃基膦过渡金属络合物催化剂及其中间体是通过（a）将具有氯，烷氧基或酰氧基的硅烷选择性加成到α，ω-二烯，（b）然后向所得到的 ω-烯基硅烷形成相应的甲硅烷基烷基膦，（c）然后通过它们的反应性硅烷取代基与二氧化硅和金属氧化物的羟基缩合反应而共价锚定或以其过渡金属配合物的形式，（d）任选地然后将固定的甲硅烷基烷基膦的游离膦基与过渡金属化合物络合。

36. 发明授权

US4160745A Method of preparing highly active nickel catalysts and catalysts prepared by said method 失效
标题翻译：通过所述方法制备高活性镍催化剂和催化剂的方法
公开(公告)号：US4160745A
公开(公告)日：1979-07-10
申请号：US856262
申请日：1977-12-01
申请人： Lawrence L. Murrell , David J. C. Yates
发明人： Lawrence L. Murrell , David J. C. Yates
IPC分类号： B01J23/755 , C07C1/00 , C07C5/10 , C07C13/18 , C07C67/00 , B01J21/04 , B01J21/08 , B01J21/12 , B01J23/74
CPC分类号： B01J23/755 , C07C5/10 , C07C2101/14 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/755 , C07C2529/04
摘要： The instant invention relates to a method for preparing high activity supported nickel catalysts. The method comprises the deposition of nickel nitrate on a carrier, typically an inert inorganic refractory oxide, by techniques known in the art followed by careful heating to a temperature of between 100.degree. to 270.degree. C., avoiding any excursions into temperatures beyond the stated maxima, in a flowing nonreactive gas atmosphere for a time sufficient to convert substantially all of the nickel nitrate into nickel oxide. When using an H.sub.2 containing atmosphere the maximum temperature is 220.degree. C. The supported nickel oxide resulting from the above procedure is then reduced to a supported nickel metal catalyst in a reducing atmosphere at a temperature ranging from about 230.degree. C. to 400.degree. C.The instant invention also relates to a new class of supported nickel metal catalysts having a specific activity of at least twice the specific activities of prior art catalysts as determined for the hydrogenation of benzene. These catalysts comprise from 0.1 to 50 wt. % nickel on a support, preferably 0.5 to 20 wt. % nickel, most preferably about 17 wt. % nickel on a support, wherein the support is as defined above.
摘要翻译： {PG，1本发明涉及一种制备高活性负载镍催化剂的方法。该方法包括通过本领域已知的技术将镍硝酸盐沉积在载体上，通常为惰性的无机难熔氧化物，然后小心地加热至100（20 {0〜270 {20 {0℃，避免任何在流动的非反应性气体气氛中，足以将基本上所有的硝酸镍转化为氧化镍的时间，超出超出所述最大值的温度。当使用H {HD 2 {L的气氛时，最高温度为220 {20 {0℃。然后将上述步骤得到的负载的氧化镍在还原气氛中，在约 230 {20 {0 C.到400 {20 {0 C.

37. 发明授权

US4134906A Silylhydrocarbyl phosphine transition metal complexes 失效
公开(公告)号：US4134906A
公开(公告)日：1979-01-16
申请号：US829898
申请日：1977-09-01
申请人： Alexis A. Oswald , Lawrence L. Murrell
发明人： Alexis A. Oswald , Lawrence L. Murrell
IPC分类号： C07C67/36 , B01J31/00 , B01J31/16 , B01J31/20 , B01J31/22 , B01J31/24 , C07B61/00 , C07C1/00 , C07C5/03 , C07C45/00 , C07C45/50 , C07C51/12 , C07C67/00 , C07F7/14 , C07F7/18 , C07F9/02 , C07F13/00 , C07F15/00 , C08F4/16
CPC分类号： C07F9/02 , B01J31/1633 , B01J31/20 , B01J31/24 , B01J31/2404 , C07C5/03 , C07C51/12 , C07F7/14 , C07F7/182 , C07F7/1868 , C07F7/1876 , C07F7/188 , C07F7/1892 , B01J2231/645 , B01J2531/822 , B01J2531/824 , B01J2531/845 , C07C2531/24
摘要： Novel heterogeneous silylhydrocarbyl phosphine transition metal complex catalysts and intermediates therefor are prepared by (a) the selective monoaddition of silane having chlorine, alkoxy or acyloxy groups to an .alpha.,.omega.-diene, (b) followed by the addition of a phosphine to the resulting .omega.-alkenyl silanes to form the corresponding silylalkyl phosphines, (c) which are then covalently anchored as such or in the form of their transition metal complexes via condensation of their reactive silane substituents with hydroxy groups of silica and metal oxides, (d) optionally followed by complexing the free phosphine groups of anchored silylalkyl phosphines with transition metal compounds.

38. 发明授权

US4039622A Catalytic process for NO.sub.X reduction under lean conditions 失效
标题翻译：催化过程为NO {HD X {B在稀薄条件下的还原
公开(公告)号：US4039622A
公开(公告)日：1977-08-02
申请号：US616752
申请日：1975-09-19
申请人： Lawrence L. Murrell , Samuel J. Tauster
发明人： Lawrence L. Murrell , Samuel J. Tauster
IPC分类号： B01D53/86 , B01D53/34
CPC分类号： B01D53/8625
摘要： It has been discovered that supported iridium catalysts will selectively reduce NO.sub.X under lean conditions in a critical temperature range.
摘要翻译：已经发现，在临界温度范围内，负载的铱催化剂将在贫条件下选择性地还原NO x。

39. 发明授权

US3990998A High surface area ruthenium bonding supports on monolithic ceramics 失效
标题翻译：高整体陶瓷表面积钌键合支持
公开(公告)号：US3990998A
公开(公告)日：1976-11-09
申请号：US583508
申请日：1975-06-03
申请人： John P. DeLuca , Gary B. McVicker , Lawrence L. Murrell
发明人： John P. DeLuca , Gary B. McVicker , Lawrence L. Murrell
IPC分类号： B01D53/94 , B01J21/00 , B01J23/46 , B01J37/02
CPC分类号： B01J21/005 , B01D53/9413 , B01J23/462 , B01J37/024 , B01D2255/1026 , B01D2255/2047 , B01D2255/405 , B01D2255/9027 , B01D2255/9207
摘要： The instant invention relates to high surface area multilayered oxide supports coated with ruthenium of the type Ru-MgO-MgAl.sub.2 O.sub.4 -MgAl.sub.2 O.sub.4 +Mg.sub.2 SiO.sub.4 -Core. The system comprises ruthenium on a critical amount of free MgO, i.e., at least 2 wt. % minimum, on pre-reacted Al.sub.2 O.sub.3 which itself is on a monolithic ceramic substrate. This combination demonstrates the desirable, and previously unachievable characteristic of resistance to ruthenium volatilization and agglomeration, coupled with high catalytic activity. The high surface area oxides (MgO+Al.sub.2 O.sub.3) are strongly bonded to and reacted with the monolithic core substructure so as to possess physical strength. Ruthenium catalyst systems prepared utilizing the supported support (multilayered mixed oxides) method disclosed by the instant invention are useful for the treatment of waste gases, particularly exhaust gases from internal combustion engines and stationary sources and the removal of oxides of nitrogen therefrom.
摘要翻译：本发明涉及涂覆有Ru-MgO-MgAl2O4-MgAl2O4 + Mg2SiO4型芯的钌的高表面积多层氧化物载体。该系统包含临界量的游离MgO的钌，即至少2wt。对本身在单片陶瓷基板上的预反应的Al 2 O 3的最小值。这种组合证明了对钌挥发和附聚的耐受性以及先前难以达到的特性，加上高催化活性。高表面积氧化物（MgO + Al2O3）与整体式核心子结构牢固地结合并与其反应以具有物理强度。使用本发明公开的支撑载体（多层混合氧化物）制备的钌催化剂体系可用于处理废气，特别是来自内燃机和固定源的废气以及从其中除去氮氧化物。

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